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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 955 records · Page 53

Low-velocity repeated impact behaviors of Polymer Fiber Reinforced Plastics (PFRPs)

Modern fiber-reinforced composites have become ubiquitous across multiple industries due to their excellent weight-to-strength ratio. Typically glass or carbon fibers are widely used. While Glass or Carbon Fiber-Reinforced Plastics (GFPRs or CFPRs) have good stiffness, strength, and fatigue life, they are expensive and difficult to recycle. Researchers are exploring Polymer Fiber-Reinforced Plastics (PFRPs) as an alternative solution. PFRPs utilize polymer fibers and a polymer matrix. A wide range of materials options is available, including low-cost thermoplastics such as polyethylene or polypropylene. These thermoplastics are easy to handle and recyclable without special methods. Manufacturing parts using thermoplastics are well-established as well. However, their mechanical performances have not been extensively studied compared to GFRPs or CFRPs. This study examines the low-velocity impact resistance of PFRPs made of different thermoplastics. The low-velocity impacts are applied through a drop-weight tower. The experiment is divided into two cases: a single perforation impact and low-energy repeated impacts. Energy absorption and the number of impacts to failure are measured. The results are compared to traditional CFRPs which have a thermoset matrix. The PFRPs demonstrate energy absorption capabilities comparable to or greater than those of CFRPs with respect to specimen thickness and density. Additionally, the PFRPs show significantly higher impacts-to-failure than the CFRPs in low-energy repeated impact tests. This is particularly noteworthy considering that the PFRPs are much simpler and more economical to manufacture than CFRPs. To further

Ko, Seunghyun↗

Resolving intragranular stress fields in plastically deformed titanium using point-focused high-energy diffraction microscopy

Abstract The response of a polycrystalline material to a mechanical load depends not only on the response of each individual grain, but also on the interaction with its neighbors. These interactions lead to local, intragranular stress concentrations that often dictate the initiation of plastic deformation and consequently the macroscopic stress–strain behavior. However, very few experimental studies have quantified intragranular stresses across bulk, three-dimensional volumes. In this work, a synchrotron X-ray diffraction technique called point-focused high-energy diffraction microscopy (pf-HEDM) is used to characterize intragranular deformation across a bulk, plastically deformed, polycrystalline titanium specimen. The results reveal the heterogenous stress distributions within individual grains and across grain boundaries, a stress concentration between a low and high Schmid factor grain pair, and a stress gradient near an extension twinning boundary. This work demonstrates the potential for the future use of pf-HEDM for understanding the local deformation associated with networks of grains and informing mesoscale models. Graphical abstract

36 MATERIALS SCIENCE↗

Modeling a Newtonian Fluid with a Rate-Dependent, Von Mises Plasticity Model for Solid Mechanics Applications

This memo derives a particular use of a rate-dependent, perfectly plastic Von Mises Plasticity constitutive model that represents a Newtonian (or Bingham) fluid. Only two parameters are needed: the viscosity and bulk modulus to complete the model parameterization. Under certain deformations, the model exactly represents a Newtonian fluid. Under others, the model shear thins. A Newtonian fluid representation may be used in confined flow applications in which a fluid-solid interaction is desired but code coupling is not.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Unified Creep Plasticity Damage (UCPD) Model for Rigid Polyurethane Foams

Numerous experiments were performed to characterize the mechanical response of several different rigid polyurethane foams (FR3712, PMDI10, PMDI20, and TufFoam35) to large deformation. In these experiments, the effects of load path, loading rate, and temperature were investigated. Results from these experiments indicated that rigid polyurethane foams exhibit significant volumetric and deviatoric plasticity when they are compressed. Rigid polyurethane foams were also found to be very strain-rate and temperature dependent. These foams are also rather brittle and crack when loaded to small strains in tension or to larger strains in compression. Thus, a new Unified Creep Plasticity Damage (UCPD) model was developed and implemented into SIERRA with the name Foam Damage to describe the mechanical response of these foams to large deformation at a variety of temperatures and strain rates. This report includes a description of recent experiments and experimental findings. Next, development of a UCPD model for rigid, polyurethane foams is described. Selection of material parameters for a variety of rigid polyurethane foams is then discussed and finite element simulations with the new UCPD model are compared with experimental results to show behavior that can be captured with this model.

