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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 973 records · Page 54

Ultrafast Triplet Pair Separation and Triplet Trapping following Singlet Fission in Amorphous Pentacene Films

In this work, ultrafast infrared and electronic spectroscopy are used to examine the dynamics of triplet pair separation following singlet fission in amorphous and crystalline films of the model singlet fission chromophore, 6,13-bis(triisopropylsilylethynyl)pentacene (TIPS-Pn). Direct probing of correlated triplet pair intermediates through their unique vibrational frequencies, infrared electronic transitions, and indirectly through their visible triplet absorptions reveals that triplet pair separation occurs on similar picosecond timescales in both amorphous and crystalline films despite their markedly different average intermolecular coupling strengths. Although triplet pair separation occurs on similar timescales in both environments, measurements of diffusion-controlled triplet-triplet annihilation reveal that the diffusivity of triplet excited states is an order of magnitude lower in amorphous films. The data reveal the presence of sparse triplet traps in the amorphous environment that inhibit the transport of triplet excitons in comparison to crystalline films. These observations inform recent efforts to develop disordered and polymeric singlet fission sensitizers that contain amorphous regions. In particular, the data suggest that it may be possible to nanostructure amorphous or polymeric singlet fission sensitizers to allow ultrafast triplet pair separation and harvesting in photovoltaic and light emitting applications despite their low triplet exciton diffusivity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Search for R-parity-violating supersymmetry in a final state containing leptons and many jets with the ATLAS experiment using $\sqrt{s}=13\hbox{TeV}$ proton–proton collision data

A search for R-parity-violating supersymmetry in final states characterized by high jet multiplicity, at least one isolated light lepton and either zero or at least three b-tagged jets is presented. The search uses 139fb –1 of $\sqrt{s}=13\hbox{TeV}$ proton–proton collision data collected by the ATLAS experiment during Run 2 of the Large Hadron Collider. The results are interpreted in the context of R-parity-violating supersymmetry models that feature gluino production, top-squark production, or electroweakino production. The dominant sources of background are estimated using a data-driven model, based on observables at medium jet multiplicity, to predict the b-tagged jet multiplicity distribution at the higher jet multiplicities used in the search. Machine-learning techniques are used to reach sensitivity to electroweakino production, extending the data-driven background estimation to the shape of the machine-learning discriminant. No significant excess over the Standard Model expectation is observed and exclusion limits at the 95% confidence level are extracted, reaching as high as 2.4 TeV in gluino mass, 1.35 TeV in top-squark mass, and 320 (365) GeV in higgsino (wino) mass.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Astrophysical tests of modified gravity: Constraints from distance indicators in the nearby universe

We use distance measurements in the nearby universe to carry out new tests of gravity, surpassing other astrophysical tests by over two orders of magnitude for chameleon theories. The three nearby distance indicators—cepheids, tip of the red giant branch (TRGB) stars, and water masers—operate in gravitational fields of widely different strengths. This enables tests of scalar-tensor gravity theories because they are screened from enhanced forces to different extents. Inferred distances from cepheids and TRGB stars are altered (in opposite directions) over a range of chameleon gravity theory parameters well below the sensitivity of cosmological probes. Using published data, we have compared cepheid and TRGB distances in a sample of unscreened dwarf galaxies within 10 Mpc. We use a comparable set of screened galaxies as a control sample. We find no evidence for the order unity force enhancements expected in these theories. Using a two-parameter description of the models (the coupling strength and background field value), we obtain constraints on both the chameleon and symmetron screening scenarios. In particular we show that f(R) models with background field values f {sub R0} above 5 × 10{sup –7} are ruled out at the 95% confidence level. We also compare TRGB and maser distances to the galaxy NGC 4258 as a second test for larger field values. While there are several approximations and caveats in our study, our analysis demonstrates the power of gravity tests in the local universe. We discuss the prospects for additional improved tests with future observations.

