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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 973 records · Page 54

A comprehensive iso-octane combustion model with improved thermochemistry and chemical kinetics

Iso-Octane (2,2,4-trimethylpentane) is a primary reference fuel and an important component of gasoline fuels. Furthermore, it is a key component used in surrogates to study the ignition and burning characteristics of gasoline fuels. This paper presents an updated chemical kinetic model for iso-octane combustion. Specifically, the thermodynamic data and reaction kinetics of iso-octane have been re-assessed based on new thermodynamic group values and recently evaluated rate coefficients from the literature. The adopted rate coefficients were either experimentally measured or determined by analogy to theoretically calculated values. New alternative isomerization pathways for peroxy-alkyl hydroperoxide ($\dot{O}$OQOOH) radicals were added to the reaction mechanism. The updated kinetic model was compared against new ignition delay data measured in rapid compression machines (RCM) and a high-pressure shock tube. Our experiments were conducted at pressures of 20 and 40 atm, at equivalence ratios of 0.4 and 1.0, and at temperatures in the range of 632–1060 K. The updated model was further compared against shock tube ignition delay times, jet-stirred reactor oxidation speciation data, premixed laminar flame speeds, counterflow diffusion flame ignition, and shock tube pyrolysis speciation data available in the literature. Finally, the updated model was used to investigate the importance of alternative isomerization pathways in the low temperature oxidation of highly branched alkanes. When compared to available models in the literature, the present model represents the current state-of-the-art in fundamental thermochemistry and reaction kinetics of iso-octane; and thus provides the best prediction of wide ranging experimental data and fundamental insights into iso-octane combustion chemistry.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Photoionization and the emission-line spectra of quasi-stellar objects.

Detailed photoionization calculations are used to examine the information conveyed by relative emission-line intensities in QSO spectra. It is found that the elemental abundances cannot be estimated with any assurance; but if ?conventional' values are assumed, then certain restrictions may be placed on the ionizing spectra and gas densities. In particular, the ratio between radiation density and gas density is determined. Narrow filaments or sheets of ionized gas seem to be indicated; these may be compressed regions behind shock fronts.

Davidson, K.↗

Effects of pulse width and coding on radar returns from clear air

In atmospheric radar studies it is desired to obtain maximum information about the atmosphere and to use efficiently the radar transmitter and processing hardware. Large pulse widths are used to increase the signal to noise ratio since clear air returns are generally weak and maximum height coverage is desired. Yet since good height resolution is equally important, pulse compression techniques such as phase coding are employed to optimize the average power of the transmitter. Considerations in implementing a coding scheme and subsequent effects of an impinging pulse on the atmosphere are investigated.

Cornish, C. R.↗

Dynamic measurements of gear tooth friction and load

As part of a program to study fundamental mechanisms of gear noise, static and dynamic gear tooth strain measurements were made on the NASA gear-noise rig. Tooth-fillet strains from low-contact ratio-spur gears were recorded for 28 operating conditions. A method is introduced whereby strain gage measurements taken from both the tension and compression sides of a gear tooth can be transformed into the normal and frictional loads on the tooth. This technique was applied to both the static and dynamic strain data. The static case results showed close agreement with expected results. For the dynamic case, the normal-force computation produced very good results, but the friction results, although promising, were not as accurate. Tooth sliding friction strongly affected the signal from the strain gage on the tensionside of the tooth. The compression gage was affected by friction to a much lesser degree. The potential of the method to measure friction force was demonstrated, but further refinement will be required before this technique can be used to measure friction forces dynamically with an acceptable degree of accuracy.

Rebbechi, Brian↗

Lateral variations in lower mantle seismic velocity

To obtain a theoretical model which provides a rationale for the observed high values of velocity variations, the effect of a 0.1 to 0.2 percent partially molten volatile-rich material in various geometries which are heterogeneously dispersed in the lower mantle is examined. Data obtained indicate that, depending on aspect ratio and geometry, 0.1-0.2 percent partial melting in conjunction with about 100 K thermal anomalies can explain the seismic variations provided the compressibility of the melt differs by less than about 20 percent from the surrounding solid.

