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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 973 records · Page 54

Optimizing performance and yield of vertical GaN diodes using wafer scale optical techniques

Abstract To improve the manufacturing of vertical GaN devices for power electronics applications, the effects of defects in GaN substrates need to be better understood. Many non-destructive techniques including photoluminescence, Raman spectroscopy and optical profilometry, can be used to detect defects in the substrate and epitaxial layers. Raman spectroscopy was used to identify points of high crystal stress and non-uniform conductivity in a substrate, while optical profilometry was used to identify bumps and pits in a substrate which could cause catastrophic device failures. The effect of the defects was studied using vertical P-i-N diodes with a single zone junction termination extention (JTE) edge termination and isolation, which were formed via nitrogen implantation. Diodes were fabricated on and off of sample abnormalities to study their effects. From electrical measurements, it was discovered that the devices could consistently block voltages over 1000 V (near the theoretical value of the epitaxial layer design), and the forward bias behavior could consistently produce on-resistance below 2 mΩ cm 2 , which is an excellent value considering DC biasing was used and no substrate thinning was performed. It was found that high crystal stress increased the probability of device failure from 6 to 20%, while an inhomogeneous carrier concentration had little effect on reverse bias behavior, and slightly (~ 3%) increased the on-resistance (R on ). Optical profilometry was able to detect regions of high surface roughness, bumps, and pits; in which, the majority of the defects detected were benign. However a large bump in the termination region of the JTE or a deep pit can induce a low voltage catastrophic failure, and increased crystal stress detected by the Raman correlated to the optical profilometry with associated surface topography.

42 ENGINEERING↗

A self-consistent and spatially dependent model of the multiband emission of pulsar wind nebulae

A self-consistent and spatially dependent model is presented to investigate the multiband emission of pulsar wind nebulae (PWNe). In this model, a spherically symmetric system is assumed and the dynamical evolution of the PWN is included. The processes of convection, diffusion, adiabatic loss, radiative loss, and photon–photon pair production are taken into account in the electron’s evolution equation, and the processes of synchrotron radiation, inverse Compton scattering, synchrotron self-absorption, and pair production are included for the photon’s evolution equation. Both coupled equations are simultaneously solved. The model is applied to explain observed results of the PWN in MSH 15–52. Our results show that the spectral energy distributions (SEDs) of both electrons and photons are all a function of distance. The observed photon SED of MSH 15–52 can be well reproduced in this model. With the parameters obtained by fitting the observed SED, the spatial variations of photon index and surface brightness observed in the X-ray band can also be well reproduced. Moreover, it can be derived that the present-day diffusion coefficient of MSH 15–52 at the termination shock is κ{sub 0}=6.6×10{sup 24} cm{sup 2} s{sup −1}, the spatial average has a value of κ-bar =1.4×10{sup 25} cm{sup 2} s{sup −1}, and the present-day magnetic field at the termination shock has a value of B{sub 0}=26.6 μG and the spatial averaged magnetic field is B-bar =14.9 μG. The spatial changes of the spectral index and surface brightness at different bands are predicted.

79 ASTRONOMY AND ASTROPHYSICS↗

Optical fiber tactile sensor

A tactile sensor comprises an array of cells which are covered by an elastic membrane, having an exposed surface which is adapted to come in contact with an object. Light is conducted to each cell from a light source by an optical fiber which terminates at the cell. Reflected light from the cell is conducted by an optical fiber to a light processor, which senses changes in the light received thereby from an ambient level whenever an object comes in contact with the membrane surface above the cell.

Bejczy, A. K.↗

Laser Polishing: Green Path to Improved Accelerator Surfaces

We pursued three paths toward reducing the initial cost and operating expense of particle accelerators. First, we investigated laser surface melting as an alternative to the present cavity processing approach using noxious chemicals. We successfully demonstrated a process that can be scaled up and defined the path to do so. Second, we sought to develop tailored laser pulsing as a way to simulate the thermal fatigue environment responsible for damaging accelerator components. Though the first three steps along the path were successfully accomplished, the final segment depended on collaborators with unique facilities, whose program was terminated. The third segment aimed to acquire a fundamental understanding of the widely used chemical process that yields the rough surfaces smoothed by laser melting. We found that the roughness is an inherent and unavoidable outcome that limits the performance of components processed thusly.