79 ASTRONOMY AND ASTROPHYSICS↗

Discovering $\mu$Hz gravitational waves and ultra-light dark matter with binary resonances

In the presence of a weak gravitational wave (GW) background, astrophysical binary systems act as high-quality resonators, with efficient transfer of energy and momentum between the orbit and a harmonic GW leading to potentially detectable orbital perturbations. In this work, we develop and apply a novel modeling and analysis framework that describes the imprints of GWs on binary systems in a fully time-resolved manner to study the sensitivity of lunar laser ranging, satellite laser ranging, and pulsar timing to both resonant and nonresonant GW backgrounds. We demonstrate that optimal data collection, modeling, and analysis lead to projected sensitivities which are orders of magnitude better than previously appreciated possible, opening up a new possibility for probing the physics-rich but notoriously challenging to access $\mu\mathrm{Hz}$ frequency GWs. We also discuss improved prospects for the detection of the stochastic fluctuations of ultra-light dark matter, which may analogously perturb the binary orbits.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Analytic Sensitivity Coefficients for General Multigroup Infinite Medium k-Eigenvalue Problems

The general multigroup infinite medium k-eigenvalue neutron transport equation is used to derive analytic expressions for the infinite medium k-eigenvalue, the scalar neutron flux and adjoint, and the sensitivity of $k$ ∞ to perturbations in the multigroup nuclear data of a single species isotropic elastic scattering material. In the appendix, we present the multigroup nuclear data for U-235 and U-238 along with the corresponding k-eigenvalue, flux, adjoint, and sensitivity profiles, which include the sensitivity of $k$ ∞ to the total, fission, capture, and scattering macroscopic cross sections as well as to the group-to-group scattering cross section matrix, group neutron production, and the unconstrained and constrained fission neutron energy distribution.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

The 21-SPONGE H i absorption survey. I. Techniques and initial results

We present methods and results from “21 cm Spectral Line Observations of Neutral Gas with the EVLA” (21-SPONGE), a large survey for Galactic neutral hydrogen (H i) absorption with the Karl G. Jansky Very Large Array (VLA). With the upgraded capabilities of the VLA, we reach median rms noise in optical depth of σ{sub τ}=9×10{sup −4} per 0.42 km s{sup −1} channel for the 31 sources presented here. Upon completion, 21-SPONGE will be the largest H i absorption survey with this high sensitivity. We discuss the observations and data reduction strategies, as well as line fitting techniques. We prove that the VLA bandpass (BP) is stable enough to detect broad, shallow lines associated with warm H i, and we show that BP observations can be combined in time to reduce spectral noise. In combination with matching H i emission profiles from the Arecibo Observatory (∼3.′5 angular resolution), we estimate excitation (or spin) temperatures (T{sub s}) and column densities for Gaussian components fitted to sightlines along which we detect H i absorption (30/31). We measure temperatures up to T{sub s}∼1500 K for individual lines, showing that we can probe the thermally unstable interstellar medium (ISM) directly. However, we detect fewer of these thermally unstable components than expected from previous observational studies. We probe a wide range in column density between ∼10{sup 16} and >10{sup 21} cm{sup −2} for individual H i clouds. In addition, we reproduce the trend between cold gas fraction and average T{sub s} found by the Kim et al. synthetic observations of a hydrodynamic ISM simulation. Finally, we compare methods for estimating T{sub s} using H i observations.

