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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 973 records · Page 54
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Formulation of Three-Phase State Estimation Problem Using a Virtual Reference

State Estimation (SE) is the backbone of modern Energy Management System (EMS) due its capability of processing real time measurements and provide reliable information to system operators. Since its introduction to power systems in the 70’s, SE has been widely used in transmission networks. Distribution grids on the other hand lack sufficient number of real time measurements, and for that reason SE has not been widely implemented on these systems. The recent increase in the number of renewable energy sources connected to the grid at lower voltage levels, the advent of Distribution Automation (DA) and Smart Grids necessitate closer monitoring of distribution networks and thus forcing utilities to upgrade their operations and deploy Advanced Distribution Management Sytems (ADMS). Therefore, Distribution System State Estimation (DSE) is paramount to provide real time monitoring of active distribution grids. This papers investigates the formulation of the three-phase distribution state estimation where in the most general case, none of the system buses may have balanced three phase voltages. In such a case, the choice and definition of the slack bus need to be revisited. Most of the existing work arbitrarily assign the root bus of the distribution feeder as the balanced three-phase reference which may not be realistic for today’s active distribution systems. This paper addresses this shortcoming of the existing SE formulations by introducing a virtual reference bus. Here, the proposed approach is effectively validated by simulations carried out on distribution test systems.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2015

Kinetic theory of phase space plateaux in a non-thermal energetic particle distribution

The transformation of kinetically unstable plasma eigenmodes into hole-clump pairs with temporally evolving carrier frequencies was recently attributed to the emergence of an intermediate stage in the mode evolution cycle, that of an unmodulated plateau in the phase space distribution of fast particles. The role of the plateau as the hole-clump breeding ground is further substantiated in this article via consideration of its linear and nonlinear stability in the presence of fast particle collisions and sources, which are known to affect the production rates and subsequent frequency sweeping of holes and clumps. In particular, collisional relaxation, as mediated by e.g. velocity space diffusion or even simple Krook-type collisions, is found to inhibit hole-clump generation and detachment from the plateau, as it should. On the other hand, slowing down of the fast particles turns out to have an asymmetrically destabilizing/stabilizing effect, which explains the well-known result that collisional drag enhances holes and their sweeping rates but suppresses clumps. It is further demonstrated that relaxation of the plateau edge gradients has only a minor quantitative effect and does not change the plateau stability qualitatively, unless the edge region extends far into the plateau shelf and the corresponding Landau pole needs to be taken into account.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1980

Conditional sampling technique to test the applicability of the Taylor hypothesis for the large-scale coherent structures

Comparisons of the distributions of large scale structures in turbulent flow with distributions based on time dependent signals from stationary probes and the Taylor hypothesis are presented. The study investigated an area in the near field of a 7.62 cm circular air jet at a Re of 32,000, specifically having coherent structures through small-amplitude controlled excitation and stable vortex pairing in the jet column mode. Hot-wire and X-wire anemometry were employed to establish phase averaged spatial distributions of longitudinal and lateral velocities, coherent Reynolds stress and vorticity, background turbulent intensities, streamlines and pseudo-stream functions. The Taylor hypothesis was used to calculate spatial distributions of the phase-averaged properties, with results indicating that the usage of the local time-average velocity or streamwise velocity produces large distortions.

