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At least 955 records · Page 53

Simulation of high temperature thermal energy storage system based on coupled metal hydrides for solar driven steam power plants

Concentrating solar power plants can achieve low cost and efficient renewable electricity production if equipped with adequate thermal energy storage systems. Metal hydride based thermal energy storage systems are appealing candidates due to their demonstrated potential for very high volumetric energy densities, high exergetic efficiencies, and low costs. The feasibility and performance of a thermal energy storage system based on NaMgH 2 F hydride paired with TiCr 1.6 Mn 0.2 is examined, discussing its integration with a solar-driven ultra-supercritical steam power plant. The simulated storage system is based on a laboratory-scale experimental apparatus. It is analyzed using a detailed transport model accounting for the thermochemical hydrogen absorption and desorption reactions, including kinetics expressions adequate for the current metal hydride system. The results show that the proposed metal hydride pair can suitably be integrated with a high temperature steam power plant. The thermal energy storage system achieves output energy densities of 226 kWh/m 3 , 9 times the DOE SunShot target, with moderate temperature and pressure swings. Also, simulations indicate that there is significant scope for performance improvement via heat-transfer enhancement strategies.

14 SOLAR ENERGY↗

Energy storage solutions to decarbonize electricity through enhanced capacity expansion modelling

To meet ambitious global decarbonization goals, electricity system planning and operations will change fundamentally. With increasing reliance on variable renewable energy resources, energy storage is likely to play a critical accompanying role to help balance generation and consumption patterns. As grid planners, non-profit organizations, non-governmental organizations, policy makers, regulators and other key stakeholders commonly use capacity expansion modelling to inform energy policy and investment decisions, it is crucial that these processes capture the value of energy storage in energy-system decarbonization. Here we conduct an extensive review of literature on the representation of energy storage in capacity expansion modelling. We identify challenges related to enhancing modelling capabilities to inform decarbonization policies and electricity system investments, and to improve societal outcomes throughout the clean energy transition. Additionally, we further identify corresponding research activities that can help overcome these challenges and conclude by highlighting tangible real-world outcomes that will result from pursuing these research activities. Capacity expansion modelling (CEM) approaches need to account for the value of energy storage in energy-system decarbonization. A new Review considers the representation of energy storage in the CEM literature and identifies approaches to overcome the challenges such approaches face when it comes to better informing policy and investment decisions.

25 ENERGY STORAGE↗

Energy storage arbitrage under day-ahead and real-time price uncertainty

Electricity markets must match real-time supply and demand of electricity. With increasing penetration of renewable resources, it is important that this balancing is done effectively, considering the high uncertainty of wind and solar energy. Storing electrical energy can make the grid more reliable and efficient and energy storage is proposed as a complement to highly variable renewable energy sources. However, for investments in energy storage to increase, participating in the market must become economically viable for owners. This paper proposes a stochastic formulation of a storage owner’s arbitrage profit maximization problem under uncertainty in day-ahead (DA) and real-time (RT) market prices. The proposed model helps storage owners in market bidding and operational decisions and in estimation of the economic viability of energy storage. Finally, case study results on realistic market price data show that the novel stochastic bidding approach does significantly better than the deterministic benchmark.

25 ENERGY STORAGE↗

System and Component Development of Particle-Based Pumped Thermal Energy Storage

Reliable power supply from variable renewable resources requires energy storage at various scales to overcome resource intermittency. Long-duration energy storage (LDES, 10-100 hours) can improve dispatchability and grid reliability with increasing levels of renewable power supply. Thermal energy storage (TES) has siting flexibility and the ability to store a large capacity of energy, and thus has the potential to meet the LDES need and provide charging and discharging durations beyond the economic capacity of conventional batteries. TES technology has evolved from concentrating solar thermal power (CSP) generation and is recognized as an economic large-scale energy storage method. A standalone electric-thermal energy storage system supporting renewable integration of wind and solar power without CSP solar field can firm renewable generation and boost overall grid resilience and security.

concentrating solar thermal power↗

Energy Northwest - Horn Rapids Solar and Storage: An Assessment of Battery Technical Performance