79 ASTRONOMY AND ASTROPHYSICS↗

Final Report for SERDP Project RC-1649: Advanced Chemical Measurements of Smoke from DoD-prescribed Burns

Objectives: Project RC-1649, “Advanced Chemical Measurement of Smoke from DoD-prescribed Burns” was undertaken to use advanced instrumental techniques to study in detail the particulate and vapor-phase chemical composition of the smoke that results from prescribed fires used as a land management tool on DoD bases, particularly bases in the southeastern U.S. The statement of need (SON) called for “(1) improving characterization of fuel consumption” and “(2) improving characterization of air emissions under both flaming and smoldering conditions with respect to volatile organic compounds, heavy metals, and reactive gases.” The measurements and fuels were from several bases throughout the southeast (Camp Lejeune, Ft. Benning, and Ft. Jackson) and were carried out in collaboration and conjunction with projects 1647 (models) and 1648 (particulates, SW bases). Technical Approach: We used an approach that featured developing techniques for measuring biomass burning emission species in both the laboratory and field and developing infrared (IR) spectroscopy in particular. Using IR spectroscopy and other methods, we developed emission factors (EF, g of effluent per kg of fuel burned) for dozens of chemical species for several common southeastern fuel types. The major measurement campaigns were laboratory studies at the Missoula Fire Sciences Laboratory (FSL) as well as field campaigns at Camp Lejeune, NC, Ft. Jackson, SC, and in conjunction with 1648 at Vandenberg AFB, and Ft. Huachuca. Comparisons and fusions of laboratory and field data were also carried out, using laboratory fuels from the same bases. Results: The project enabled new technologies and furthered basic science, mostly in the area of infrared spectroscopy, a broadband method well suited to biomass burn studies. Advances in hardware, software and supporting reference data realized a nearly 20x improvement in sensitivity and now provide quantitative IR spectra for potential detection of ~60 new species and actual field quantification of several new species such as nitrous acid, glycolaldehyde, α-/β-pinene and D-limonene. The new reference data also permit calculation of the global warming potential (GWP) of the greenhouse gases by enabling 1) detection of their ambient concentrations, and 2) quantifying their ability to absorb IR radiation.

47 OTHER INSTRUMENTATION↗

RINGFINDER: Automated detection of galaxy-scale gravitational lenses in ground-based multi-filter imaging data

We present RINGFINDER, a tool for finding galaxy-scale strong gravitational lenses in multi-band imaging data. By construction, the method is sensitive to configurations involving a massive foreground ETG and a faint, background, blue source. RINGFINDER detects the presence of blue residuals embedded in an otherwise smooth red light distribution by difference imaging in two bands. The method is automated for efficient application to current and future surveys, having originally been designed for the 150 deg{sup 2} Canada-France-Hawaii Telescope Legacy Survey (CFHTLS). We describe each of the steps of RINGFINDER. We then carry out extensive simulations to assess completeness and purity. For sources with magnification μ > 4, RINGFINDER reaches 42% (25%) completeness and 29% (86%) purity before (after) visual inspection. The completeness of RINGFINDER is substantially improved in the particular range of Einstein radii 0.''8 ≤ R {sub Ein} ≤ 2.''0 and lensed images brighter than g = 22.5, where it can be as high as ∼70%. RINGFINDER does not introduce any significant bias in the source or deflector population. We conclude by presenting the final catalog of RINGFINDER CFHTLS galaxy-scale strong lens candidates. Additional information obtained with Hubble Space Telescope and Keck adaptive optics high-resolution imaging, and with Keck and Very Large Telescope spectroscopy, is used to assess the validity of our classification and measure the redshift of the foreground and the background objects. From an initial sample of 640,000 ETGs, RINGFINDER returns 2500 candidates, which we further reduce by visual inspection to 330 candidates. We confirm 33 new gravitational lenses from the main sample of candidates, plus an additional 16 systems taken from earlier versions of RINGFINDER. First applications are presented in the Strong Lensing Legacy Survey galaxy-scale lens sample paper series.