Hussain, A. K. M. F.↗
DOE OSTI2013

Actively triggered 4d cone-beam CT acquisition

Purpose: 4d cone-beam computed tomography (CBCT) scans are usually reconstructed by extracting the motion information from the 2d projections or an external surrogate signal, and binning the individual projections into multiple respiratory phases. In this “after-the-fact” binning approach, however, projections are unevenly distributed over respiratory phases resulting in inefficient utilization of imaging dose. To avoid excess dose in certain respiratory phases, and poor image quality due to a lack of projections in others, the authors have developed a novel 4d CBCT acquisition framework which actively triggers 2d projections based on the forward-predicted position of the tumor.Methods: The forward-prediction of the tumor position was independently established using either (i) an electromagnetic (EM) tracking system based on implanted EM-transponders which act as a surrogate for the tumor position, or (ii) an external motion sensor measuring the chest-wall displacement and correlating this external motion to the phase-shifted diaphragm motion derived from the acquired images. In order to avoid EM-induced artifacts in the imaging detector, the authors devised a simple but effective “Faraday” shielding cage. The authors demonstrated the feasibility of their acquisition strategy by scanning an anthropomorphic lung phantom moving on 1d or 2d sinusoidal trajectories.Results: With both tumor position devices, the authors were able to acquire 4d CBCTs free of motion blurring. For scans based on the EM tracking system, reconstruction artifacts stemming from the presence of the EM-array and the EM-transponders were greatly reduced using newly developed correction algorithms. By tuning the imaging frequency independently for each respiratory phase prior to acquisition, it was possible to harmonize the number of projections over respiratory phases. Depending on the breathing period (3.5 or 5 s) and the gantry rotation time (4 or 5 min), between ∼90 and 145 projections were acquired per respiratory phase resulting in a dose of ∼1.7–2.6 mGy per respiratory phase. Further dose savings and decreases in the scanning time are possible by acquiring only a subset of all respiratory phases, for example, peak-exhale and peak-inhale only scans.Conclusions: This study is the first experimental demonstration of a new 4d CBCT acquisition paradigm in which imaging dose is efficiently utilized by actively triggering only those projections that are desired for the reconstruction process.

61 RADIATION PROTECTION AND DOSIMETRY↗
DOE OSTI2013

Distribution change of oxygen vacancies in layered perovskite type(Sr, La){sub n+1}Fe{sub n}O{sub 3n+1} (n=3)

To elucidate characteristic oxygen vacancy formation in layered perovskite (Sr, La){sub n+1}Fe{sub n}O{sub 3n+1} with the perovskite layer number: n=3, oxygen vacancy content δ of the (Sr{sub 0.775}La{sub 0.225}){sub 4}Fe{sub 3}O{sub 10−δ} (SLF4310) was investigated using a titration technique and a thermogravimetric analysis. The equilibrium constant K for the reduction reaction: Oo{sup ×}+2Fe{sub Fe}{sup ∙} (Fe{sup 4+})=1/2O{sub 2}+Vo{sup ∙∙}+2Fe{sub Fe}{sup ×}(Fe{sup 3+}) was estimated using the vacancy content δ. The Arrhenius plot of the K reveals slope change at approximately 775 °C. From the Rietveld analysis, the oxygen vacancies are the most remarkable at the O2 (O4) sites at lower (higher) temperatures than about 800 °C, which temperature is approximately comparable with that of slope change in the K. These facts mean that distribution of vacancy sites in the SLF4310 changes at approximately 775 °C, accompanying no structural phase transition. The vacancy distribution change affects to the ion conductivity of the SLF4310. - Graphical abstract: Crystal structure of (Sr{sub 0.775}La{sub 0.225}){sub 4}Fe{sub 3}O{sub 10−δ} (SLF4310) at 1000 °C. Display Omitted - Highlights: • Distribution change of oxygen vacancies is appeared at approximately 775 °C. • The distribution change with no structure phase transition is the first observation. • The vacancy distribution change affects the ion conductivity of the SLF4310.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1985

Structure of nonevaporating sprays. I - Initial conditions and mean properties

Structure measurements were completed within the dilute portion of axisymmetric nonevaporating sprays. Measurements included: mean velocities, velocity fluctuations, and Reynolds stress of the gas phase; and mean velocities, fluctuating velocities, mass flux, and diameter distributions of the drop phase. The measurements were used to evaluate three typical methods of analyzing sprays: (1) a locally homogeneous flow (LHF) analysis, where slip between the phases is neglected; (2) a deterministic separated flow (DSF) analysis, where slip is considered but effects of drop interactions with turbulence are ignored; and (3) a stochastic separated flow (SSF) analysis, where effects of both slip and turbulence are considered using random-walk computations for drop motion. Measurements of initial conditions of both phases near the injector, mean gas-phase properties, and liquid flux distributions are described herein. Best agreement between predictions and measurements was obtained with the SSF model, which provided a reasonable representation of turbulent dispersion of drops. A companion paper presents additional measurements of drop continuous phase properties.

