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At least 955 records · Page 53

Glucose metabolism in different regions of the rat brain under hypokinetic stress influence

Glucose metabolism in rats kept under long term hypokinetic stress was studied in 7 brain regions. Determination was made of the regional levels of glucose, lactate, glutamate, glutamine, aspartate, gamma-aminobutyrate and the incorporation of C-14 from plasma glucose into these metabolites, in glycogen and protein. From the content and activity data the regional glucose flux was approximated quantitatively. Under normal conditions the activity gradient cortex and frontal pole cerebellum, thalamus and mesencephalon, hypothalamus and pons and medulla is identical with that of the regional blood supply (measured with I131 serum albumin as the blood marker). Within the first days of immobilization a functional hypoxia occurred in all brain regions and the utilization of cycle amino acids for protein synthesis was strongly diminished. After the first week of stress the capillary volumes of all regions increased, aerobic glucose metabolism was enhanced (factors 1.3 - 2.0) and the incorporation of glucose C-14 via cycle amino acids into protein was considerably potentiated. The metabolic parameters normalized between the 7th and 11th week of stress. Blood supply and metabolic rate increased most in the hypothalamus.

Konitzer, K.↗

Microstructure and mechanical properties of high Mn-containing ferritic-martensitic alloys exposed to cyclical thermal treatment

Substantial residual tensile stress tends to accumulate in currently available high-Cr ferritic martensitic steels that are subjected to cyclical heat treatment, which leads to premature brittle fracture. By tailoring the alloy composition, this thermal cycling can be exploited to induce a high number density of nanoprecipitates and phase transformations countering residual tensile stresses. In this work, three new variants of ferritic-martensitic steels have been designed with computational thermodynamics to meet the goals of mitigating residual tensile stresses by lowering martensite start temperatures and of enhancing mechanical strength and irradiation sink strength by increasing the number density of nanoprecipitates. Furthermore, ctenast materials were subjected to cyclical heat treatment. The thermally cycled samples were evaluated with mechanical testing and microstructural analysis to identify the optimal composition in which figures of merit include low residual stress and a high density of nanoscale MX (M = metal, X = C/N) precipitates, leading to high yield strength with reasonable ductility. The noticeably higher density of nanoprecipitates in the optimal alloy favor its higher yield strength, which is supported by the microstructure-derived yield strength calculation and precipitation kinetics simulation.

36 MATERIALS SCIENCE↗

Accelerated Stress Testing of Fuel Cell Membranes Subjected to Combined Mechanical/Chemical Stressors and Cerium Migration

A highly accelerated stress test (HAST) has been developed to generate local stressful conditions that are representative of those in automotive fuel cell stacks. Using a 50-cm 2 cell cycled between 0.05 and 1.2 A/cm 2 with a low inlet RH in the co-flow configuration, the HAST creates a distribution of combined mechanical/chemical stressors in the membrane with the maximum chemical stress occurring near the gas inlets and the maximum mechanical stress near the outlets. Conducting HASTs using a current distribution measurement tool and a shorting/crossover diagnostic method to track the state of health of a robust membrane containing both a mechanical support and a chemical stabilizing additive, the result shows that the membrane location with the most severe thinning coincides with that of the deepest membrane hydration cycling. Upon examination of the cerium redistribution patterns after the test, it was found that the severe humidity cycling generated by the HAST condition near the outlet region not only generated the highest membrane mechanical stress but also resulted in the strongest water flux, which may cause local depletion of the cerium added as chemical stabilizer. Further study is required to decouple the cerium migration effect from the possible mechanical/chemical synergistic degradation effect.