Duffy, Thomas S.↗

The Aeroacoustics of Supersonic Coaxial Jets

Instability waves have been established as the dominant source of mixing noise radiating into the downstream arc of a supersonic jet when the waves have phase velocities that are supersonic relative to ambient conditions. Recent theories for supersonic jet noise have used the concepts of growing and decaying linear instability waves for predicting radiated noise. This analysis is extended to the prediction of noise radiation from supersonic coaxial jets. Since the analysis requires a known mean flow and the coaxial jet mean flow is not described easily in terms of analytic functions, a numerical prediction is made for its development. The Reynolds averaged, compressible, boundary layer equations are solved using a mixing length turbulence model. Empirical correlations are developed for the effects of velocity and temperature ratios and Mach number. Both normal and inverted velocity profile coaxial jets are considered. Comparisons with measurements for both single and coaxial jets show good agreement. The results from mean flow and stability calculations are used to predict the noise radiation from coaxial jets with different operating conditions. Comparisons are made between different coaxial jets and a single equivalent jet with the same total thrust, mass flow, and exit area. Results indicate that normal velocity profile jets can have noise reductions compared to the single equivalent jet. No noise reductions are found for inverted velocity profile jets operated at the minimum noise condition compared to the single equivalent jet. However, it is inferred that changes in area ratio may provide noise reduction benefits for inverted velocity profile jets.

Dahl, Milo D.↗

Aeroacoustic Characteristics of Model Jet Test Facility Flow Conditioners

An experimental investigation of flow conditioning devices used to suppress internal rig noise in high speed, high temperature experimental jet facilities is discussed. The aerodynamic and acoustic characteristics of a number of devices including pressure loss and extraneous noise generation are measured. Both aerodynamic and acoustic characteristics are strongly dependent on the porosity of the flow conditioner and the closure ratio of the duct system. For unchoked flow conditioners, the pressure loss follows conventional incompressible flow models. However, for choked flow conditioners, a compressible flow model where the duct and flow conditioner system is modeled as a convergent-divergent nozzle can be used to estimate pressure loss. Choked flow conditioners generate significantly more noise than unchoked conditioners. In addition, flow conditioners with small hole diameters or sintered metal felt material generate less self-noise noise compared to flow conditioners with larger holes.

Kinzie, Kevin W.↗

The effect of aspect ratio on the mechanical behavior of Li metal in solid-state cells

The Li metal anode is necessary for solid-state batteries to dramatically exceed the energy density of state-of-the-art conventional Li-ion batteries. To enable the Li metal anode, the mechanical properties of Li metal under compression in a commercially relevant cell configuration must be determined. This work examines the compression creep behavior of Li metal coupled with a relevant model solid-state electrolyte (Li 6.5 La 3 Ta 0.5 Zr 1.5 O 12 ) and current collector (Ni) as a function of applied stress (1–10 MPa) and Li foil thickness (100–700 μm). At 1 MPa applied stress, the strain rate of all Li foil thicknesses under compression was almost four orders of magnitude lower than what is predicted from tensile creep tests. Steady-state creep behavior was observed for Li foil ≥350 μm at 5 MPa and ≥250 μm at 10 MPa. Conversely, sustained creep deformation was not observed for 100 and 150 μm Li foils at any applied stress. It is suggested that friction at the Li/LLZO and Li/Ni interfaces leads to the formation of hydrostatic stress that controls Li deformation at low aspect ratios. Finally, these results have implications for battery pack stack pressure requirements, particularly relating to void formation during stripping and Li metal filament penetration during plating.

25 ENERGY STORAGE↗

Preliminary Investigation of an Underwater Ramjet Powered by Compressed Air

Part I contains the results of a preliminary experimental investigation of a particular design of an underwater ramjet or hydroduct powered by compressed air. The hydroduct is a propulsion device in which the energy of an expanding gas imparts additional momentum to a stream of water through mixing. The hydroduct model had a fineness ratio of 5.9, a maximum diameter of 3.2 inches, and a ratio of inlet area to frontal area of 0.32. The model was towed at a depth of 1 inch at forward speeds between 20 and 60 feet per second for airflow rates from 0.1 to 0.3 pound per second. Longitudinal force and pressures at the inlet and in the mixing chamber were determined. The hydroduct produced a positive thrust-minus-drag force at every test speed. The force and pressure coefficients were functions primarily of the ratio of weight airflow to free-stream velocity. The maximum propulsive efficiency based on the net internal thrust and an isothermal expansion of the air was approximately 53 percent at a thrust coefficient of 0.10. The performance of the test model may have been influenced by choking of the exit flow. Part II is a theoretical development of an underwater ramjet using air as "fuel." The basic assumption of the theoretical analysis is that a mixture of water and air can be treated as a compressible gas. More information on the properties of air-water mixtures is required to confirm this assumption or to suggest another approach. A method is suggested from which a more complete theoretical development, with the effects of choking included, may be obtained. An exploratory computation, in which this suggested method was used, indicated that the effect of choked flow on the thrust coefficient was minor.