Chartered in 1957 as a joint action agency of the state, Energy Northwest (ENW) is a consortium of 27 public utility districts and municipalities across Washington state. ENW takes advantage of economies of scale and shared services to help utilities run their operations more efficiently and at lower cost, to the benefit of more than 1.5 million customers. ENW develops, owns, and operates a diverse mix of electricity generating resources, including hydro, solar, and wind projects – and the Northwest’s only active nuclear energy facility. These projects provide enough reliable, affordable, and environmentally responsible energy to power more than a million homes each year, and that carbon-free electricity is provided at the cost of generation. The agency continually explores new generation projects to meet its members’ needs. In 2017, as part of the second round of funding from the Washington state Clean Energy Fund, the Washington State Department of Commerce granted up to $3 million in matching funds to develop an estimated $6.5 million project that deployed a 4-MW, 20-acre solar generating array of photovoltaic (PV) panels coupled with a 1 MW/5.5 MWh lithium-iron-phosphate battery energy storage system (BESS) in Richland, Washington. The combination of PV and BESS will provide a predictable, renewable generating source and will also serve as a training ground for solar and battery technicians throughout the nation. The City of Richland will purchase the power from the project and utilize the benefits of the energy storage. The project provides Washington state with its first opportunity to integrate a large-scale solar and storage facility into its clean mix of hydro, nuclear, and wind resources. This first-of-its-kind facility combines solar generation with battery storage and technician training. In 2019, Pacific Northwest National Laboratory (PNNL) worked with ENW to assess the integrated PV and BESS in representative use cases that could benefit the City of Richland. Between March and May 2022, extensive testing was conducted, and the results were used to assess the technical performance of the BESS subjected to actual field operations. Both reference performance and use case tests were performed: (A) Reference performance tests assess the general technical capabilities of the BESS, such as energy capacity, round-trip efficiency (RTE), ramp rate, and signal tracking capability. These are the first tests performed (baseline), and they are repeated after use case tests (post cycle). A standardized U.S. Department of Energy (DOE) energy storage performance protocol was used to characterize the BESS, including representative duty cycle profiles, test procedure guidance, and calculation guidance for determining key characteristics. (B) Use case tests examine the performance of the BESS for specific use cases using duty cycles developed by PNNL in collaboration with ENW. Five use cases were selected for testing: 1) demand charge reduction, 2) load shaping, 3) transmission charge reduction, 4) Volt-VAR service, and 5) outage mitigation. The use case duty cycles were developed based on utility and site-specific characteristics in addition to the technical characteristics and physical capabilities of the BESS. Use case tests were performed between the baseline and post cycle tests. This report describes the BESS and its components, presents testing and performance analysis results, and shares key insights and lessons learned from this project. Outcomes of the tests and analyses will help ENW understand the performance of the Horn Rapids BESS in its current state and design appropriate operational strategies for this and other BESSs over the long term.

14 SOLAR ENERGY↗

Integrated Hydrogen Energy Storage System (IHESS) for Power Generation (Final Report)

GTI Energy partnered with Praxair Inc., a subsidiary of Linde PLC (Praxair), the Center for Electromechanics at the University of Texas at Austin (CEM), Entergy Corporation (Entergy), Quanta Services (Quanta) and Mitsubishi Heavy Industries (MHI) to perform a feasibility study that determines the economic and technical feasibility of low-carbon hydrogen energy storage integrated with a site-specific fossil fuel asset to decarbonize electricity production using the Integrated Hydrogen Energy Storage System (IHESS). The proposed IHESS concept is novel, as it sought to leverage the existing natural gas infrastructure, hydrogen production and pipelines, existing underground hydrogen storage system and power plants in the Gulf Coast region to reduce carbon emissions and generate lowcarbon electricity. This study has shown that IHESS has a promising commercial outlook as the concept leverages existing natural gas infrastructure assets and hydrogen production and storage that are unique to the Texas gulf coast region. A key hurdle with hydrogen supply and transportation has been capital investment. By storing hydrogen in underground storage and delivering it as a fuel source during peak demand using the existing infrastructure minimizes the capital investment. Regional petrochemical producers who are actively seeking opportunities to reduce costs and lower emissions should find the IHESS concept very appealing.