Solomon, A. S. P.↗
DOE OSTI2016

Vacancy structures and melting behavior in rock-salt GeSbTe

Ge-Sb-Te alloys have been widely used in optical/electrical memory storage. Because of the extremely fast crystalline-amorphous transition, they are also expected to play a vital role in next generation nonvolatile microelectronic memory devices. However, the distribution and structural properties of vacancies have been one of the key issues in determining the speed of melting (or amorphization), phase-stability, and heat-dissipation of rock-salt GeSbTe, which is crucial for its technological breakthrough in memory devices. Using spherical aberration-aberration corrected scanning transmission electron microscopy and atomic scale energy-dispersive X-ray mapping, we observe a new rock-salt structure with high-degree vacancy ordering (or layered-like ordering) at an elevated temperature, which is a result of phase transition from the rock-salt phase with randomly distributed vacancies. First-principles calculations reveal that the phase transition is an energetically favored process. Furthermore, molecular dynamics studies suggest that the melting of the cubic rock-salt phases is initiated at the vacancies, which propagate to nearby regions. The observation of multi-rock-salt phases suggests another route for multi-level data storage using GeSbTe.

36 MATERIALS SCIENCE↗
NASA NTRS2007

SPOT-VEG Based Analysis of Siberian Silkmoth Outbreak

The spatial and temporal dynamics of an outbreak of the Siberian silkmoth were correlated with topographic features of the affected area using SPOT-VEG data and a high resolution digital elevation model (DEM). In 2002-2003 an outbreak affected approximately 20,000 ha in the South Siberian mountains of Russia. The outbreak began between the elevations of approximately 430- 480 m and on southwest slopes with steepness < 5 degrees. As the pest searched for food it moved up and down slope, resulting in an elevation distribution split within a range of approximately 390-540 m and slope steepness up to 15 degrees. In the final phase the azimuth distribution of damaged stands became even. The correlation between the initial phase and topographic features can be used to prioritize monitoring forest areas most vulnerable to destruction by pests.

Kharuk, Viatcheslav I.↗
DOE OSTI2018

Element Distribution in the Silicomanganese Production Process

A pilot scale, silicomanganese alloy production campaign was performed in a 440 kVA, single phase electric furnace in order to establish an overview of the minor- and trace element contents in process input raw materials and their distribution in the resulting primary and secondary products. Samples of the in-going raw materials (manganese ore, coke, quartzite, and high carbon ferromanganese slag) and the out-going products (silicomanganese alloy, silicomanganese slag, and dust) were analyzed by inductively coupled plasma mass spectrometry. The distribution of 51 elements between the product phases was discussed in terms of their boiling temperatures, Gibbs energies of oxidation and activity coefficients of elements in the metal. A thermochemical simulation using the thermochemical software FactSage 7.1 was also carried out in order to model element phase distribution between the alloy, slag, and dust/gas. The correlation between the model and experimental element concentrations in the silicomanganese slag and dust is fair for most elements. However, in the metal phase, fewer elements show good correlation between modeled results and measured experimental concentrations. The discrepancy could be explained by a lack of accurate thermodynamic descriptions for several minor species in the database.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Computational design and performance prediction of creep-resistant ferritic superalloys