Mottard, Elmo J.↗

Inlet performance of the integrated Langley scramjet module

The inlet concept for the Langley Scramjet Module has been developed and proven in Langley wind tunnels over a Mach number range from 2.3 to 6.0 (flight simulation of Mach 2.6 to 7.6). This modular engine concept is designed to integrate with the airframe, which results in precompression of the engine airflow by the vehicle bow shock and additional expansion of the nozzle exhaust gas by the afterbody of the vehicle. With these integration advantages, the inlet can be designed with modest contraction ratios and fixed geometry. Also, the module nozzle exit area can be equal to the capture area, which permits the cowl to be alined with the local flow producing minimum external drag. The inlet leading edges and planar compression surfaces are swept at 48 deg, which provides spillage at low Mach numbers for starting and which reduces the pressure gradient on the top surface to permit ingestion of the vehicle forebody boundary layer into the inlet without separating. Three fuel injection struts provide for the use of a short combustor having low internal cooling requirements. Schedules for mass capture ratio, contraction ratio, and total pressure recovery are well within the acceptable range for a good scramjet propulsion device. The fixed geometry, minimum external drag design has proven to be a practical, high-performance inlet concept.

Trexler, C. A.↗

Experimental and Numerical Investigation of a Miniature Additively Manufactured Vortex Tube

Ranque–Hilsch vortex tubes are simple devices that can produce a cooling effect using compressed air. A key advantage of vortex tubes is the lack of moving solid parts; however, their efficiencies are relatively low. The present study focuses on the development of a miniature variable-diameter tube using additive manufacturing. A metal-based 3D printing technique was utilized to fabricate this vortex tube monolithically. Computational fluid dynamics simulations employing software STAR-CCM + with a compressible Reynolds-Averaged Navier–Stokes (RANS) approach and the elliptic-blending lag k-epsilon turbulence model have been applied to model thermofluid processes inside the vortex tube, to good agreement with the experiment. In conclusion, a temperature decrease of 13.3 °C and a cooling power of approximately 4 W were experimentally achieved with a pressure ratio of 4 in the air at normal conditions. This result shows promise for the goal of utilizing additive manufacturing to design and build complex-geometry vortex tubes intended for use with cryogenic fluids.

08 HYDROGEN↗

Synthesis and Properties of Porous Ti-20 wt.% HA Nanocomposites

In the present study, porous titanium-20 wt.% hydroxyapatite nanocomposites were produced by the combination of mechanical alloying and powder metallurgical process with the addition of titanium hydride particles as the blowing agent. The powder mixture of Ti, HA and spacer particles were milled, pressed and heat-treated to decompose the hydride particles and to sinter into highly porous Ti-HA materials. The resulting microstructures were characterized using x-ray diffraction and scanning electron microscope with energy-dispersive spectrometry. The porosity, compressive strength and corrosion resistance of the porous nanocomposites were investigated. The results show that the compressive strength of porous Ti-HA can be tailored between 210 and 497 MPa by changing the content of blowing agent between 25 and 75%. The increase in the weight ratio of titanium hydride (from 25 to 75%) causes almost a twofold increase in the porosity and decreases the corrosion resistance (by almost two orders of magnitude). The present study has demonstrated that the porous Ti-HA nanocomposites are promising scaffold biomaterials for bone tissue engineering by virtue of their appropriate mechanical and corrosion properties and highly porous structure.

36 MATERIALS SCIENCE↗

Effect of Coolant Temperature and Mass Flow on Film Cooling of Turbine Blades

A three-dimensional Navier Stokes code has been used to study the effect of coolant temperature, and coolant to mainstream mass flow ratio on the adiabatic effectiveness of a film-cooled turbine blade. The blade chosen is the VKI rotor with six rows of cooling holes including three rows on the shower head. The mainstream is akin to that under real engine conditions with stagnation temperature = 1900 K and stagnation pressure = 3 MPa. Generally, the adiabatic effectiveness is lower for a higher coolant temperature due to nonlinear effects via the compressibility of air. However, over the suction side of shower-head holes, the effectiveness is higher for a higher coolant temperature than that for a lower coolant temperature when the coolant to mainstream mass flow ratio is 5% or more. For a fixed coolant temperature, the effectiveness passes through a minima on the suction side of shower-head holes as the coolant to mainstream mass flow, ratio increases, while on the pressure side of shower-head holes, the effectiveness decreases with increase in coolant mass flow due to coolant jet lift-off. In all cases, the adiabatic effectiveness is highly three-dimensional.