03 NATURAL GAS↗

Principles and Options for Designing Battery Energy Storage Zoning Ordinances

Deployment of battery energy storage (BESS) systems, both standalone and as part of hybrid systems paired with generation, has rapidly increased in the United States in recent years as utilities and communities have deployed storage to improve electric grid reliability and act as a cost-effective alternative to larger grid infrastructure. The modular nature of BESS technologies means systems may be built near other existing land uses, creating the potential for conflicts with neighboring landowners that can be managed and mitigated through zoning and permitting requirements established by local jurisdictions. While many cities and counties have adopted ordinances specific to BESS into their local zoning codes, these ordinances vary significantly in their requirements and level of detail. Meanwhile, many other jurisdictions, including those home to proposed or existing BESS projects, lack any specific language related to BESS in their zoning codes. Local planning and zoning officials have limited capacity and may lack the familiarity with BESS technologies needed to develop ordinances or otherwise make reasonable zoning decisions that balance safety, community impacts, and other goals. The resulting uncertainty at the local zoning level has led developers to withdraw projects in some areas and has spurred moratoria or bans on energy storage projects in others. This report intends to provide practical resources for practitioners interested in reasonable and effective local regulation of battery energy storage. It does not present a model zoning ordinance, but rather is intended to complement model ordinances developed by others by providing additional context and analysis regarding the structure of energy storage zoning ordinances and the decision points for local officials. Zoning ordinances at the city, town, and county level across the U.S. were surveyed alongside two template model ordinances to identify common elements and options for regulating the zoning and siting of BESS. Common elements identified and analyzed include definitions and general requirements, including cutoffs or tiers used to apply regulations to different system sizes and the permitted zones where jurisdictions allow BESS to be sited; visual, noise, and aesthetic requirements, including property line setbacks, fencing and visual screening, noise, and lighting requirements; and safety and planning requirements, such as site plans, decommissioning plans or funds, and requirements for access by emergency services. The report also summarizes some of the more unique regulations, including those that place additional restrictions on BESS at the local level.

25 ENERGY STORAGE↗

Prairie State Generating Company Site: Storage Field Development Plan

This Storage Field Development plan presents the Storage Complex characterization results, construction, monitoring, operational plans, and costs associated with the proposed Prairie State Energy Campus - Carbon Capture and Storage (PSEC-CCS) project in Washington County, Illinois, near Marissa. The proposed storage complex, known as the St. Peter-Everton Storage Complex, comprises the St. Peter Sandstone and Everton sandstone reservoirs, with the Maquoketa Shale serving as the primary confining unit and the Knox Group as lower confining unit. The lowermost Underground Source of Drinking Water (USDW) identified for the site is the Pennsylvanian section.

01 COAL, LIGNITE, AND PEAT↗

Techno-Economic Analysis and Optimization of a Compressed-Air Energy Storage System Integrated with a Natural Gas Combined-Cycle Plant

To address the rising electricity demand and greenhouse gas concentration in the environment, considerable effort is being carried out across the globe on installing and operating renewable energy sources. However, the renewable energy production is affected by diurnal and seasonal variability. To ensure that the electric grid remains reliable and resilient even for the high penetration of renewables into the grid, various types of energy storage systems are being investigated. In this paper, a compressed-air energy storage (CAES) system integrated with a natural gas combined-cycle (NGCC) power plant is investigated where air is extracted from the gas turbine compressor or injected back into the gas turbine combustor when it is optimal to do so. First-principles dynamic models of the NGCC plant and CAES are developed along with the development of an economic model. The dynamic optimization of the integrated system is undertaken in the Python/Pyomo platform for maximizing the net present value (NPV). NPV optimization is undertaken for 14 regions/cases considering year-long locational marginal price (LMP) data with a 1 h interval. Design variables such as the storage capacity and storage pressure, as well as the operating variables such as the power plant load, air injection rate, and air extraction rate, are optimized. Results show that the integrated CAES system has a higher NPV than the NGCC-only system for all 14 regions, thus indicating the potential deployment of the integrated system under the assumption of the availability of caverns in close proximity to the NGCC plant. The levelized cost of storage is found to be in the range of 136–145 $/MWh. Roundtrip efficiency is found to be between 74.6–82.5%. A sensitivity study with respect to LMP shows that the LMP profile has a significant impact on the extent of air injection/extraction while capital expenditure reduction has a negligible effect.

25 ENERGY STORAGE↗

Valuing the Resilience Provided by Solar and Battery Energy Storage Systems

This paper explores the impact of valuing resilience on the economics of photovoltaics (PV) and storage systems for commercial buildings. The analysis presented here illustrates that accounting for the cost of grid power outages can change the breakeven point for PV and storage system investment, and increase the size of systems designed to deliver the greatest economic benefit over time. In other words, valuing resilience can make PV and storage systems economical in cases where they would not be otherwise. As storage costs decrease, and outages occur more frequently, PV and storage are likely to play a larger role in building design and management considerations.