43 PARTICLE ACCELERATORS↗

Mechanistic Studies of Chain Termination and Monomer Absorption in Molecular Layer Deposition

Here, molecular layer deposition (MLD) is of growing interest as a vapor-phase method for depositing ultrathin polymeric films. The amount of material deposited per cycle of MLD is believed to be strongly dependent on the number of available surface reaction sites. However, the factors that alter the number of reactive sites during cycling have not been well understood. In this work, we provide concrete evidence that although chain termination reactions may reduce the number of reaction sites, the adsorption or absorption of monomers allows for the introduction of new reaction sites. These absorbed monomers are strongly bound to the film and allow the films to recover from growth defects introduced by chain terminations. A mathematical model for growth is developed and suggests that these absorptions eventually lead to the characteristic steady-state growth rate seen for MLD processes. Fits of the model to the experimental data for polyurea MLD indicate that ~3% of the chains experience termination events during each cycle at steady state, with any given chain having an ≈50% chance to be terminated before reaching 22 cycles; this termination is then compensated for by uptake of new monomers. Together, these results indicate that typical MLD growth involves the continuous occurrence of termination reactions and the renucleation of chains within the film via the absorption of monomers.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The role of double TiO 2 layers at the interface of FeSe/SrTiO 3 superconductors

We determine the surface reconstruction of SrTiO 3 used to achieve superconducting FeSe films in experiments, which is different from the 1×1 TiO 2 -terminated SrTiO 3 assumed by most previous theoretical studies. In particular, we identify the existence of a double TiO 2 layer at the FeSe/SrTiO 3 interface that plays two important roles. First, it facilitates the epitaxial growth of FeSe. Second, ab initio calculations reveal a strong tendency for electrons to transfer from an oxygen deficient SrTiO 3 surface to FeSe when the double TiO 2 layer is present. The double layer helps to remove the hole pocket in the FeSe at the Γ point of the Brillouin zone and leads to a band structure characteristic of superconducting samples. The characterization of the interface structure presented here is a key step towards the resolution of many open questions about this superconductor.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Origin of hydroxyl pair formation on reduced anatase TiO 2 (101)

The interaction of water with metal oxide surfaces is of key importance to several research fields and applications. Because of its ability to photo-catalyze water splitting, reducible anatase TiO 2 (a-TiO 2 ) is of particular interest. Here, we combine experiments and theory to study the dissociation of water on bulk-reduced a-TiO 2 (101). Following large water exposures at room temperature, point-like protrusions appear on the a-TiO 2 (101) surface, as shown by scanning tunneling microscopy (STM). These protrusions originate from hydroxyl pairs, consisting of terminal and bridging OH groups, OH t /OH b , as revealed by infrared reflection absorption spectroscopy (IRRAS) and valence band experiments. Utilizing density functional theory (DFT) calculations, we offer a comprehensive model of the water/a-TiO 2 (101) interaction. In conclusion, this model also explains why the hydroxyl pairs are thermally stable up to ~480 K.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Structural and functional insights into the interaction between the bacteriophage T4 DNA processing proteins gp32 and Dda

Abstract Bacteriophage T4 is a classic model system for studying the mechanisms of DNA processing. A key protein in T4 DNA processing is the gp32 single-stranded DNA-binding protein. gp32 has two key functions: it binds cooperatively to single-stranded DNA (ssDNA) to protect it from nucleases and remove regions of secondary structure, and it recruits proteins to initiate DNA processes including replication and repair. Dda is a T4 helicase recruited by gp32, and we purified and crystallized a gp32–Dda–ssDNA complex. The low-resolution structure revealed how the C-terminus of gp32 engages Dda. Analytical ultracentrifugation analyses were consistent with the crystal structure. An optimal Dda binding peptide from the gp32 C-terminus was identified using surface plasmon resonance. The crystal structure of the Dda–peptide complex was consistent with the corresponding interaction in the gp32–Dda–ssDNA structure. A Dda-dependent DNA unwinding assay supported the structural conclusions and confirmed that the bound gp32 sequesters the ssDNA generated by Dda. The structure of the gp32–Dda–ssDNA complex, together with the known structure of the gp32 body, reveals the entire ssDNA binding surface of gp32. gp32–Dda–ssDNA complexes in the crystal are connected by the N-terminal region of one gp32 binding to an adjacent gp32, and this provides key insights into this interaction.

