Stress Engineering for Mitigating Thermal Cycling Fatigue in Perovskite Photovoltaics
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14 SOLAR ENERGY↗
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Results for “Power conversion efficiency”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Energy Selects
In this work, we present a few key highlights from our editorial advisory board members. They discuss three articles published recently in ACS Energy Letters. These articles discuss major advances in designing advanced energy storage systems and perovskite photovoltaic modules. The importance of designing solid electrolytes and efforts to overcome the challenges in aqueous Zn batteries are also presented.
25 ENERGY STORAGE↗
Compliant and stretchable thermoelectric coils for energy harvesting in miniature flexible devices
With accelerating trends in miniaturization of semiconductor devices, techniques for energy harvesting become increasingly important, especially in wearable technologies and sensors for the internet of things. Although thermoelectric systems have many attractive attributes in this context, maintaining large temperature differences across the device terminals and achieving low–thermal impedance interfaces to the surrounding environment become increasingly difficult to achieve as the characteristic dimensions decrease. Here, we propose and demonstrate an architectural solution to this problem, where thin-film active materials integrate into compliant, open three-dimensional (3D) forms. This approach not only enables efficient thermal impedance matching but also multiplies the heat flow through the harvester, thereby increasing the efficiencies for power conversion. Interconnected arrays of 3D thermoelectric coils built using microscale ribbons of monocrystalline silicon as the active material demonstrate these concepts. Quantitative measurements and simulations establish the basic operating principles and the key design features. The results suggest a scalable strategy for deploying hard thermoelectric thin-film materials in harvesters that can integrate effectively with soft materials systems, including those of the human body.
42 ENGINEERING↗
Semiconductor Quantum Dots for Applications to Advanced Concepts for Solar Photon Conversion to Electricity and Solar Fuels
The challenge of photoconversion research is to produce photovoltaic electricity at costs much less than those based on fossil fuels. Novel photoactive semiconductors and molecules of various types and structures are discussed for this purpose.
14 SOLAR ENERGY↗
Compact microwave mixer has high conversion efficiency
Compact, lightweight microwave mixer has a relatively high conversion efficiency and power output. The mixer employs a pair of back-to-back voltage-variable capacitors in a stripline network.
Penque, N. J.↗
Preliminary design of reactor power systems for the manned space base.
The results of design integration studies of uranium-zirconium hydride (UZr-Hx) reactor power systems for the NASA space base study program are presented. The power conversion systems investigated include the Brayton cycle, the organic Rankine cycle, the SNAP-8 mercury Rankine cycle, and thermoelectric (PbTe). The proposed space base has a 10-year life and requires 100 kWe of power. Two 50-kWe power systems with a nominal replacement life of 5 years are utilized. Parametric design data such as life, weight, radiator area, reactor outlet-temperature, reactor thermal power, and power conversion system efficiency are presented and used for the design and integration of the system with the space base.
Mckhann, G. G.↗
Nickel-doped silicon for solar cells
Large grain boundaries in polycrystals act as gettering centers for nickel precipitates, improving cell performance. Effects are described in report. Data on open-circuit voltage, short-circuit current, maximum power, and conversion efficiency for illuminated cells are compared with values for undoped cells. Dark forward current versus voltage is also measured for cell types.
Salama, A. M.↗
The theory of an auto-resonant field emission cathode relativistic electron accelerator for high efficiency microwave to direct current power conversion
A novel method of microwave power conversion to direct current is discussed that relies on a modification of well known resonant linear relativistic electron accelerator techniques. An analysis is presented that shows how, by establishing a 'slow' electromagnetic field in a waveguide, electrons liberated from an array of field emission cathodes, are resonantly accelerated to several times their rest energy, thus establishing an electric current over a large potential difference. Such an approach is not limited to the relatively low frequencies that characterize the operation of rectennas, and can, with appropriate waveguide and slow wave structure design, be employed in the 300 to 600 GHz range where much smaller transmitting and receiving antennas are needed.
Manning, Robert M.↗
Lightweight, Efficient Power Converters for Advanced Turboelectric Aircraft Propulsion Systems
NASA is investigating advanced turboelectric aircraft propulsion systems that use superconducting motors to drive multiple distributed turbofans. Conventional electric motors are too large and heavy to be practical for this application; therefore, superconducting motors are required. In order to improve aircraft maneuverability, variable-speed power converters are required to throttle power to the turbofans. The low operating temperature and the need for lightweight components that place a minimum of additional heat load on the refrigeration system open the possibility of incorporating extremely efficient cryogenic power conversion technology. This Phase II project is developing critical components required to meet these goals.