36 MATERIALS SCIENCE↗

Creating physically-based three-dimensional microstructures: Bridging phase-field and crystal plasticity models.

In order to better incorporate microstructures in continuum scale models, we use a novel finite element (FE) meshing technique to generate three-dimensional polycrystalline aggregates from a phase field grain growth model of grain microstructures. The proposed meshing technique creates hexahedral FE meshes that capture smooth interfaces between adjacent grains. Three dimensional realizations of grain microstructures from the phase field model are used in crystal plasticity-finite element (CP-FE) simulations of polycrystalline a -iron. We show that the interface conformal meshes significantly reduce artificial stress localizations in voxelated meshes that exhibit the so-called "wedding cake" interfaces. This framework provides a direct link between two mesoscale models - phase field and crystal plasticity - and for the first time allows mechanics simulations of polycrystalline materials using three-dimensional hexahedral finite element meshes with realistic topological features.

36 MATERIALS SCIENCE↗

Using Statistical Analysis Software to Advance Nitro Plasticizer Wettability

Statistical analysis in science is an extremely powerful tool that is often underutilized. Additionally, it is frequently the case that data is misinterpreted or not used to its fullest extent. Utilizing the advanced software JMP®, many aspects of experimental design and data analysis can be evaluated and improved. This overview will detail the features of JMP® and how they were used to advance a project, resulting in time and cost savings, as well as the collection of scientifically sound data. The project analyzed in this report addresses the inability of a nitro plasticizer to coat a gold coated quartz crystal sensor used in a quartz crystal microbalance. Through the use of the JMP® software, the wettability of the nitro plasticizer was increased by over 200% using an atmospheric plasma pen, ensuring good sample preparation and reliable results.

36 MATERIALS SCIENCE↗

Integrated Plastic Substrates for OLED Lighting

OLED lighting has immense potential as aesthetically pleasing, energy-efficient general illumination. Unlike other light sources, such as incandescents, fluorescents, and inorganic LEDs, OLEDs naturally emit over a large-area surface. They are glare free, do not need to be shaded, and are cool to the touch, requiring no heatsink. The best efficiencies and lifetimes reported are on par with or better than current forms of illumination. However, the cost for OLED lighting remains high – so much so that these products are not market competitive and there is very low consumer demand. We believe that flexible, plastic-based devices will highlight the advantages of aesthetically-pleasing OLED lighting systems while paving the way for lowering both materials and manufacturing costs. These flexible devices require new development in substrate and support technology, which was the focus of the work reported here. The project team, led by Sinovia Technologies, has developed integrated plastic substrates to serve as supports for flexible OLED lighting. The substrates created in this project would enable large-area, flexible devices and are specified to perform three functions. They include a barrier to protect the OLED from moisture and oxygen-related degradation, a smooth, highly conductive transparent electrode to enable large-area device operation, and a light scattering layer to improve emission efficiency. Through the course of this project, integrated substrates were fabricated, characterized, evaluated for manufacturing feasibility and cost, and used in white OLED demonstrations to test their impact on flexible OLED lighting. Our integrated substrates meet or exceed the DOE specifications for barrier performance in water vapor and oxygen transport rates, as well as the transparency and conductivity of the anode film. We find that these integrated substrates can be manufactured in a completely roll-to-roll, high throughput process and have developed and demonstrated manufacturing methods that can produce thousands of feet of material without defects. We have evaluated the materials and manufacturing costs of these films at scale and find that they meet the current and future cost targets for bringing down the cost of OLED lighting while enabling future roll-to-roll manufacturing of the complete device. And finally, we have demonstrated that the inherent light-scattering properties of our films enhance white OLED emission efficiency from 20% to 50% depending on the metric. This work has shown that these substrates can be created, manufactured, and will perform as needed to enable flexible OLED lighting to enter the marketplace.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Adjoint-based Calibration of Plasticity Model Parameters from Digital Image Correlation Data

