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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 973 records · Page 54

SU-F-T-211: Evaluation of a Dual Focusing Magnet System for the Treatment of Small Proton Targets

Purpose: To investigate magnetic focusing for small volume proton targets using a doublet combination of quadrupole rare earth permanent magnet Halbach cylinder assemblies Methods: Monte Carlo computer simulations were performed using the Geant4 toolkit to compare dose depositions of proton beams transported through two focusing magnets or in their absence. Proton beams with energies of 127 MeV and initial diameters of 5, 8 and 10 mm were delivered through two identical focusing magnets similar to those currently in experimental use at Loma Linda University Medical Center. Analogous experiments used optimized configurations based on the simulation results. Dose was measured by a diode detector and Gafchromic EBT3 film and compared to simulation data. Based on results from the experimental data, an additional set of simulations was performed with an initial beam diameter of 18 mm and a two differing length magnets (40mm & 68mm). Results: Experimental data matched well with Monte Carlo simulations. However, under conditions necessary to produce circular beam spots at target depth, magnetically focused beams using two identical 40 mm length magnets did not meet all of our performance criteria of circular beam spots, improved peak to entrance (P/E) dose ratios and dose delivery efficiencies. The simulations using the longer 68 mm 2nd magnet yielded better results with 34% better P/E dose ratio and 20–50% better dose delivery efficiencies when compared to unfocused 10 mm beams. Conclusion: While magnetic focusing using two magnets with identical focusing power did not yield desired results, ongoing Monte Carlo simulations suggest that increasing the length of the 2nd magnet to 68 mm could improve P/E dose ratios and dose efficiencies. Future work includes additional experimental validation of the longer 2nd magnet setup as well as experiments with triplet magnet systems. This project was sponsored with funding from the Department of Defense (DOD# W81XWH-BAA-10-1).

60 APPLIED LIFE SCIENCES↗

Manufacturing of Advanced Alnico Magnets for Energy Efficient Traction Drive Motors CRADA Final Report

The primary theme of this Technology Commercialization Fund (TCF) project was refining the pre-alloyed powder processing approach (with alnico 8, modified for higher coercivity) of that came out of the previous Development of Radically Enhanced alnico Magnets (DREaM) project to permit full size net-shape alnico magnets to be produced in a reproducible manner that could allow testing in an advanced Permanent Magnet (PM) drive motor. Previously, a lack of sufficient coercivity in alnico magnets limits their energy product and their application in automotive traction drive motors, despite their high temperature stability. Use of enhanced sintered alnico magnets, instead of rare earth (RE) magnets or larger cast alnico magnets, could lower costs and decrease cooling needs of these motors. Conventional production of the best (aligned) alnico magnets (alnico 9) involves costly directional solidification (DS) and achieves good alignment, but modest energy product (10 MGOe), because of low coercivity. Other limitations of cast alnico 9 magnets are poor mechanical properties and difficulty in scaling special casting molds to mass production. In spite of these problems with alnico 9, a commercial electric motor company, UQM, developed a fully capable traction drive motor that met many 2022 DOE-VTO performance targets, except full speed operation, due to brittle mechanical behavior. While UQM demonstrated an advanced drive motor that used alnico 9, they also encouraged the development of improved alnico, especially for greater coercivity (seeking 2X) and improved mechanical properties. While commercial sintered alnico magnets are less brittle and have improved coercivity, they have an inferior energy product due to their non-aligned, fine-grained microstructure. Thus, full development and up-scaling of well-aligned alnico magnets with a further increase in coercivity and good mechanical properties by a low cost powder processing route became the theme of this TCF project. The processing route for this project involved high-pressure gas atomization, at Ames and Carpenter, of modified alnico 8 compositions, compression molding of the resulting pre-alloyed powders into bulk samples, de-binding and sintering the samples to full density, and a final magneto-thermal treatment of the resulting bulk magnets, at Ames and Arnold Magnetic Technologies, to produce aligned magnets, which were intended for motor testing at UQM and Ford.