Ferritic superalloys containing the B2 phase with the parent L21 phase precipitates in a disordered solid-solution matrix, also known as a hierarchical-precipitate-strengthened ferritic alloy (HPSFA), had been developed for high-temperature structural applications in fossil-energy power plants. These alloys were designed by adding Ti into a previously-studied NiAl-strengthened ferritic alloy (denoted as FBB8 in this study). Following with the concept of HPSFAs, in the present research, a systematic investigation on adding other elements, such as Hf and Zr, and optimizing the Ti content within the alloy system, has been conducted, in order to further improve the creep resistance of the model alloys. Studies include advanced experimental techniques, first-principles calculations on thermodynamic and mechanical properties, and numerical simulations on precipitation hardening, have been integrated and conducted to characterize the complex microstructures and excellent creep resistance of alloys. The experimental techniques include transmission-electron microscopy (TEM), scanning-electron microscopy (SEM), neutron diffraction (ND), and atom-probe tomography (APT), which provide the detailed microstructural information of the model alloys. Systematic tension/compression creep tests have also been conducted in order to verify the creep resistance of the potential alloy compositions. The results show that when replacing Ti with Hf and Zr, it does not form the L21 phase. Instead, the hexagonal Laves phase forms and distributes majorly along the grain boundary, or large segregation within grains. Since the Laves phase does not form parent to the B2-phase precipitates, it cannot bring the strengthening effect of HPSFAs. As a result, the FBB8 + 2 wt. % Hf and FBB8 + 2 wt. % Zr alloys have similar mechanical properties to the original FBB8. The FBB8 + Ti series alloys had also been studied, from the creep tests and microstructural characterizations, the FBB8 + 3.5 wt.% Ti possesses the greatest creep resistance, with the L21/B2 phase ratio of 4 (80% of the precipitates is the L21 phase, and 20% is the B2 phase). First-principles calculations include thermodynamics, elastic properties, and interfacial properties, which have been conducted for the understanding of the thermodynamic and mechanical properties of HPSFAs. In addition to the systematic experimental approach and first-principles calculations, a series of numerical tools and algorithms, which assist in the optimization of creep properties of ferritic superalloys, are utilized and developed. These numerical simulation results are compared with the available experimental data and previous first-principles calculations, providing the deep insight of creep mechanisms of the creep-resistant ferritic superalloys. To conclude the present research, we’ve found that (1) only FBB8 + Ti alloys have the potential of forming HPSFA, and FBB8 + Hf and FBB8 + Zr do not work. Therefore, only FBB8 + Ti alloys have desirable creep resistance, (2) the optimum composition for the FBB8 + Ti alloys is FBB8 + 3.5% Ti, which has the greatest creep resistance (218.8 MPa as the threshold stress at 700 oC), (3) first-principle calculations obtained results that could not be obtained in experiments, which are relevant to develop ferritic superalloys with the improved creep resistance, and (4) two-dimensional dislocation-dynamics simulations investigate effects of factors like precipitate volume fractions and precipitate radii in the alloy systems, which helps in developing the most desirable microstructure with greatest strengthening.

20 FOSSIL-FUELED POWER PLANTS↗
NASA NTRS1992

Phase partitioning experiment (8-IML-1)

Phase partitioning is a method of separating biological cells and macromolecules via their differential distribution in two phase aqueous polymer solutions. The ultimate goal of the experiment is to test the hypothesis that the efficiency of separation of closely related cell types, by partitioning in immiscible aqueous phases, will be enhanced in the non-convective environment provided by space. Before a cell separation experiment can be performed, the demixing of immiscible aqueous polymer solutions must be understood and controlled in order to optimize the experimental conditions for a cell separation experiment in the future. The present Phase Partitioning Experiment (PPE) is the third in a series, the first two flew on STS 51-D in Apr. 1985 and STS 26 in Oct. 1988. In those experiments the immiscible aqueous phases demixed spontaneously at different rates, the final disposition being one in which the phase which wetted the container wall surrounded the second phase which formed an 'egg yolk' in the center of the chamber.

Brooks, Donald E.↗
DOE OSTI2015

Parallel Harmony Search Based Distributed Energy Resource Optimization

This paper presents a harmony search based parallel optimization algorithm to minimize voltage deviations in three phase unbalanced electrical distribution systems and to maximize active power outputs of distributed energy resources (DR). The main contribution is to reduce the adverse impacts on voltage profile during a day as photovoltaics (PVs) output or electrical vehicles (EVs) charging changes throughout a day. The IEEE 123- bus distribution test system is modified by adding DRs and EVs under different load profiles. The simulation results show that by using parallel computing techniques, heuristic methods may be used as an alternative optimization tool in electrical power distribution systems operation.