Parameter estimation for mechanical models of plastic deformation utilized in nuclear weapons systems is a laborious process for both experimentalists and constitutive modelers and is critical to producing meaningful numerical predictions. In this work we derive an adjoint-based optimization approach for a stabilized, large-deformation J 2 plasticity model that is considerably more computationally efficient but no less accurate than current state of the art methods. Unlike most approaches to model calibration, we drive the inversion procedure with full-field deformation data that can be experimentally measured through established digital image or volume correlation techniques. We present numerical results for two and three dimensional model problems and comment on various directions of future research.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

FY18 Thermal Mechanical Failure: SS-304L calibration Taylor-Quinney parameter measurement and kinematic hardening plasticity

The Thermal-Mechanical Failure project conducted in FY 2018 was divided into three sub projects: 1. Calibration of the uniaxial response of 304L stainless steel specimens at three temperatures (20, 150 and 310°C) and two strain rates (2 x 10 -4 and 8 x 10 -2 s -1 ); 2. Measurements of the fraction of plastic work that is converted to heat (Taylor-Quinney parameter) for 304L stainless steel. This fraction is usually assumed to be 0.95 in analysis because data is only available for a few materials; 3. Comparison of the predicted responses by isotropic and kinematic hardening plasticity models in a couple of simplified structural problems. One problem is a can crush followed by pressurization and is loosely associated with a crush-and-burn scenario. The other problem consists of a drop scenario of a thin-walled cylinder that carries a cantilevered internal mass.

36 MATERIALS SCIENCE↗

A Themodynamically Consistent Fractional Visco-Elasto-Plastic Model with Memory-Dependent Damage for Anomalous Materials

We develop a thermodynamically consistent, fractional visco-elastoplastic model coupled with damage for anomalous materials. The model utilizes Scott-Blair rheological elements for both visco- elastic/plastic parts. The constitutive equations are obtained through Helmholtz free-energy potentials for Scott-Blair elements, together with a memory-dependent fractional yield function and dissipation inequalities. A memory-dependent Lemaitre-type damage is introduced through fractional damage energy release rates. For time-fractional integration of the resulting nonlinear system of equations, we develop a first-order semi-implicit fractional return-mapping algorithm. We also develop a finite-difference discretization for the fractional damage energy release rate, which results into Hankel-type matrix-vector operations for each time-step, allowing us to reduce the computational complexity from O(N 3 ) to O(N 2 ) through the use of Fast Fourier Transforms. Our numerical results demonstrate that the fractional orders for visco-elasto-plasticity play a crucial role in damage evolution, due to the competition between the anomalous plastic slip and bulk damage energy release rates.

36 MATERIALS SCIENCE↗

Modular Plane Stress Plasticity Material Model

A variety of recent work has expanded capabilities in LAMÉ with respect to anisotropic and modular plasticity model. In this context, modular refers to a flexible framework and consistent implementation such that different hardening functional forms may all be incorporated into the same material model implementation rather than needing a new model for each description. However, such work has been focused on three-dimensional formulations and limited attention has been paid to structural formulations; i.e. for use with beam or shell elements. As a first step to bringing some of these recent advances towards structural elements, modular isotropic hardening capabilities will be added to the J2 von Mises plane-stress plasticity formulation of Simo and Taylor. To accomplish this effort, in Section 2 and 3 the theory and numerical formulation of the model are given. Specific functional forms of the hardening and example syntax to use them are then presented in Section 4 while verification exercises are documented in Section 5. Finally, some concluding thoughts about future work are given in Section 6.

36 MATERIALS SCIENCE↗

Discovering New Biodegradable Plastics [Slides]

Single use conventional plastics are extremely durable, rarely recycled and a source of pollution in nature. We help discover new biodegradable plastics to replace the highly polluting ones!