Hennessy, Michael J.↗
NASA Glenn Research Center Support of the Advanced Stirling Radioisotope Generator Project
A high-efficiency radioisotope power system was being developed for long-duration NASA space science missions. The U.S. Department of Energy (DOE) managed a flight contract with Lockheed Martin Space Systems Company to build Advanced Stirling Radioisotope Generators (ASRGs), with support from NASA Glenn Research Center. DOE initiated termination of that contract in late 2013, primarily due to budget constraints. Sunpower, Inc., held two parallel contracts to produce Advanced Stirling Convertors (ASCs), one with Lockheed Martin to produce ASC-F flight units, and one with Glenn for the production of ASC-E3 engineering unit "pathfinders" that are built to the flight design. In support of those contracts, Glenn provided testing, materials expertise, Government-furnished equipment, inspection capabilities, and related data products to Lockheed Martin and Sunpower. The technical support included material evaluations, component tests, convertor characterization, and technology transfer. Material evaluations and component tests were performed on various ASC components in order to assess potential life-limiting mechanisms and provide data for reliability models. Convertor level tests were conducted to characterize performance under operating conditions that are representative of various mission conditions. Despite termination of the ASRG flight development contract, NASA continues to recognize the importance of high-efficiency ASC power conversion for Radioisotope Power Systems (RPS) and continues investment in the technology, including the continuation of the ASC-E3 contract. This paper describes key Government support for the ASRG project and future tests to be used to provide data for ongoing reliability assessments.
Technology Transfer↗
An Autonomous Robot for Shell and Tube Heat Exchanger Inspection
Shell and tube heat exchangers (STHEs) are critical to energy conversion efficiency of power plants. Eddy current examination is a way to evaluate working conditions of these tubes. However, the current testing apparatus requires human to manually insert an eddy current testing (ECT) probe into and extract it out of individual tubes, and meanwhile monitor measurement results for diagnosis. It is a time-consuming and labor-intensive procedure even for an experienced technician. To tackle this challenge, in this work, we developed a robot enabled ECT system for autonomous inspection of STHEs. The robotic platform employs Mecanum wheeled chassis for high mobility, machine vision to locate tube bundle and tube inlets, a rotational Cartesian mechanism to operate at planes with all possible inclinations, and a task-specific mechanism for ECT probe delivery. Machine vision locates tube bundle and tube inlets by an April tag detection algorithm and a Circle Hough Transform (CHT) algorithm, respectively. Assisted by a guidance cone, the ECT probe is continuously fed into the tubes with a fill factor of 0.819. During this process, the eddy current data are automatically collected and real-time analyzed by convolutional neural networks (CNN), showing accuracy of nearly 100% for identifying defective and non-defective tubes and 85% for four types of defective tubes and non-defective tubes.
autonomy, deep learning, eddy current testing, hea↗
Thermocouple-tip-exposing temperature assessment technique for evaluating photothermal conversion efficiency of plasmonic nanoparticles at low laser power density
A new thermocouple (TC) tip-exposing temperature assessment technique that combines experimental temperature measurements with a numerical model of the photothermal conversion efficiency η is presented. The proposed technique is designed to evaluate η for a gold-coated superparamagnetic iron oxide nanoparticle (SPIO-Au NP) solution (26 nm, 12–70 ppm) at low continuous wave laser power (103 mW, 532 nm) irradiation in a convenient manner under ambient conditions. The TC tip temperature is measured during the first 30 s of the laser exposure, and the results are combined with a finite element model to simulate the temperature rise of the NP solution for a given concentration. The value of η is adjusted in the model until the model agrees with the measured transient TC temperature rise. Values of η = 1.00 were observed for all concentrations. Theoretical predictions of η derived by Mie theory confirmed the near unity conversion efficiency of the as-synthesized SPIO-Au NPs. Advantages of the current technique include co-locating the TC tip in the geometric center of the laser-heated region, rather than outside of this region. In addition, the technique can be done under ambient room conditions using unmodified commercially available hardware.
Numerical methods↗
Silicon Carbide Radioisotope Batteries
The substantial radiation resistance and large bandgap of SiC semiconductor materials makes them an attractive candidate for application in a high efficiency, long life radioisotope battery. To evaluate their potential in this application, simulated batteries were constructed using SiC diodes and the alpha particle emitter Americium Am-241 or the beta particle emitter Promethium Pm-147. The Am-241 based battery showed high initial power output and an initial conversion efficiency of approximately 16%, but the power output decayed 52% in 500 hours due to radiation damage. In contrast the Pm-147 based battery showed a similar power output level and an initial conversion efficiency of approximately 0.6%, but no degradation was observed in 500 hours. However, the Pm-147 battery required approximately 1000 times the particle fluence as the Am-242 battery to achieve a similar power output. The advantages and disadvantages of each type of battery and suggestions for future improvements will be discussed.