14 SOLAR ENERGY↗

An Empirical Model for Energy Storage Systems

Improved models of energy storage systems are needed to enable the electric grid’s adaptation to increasing penetration of renewables. This paper develops a generic empirical model of energy storage system performance agnostic of type, chemistry, design or scale. Parameters for this model are calculated using test procedures adapted from the US DOE Protocol for Uniformly Measuring and Expressing the Performance of Energy Storage. We then assess the accuracy of this model for predicting the performance of the TransPower GridSaver – a 1 MW rated lithium-ion battery system that underwent laboratory experimentation and analysis. The developed model predicts a range of energy storage system performance based on the uncertainty of estimated model parameters. Finally, this model can be used to better understand the integration and coordination of energy storage on the electric grid.

25 ENERGY STORAGE↗

Storage Futures Study: Four Phases Framework and Modeling

This webinar, presented by Paul Denholm and Will Frazier, incorporates material from two publications of the NREL Storage Futures Study: "The Four Phases of Storage Deployment: A Framework for the Expanding Role of Storage in the U.S. Power System" (https://www.nrel.gov/docs/fy21osti/77480.pdf) and "Storage Futures Study: Economic Potential of Diurnal Storage in the U.S. Power Sector" (https://www.nrel.gov/docs/fy21osti/77449.pdf).

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Geological Thermal Energy Storage Using Solar Thermal and Carnot Batteries: Techno-Economic Analysis: Preprint

Energy storage is increasingly necessary as Variable Renewable Energy (VRE) technologies are deployed. Seasonal energy storage can shift energy generation from the summer to the winter, but these technologies must have extremely large energy capacities and low costs. Geological Thermal energy storage (GeoTES) is proposed as a solution for long-term energy storage. Excess thermal energy can be stored in permeable reservoirs such as aquifers and depleted hydrocarbon reservoirs for several months. In this article, we describe a techno-economic model that has been developed to evaluate GeoTES systems. The models are developed by combining the output of specialist models which enables the performance and cost of both the subsurface and surface systems to be captured. Off-design models are developed so that the performance can be evaluated at each hour of the year. GeoTES can be charged with two different energy sources: (1) concentrating solar thermal and (2) renewable electricity using heat pumps (henceforth known as a "Carnot Battery"). The stored thermal energy can be used to generate electricity and - uniquely - also directly produce heat that can be used by industrial processes. Furthermore, Carnot-Battery-GeoTES can also be used to form a cold storage reservoir. Preliminary results that quantify the technical and economic performance of these two GeoTES systems are presented.

carnot battery↗

Alternative Canister Processing Operations at an Interim Storage Facility - 16617

The US Department of Energy (DOE) is laying the groundwork for implementing interim storage of spent nuclear fuel (SNF) in response to recommendations by the Blue Ribbon Commission on America's Nuclear Future in their report to the Secretary of Energy published January 2012. These efforts include planning for a Pilot Interim Storage Facility (ISF) and a Larger ISF. In March 2014, the DOE employed the CB and I team to evaluate design alternatives for cask handling operations and storing SNF at an ISF. The report, 'Generic Design Alternatives for Dry Storage of Used Nuclear Fuel', (Alternatives Report) evaluates different aspects of an ISF, including a study on alternative approaches for processing SNF canisters such as different cask handling methods and configurations which might be used to transfer canisters from shipping casks into storage locations at an ISF. The purpose of this paper is to report on the development of alternative cask handling operations that have been evaluated for the receipt and storage of the SNF at an initial Pilot ISF and a Larger ISF. This design study is relevant for host communities considering near-term development of a Pilot ISF. DOE-sponsored system analyses indicate that a processing rate of up to 3,000 MTU/yr (approximately 230 to 300 canisters) would be needed for a single Larger ISF (less if more than one ISF were developed) to remove SNF from commercial nuclear plants in a reasonable amount of time. The study evaluated different canister processing operation methodologies in order to reduce the complexity, cost, and personnel exposure associated with processing operations at an ISF. The conclusions from this design study could help to inform the selection of future canister processing operations for an ISF. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Systems and Tools to Facilitate Aging Management Inspections of Used Nuclear Fuel Dry Storage Systems - 18382