Ceylan, Oguzhan↗
DOE OSTI2025

Simultaneous Absorption and Desorption Isotherms of Various Hydrogen and Deuterium Mixtures between 20 and 120 °C Are Used to Determine the Activity Coefficients for Palladium-Hydride Solutions

A test bed was constructed to measure the absorption and desorption isotherms for palladium hydride using H 2 , D 2 , and various H 2 /D 2 mixtures for temperatures in the range 20 °C ≤ T ≤ 120 °C. The pressure–composition–temperature isotherms were measured. The pressures obtained with mixtures between each pure isotope were monotonic, yet nonlinear. This nonlinear dependence of total pressure with feed gas protium concentration reveals the mixed isotope hydride system behaves nonideally. A thermodynamic model was adapted from the literature, which accounts for the nonideal nature of the mixed-isotope system. The measured data were used as constraints in this model in order to calculate the protium mole fractions in the hydride phase and the protium activity coefficients for palladium hydride at various temperatures and protium concentrations in the system. Knowing the protium mole fraction and activity coefficients allows for a priori calculation of the isotopologue distribution in the gas phase and the isotope distribution in the hydride phase, given a palladium temperature and equilibrium pressure.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2011

Partitioning of Nanoparticles into Organic Phases and Model Cells

There is a recognized need to understand and predict the fate, transport and bioavailability of engineered nanoparticles (ENPs) in aquatic and soil ecosystems. Recent research focuses on either collection of empirical data (e.g., removal of a specific NP through water or soil matrices under variable experimental conditions) or precise NP characterization (e.g. size, degree of aggregation, morphology, zeta potential, purity, surface chemistry, and stability). However, it is almost impossible to transition from these precise measurements to models suitable to assess the NP behavior in the environment with complex and heterogeneous matrices. For decades, the USEPA has developed and applies basic partitioning parameters (e.g., octanol-water partition coefficients) and models (e.g., EPI Suite, ECOSAR) to predict the environmental fate, bioavailability, and toxicity of organic pollutants (e.g., pesticides, hydrocarbons, etc.). In this project we have investigated the hypothesis that NP partition coefficients between water and organic phases (octanol or lipid bilayer) is highly dependent on their physiochemical properties, aggregation, and presence of natural constituents in aquatic environments (salts, natural organic matter), which may impact their partitioning into biological matrices (bioaccumulation) and human exposure (bioavailability) as well as the eventual usage in modeling the fate and bioavailability of ENPs. In this report, we use the terminology "partitioning" to operationally define the fraction of ENPs distributed among different phases. The mechanisms leading to this partitioning probably involve both chemical force interactions (hydrophobic association, hydrogen bonding, ligand exchange, etc.) and physical forces that bring the ENPs in close contact with the phase interfaces (diffusion, electrostatic interactions, mixing turbulence, etc.). Our work focuses on partitioning, but also provides insight into the relative behavior of ENPs as either "more like dissolved substances" or "more like colloids" as the division between behaviors of macromolecules versus colloids remains ill-defined. Below we detail our work on two broadly defined objectives: (i) Partitioning of ENP into octanol, lipid bilayer, and water, and (ii) disruption of lipid bilayers by ENPs. We have found that the partitioning of NP reaches pseudo-equilibrium distributions between water and organic phases. The equilibrium partitioning most strongly depends on the particle surface charge, which leads us to the conclusion that electrostatic interactions are critical to understanding the fate of NP in the environment. We also show that the kinetic rate at which particle partition is a function of their size (small particles partition faster by number) as can be predicted from simple DLVO models. We have found that particle number density is the most effective dosimetry to present our results and provide quantitative comparison across experiments and experimental platforms. Cumulatively, our work shows that lipid bilayers are a more effective organic phase than octanol because of the definable surface area and ease of interpretation of the results. Our early comparison of NP partitioning between water and lipids suggest that this measurement can be predictive of bioaccumulation in aquatic organisms. We have shown that nanoparticle disrupt lipid bilayer membranes and detail how NP-bilayer interaction leads to the malfunction of lipid bilayers in regulating the fluxes of ionic charges and molecules. Our results show that the disruption of the lipid membranes is similar to that of toxin melittin, except single particles can disrupt a bilayer. We show that only a single particle is required to disrupt a 150 nm DOPC liposome. The equilibrium leakage of membranes is a function of the particle number density and particle surface charge, consistent with results from our partitioning experiments. Our disruption experiments with varying surface functionality show that positively charged particles (poly amine) are most disruptive, consistent with in in vitro toxicity panels using cell cultures. Overall, this project has resulted in 8 published or submitted archival papers and has been presented 12 times. We have trained five students and provided growth opportunities for a postdoc.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1989