25 ENERGY STORAGE↗

Thermal Cycling Fatigue in DIPs Mounted with Eutectic Tin-Lead Solder Joints in Stub and Gullwing Geometries

It has long been known that solder joints under mechanical stress are subject to failure. In early electronic systems, such failures were avoided primarily by avoiding the use of solder as a mechanical structural component. The rule was first to make sound wire connections that did not depend mechanically on solder, and only then to solder them. Careful design and miniaturization in modern electronic systems limits the mechanical stresses exerted on solder joints to values less than their yield points, and these joints have become integral parts of the mechanical structures. Unfortunately, while these joints are strong enough when new, they have proven vulnerable to fatigue failures as they age. Details of the fatigue process are poorly understood, making predictions of expected lifetimes difficult.

fatigue failure solder joints failure mechanisms s↗

Mechanical property characterization of Borsic/aluminum laminates at room and elevated temperatures

Six Borsic/aluminum laminate orientations exposed to a braze temperature cycle were tested in tension, compression, and shear to determine tangent modulus, maximum stress and strain, and Poisson's ratio of the laminates at room and elevated temperatures. Mechanical properties in tension were determined from flat tensile and sandwich beam tests. Room temperature flat tensile tests were performed on laminates in the as-received condition to compare with specimens exposed to a braze temperature cycle. Sandwich beam tests were also used to determine mechanical properties in compression. Shear properties were determined from biaxially loaded, picture frame shear specimens. Results are presented by using functional relations between stress and strain and tangent modulus and strain, and in tables by indicating maximum stress and strain and Poisson's ratio.

Mcwithey, R. R.↗

Dual-precipitates enhance fatigue resistance in an additively manufactured high-entropy alloy

To accomplish the intense desire of high-strength materials for enhanced energy-efficiency, recent research applies a combined strategy of additive-manufacturing and precipitation-strengthening in high entropy alloys. In a context, Al 0.2 Co 1.5 CrFeNi 1.5 Ti 0.3 nanoprecipitation-strengthened system was developed, demonstrating very convincing strength and toughness. Moreover, additive-manufacturing facilitated additional strength by well-decorated cell-boundaries with blocky L2 1 precipitates and homogeneously distributed L1 2 precipitates. However, fatigue research of this alloy remained unexplored despite being the main precursor for structural applications. In this study low-cycle fatigue behavior of this alloy in both as-built and precipitation-strengthened (aged) conditions has been explored, combined with in-situ neutron diffraction investigation. Findings revealed a substantial cyclic-stress profile and a notable fatigue-life below ±0.50% strain-amplitude, exceeding 10 5 cycles at ±0.30% strain-amplitude. These demonstrate the potential to carry higher payloads with marked engineering-reliability. Residual-stress estimation revealed strain-compatibility between the matrix and L1 2 precipitate, indicating a crack-initiation immune interface. A comparative examination of dislocation character revealed shifting towards pure edge-character in aged alloy indicates precipitates promoted planar-slip during deformation.

36 MATERIALS SCIENCE↗

The cyclic stress-strain behavior of PWA 1480 at 650 deg C

The monotonic plastic flow behavior of several single crystal nickel-base, superalloys has been shown to vary significantly with crystallographic orientation. In the present study, the cyclic plastic flow response of one such alloy, PWA 1480, was examined at 650 deg C in air. Single crystal specimens aligned near several crystallographic directions were tested in fully reversed, total-strain-controlled low cycle fatigue tests at a frequency of 0.1 Hz. The cyclic stress-strain response and general cyclic hardening behavior was analyzed as a function of crystallographic orientation and inelastic strain range.

Gabb, T. P.↗

On the variation in crack-opening stresses at different locations in a three-dimensional body

Crack propagation and closure behavior of thin, and thick middle crack tension specimens under constant amplitude loading were investigated using a three dimensional elastic plastic finite element analysis of fatigue crack propagation and closure. In the thin specimens the crack front closed first on the exterior (free) surface and closed last in the interior during the unloading portion of cyclic loading; a load reduced displacement technique was used to determine crack opening stresses at specified locations in the plate from the displacements calculated after the seven cycle. All the locations were on the plate external surface and were located near the crack tip, behind the crack tip, at the centerline of the crack. With this technique, the opening stresses at the specified points were found to be 0.52, 0.42, and 0.39 times the maximum applied stress.