The Used Nuclear Fuel (UNF) dry storage systems (DSSs) are currently used at almost all the nuclear plants in the USA for the storage of their UNF as the spent fuel pools are running out of capacity to store any additional discharged fuel. Even though these DSSs are supposed to be at the reactor site for a short amount of time, they are expected to be at the reactor sites for an extended duration due to the unavailability of Interim Storage Facilities (ISF) or a permanent disposal sites like Yucca Mountain. Maintaining the integrity of the DSS canisters and storage overpacks so they can safely protect the fuel and maintain the integrity of UNF is of utmost importance during storage at reactor site ISFSI or at the ISF. Comprehensive and robust Aging Management Program (AMP) is an important aspect for DSSs to satisfy these requirements. In order to address this industry need, TN Americas have developed an enhanced NUHOMS{sup R} DSS licensed by NRC under 10 CFR Part 72 regulations and a comprehensive AMP development which includes prevention, inspection, monitoring and mitigation of any corrosion or degradation of DSS components. For DSC and HSM inspection, two remotely operating delivery systems have been developed using non-destructive examination (NDE) methods including robotic crawler and inspection ring system. This paper describes details of these developments and status of their deployment for implementation at various utility ISFSI sites. TN Americas completed the detailed design of the DSC inspection system and conducted functional tests of the inspection system on a DSC mockup and the system is ready for deployment at any NUHOMS{sup R} ISFSI site. TN Americas is committed to offer the most robust and comprehensive AMP systems, tools and services to the industry to assure the safety of the deployed DSS at the utility sites. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Monitoring and Modeling Caprock Integrity at the In Salah Carbon Dioxide Storage Site, Algeria

The In Salah gas development project, initiated in 2004, involves the long-term storage of waste carbon dioxide associated with natural gas production at several central Algerian fields. Rather then vent the extracted CO 2 into the atmosphere the operators, BP, Sonatrach, and Statoil chose to have the gas compressed, dehydrated, transported, and injected into a deep saline aquifer leg of the Krechba gas reservoir (Matheison et al. 2011). For this effort three horizontal state-of-the-art injection wells were drilled to a depth of 1500-1800m, using geo-steering technology to follow the roughly 20m thick reservoir. To maximize the injectivity, the wells were oriented perpendicular to the direction of maximum stress, the dominant fracture direction. Long-term plans were to store up to 17 million tonnes of carbon dioxide during the life of the program (Matheison et al. 2010). The project at In Salah was a pioneering effort in several respects and involved the investment of over 100 million dollars by the member companies. One feature that distinguishes In Salah from several other industrialscale CO 2 sequestration projects, such as Sleipner (Chadwick et al. 2012), Weyburn (White et al. 2011), Decatur (Kaven et al. 2014), and Aquastore (Worth et al. 2014) is the generally smaller storage volume in terms of overall reservoir thickness and lower average porosities of around 15%. With the exception of Weyburn, these other sites are characterized by generally thick sequences of high porosity sandstones. Therefore, one might expect that the pressure buildup near the wells could be larger at In Salah, with consequences for reservoir deformation and caprock strain. The role of fractures in providing storage and increasing reservoir permeability is one factor that would likely impact the pressure distribution around the well. However, the detailed effect of existing fractures on flow was not established prior to the injection at In Salah. The unique features of the In Salah storage site point to the importance of wellbore, geophysical, and geochemical monitoring to ensure that the integrity of the storage complex is maintained both during and after injection. In 2005 a Joint Industry Project (JIP) was set up, in an effort to use various geophysical, geochemical, and production techniques to monitor the fate of the injected carbon dioxide (Matheison et al. 2011). Here in this paper we describe the efforts made to monitoring the fate of the injected carbon dioxide, the state of the caprock, the estimated outcome of the storage effort, and some of the uncertainties that remain.