Systems analysis for DSN microwave antenna holography

Proposed systems for Deep Space Network (DSN) microwave antenna holography are analyzed. Microwave holography, as applied to antennas, is a technique which utilizes the Fourier Transform relation between the complex far-field radiation pattern of an antenna and the complex aperture field distribution to provide a methodology for the analysis and evaluation of antenna performance. Resulting aperture phase and amplitude distribution data are used to precisely characterize various crucial performance parameters, including panel alignment, subreflector position, antenna aperture illumination, directivity at various frequencies, and gravity deformation. Microwave holographic analysis provides diagnostic capacity as well as being a powerful tool for evaluating antenna design specifications and their corresponding theoretical models.

Rochblatt, D. J.↗
NASA NTRS2020

Automated Identification and Differentiation of Spectrally Similar Hydrothermal Minerals on Mars

Early telescopic observations corroborated hydration related absorptions on Mars in the infrared. Images from the Viking missions led to speculation of hydrothermal alteration and were followed by two missions which mapped the spatial variability of the ~ 3 μm hydration feature. Since then, the Compact Reconnaissance Imager for Mars (CRISM) has provided high spatial resolution (up to 18m) spectral identification of a suite of hydrothermal and diagenetic minerals which have illuminated a range of formation mechanisms. Presence/absence and spatial segregation or mixing of minerals like prehnite, epidote, chlorite amphiboles, and mixed-layer Fe/Mg smectite-chlorite provide valuable evidence for the geologic setting of deposits on Earth, and these phases are often used as temperature and aqueous chemistry indicators in terrestrial systems. Mapping the distribution of these phases will help to answer whether Mars had widespread conditions favorable for low-grade metamorphism and diagenesis, or only focused hydrothermal systems in areas of high heat flow. Further characterizing the chemistry and structure of these phases will then help to answer how most of the widespread Fe/Mg phyllosilicates formed, further defining early geochemical cycling and climate. A fully automated approach for accurate mapping of important hydrothermal mineral phases on Mars has been a challenge. Due to overlapping features in the M-OH region (~2.2-2.4 μm), the strongest absorption features of chlorite, prehnite, and epidote in the short-wave infrared are difficult to distinguish from one another and from the most commonly occurring hydrated silicates on Mars, Fe/Mg smectites. Weaker absorptions are present in both prehnite and epidote which help to distinguish them from chlorite and smectites, but their relative strength in the presence of noise and spatial mixing is often too low to confidently identify them without the noise suppression and feature enhancement methods described here. The spectral signatures of mixed-layer Fe/Mg smectite-chlorite and partially chloritized Fe/Mg smectites have not yet been adequately assessed. Here we evaluate the effectiveness of two empirical and statistical methods for identifying and differentiating these phases using CRISM data.

Rasmussen, B. P.↗
DOE OSTI2022

BattPhase—A Convergent, Non-Oscillatory, Efficient Algorithm and Code for Predicting Shape Changes in Lithium Metal Batteries Using Phase-Field Models: Part I. Secondary Current Distribution

Electrochemical models at different scales and varying levels of complexity have been used in the literature to study the evolution of the anode surface in lithium metal batteries. This includes continuum, mesoscale (phase-field approaches), and multiscale models. Thermodynamics-based equations have been used to study phase changes in lithium batteries using phase-field approaches. However, grid convergence studies and the effect of additional parameters needed to simulate these models are not well-documented in the literature. In this paper, using a motivating example of a moving boundary model in one- and two-dimensions, we show how one can formulate phase-field models, implement algorithms for the same and analyze the results. An open-access code with no restrictions is provided as well. This article concludes with some thoughts on the computational efficiency of phase-field models for simulating dendritic growth.

25 ENERGY STORAGE↗