Biochemistry & Molecular Biology↗

Polyhedral 3D structure of human plasma very low density lipoproteins by individual particle cryo-electron tomography

Human VLDLs assembled in the liver and secreted into the circulation supply energy to peripheral tissues. VLDL lipolysis yields atherogenic LDLs and VLDL remnants that strongly correlate with CVD. Although the composition of VLDL particles has been well-characterized, their 3D structure is elusive because of their variations in size, heterogeneity in composition, structural flexibility, and mobility in solution. Here, we employed cryo-electron microscopy and individual-particle electron tomography to study the 3D structure of individual VLDL particles (without averaging) at both below and above their lipid phase transition temperatures. The 3D reconstructions of VLDL and VLDL bound to antibodies revealed an unexpected polyhedral shape, in contrast to the generally accepted model of a spherical emulsion-like particle. The smaller curvature of surface lipids compared with HDL may also reduce surface hydrophobicity, resulting in lower binding affinity to the hydrophobic distal end of the N-terminal β-barrel domain of cholesteryl ester transfer protein (CETP) compared with HDL. The directional binding of CETP to HDL and VLDL may explain the function of CETP in transferring TGs and cholesteryl esters between these particles. This first visualization of the 3D structure of VLDL could improve our understanding of the role of VLDL in atherogenesis.

59 BASIC BIOLOGICAL SCIENCES↗

Phase and amplitude scintillations at 9.6 GHz on an elevated path

Deep fading, e.g., greater than 40 dB, was observed at 9.6 GHz on a 150 km path with terminals at 3025 and 3300 m elevations and with no significant illumination of the earth's surface. Fades at two antennas separated horizontally by 100 m were largely uncorrelated. Phase variability was also measured and is presented in terms of spectra and coherency between antennas with 10 m and 100 m horizontal spacing.

Thompson, M. C.↗

Stellar winds, fast rotators, and magnetic acceleration

The assumption that observed mass outflow from a star is due to a magnetically driven wind implies an upper bound on the surface magnetic field strength from regions where the wind originates. Evidence is reported that corroborates Rosendhal's observation of an abrupt change in the velocity-gradient-luminosity relationship for B8 and later supergiants. The smallest upper bounds correspond to later spectral types, for which radiation would be a relatively inefficient mechanism for driving wind; these winds may in fact be magnetically driven. Be stars are prime candidates for magnetically accelerated winds due to large rotation rates and small mass loss rates. Observed flows can be driven by 0.1-10 gauss surface fields. Intense field in fast rotators can lead to dramatic mass loss rates and large terminal velocities; sigma Ori E may be such an object. Finally, the effect of magnetic acceleration on the dispersal of solar nebula is considered. The increased velocities allow the wind to disperse a mass of 90 times the initial outflowing mass in the wind.

Nerney, S.↗

Surface Analysis of 4-Aminothiophenol Adsorption at Polycrystalline Platinum Electrodes

Formation of self-assembled monolayer (SAM) of 4-aminothiophenol (4-ATP) on polycrystalline platinum electrodes has been studied by surface analysis and electrochemistry techniques. The 4-ATP monolayer was characterized by cyclic voltammetry (CV), Raman spectroscopy, reflection absorption infrared (RAIR) spectroscopy, and X-ray photoelectron spectroscopy (XPS). Cyclic voltammetry (CV) experiments give an idea about the packing quality of the monolayer. RAIR and Raman spectra for 4-ATP modified platinum electrodes showed the characteristic adsorption bands for neat 4-ATP indicating the adsorption of 4-ATP molecules on platinum surface. The adsorption on platinum was also evidenced by the presence of sulfur and nitrogen peaks by XPS survey spectra of the modified platinum electrodes. High resolution XPS studies and RAIR spectrum for platinum electrodes modified with 4-ATP indicate that molecules are sulfur-bonded to the platinum surface. The formation of S-Pt bond suggests that ATP adsorption gives up an amino terminated SAM. Thickness of the monolayer was evaluated via angle-resolved XPS (AR-XPS) analyses. Derivatization of 4-ATP SAM was performed using 16-Br hexadecanoic acid.

Rosario-Castro, Belinda I.↗

ATD-2 Field Evaluation of Pre-Departure Trajectory Option Set Reroutes in North Texas Metroplex

The NASA Airspace Technology Demonstration-2 Phase 3 capabilities extend Integrated Arrival, Departure and Surface scheduling to a Metroplex environment where multiple airports are interacting and sharing resources along the terminal boundary. The Phase 3 coordinated scheduling provides pre-departure reroute recommendations to flight operators which reduce delay caused by terminal restrictions. This paper reports results of the Phase 3 Stormy 2021 Field Evaluation conducted between November 2020 and September 2021 in the North Texas Metroplex. During the field evaluation NASA partnered with the FAA, American Airlines, Southwest Airlines, and Envoy Airlines to evaluate Phase 3 capabilities in an operational environment. The benefits results are provided as delay savings metrics measured in time and converted to fuel and emissions savings using detailed fuel flow models provided by flight operators.