58 GEOSCIENCES↗

Radial storage efficiency for CO 2 injection: Quantifying effectiveness of local flow control methods

Basin-scale geologic carbon sequestration will require hundreds of injection wells, each of which has costs related to property rights and regulatory requirements that correlate with the areal size of the carbon dioxide plume. These surface-footprint-related issues motivate maximizing storage efficiency radially away from each well. Radial storage efficiency (RSE) is defined here as the ratio of the volumetrically weighted carbon dioxide free-phase saturation within a given radius away from the injection well to the available pore space within that same radius. Maximizing RSE effectively minimizes the radial extent of the CO 2 plume. Optimizing RSE around individual wells requires local flow control injection strategies that can increase the uniformity of the filling of pore space around the well over the entire length of the perforated injection interval despite differences in local formation transmissivity. The goal of uniform filling of the storage reservoir starting from the well outward is to maximize carbon dioxide sweep and trapping locally outward from the well in all of the layers of the storage region before buoyancy forces predominate and drive carbon dioxide upward where it will spread laterally under lower-permeability layers. Example simulations of carbon dioxide injection into a layered storage system with and without local flow control are presented to show the advantage of uniformly filling all layers and how RSE can be used to quantify storage efficiency for the two different injection approaches. Published 2021. This article is a U.S. Government work and is in the public domain in the USA.

03 NATURAL GAS↗

Immobile Pore-Water Storage Enhancement and Retardation of Gas Transport in Fractured Rock

The effect of immobile pore-water on gas transport in fractured rock has implications for numerical modeling of soil vapor extraction, methane leakage, gaseous CO 2 leakage from sequestration operations, radionuclide transport from underground nuclear explosions, and nuclear waste disposal. While the ability for immobile pore-water storage to effect gas transport has been recognized in the past, the details and specific scenarios leading to enhanced, retarded, or unaffected gas transport have not been explored. In this paper, we performed numerical investigations into the enhancement and retardation of gas transport due to immobile pore-water storage in order to identify implications for gas transport applications. To do this, we developed a numerical approach to model gas transport with a single-phase flow solution coupled to the advection–dispersion equation modified to account for immobile pore-water storage. Other than the immobility of pore water, the formulation contains all other physics included in two-phase formulations (advective and diffusive gas transport in fractures and rock matrix and dissolution in immobile pore water). The assumption of immobile pore water is valid here since for many applications involving transport of soluble gases in fractured rock, the rate of aqueous transport is insignificant compared to gas transport. We verify our modeling approach with analytical solutions of: (1) 1D gas diffusion, (2) 1D gas advection, (3) barometric pumping of a fracture, and (4) gas transport with uniform fracture flow and diffusion into the matrix. We account for pore-water storage in our model by implementing a kinetic formulation of gas dissolution wherein the dissolved (aqueous) phase is considered an immobile constituent. Using this formulation, we model the effect of dissolution rate and saturation on the retardation of gas transport during pure diffusion and pure advection. We also demonstrate that although it is commonly believed that pore-water storage will always enhance gas transport in fractures during oscillatory flow (e.g., during reversing pressure gradients such as barometric pumping cycles), our simulations indicate that this may not always be the case. Our numerical investigations indicate that scenarios with lower effective diffusion coefficients ( &#x2A85;<!-- <≈ --> 10 &#x2212;<!-- - --> 5 &#xA0;m 2 / s ) and lower dissolution coefficients (i.e., the dissolution diffusion coefficient) ( &#x2A85;<!-- <≈ --> 10 &#x2212;<!-- - --> 11 &#xA0;m 2 / s ) will result in enhanced gas transport. Other combinations of gaseous diffusion and dissolution coefficients result in delayed gas transport or insignificant effect on gas transport. Based on these results, and given the fact that the free-air diffusion coefficients for many gases are slightly above 10 &#x2212;<!-- - --> 5 &#xA0;m 2 / s (near the boundary of enhanced/non-enhanced gas transport), tortuosity would have to be significant for gas transport enhancement to occur. Similarly, if we consider the free-water diffusion coefficient of gases (around 10 &#x2212;<!-- - --> 9 &#xA0;m 2 / s for many gases of interest) to be a maximum bound for the effective dissolution coefficients (i.e., the rate of diffusion into the water away from the air/water interface will limit the dissolution rate), the effective dissolution coefficient would have to be at least 2 orders of magnitude less for enhanced gas transport to occur. Otherwise, pore-water storage will delay or have negligible effect on the gas transport. The results also indicate that the assumption of instantaneous equilibrium, often invoked in numerical codes for dissolution processes (i.e., dissolution coefficient is effectively infinite), will fail to accurately capture important details of soluble gas transport. Finally, the implication of our results is that gas breakthrough times in fractured rock during oscillatory flow may be highly dependent on the effective gaseous diffusion and dissolution coefficients.

58 GEOSCIENCES↗