36 MATERIALS SCIENCE↗

Achieving high-ZT in Te/Se-based thermoelectric materials via volume-constrained shear-induced plastic deformation

This study investigated the correlation between severe plastic deformation and microstructural evolution, along with the corresponding response in the thermoelectric performance. Specifically, severe plastic deformation introduced into intrinsically brittle thermoelectric materials like Bi 2 Te 3 - x Se x leads to microstructural changes ranging from nano- to micro- scales, including phase transformation, phase segregation, and stacking faults. The resultant residual strain and lattice defects in the Bi 2 Te 3-x Se x materials led to engineering of electronic bands, which increases the effective mass of electrons while controlling their concentration, thereby enhancing the power factor.

36 MATERIALS SCIENCE↗

Microwave-Assisted Catalytic Gasification of Various Biomass with Mixed Plastic Wastes for H2-Rich Syngas Production

Co-gasification of plastics mixture with biomass has shown synergistic effects in Microwave (MW) reactor resulting in higher H2-rich syngas yield and reduced char/tar. This study investigates a microwave-assisted catalytic gasification of variable feedstock such as various biomass blended with mixed plastics waste using Fe-based catalyst to produce H2 rich syngas as a primary product.

catalysis, biomass gasification↗

Plastic Additive, Sorbent-Coated, Thermally Integrated Contactor for CO 2 Capture (PLASTIC4CO2) (Final Report)

Final report for Plastic Additive, Sorbent-Coated, Thermally Integrated Contactor for CO2 Capture (PLASTIC4CO2) DE-FE-0032132. The goal of the work was to investigate at a technology readiness level of 3 (TRL 3), the proof of concept of an additively printed plastic 2-channel heat exchanger/sorbent contactor system to achieve a 15% lower levelized cost of electricity (LCOE) than a baseline liquid phase amine adsorber system for 90% and 95% capture of CO 2 from both a 7F02 2x1CC and 7HA02 2x1CC natural gas turbines.

03 NATURAL GAS↗

On the Onset of Plasticity

The onset of plasticity can be assessed and related to ensuing plastic deformation up to the structural instability using one constitutive relationship that incorporates both behaviors of rapid work hardening (Stage 3) and the asymptotic leveling of stress (Stage 4). Results are presented wherein the work hardening variation of Stages 3 and 4 are found to be dependent through a constitutive relationship and useful in a Hall-Petch formulation of strength.

Jankowski, Alan F.↗

How Clonal Is Clonal? Genome Plasticity across Multicellular Segments of a “Candidatus Marithrix sp.” Filament from Sulfidic, Briny Seafloor Sediments in the Gulf of Mexico

“Candidatus Marithrix” is a recently described lineage within the group of large sulfur bacteria (Beggiatoaceae, Gammaproteobacteria). This genus of bacteria comprises vacuolated, attached-living filaments that inhabit the sediment surface around vent and seep sites in the marine environment. A single filament is ca. 100 µm in diameter, several millimeters long, and consists of hundreds of clonal cells, which are considered highly polyploid. Based on these characteristics, “Candidatus Marithrix” was used as a model organism for the assessment of genomic plasticity along segments of a single filament using next generation sequencing to possibly identify hotspots of microevolution. Using six consecutive segments of a single filament sampled from a mud volcano in the Gulf of Mexico, we recovered ca. 90% of the “Candidatus Marithrix” genome in each segment. There was a high level of genome conservation along the filament with average nucleotide identities between 99.98 and 100%. Different approaches to assemble all reads into a complete consensus genome could not fill the gaps. Each of the six segment datasets encoded merely a few hundred unique nucleotides and 5 or less unique genes—the residual content was redundant in all datasets. Besides the overall high genomic identity, we identified a similar number of single nucleotide polymorphisms (SNPs) between the clonal segments, which are comparable to numbers reported for other clonal organisms. An increase of SNPs with greater distance of filament segments was not observed. The polyploidy of the cells was apparent when analyzing the heterogeneity of reads within a segment. Here, a strong increase in single nucleotide variants, or “intrasegmental sequence heterogeneity” (ISH) events, was observed. These sites may represent hotspots for genome plasticity, and possibly microevolution, since two thirds of these variants were not co-localized across the genome copies of the multicellular filament.

59 BASIC BIOLOGICAL SCIENCES↗