Garg, Vijay K.↗

Structure-property relation and Weibull analysis of calcium aluminate cement pastes

Highlights: • Weibull distribution analysis was conducted for calcium aluminate cement pastes with 52 wt% and 71 wt% of alumina contents. • Compressive strength ranged from 10 to 45 MPa. • The hydrated phases found showed diverse polymorphisms of Gibbsite (Nordstrandite, Bayerite, Hidrogarnet and Gehlenite). - Abstract: In this investigation calcium aluminate cement (CAC) pastes with 52 wt% and 71 wt% of alumina contents were fabricated and characterized with different techniques. Samples were made with 0.4 and 0.5 water to cement (W/C) ratios. Both the raw cement powders and their corresponding samples after hydration were characterized in their microstructure by scanning electron microscopy, X-ray diffraction (with Rietveld refinement), X-ray fluorescence (XRF), Fourier Transform Infrared Spectroscopy (FTIR), density, and compression tests. With the compressive strength results, Weibull distribution analysis was conducted for 20 samples per composition. The higher compression strength obtained was about 45 MPa, which corresponds to samples with the higher W/C contents. The hydrated phases found showed diverse polymorphisms of Gibbsite (Nordstrandite, Bayerite, Hidrogarnet and Gehlenite).

36 MATERIALS SCIENCE↗

A Computational Investigation of Engine Heat Transfer with Ducted Fuel Injection

Ducted fuel injection (DFI) is an innovative method that curtails or prevents soot formation in direct-injection compression-ignition engines. DFI uses a simple duct, positioned outside each injector hole, facilitating the fuel/charge gas mixing before ignition. This reduces the equivalence ratio below two, in the autoignition zone, which in turn decreases soot formation. But this method also reduces fuel-conversion efficiency. This study investigates the effects of DFI on in-cylinder heat transfer. Experiments with conventional diesel combustion (CDC) and DFI were performed at four different dilution levels. Computational fluid dynamics (CFD) simulations were carried out at conditions matching those of the experiments, and the simulations were validated by the experimental data. The CFD simulations enabled to examine of in-cylinder heat release and temperature distributions. The heat transfer to the piston, head, and cylinder was investigated. The results show that DFI increased the heat transfer to the walls compared to CDC under the same conditions. This could help explain why DFI has been observed to reduce fuel-conversion efficiency by approximately 1% (absolute) relative to CDC under certain conditions. The efficiency loss typically decreases with dilution, such that DFI can improve fuel-conversion efficiencies relative to CDC at higher dilution levels.

Şener, Ramazan↗

Experimental Investigation of Concrete Fatigue in Axial Compression

The use of concrete in fatigue critical structures, such as wind turbine towers, has necessitated the replacement of simplistic (and therefore insufficient) fatigue design recommendations with more accurate and advanced fatigue models that can consider a greater complexity of stress states and materials. As the first part of a multistage test series, an experimental investigation was conducted to determine the fatigue life of concrete subjected to axial compressive fatigue loading, focusing on the relatively high-cycle fatigue domain. Here, a wide range of values for maximum stress levels and stress ratios were considered. The experimental results were compared against existing predictive models, and the most applicable model was identified. Concrete strain and stiffness behavior during fatigue loading were also investigated and reported. Based on the observed behavior, a hypothesis for identifying the impending occurrence of fatigue failure, based on the monotonic stress-strain curve, is examined.

17 WIND ENERGY↗

Utilization of Existing Pipelines in Hydrogen Transport: Literature Review Report

This report critically reviews the flow behavior of hydrogen-natural gas (H 2 -NG) mixtures in pipelines and examines the critical factors of hydrogen integration into existing natural gas infrastructure. It addresses the choking behavior characterized by velocity increase and pressure drop, as well as the effects of flow restrictions and pressure losses during hydrogen transport. Computational and analytical models are used to investigate these effects, and their effects on thermodynamic properties and system performance are evaluated. The study also reviews the energy efficiency and flow dynamics of hydrogen and methane-hydrogen mixtures and optimizes the hydrogen flow rate. In addition, the effects of these mixtures on the flow characteristics are discussed in detail, with special emphasis on the compressibility factor (z factor) and fluid properties based on equations of state for hydrogen-natural gas mixtures. The study also analyzes the mixture ratios and highlights the thermophysical properties, flow dynamics, and hydrogen-blended natural gas application potential. These investigations assess flow stability, material interactions, and operational feasibility of transporting hydrogen mixtures through natural gas pipelines, which contribute to developing sustainable and efficient energy systems.

08 HYDROGEN↗

Side cracked plated subject to combined direct and bending forces

The opening mode stress intensity factor and the associated crack mouth displacement are comprehensively treated using planar boundary collocation results supplemented by end point values from the literature. Data are expressed in terms of dimensionless coefficients of convenient form which are each functions of two dimensionless parameters, the relative crack length, and a load combination parameter which uniquely characterizes all possible combinations of tension or compression with bending or counterbending. Accurate interpolation expressions are provided which cover the entire ranges of both parameters. Application is limited to specimens with ratios of effective half-height to width not less than unity.

Srawley, J. E.↗