ATD-2 Field Evaluation, Trajectory Option Set, Pre↗

ATD-2 Field Evaluation of Pre-Departure Trajectory Option Set Reroutes in North Texas Metroplex

The NASA Airspace Technology Demonstration-2 Phase 3 capabilities extend Integrated Arrival, Departure and Surface scheduling to a Metroplex environment where multiple airports are interacting and sharing resources along the terminal boundary. The Phase 3 coordinated scheduling provides pre-departure reroute recommendations to flight operators which reduce delay caused by terminal restrictions. This paper reports results of the Phase 3 Stormy 2021 Field Evaluation conducted between November 2020 and September 2021 in the North Texas Metroplex. During the field evaluation NASA partnered with the FAA, American Airlines, Southwest Airlines, and Envoy Airlines to evaluate Phase 3 capabilities in an operational environment. The benefits results are provided as delay savings metrics measured in time and converted to fuel and emissions savings using detailed fuel flow models provided by flight operators.

ATD-2↗

Interconnect system with friction fit backshell

Various technologies described herein pertain to interconnect systems for electrical cables. An interconnect system can include a connector, an adapter ring, and a backshell. The connector includes a threaded distal coupling portion. The adapter ring includes a threaded proximal coupling portion and a non-threaded distal coupling portion. The backshell includes a proximal coupling portion and a port. The threaded proximal coupling portion of the adapter ring and the threaded distal coupling portion of the connector can be mechanically attached. Additionally, the proximal coupling portion of the backshell and the non-threaded distal coupling portion of the adapter ring can be mechanically attached. A wire bundle can enter the backshell through the port, pass through the adapter ring, and terminate at the connector. A shield that encloses the wire bundle can terminate at the backshell such that an end of the shield is positioned around an outer surface of the port.

42 ENGINEERING↗

Interconnect system with friction fit backshell

Various technologies described herein pertain to interconnect systems for electrical cables. An interconnect system can include a connector, an adapter ring, and a backshell. The connector includes a threaded distal coupling portion. The adapter ring includes a threaded proximal coupling portion and a non-threaded distal coupling portion. The backshell includes a proximal coupling portion and a port. The threaded proximal coupling portion of the adapter ring and the threaded distal coupling portion of the connector can be mechanically attached. Additionally, the proximal coupling portion of the backshell and the non-threaded distal coupling portion of the adapter ring can be mechanically attached. A wire bundle can enter the backshell through the port, pass through the adapter ring, and terminate at the connector. A shield that encloses the wire bundle can terminate at the backshell such that an end of the shield is positioned around an outer surface of the port.

42 ENGINEERING↗

Dusty plasma in the region of the lunar terminator

Dusty plasma in the region of the lunar terminator is considered. It is shown that, in this region, a structure resembling a plasma sheath forms near the lunar surface. This sheath creates a potential barrier, due to which electrons over the illuminated part of the Moon are confined by electrostatic forces. The width of the sheath-like structure is on the order of the ion Debye length. In this structure, significant (about several hundred V/m) electric fields arise, which lift charged micron-size dust grains to heights of several tens of centimeters. The suggested effect may be used to explain the glow observed by the Surveyor spacecraft over the lunar terminator.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Leveraging Resonant Terminator Orbits for the Trajectory Design of OSIRIS-APEX at (99942) Apophis

The OSIRIS-REx spacecraft has been approved for an extended mission (OSIRIS-APEX) to visit the asteroid (99942) Apophis. In this paper we outline a potential design for the spacecraft’s trajectory during the variable phase orbit segment of the APEX mission. This phase of the mission, nominally expected to begin in January2030, has the primary goal of collecting image and spectral data of the full asteroid surface at a wide variety of illumination conditions without requiring frequent firing of the spacecraft thrusters. This work will focus on leveraging resonant terminator orbits (RTOs) in order to satisfy these goals and the associated science requirements. Though this segment will occur after Apophis’ closest flyby of Earth in April 2029, the proposed design utilizes the current best estimates of the asteroid’s orbital elements and physical properties at that time when designing the spacecraft’s orbit.

Gavin M Brown↗