Rybicki, George C.↗
Fabrication of Very High Efficiency 5.8 GHz Power Amplifiers using AlGaN HFETs on SiC Substrates for Wireless Power Transmission
For wireless power transmission using microwave energy, very efficient conversion of the DC power into microwave power is extremely important. Class E amplifiers have the attractive feature that they can, in theory, be 100% efficient at converting, DC power to RF power. Aluminum gallium nitride (AlGaN) semiconductor material has many advantageous properties, relative to silicon (Si), gallium arsenide (GaAs), and silicon carbide (SiC), such as a much larger bandgap, and the ability to form AlGaN/GaN heterojunctions. The large bandgap of AlGaN also allows for device operation at higher temperatures than could be tolerated by a smaller bandgap transistor. This could reduce the cooling requirements. While it is unlikely that the AlGaN transistors in a 5.8 GHz class E amplifier can operate efficiently at temperatures in excess of 300 or 400 C, AlGaN based amplifiers could operate at temperatures that are higher than a GaAs or Si based amplifier could tolerate. Under this program, AlGaN microwave power HFETs have been fabricated and characterized. Hybrid class E amplifiers were designed and modeled. Unfortunately, within the time frame of this program, good quality HFETs were not available from either the RSC laboratories or commercially, and so the class E amplifiers were not constructed.
Sullivan, Gerry↗
Spectral splitting optimization for high-efficiency solar photovoltaic and thermal power generation
Utilizing the full solar spectrum is desirable to enhance the conversion efficiency of a solar power generator. In practice, this can be achieved through spectral splitting between multiple converters in parallel. However, it is unclear which wavelength bands should be directed to each converter in order to maximize the efficiency. We developed a model of an ideal hybrid solar converter which utilizes both a single-junction photovoltaic cell and a thermal engine. We determined the limiting efficiencies of this hybrid strategy and the corresponding optimum spectral bandwidth directed to the photovoltaic cell. This optimum width is inversely proportional to the thermal engine efficiency and scales with the bandgap of the photovoltaic cell. This bandwidth was also obtained analytically through an entropy minimization scheme and matches well with our model. We show that the maximum efficiency of the system occurs when it minimizes the spectral entropy generation. This concept can be extended to capture generalized non-idealities to increase the usefulness of this technique for a range of full solar spectrum utilization technologies.
14 SOLAR ENERGY↗
Parametric generation in a PPLN crystal pumped by a Q-switched mode-locked Nd : YAG laser: comparison of the superluminescent and singly resonant operation regimes
The output characteristics of light in two parametric generation regimes [parametric superluminescence and parametric generation in a singly resonant optical parametric oscillator (OPO) based on a 50-mm long PPLN crystal, synchronously pumped by a 50-ps Nd : YAG laser] are compared. The total average output power at the wavelengths of signal (λ = 1475 nm) and idler (λ = 3820 nm) waves in the superluminescence regime is ∼120 mW (peak power ∼120 kW). The maximum total conversion efficiency with respect to the absorbed power in the superluminescence regime is ∼60%. The maximum conversion efficiency into the idler wave with respect to the absorbed pump power is 15% and 25% (quantum efficiencies of 54% and 90%) for the superluminescence and singly resonant OPO regimes, respectively. The maximum values of the average output power at the idler wavelength are ∼30 and ∼60 mW at degrees of pump depletion of 47% and 55% for the superluminescence and singly resonant OPO regimes, respectively. (paper)
71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
Comprehensive energy balance analysis of photon-enhanced thermionic power generation considering concentrated solar absorption distribution
The present article reports a comprehensive energy balance analysis of a photon-enhanced thermionic emission (PETE) device when it is used for concentrated solar power (CSP) generation. To this end, we consider a realistic PETE device composed of a boron-doped silicon emitter on glass and a phosphorus-doped diamond collector on tungsten separated by the interelectrode vacuum gap. Here, depth-dependent spectral solar absorption and its photovoltaic and photothermal energy conversion processes are rigorously calculated to predict the PETE power output and energy conversion efficiency. Our calculation predicts that when optimized, the power output of the considered PETE device can reach 1.6 W/cm 2 with the energy conversion efficiency of ~ 18% for 100× solar concentration, which is substantially lower than those predicted in previous works under ideal conditions. In addition, the photon-enhancement ratio is lower than 10 and decreases with the increasing solar concentration due to the photothermal heating of the emitter assembly, suggesting that PETE should be more suitable for lowto- medium CSP below ~ 100× concentration. These observations signify the importance of a rigorous energy balance analysis based on spectral and spatial solar absorption distribution for the accurate prediction of PETE power generation.
14 SOLAR ENERGY↗
ZrCoBi based half Heuslers with high thermoelectric conversion efficiency
A method of thermoelectric power generation by converting heat to electricity via the use of a ZrCoBi-based thermoelectric material, wherein a thermoelectric conversion efficiency of the ZrCoBi-based thermoelectric material is greater than or equal to 7% at a temperature difference of up to 800 K.
Ren, Zhifeng↗