Chermahini, R. G.↗

Laser High-Cycle Thermal Fatigue of Pulse Detonation Engine Combustor Materials Tested

Pulse detonation engines (PDE's) have received increasing attention for future aerospace propulsion applications. Because the PDE is designed for a high-frequency, intermittent detonation combustion process, extremely high gas temperatures and pressures can be realized under the nearly constant-volume combustion environment. The PDE's can potentially achieve higher thermodynamic cycle efficiency and thrust density in comparison to traditional constant-pressure combustion gas turbine engines (ref. 1). However, the development of these engines requires robust design of the engine components that must endure harsh detonation environments. In particular, the detonation combustor chamber, which is designed to sustain and confine the detonation combustion process, will experience high pressure and temperature pulses with very short durations (refs. 2 and 3). Therefore, it is of great importance to evaluate PDE combustor materials and components under simulated engine temperatures and stress conditions in the laboratory. In this study, a high-cycle thermal fatigue test rig was established at the NASA Glenn Research Center using a 1.5-kW CO2 laser. The high-power laser, operating in the pulsed mode, can be controlled at various pulse energy levels and waveform distributions. The enhanced laser pulses can be used to mimic the time-dependent temperature and pressure waves encountered in a pulsed detonation engine. Under the enhanced laser pulse condition, a maximum 7.5-kW peak power with a duration of approximately 0.1 to 0.2 msec (a spike) can be achieved, followed by a plateau region that has about one-fifth of the maximum power level with several milliseconds duration. The laser thermal fatigue rig has also been developed to adopt flat and rotating tubular specimen configurations for the simulated engine tests. More sophisticated laser optic systems can be used to simulate the spatial distributions of the temperature and shock waves in the engine. Pulse laser high-cycle thermal fatigue behavior has been investigated on a flat Haynes 188 alloy specimen, under the test condition of 30-Hz cycle frequency (33-msec pulse period and 10-msec pulse width including a 0.2-msec pulse spike; ref. 4). Temperature distributions were calculated with one-dimensional finite difference models. The calculations show that that the 0.2-msec pulse spike can cause an additional 40 C temperature fluctuation with an interaction depth of 0.08 mm near the specimen surface region. This temperature swing will be superimposed onto the temperature swing of 80 C that is induced by the 10-msec laser pulse near the 0.53-mm-deep surface interaction region.

Zhu, Dong-Ming↗

Neutron Residual Stress Mapping for Spent Nuclear Fuel Storage Canister Weldment

Many radioactive materials within the nuclear fuel cycle present a significant hazard. Such materials include spent nuclear fuel, high-level waste, legacy waste and other nuclear materials that have no current outlet than storage. These materials are often held in long-term storage as an interim stage within their lifecycle. Lifecycles can include reuse or disposal. Safety and security of spent nuclear fuel (SNF) interim storage installations are very important, due to a great concentration of fission products, actinides and activation products. Stress corrosion cracking of interim storage containers has been identified as a high priority data gap by the Department of Energy. However, little has been done with regards to the canister weld material properties and their impact on stress corrosion, until recently from Sandia National Laboratory canister mockup program. Furthermore, because no post-weld heat treatment was required, the associated high tensile residual stress within these canister welds can drive the initiation and growth of stress corrosion cracking (SCC) cracks. In this work, we carried out in-situ neutron residual stress mapping on a weld plate sectioned from Sandia mock-up canister wall. Significant residual stress profiles were identified from the received longitudinal weld sample. The details of the weldment residual stress program development at ORNL are presented in this progress report. The generated residual stress profile from neutron diffraction technique is similar to that of Sandia residual stress data obtained from the deep hole drilling approach.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

The Influence of Alternating Low-Cycle Bending Loads on Sheet Properties Having an Hcp Crystal Lattice

The process of cyclic bending was investigated using thin sheets of the magnesium alloy AZ31 and α-titanium. These materials possess an hcp crystal lattice with different c/a ratios. It turned out that the latter have a substantial influence on the sheet deformation behavior. Even for small deformations (up to 2% strain), a large influence on the yield stress was present for both materials. In addition, cyclic bending contributes to the activation of prismatic slip, which is accompanied by twinning and detwinning. The changes in sheet anisotropy following cyclic bending were determined using texture measurements. Specifically, the AZ31 alloy sheets exhibited a considerable change in anisotropy of the mechanical properties with an increasing number of bending cycles. The anisotropy in the yield stress increases from 15% in the initial condition to 40% after three cycles. For the α-titanium sheet, the change in anisotropy was approx. 26% less. In general, the largest changes in properties occurred already in the first bending cycle and a stabilization took place upon further cycling.