42 ENGINEERING↗

Bottom-Up Soft Magnetic Composites

In order to meet 2025 goals for enhanced peak power (100 kW), specific power (50 kW/L), and reduced cost (3.3 $/kW) in a motor that can operate at ≥ 20,000 rpm, improved soft magnetic materials must be developed. Better performing soft magnetic materials will also enable electric motors without rare earth elements. In fact, replacement of permanent magnets with soft magnetic materials was highlighted in the Electrical and Electronics Technical Team (EETT) Roadmap as a R&D pathway for meeting 2025 targets. Eddy current losses in conventional soft magnetic materials, such as silicon steel, begin to significantly impact motor efficiency as rotational speed is increased. Soft magnetic composites (SMCs), which combine magnetic particles with an insulating matrix to boost electrical resistivity (ρ) and decrease eddy current losses, even at higher operating frequencies (or rotational speeds), are an attractive solution. Today, SMCs are being fabricated with values of ρ ranging between 10 -3 to 10 -1 μohm∙m, which is significantly higher than 3% silicon steel (~0.5 μohm∙m). The isotropic nature of SMCs is ideally suited for motors with 3D flux paths, such as axial flux motors. Additionally, the manufacturing cost of SMCs is low and they are highly amenable to advanced manufacturing and net-shaping into complex geometries, which further reduces manufacturing costs. There is still significant room for advancement in SMCs, and therefore additional improvements in electrical machine performance. For example, despite the inclusion of a non-magnetic insulating material, the electrical resistivities of SMCs are still far below that of soft ferrites (10 – 10 8 μohm∙m).

36 MATERIALS SCIENCE↗

Measuring Fan-Blade-Tip Displacements

Magnets and Hall-effect transducers used to monitor tip-to-shroud clearances. Mounting permanent magnet in end of fan blade and monitoring tip-to-shroud distance by use of output of Hall-effect transducers affixed to surface of shroud. Transducers provide real-time information. By placing magnets in each fan-blade tip, complete set monitored sequentially as each blade rotates past sensor. Application in many rotating machines, providing surrounding materials nonmagnetic and temperatures not severe.

Berry, Robert F., Jr.↗

Design of a Microwave Assisted Discharge Inductive Plasma Accelerator

The design and construction of a thruster that employs electrodeless plasma preionization and pulsed inductive acceleration is described. Preionization is achieved through an electron cyclotron resonance discharge that produces a weakly-ionized plasma at the face of a conical theta pinch-shaped inductive coil. The presence of the preionized plasma allows for current sheet formation at lower discharge voltages than those employed in other pulsed inductive accelerators that do not employ preionization. The location of the electron cyclotron resonance discharge is controlled through the design of the applied magnetic field in the thruster. Finite element analysis shows that there is an arrangement of permanent magnets that yields a small volume of resonant magnetic field at the coil face. Preionization in the resonant zone leads to current sheet formation at the coil face, which minimizes the initial inductance of the pulse circuit and maximizes the potential electrical efficiency of the accelerator. A magnet assembly was constructed around an inductive coil to provide structural support to the selected arrangement of neodymium magnets. Measured values of the resulting magnetic field compare favorably with the finite element model.

Hallock, Ashley K.↗

Magnetic BiMn-α phase synthesis prediction: First-principles calculation, thermodynamic modeling and nonequilibrium chemical partitioning

BiMn-α is promising permanent magnet. Due to its peritectic formation feature, there is a synthetic challenge to produce single BiMn-α phase. The objective of this study is to assess driving force for crystalline phase pathways under far-from-equilibrium conditions. First-principles calculations with Hubbard U correction are performed to provide a robust description of the thermodynamic behavior. The energetics associated with various degrees of the chemical partitioning are quantified to predict temperature, magnetic field, and time dependence of the phase selection. By assessing the phase transformation under the influence of the chemical partitioning, temperatures, and cooling rate from our calculations, we suggest that it is possible to synthesize the magnetic BiMn-α compound in a congruent manner by rapid solidification. The external magnetic field enhances the stability of the BiMn-α phase. In conclusion, the compositions of the initial compounds from these highly driven liquids can be far from equilibrium.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Magnetic field control of microstructural development in melt-spun Pr 2 Co 14 B