79 ASTRONOMY AND ASTROPHYSICS↗

Aerosol responses to precipitation along North American air trajectories arriving at Bermuda

North American pollution outflow is ubiquitous over the western North Atlantic Ocean, especially in winter, making this location a suitable natural laboratory for investigating the impact of precipitation on aerosol particles along air mass trajectories. We take advantage of observational data collected at Bermuda to seasonally assess the sensitivity of aerosol mass concentrations and volume size distributions to accumulated precipitation along trajectories (APT). The mass concentration of particulate matter with aerodynamic diameter less than 2.5 µm normalized by the enhancement of carbon monoxide above background (PM 2.5 /ΔCO) at Bermuda was used to estimate the degree of aerosol loss during transport to Bermuda. Results for December–February (DJF) show that most trajectories come from North America and have the highest APTs, resulting in a significant reduction (by 53 %) in PM 2.5 /ΔCO under high-APT conditions (> 13.5 mm) relative to low-APT conditions (< 0.9 mm). Moreover, PM 2.5 /ΔCO was most sensitive to increases in APT up to 5 mm (–0.044 µg m –3 ppbv –1 mm –1 ) and less sensitive to increases in APT over 5 mm. While anthropogenic PM 2.5 constituents (e.g., black carbon, sulfate, organic carbon) decrease with high APT, sea salt, in contrast, was comparable between high- and low-APT conditions owing to enhanced local wind and sea salt emissions in high-APT conditions. The greater sensitivity of the fine-mode volume concentrations (versus coarse mode) to wet scavenging is evident from AErosol RObotic NETwork (AERONET) volume size distribution data. A combination of GEOS-Chem model simulations of the 210 Pb submicron aerosol tracer and its gaseous precursor 222 Rn reveals that (i) surface aerosol particles at Bermuda are most impacted by wet scavenging in winter and spring (due to large-scale precipitation) with a maximum in March, whereas convective scavenging plays a substantial role in summer; and (ii) North American 222 Rn tracer emissions contribute most to surface 210 Pb concentrations at Bermuda in winter (~75 %–80 %), indicating that air masses arriving at Bermuda experience large-scale precipitation scavenging while traveling from North America. A case study flight from the ACTIVATE field campaign on 22 February 2020 reveals a significant reduction in aerosol number and volume concentrations during air mass transport off the US East Coast associated with increased cloud fraction and precipitation. These results highlight the sensitivity of remote marine boundary layer aerosol characteristics to precipitation along trajectories, especially when the air mass source is continental outflow from polluted regions like the US East Coast.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

VLA-ANGST: A HIGH-RESOLUTION H I SURVEY OF NEARBY DWARF GALAXIES

We present the 'Very Large Array survey of Advanced Camera for Surveys Nearby Galaxy Survey Treasury galaxies (VLA-ANGST)'. VLA-ANGST is a National Radio Astronomy Observatory Large Program consisting of high spectral (0.6-2.6 km s{sup -1}) and spatial ({approx}6'') resolution observations of neutral, atomic hydrogen (H I) emission toward 35 nearby dwarf galaxies from the ANGST survey. ANGST is a systematic Hubble Space Telescope survey to establish a legacy of uniform multi-color photometry of resolved stars for a volume-limited sample of nearby galaxies (D {approx}< 4 Mpc). VLA-ANGST provides VLA H I observations of the sub-sample of ANGST galaxies with recent star formation that are observable from the northern hemisphere and that were not observed in the 'The H I Nearby Galaxy Survey' (THINGS). The overarching scientific goal of VLA-ANGST is to investigate fundamental characteristics of the neutral interstellar medium (ISM) of dwarf galaxies. Here we describe the VLA observations, the data reduction, and the final VLA-ANGST data products. We present an atlas of the integrated H I maps, the intensity-weighted velocity fields, the second moment maps as a measure for the velocity dispersion of the H I, individual channel maps, and integrated H I spectra for each VLA-ANGST galaxy. We closely follow the observational setup and data reduction of THINGS to achieve comparable sensitivity and angular resolution. A major difference between VLA-ANGST and THINGS, however, is the high velocity resolution of the VLA-ANGST observations (0.65 and 1.3 km s{sup -1} for the majority of the galaxies). The VLA-ANGST data products are made publicly available through a dedicated Web site (https://science.nrao.edu/science/surveys/vla-angst). With available star formation histories from resolved stellar populations and lower resolution ancillary observations from the far-infrared to the ultraviolet, VLA-ANGST will enable detailed studies of the relationship between the ISM and star formation in dwarf galaxies on a {approx}100 pc scale.