36 MATERIALS SCIENCE↗

Design and Performance Evaluation of Al{sub 2}O{sub 3}-SiC Composite for Direct-Bonded Copper Substrate

A computational material design approach is applied to propose a novel ceramic material for direct-bonded copper (DBC) substrate with enhanced thermal and structural performance. The material design inherently consists of many competing requirements that require careful decisions regarding key trade-offs in terms of material composition, inclusion size, shape, and distribution to achieve the target properties. The alumina-silicon (Al{sub 2}O{sub 3}-SiC) composite, as compared to commercial alumina, used in DBC is found to be the most suitable design among other candidates with improved thermal and structural properties. In order to study the performance characteristics and the effects of the new ceramic composite with improved properties in terms of structural behavior and fatigue life of the DBC substrate, the normal working and extreme thermal cycling conditions were simulated and analyzed using finite element method. The temperature, strain, and localized stress distribution within the substrate at a steady-state condition were analyzed, and the improved Coffin–Manson law was used to calculate the fatigue life of the substrate under extreme thermal cycling conditions. The proposed Al{sub 2}O{sub 3}-SiC composite is found to be more robust than the commercial alumina as DBC substrates considering the thermal–mechanical performance. The fatigue life cycle of the DBC substrate with the proposed material is predicted to be about two times longer than the commercial alumina DBC ceramic under transient thermal cycling test.

36 MATERIALS SCIENCE↗

A low temperature unitized regenerative fuel cell realizing 60% round trip efficiency and 10 000 cycles of durability for energy storage applications

Unitized regenerative fuel cells (URFC) convert electrical energy to and from chemical bonds in hydrogen. URFCs have the potential to provide economical means for efficient long-term, seasonal, energy storage and on-demand conversion back to electrical energy. We first optimize the catalyst layer for discrete electrolyzer and fuel cell and then configure the URFC. The goal is to identify a cost competitive configuration for URFCs, and demonstrate it in terms of upper limit of round trip efficiencies (RTEs). Two possible configurations of URFCs are compared via experiments and techno-economic analysis (TEA), which emphasize the advantages of the unconventional constant-electrode (CE) URFC over the traditional constant-gas (CG) configuration. We also study the stability via accelerated stress tests (ASTs) and demonstrate steady state operation in a daily cycle for day to night energy shifting. From the investigations, the optimum composition of the URFC anode catalyst layer is 90 at% Ir-black balanced by Pt-black for both CE and CG configurations. At 80 °C and 1 A cm -2 , the optimized CE URFC achieves 57% and 60% RTE with air and O 2 as the reductant gases, respectively. We then evaluated the differences in durability using an AST over 10k charge–discharge cycles; the results reveal that the wider potential window at the anode in CE (0.05–1.55 V) has minimal effect on catalyst layer stability compared to CG (0.55–1.55 V). Furthermore, there was no degradation up to the range of 2k–5k cycles; beyond that the fuel cell (discharge) performance degraded while the electrolyzer (charge) performance was still stable. Finally, the observations here indicate substantial potential to employ URFCs as efficient and cost-effective bidirectional energy-conversion devices within energy storage and utilization systems after appropriate technological and operational optimizations.