In the processing of commercial rare earth permanent magnets, use of external magnetic fields is limited mainly to the alignment of anisotropic particles and the polarization of the finished magnets. Here we explore the effects of high magnetic fields on earlier stages of magnet synthesis, including the crystallization and chemical phase transformations that produce the 2:14:1 phase in the Pr-Co-B system. Pr 2 Co 14 B alloys produced by melt-spinning were annealed in the presence of strong applied magnetic fields (H=90 kOe). The resulting materials were characterized by x-ray diffraction, electron microscopy, and magnetization measurements. We find that magnetic fields suppress the nucleation and growth of crystalline phases, resulting in significantly smaller particle sizes. In addition, magnetic fields applied during processing strongly affects chemical phase selection, suppressing the formation of Pr 2 Co 14 B and α-Co in favor of Pr 2 Co 17 . Here, the results demonstrate that increased control over key microstructural properties is achievable by including a strong magnetic field as a processing parameter for rare-earth magnet materials.

36 MATERIALS SCIENCE↗

Metastable cobalt nitride structures with high magnetic anisotropy for rare-earth free magnets

Metastable structures of cobalt nitrides and Fe-substituted cobalt nitrides are explored as possible candidates for rare-earth free permanent magnets. Through crystal structure searches using an adaptive genetic algorithm, new structures of Co n N (n = 3…8) are found to have lower energies than those previously discovered by experiments. Some structures exhibit large magnetic anisotropy energy, reaching as high as 200 μeV per Co atom (or 2.45 MJ m -3 ) based on first-principles density functional calculation. Substituting a fraction of Co with Fe helps in stabilizing new structures and at the same time further improves the magnetic properties. Our theoretical predictions provide useful insights into a promising system for the discovery of new rare-earth free magnets by experiment.

Zhao, Xin↗

Microstructure and Hard Magnetic Properties of Sm 1-x Zr x (Fe,Co) 11.3-y Ti 0.7 By Ingots and Thick Melt-Spun Ribbons

Permanent magnets made from Sm(Fe,Co) 12 -based compounds are being actively pursued through nanostructuring and powder metallurgy. This study was aimed at the development of hard magnetic properties in bulk as-cast alloys and in melt-spun alloys for very low wheel speeds. Slower solidification rates and alloying with Zr promote the tetragonal ThMn 12 -type crystal structure, whereas higher solidification rates and alloying with B replace the ThMn 12 structure type with the TbCu 7 structure type. When introduced simultaneously, Zr and B dramatically reduce the alloy solidification rates required for both the refinement of the 1:12 crystallites and their replacement with the 1:7 phase. In bulk arc-melted alloys, this allowed for a microstructure of separated 1:12 crystallites 1–3 μm in size, although, because of the ferromagnetic nature of a minority phase, the coercivity of these fine-grained alloys reached only 0.73 kOe. A moderately accelerated solidification further refined the 1:12 crystallites and increased the coercivity; a Sm 0.7 Zr 0.4 (Fe,Co) 10.8 Ti 0.7 B 0.5 alloy exhibited a coercivity of 1.5 kOe and a maximum energy product of 3.4 MGOe when it was melt-spun into a 0.26-mm-thick ribbon. A more rapid solidification suppressed the 1:12 phase and after annealing at 800–850 °C, the alloys modified with Zr and B developed reasonably high coercivity and maximum energy product even when melt-spun at a wheel speed of 6 m/s. For the above-mentioned alloy, these values were 4.1 kOe and 7.8 MGOe, respectively. Further, a similarly processed very-Sm-lean Sm 0.5 Zr 0.6 (Fe,Co) 10.6 Ti 0.7 B 0.7 alloy exhibited a remanence of 8.8 kG and an energy product of 7.4 MGOe.

36 MATERIALS SCIENCE↗

Magnetic shielding in a low temperature torsion pendulum experiment

A new type of ether drift experiment searches for anomalous torques on a permanent magnet. A torsion pendulum is used at liquid helium temperature, so that superconducting cylinders can be used to shield magnetic fields. Lead shields attenuate the earth's field, while Nb-Sn shields fastened to the pendulum contain the fields of the magnet. The paper describes the technique by which the earth's field can be reduced below 0.0001 G while simultaneously the moment of the magnet can be reduced by a factor 7 x 10 to the 4th.