79 ASTRONOMY AND ASTROPHYSICS↗

BEBOP II: sensitivity to sub-Saturn circumbinary planets using radial-velocities

ABSTRACT BEBOP is a radial-velocity survey that monitors a sample of single-lined eclipsing binaries, in search of circumbinary planets by using high-resolution spectrographs. Here, we describe and test the methods we use to identify planetary signals within the BEBOP data and establish how we quantify our sensitivity to circumbinary planets by producing detection limits. This process is made easier and more robust by using a diffusive nested sampler. In the process of testing our methods, we notice that contrary to popular wisdom, assuming circular orbits in calculating detection limits for a radial-velocity survey provides overoptimistic detection limits by up to $40{{\ \rm per\ cent}}$ in semi-amplitude with implications for all radial-velocity surveys. We perform example analyses using three BEBOP targets from our Southern HARPS survey. We demonstrate for the first time a repeated ability to reach a residual root mean squared scatter of $3\, \rm m\, s^{-1}$ (after removing the binary signal), and find that we are sensitive to circumbinary planets with masses down to that of Neptune and Saturn, for orbital periods up to $1000\, \rm d$.

Standing, Matthew R. (ORCID:0000000276088905)↗

Advanced Interactive 3D Visualization Tool for Customizable Analyses of Tomography Datasets in Material Science

Current methods for visualizing and analyzing 3D tomography datasets in materials science often lack the interactivity and depth required for detailed structural insights. This limitation restricts a researchers' ability to accurately interpret complex data, which is critical for advancing material innovations and understanding structural properties. To address this issue, we have developed a novel, web-based interactive 3D visualization and analysis tool from the Trame framework that offers customizable features to enhance data interpretability. The tool allows users to adjust parameters such as visible range, slice planes, data rotation, and layering, providing a more detailed and dynamic view of complex structures. Its user-friendly web interface increases the accessibility and ease of use for both novice and experienced researchers, to visualize large volumetric datasets. The tool supports a diverse range of data formats, making it versatile for various research applications. Unique capabilities include real-time data manipulation, automated feature detection, context-sensitive feedback, and real-time volume calculations and distributions per sliced region or layer, alongside the ability to quickly generate high-quality screenshots and videos for presentations and reports. These advancements offer a comprehensive solution for enhanced 3D data exploration, significantly improving the analysis process and communication of results in materials science.

36 - MATERIALS SCIENCE↗

Heavy neutrino searches through double-bang events at Super-Kamiokande, DUNE, and Hyper-Kamiokande

A variety of new physics scenarios allows for neutrinos to up-scatter into a heavy neutral lepton state. For a range of couplings and neutrino energies, the heavy neutrino may travel some distance before decaying to visible final states. When both the up-scattering and decay occur within the detector volume, these “double bang” events produce distinctive phenomenology with very low background. In this work, we first consider the current sensitivity at Super-Kamiokande via the atmospheric neutrino flux, and find current data may already provide new constraints. We then examine projected future sensitivity at DUNE and Hyper-Kamiokande, including both atmospheric and beam flux contributions to double-bang signals.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Rate-equation modelling and ensemble approach to extraction of parameters for viral infection-induced cell apoptosis and necrosis

