Methods for radiological assessment of C-14 in air effluents - 15419
The purpose of this paper is to report on methods used for the assessment of -dose significant- C-14 being discharged into the air from nuclear facilities. GEL laboratories, LLC and GEL Engineering LLC, (GEL) undertook the task of developing new and improved methods to better identify the release of C-14 in the various chemical forms released from nuclear reactors and fuel reprocessing facilities. To completely understand the environmental releases and impact to the public a two-step approach was selected. The first step was to develop a sampling method that would enable an accurate assessment of the ratio of C-14 discharged as carbon dioxide compared to organic gases like methane. This is very important to dose modeling calculations to members of the public. Once this ratio was understood, the second step was to develop a method to track inorganic forms of C-14 with standard environmental air monitoring equipment and achieve a detection limit that was in line with NRC 10CFR Appendix I dose modeling requirements. GEL development efforts focused on using a solid sample cartridge that would fit into standard air sampling equipment used at nuclear plants. The cartridge and sorbent needed to be capable of running 7 days at 24 hours per day and not saturate with stable carbon dioxide. The process developed for analyzing the sorbent involves chemically removing the carbon dioxide and ultimately counting by liquid scintillation counting. The method yields a detection limit for C-14 of 0.02 Bq/m{sup 3} which provides a dose calculation of approximately 0.1 mSv/yr when applied to the child model. This paper will describe the methods and results used to determine field environmental monitoring for C-14 using GEL cartridges also known as -GELsorb C14-. (authors)