Phillips, P. R.↗

Magnetic Shield Design Modeling and Validation for SWOT Spacecraft Ka-Band Extended Interaction Klystron

Two Extended Interaction Klystrons (EIKs) containing strong permanent magnets were modeled magnetically in a representative spacecraft geometry using commercial finite element modeling techniques and were validated against measurements made at varying distances. Initial modeling results for the 63 A-m2 (amperes per square meter) dipole moment magnets showed that magnetic shields would be necessary in order to meet magnetic field requirements for the Surface Water and Ocean Topography (SWOT) spacecraft, which contains components that are susceptible to external DC (Direct Current) magnetic fields. JPL (Jet Propulsion Laboratory) and the EIK vendor proposed cold rolled steel and mu-metal as potential shield materials along with proposed thicknesses of 0.5 millimeters and 1.5 millimeters. Magnetic shields made from each of these materials were designed and modeled in software, taking high-field saturation into account. Prototype magnetic shields with these parameters were then built, measured with an existing EIK, and compared against modeling results. For single-axis field measurements along the dipole axis, modeling results were within 7 gauss of the measured values at 10 centimeters from the magnet, and converged to less than 1.5 gauss at distances greater than 14 centimeters from the magnet. Three-axis field measurements at locations of interest showed that model correlation improved to within 4 gauss at 11 centimeters and 2 gauss for distances ranging between 15 centimeters and 36 centimeters.

Gonzales, Edward↗

Magnetic Shield Design Modeling and Validation for SWOT Spacecraft Ka-Band Extended Interaction Klystron

Two Extended Interaction Klystrons (EIKs) containing strong permanent magnets were modeled magnetically in a representative spacecraft geometry using commercial finite element modeling techniques and were validated against measurements made at varying distances. Initial modeling results for the 63 A-m2 dipole moment magnets showed that magnetic shields would be necessary in order to meet magnetic field requirements for the Surface Water and Ocean Topography (SWOT) spacecraft, which contains components that are susceptible to external DC magnetic fields. JPL and the EIK vendor proposed cold rolled steel and mu-metal as potential shield materials along with proposed thicknesses of 0.5 mm and 1.5 mm. Magnetic shields made from each of these materials were designed and modeled in software, taking highfield saturation into account. Prototype magnetic shields with these parameters were then built, measured with an existing EIK, and compared against modeling results. For single-axis field measurements along the dipole axis, modeling results were within 7 gauss of the measured values at 10 cm from the magnet, and converged to less than 1.5 gauss at distances greater than 14 cm from the magnet. Three-axis field measurements at locations of interest showed that model correlation improved to within 4 gauss at 11 cm and 2 gauss for distances ranging between 15 cm and 36 cm.

Gonzales, Edward↗

TU-H-CAMPUS-TeP1-03: Magnetically Focused Proton Irradiation of Small Volume Radiosurgery Targets

Purpose: To investigate the use of magnetic focusing for small volume proton radiosurgery targets using a triplet combination of quadrupole rare earth permanent magnet Halbach cylinder assemblies Methods: Fourteen quadrupole magnets consisting of 24 segments of radiation hard samarium-cobalt adhered into k=3 Halbach cylinders with various field gradients (100 to 250 T/m) were designed and manufactured. Triplet combinations of the magnets were placed on a positioning track on our Gantry 1 treatment table. Unmodulated 127 MeV proton beams with initial diameters of 3 to 20 mm were delivered to a water tank using single-stage scattering. Depth and transverse dose distributions were measured using a PTW PR60020 diode detector and EBT3 film, respectively. This data was compared with unfocused passively collimated beams. Monte Carlo simulations were also performed - both for comparison with experimental data and to further investigate the potential of triplet magnetic focusing. Results: Experimental results using 150 T/m gradient magnets and 15 to 20 mm initial diameter beams show peak to entrance dose ratios that are ∼ 43 to 48 % larger compared with spot size matched 8 mm collimated beams (ie, transverse profile full-widths at 90% maximum dose match within 0.5 mm of focused beams). In addition, the focusing beams were ∼ 3 to 4.4 times more efficient per MU in dose to target delivery. Additional results using different magnet combinations will also be presented. Conclusion: Our results suggest that triplet magnetic focusing could reduce entrance dose and beam number while delivering dose to small (∼≤ 10 mm diameter) radiosurgery targets in less time compared to unfocused beams. Immediate clinical applications include those associated with proton radiosurgery and functional radiosurgery of the brain and spine, however other treatment sites can be also envisioned. This project was sponsored with funding from the Department of Defense (DOD# W81XWH-BAA-10-1).