We develop a theoretical approach that uses physiochemical kinetics modelling to describe cell population dynamics upon progression of viral infection in cell culture, which results in cell apoptosis (programmed cell death) and necrosis (direct cell death). Several model parameters necessary for computer simulation were determined by reviewing and analyzing available published experimental data. By comparing experimental data to computer modelling results, we identify the parameters that are the most sensitive to the measured system properties and allow for the best data fitting. Our model allows extraction of parameters from experimental data and also has predictive power. Using the model we describe interesting time-dependent quantities that were not directly measured in the experiment and identify correlations among the fitted parameter values. Numerical simulation of viral infection progression is done by a rate-equation approach resulting in a system of “stiff” equations, which are solved by using a novel variant of the stochastic ensemble modelling approach. The latter was originally developed for coupled chemical reactions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

TwinMe4AD: WGAN-based Digital Twins for Anomaly Detection

SAND2024-08373O TwinMe4AD is a Python-based software tool designed for anomaly detection using digital twins that closely mimic real, wearable healthcare datasets. The tool is invaluable for scenarios where collecting data is either expensive or impractical, serving as a privacy-preserving solution. Sensitive information is protected by training deep learning models on synthetic data derived from real datasets. One of TwinMe4AD's key features is its anomaly detection capability, which is based on fourth-order moments of parameters. This versatile approach can be applied across a range of datasets, from univariate to multivariate, making it compatible with various types of data. It also generates synthetic twins using Wasserstein Generative Adversarial Networks (WGANs), allowing users to create a small cohort of a population similar to that of a village population. Sandia National Laboratories is a multimission laboratory managed and operated by National Technology & Engineering Solutions of Sandia, LLC, a wholly owned subsidiary of Honeywell International Inc., for the U.S. Department of Energy’s National Nuclear Security Administration under contract DE-NA0003525.

Poorey, Kunal↗

Investigation of cluster structure of {sup 9}Be from high precision elastic scattering data

The cluster structure of {sup 9}Be has been investigated through high precision elastic scattering cross-section measurements of a {sup 9}Be + {sup 208}Pb system at below barrier energies, E= 24-34 MeV.The observed deviation from the Rutherford scattering can only be explained by an n + {sup 8}Be cluster description of {sup 9}Be, whereas the {alpha} + {sup 5}He cluster picture fails to explain the measured data, indicating the dominance of the n + {sup 8}Be cluster structure of {sup 9}Be. In addition to sequential and direct breakup, the coupling effect of one neutron stripping on elastic scattering is significant even at 10 MeV below the barrier. The sensitivity of the high precision elastic scattering data to the cluster structure of {sup 9}Be has been demonstrated.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

A Synoptic VLBI Technique for Localizing Nonrepeating Fast Radio Bursts with CHIME/FRB

We demonstrate the blind interferometric detection and localization of two fast radio bursts (FRBs) with subarcminute precision on the 400 m baseline between the Canadian Hydrogen Intensity Mapping Experiment (CHIME) and the CHIME Pathfinder. In the same spirit as Very Long Baseline Interferometry (VLBI), the telescopes were synchronized to separate clocks, and the channelized voltage (herein referred to as baseband) data were saved to a disk with correlation performed offline. The simultaneous wide field of view and high sensitivity required for blind FRB searches implies a high data rate—6.5 terabits per second (Tb/s) for CHIME and 0.8 Tb s{sup −1} for the Pathfinder. Since such high data rates cannot be continuously saved, we buffer data from both telescopes locally in memory for ≈40 s, and write to the disk upon receipt of a low-latency trigger from the CHIME Fast Radio Burst Instrument (CHIME/FRB). The ≈200 deg{sup 2} field of view of the two telescopes allows us to use in-field calibrators to synchronize the two telescopes without needing either separate calibrator observations or an atomic timing standard. In addition to our FRB observations, we analyze bright single pulses from the pulsars B0329+54 and B0355+54 to characterize systematic localization errors. Our results demonstrate the successful implementation of key software, triggering, and calibration challenges for CHIME/FRB Outriggers: cylindrical VLBI outrigger telescopes which, along with the CHIME telescope, will localize thousands of single FRB events with sufficient precision to unambiguously associate a host galaxy with each burst.

47 OTHER INSTRUMENTATION↗