25 ENERGY STORAGE↗

Thermal-stress fatigue behavior of twenty-six superalloys

The comparative thermal-stress fatigue resistances of 26 nickeland cobalt-base alloys were determined by fluidized bed tests. Cycles to cracking differed by almost three orders of magnitude for these materials, with directional solidification and surface protection showing definite benefit. The alloy-coating combination with the highest thermal-stress fatigue resistance was directionally solidified NASA TAZ-8A with an RT-SP coating. Its oxidation resistance was also excellent, showing approximately a 1/2 percent weight loss after 14,000 fluidized bed cycles.

Bizon, P. T.↗

Tensile and Fatigue Testing and Material Hardening Model Development for 508 LAS Base Metal and 316 SS Similar Metal Weld under In-air and PWR Primary Loop Water Conditions

This report provides an update on an assessment of environmentally assisted fatigue for light water reactor components under extended service conditions. This report is a deliverable in September 2015 under the work package for environmentally assisted fatigue under DOE’s Light Water Reactor Sustainability program. In an April 2015 report we presented a baseline mechanistic finite element model of a two-loop pressurized water reactor (PWR) for systemlevel heat transfer analysis and subsequent thermal-mechanical stress analysis and fatigue life estimation under reactor thermal-mechanical cycles. In the present report, we provide tensile and fatigue test data for 508 low-alloy steel (LAS) base metal, 508 LAS heat-affected zone metal in 508 LAS–316 stainless steel (SS) dissimilar metal welds, and 316 SS-316 SS similar metal welds. The test was conducted under different conditions such as in air at room temperature, in air at 300 oC, and under PWR primary loop water conditions. Data are provided on materials properties related to time-independent tensile tests and time-dependent cyclic tests, such as elastic modulus, elastic and offset strain yield limit stress, and linear and nonlinear kinematic hardening model parameters. The overall objective of this report is to provide guidance to estimate tensile/fatigue hardening parameters from test data. Also, the material models and parameters reported here can directly be used in commercially available finite element codes for fatigue and ratcheting evaluation of reactor components under in-air and PWR water conditions.

316 Stainless Steel↗

Dynamically triggered slip leading to sustained fault gouge weakening under laboratory shear conditions

We investigate dynamic wave-triggered slip under laboratory shear conditions. The experiment is composed of a three-block system containing two gouge layers composed of glass beads and held in place by a fixed load in a biaxial configuration. When the system is sheared under steady state conditions at a normal load of 4 MPa, we find that shear failure may be instantaneously triggered by a dynamic wave, corresponding to material weakening and softening if the system is in a critical shear stress state (near failure). Following triggering, the gouge material remains in a perturbed state over multiple slip cycles as evidenced by the recovery of the material strength, shear modulus, and slip recurrence time. This work suggests that faults must be critically stressed to trigger under dynamic conditions and that the recovery process following a dynamically triggered event differs from the recovery following a spontaneous event.

58 GEOSCIENCES↗

Enhancing SWAT with mechanistic plant hydraulics: development and application in the Hanjiang River Basin

Plant transpiration plays a critical role in global water and energy cycles, requiring better process understanding as climate change intensifies drought stress and alters plant responses. Most hydrological models such as the widely-used SWAT lack representation of plant hydraulics, the mechanistic processes controlling plant water regulation and transpiration. Here, this study developed SWAT-PHS by integrating a plant hydraulics scheme (PHS) into SWAT hydrological model, enabling explicit simulation of root water uptake, sap flow, storage and transpiration at 30-minute timescales for watershed-scale modeling. In the Hanjiang River Basin, SWAT-PHS mitigated overestimation of runoff during the rainy season and underestimation during the dry season, reducing the overall simulation error by 29% across the entire simulation period. The model can simulate reasonable plant water dynamics, including diurnal transpiration patterns and drought responses showing declining transpiration flux, hydraulic buffering through stem water storage, and depth-dependent root water uptake strategies. Sensitivity analysis shows that SWAT-PHS captured mechanistic relationships between plant hydraulic traits and transpiration, with root distribution and stem capacitance positively affecting annual transpiration while vulnerability parameters showed negative effects. This work provides a pathway for improving hydrologic modeling and water resource management by better representing plant water regulation under climate change and expected intensifying water stress conditions.

China↗