60 APPLIED LIFE SCIENCES↗

Probing the electronic structure of buried interfaces via resonant scattering methods

Devices such as next-generation magnetic read heads demand energy storage capabilities and switching times beyond what is met by current permanent magnets. Superlattices of soft and hard ferromagnets (FM) that exhibit exchange-spring coupling are well-suited to be optimized for this purpose. Because of perovskites’ tunable properties from competing charge and spin degrees of freedom, one such system of interest is (001)-oriented La 0.7 Sr 0.3 CoO 3 (LSCO) capped with La 0.7 Sr 0.3 MnO 3 (LSMO). In the interfacial layers, FM moments are exchange-coupled strongly to each other, increasing overall coercivity. However, this system has subtleties that cannot be teased out in simple spin orientation models. In particular, growth mechanisms lead to rough interfaces and interlayer diffusion, which may drive a poorly understood phenomenon. The LSCO interfaces exhibit distinct magnetic properties from the bulk, possibly owing to an unexpected Co 2+ oxidation state near the LSMO that could lead to superexchange with Mn 4+ or possibly antiferromagnetism. Therefore the characterization of the electronic structure of interfaces is crucial to our understanding of the magnetic structure, but this is impossible with surface techniques, since most interfaces are buried, as well as spectroscopy, because the layers are similar in density. Specular x-ray reflectivity (SXR) is one method that describes layer thickness, density, and out-of-plane interface roughness of surfaces and buried interfaces. To characterize further, we apply SXR over absorption edges to increase Co/Mn contrast. Back-conversion to x-ray absorption near-edge structure (XANES) provides spectroscopic information on oxidation states that considers each sublayer separately, thereby determining how the sublayers couple.

36 MATERIALS SCIENCE↗

Flywheel energy storage. II - Magnetically suspended superflywheel

This article, the second of a two part paper, describes the general design requirements for a flywheel energy storage system. A new superflywheel energy storage system, using a spokeless, magnetically suspended, composite material pierced disk rotor is proposed. The new system is configured around a permanent magnet ('flux biased') magnetic suspension system with active control in the radial direction and passive control in the axial direction. The storage ring is used as a moving rotor and electronic commutation of stationary armature coils is proposed. There is no mechanical contact with the rotating ring and long life and low run down losses are projected. A discussion of major components for a 10 kwh system is presented.

Kirk, J. A.↗

Design of a Microwave Assisted Discharge Inductive Plasma Accelerator

A new plasma accelerator concept that employs electrodeless plasma preionization and pulsed inductive acceleration is presented. Preionization is achieved through an electron cyclotron resonance discharge that produces a weakly-ionized plasma at the face of a conical theta pinch-shaped inductive coil. The presence of the preionized plasma allows for current sheet formation at lower discharge voltages than those found in other pulsed inductive accelerators. The location of an electron cyclotron resonance discharge can be controlled through the design of the applied magnetic field in the thruster. A finite-element model of the magnetic field was used as a design tool, allowing for the implementation of an arrangement of permanent magnets that yields a small volume of preionized propellant at the coil face. This allows for current sheet formation at the face of the inductive coil, minimizing the initial inductance of the pulse circuit and maximizing the potential efficiency of the new accelerator.

Hallock, Ashley K.↗

A Medium Frequency RF Sensor for Detection of Magnetized Quark Nuggets

It is hypothesized that dark matter is composed of particles called quark nuggets, and further that these particles have a permanent magnetic dipole moment. If this hypothesis is true, calculations predict that a magnetized quark nugget (MQN) will oscillate when encountering the Earth's magnetosphere, and emit RF radiation between 30kHz and 30MHz. To support testing this hypothesis, a loop antenna sensor was designed and developed, which is described in this report. This sensor operates between 300kHz and 3MHz and achieves about -11dBfT/vHz sensitivity at 1.5MHz.

42 ENGINEERING↗

ORNL researchers repurpose rare earth magnets in electric engine

In work funded by the Department of Energy's Critical Materials Institute, ORNL researchers are demonstrating how rare earth permanent magnets can be harvested from used computer disk drives and repurposed in an axial gap motor. Learn more: https://www.ornl.gov/news/magnets-coming-around-again.

36 MATERIALS SCIENCE↗