A program to develop a high-energy density primary battery with a minimum of 200 watt hours per pound of total battery weight first quarterly report, jul. - sep. 1964
Highly conductive nonaqueous electrolytes for high energy battery
SEARCH · Search NASA
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Highly conductive nonaqueous electrolytes for high energy battery
An apparatus [10] is disclosed for a lightweight bipolar battery of the end-plate cell stack design. Current flow through a bipolar cell stack [12] is collected by a pair of copper end-plates [16a,16b] and transferred edgewise out of the battery by a pair of lightweight, low resistance copper terminals [28a,28b]. The copper terminals parallel the surface of a corresponding copper end-plate [16a,16b] to maximize battery throughput. The bipolar cell stack [12], copper end-plates [16a,16b] and copper terminals [28a,28b] are rigidly sandwiched between a pair of nonconductive rigid end-plates [20] having a lightweight fiber honeycomb core which eliminates distortion of individual plates within the bipolar cell stack due to internal pressures. Insulating foam [30] is injected into the fiber honeycomb core to reduce heat transfer into and out of the bipolar cell stack and to maintain uniform cell performance. A sealed battery enclosure [ 22] exposes a pair of terminal ends [26a,26b] for connection with an external circuit.
High power solutions for spacecraft are becoming increasingly sought after in the new era of space exploration, with energy intensive in-situ lunar surface exploration becoming a key part of the roadmap for major space agencies, as well as commercial companies. Nuclear power provides the most feasible solution to achieve continued operation through the long lunar night, and in extended periods in Permanently Shadowed Regions (PSRs). Americium-241 (241Am) is used as the fuel of choice in European Radioisotope Power Systems (RPS). The University of Leicester have developed a number of systems using this fuel type, including a 200 Wth heat source. Building on existing international partnerships, the University of Leicester is continuing to work with NASA Glenn Research Center (GRC) to maximise the electrical output that can be generated from the heat source by progressing the radioisotope-Stirling generator concept to elegant breadboard level, building on the long heritage of dynamic power conversion developments at NASA Glenn. Presented in the following conference paper is the next iteration of the Americium-fuelled Radioisotope Stirling Generator (Am-RSG) Elegant Breadboard, following on from a successful technology demonstration design conducted at NASA Glenn in early 2025. The design laid-out in this paper is a more flight-like version of the technology demonstrator, and is intended to pair with the next generation of Stirling convertor technology, the SunPower Robust Stirling Converter (SRSC). The SRSC is able to operate more efficiently at lower thermal power levels than the previous Advanced Stirling Convertor (ASC), making it more suitable for the 241Am system.
A future X-ray telescope mission like Lynx, a X-ray flagship mission concept, requires a large field of view, high energy resolution, and high spatial resolution. The Magnetic Microcalorimeter (MMC) detectors we are developing for such a mission feature a 5-arcminute field of view, approximately 100,000 pixels, each spanning 0.5–1 arcsecond. These detectors require the readout of 8,000 sensors. Three different array types have been designed to meet scientific goals, two of which utilize thermal multiplexing to reduce the number of readout channels in a scheme called “Hydra.” We are currently fabricating detectors on a recently completed buried wiring wafer with connections to every sensor. The sensors are read out using a microwave multiplexer (μMUX) with flux ramp modulation. A single μMUX can read out approximately 1,000 sensors with only two feed lines. We will report on the test of the first two-dimensional μMUX chip, consisting of 78 resonators. μMUX chips that pass screening will be directly bonded to MMC array chips using indium bump bonding. In parallel, we have tested a kinetic inductance traveling wave parametric amplifier (KI-TWPA) to amplify signals at low temperatures. The KI-TWPA exhibits extremely low internal noise, approaching the standard quantum limit. Since the energy resolution of an MMC is primarily limited by the readout system, the KI-TWPA is an ideal amplifier for MMCs with μMUX readout. We recently measured the readout noise of a μMUX with a KI-TWPA, demonstrating its capability for reading out MMC arrays. We present the design and fabrication of the latest MMC detectors, along with its readout performance.
Selected properties of 57Ni-40Ti-3Hf (wt%) were measured to further develop this material for use in aerospace rolling-element bearings. The average grain size and microindentation hardness of the material at room temperature were 90 μm and 549 HV, respectively. From room temperature to 500 °C, electrical resistivity increased from 8.9×10–7 to 11.3×10–7 Ω⋅m, thermal expansion coefficients varied from 1.1×10–5 to 1.2×10–5 mm/mm⋅°C, specific heat increased from 0.44 to 0.53 W⋅sec/g⋅K, thermal diffusivity rose from approximately 0.003 to 0.005 cm2/sec and thermal conductivity increased from approximately 0.09 to 0.19 W/cm⋅K. The behavior of the material can be explained by well-known metallurgical theory. These results are expected to provide a basis for design and modeling of future aerospace components.
Zinc-silver oxide battery design for improved and activated charge retention, voltage control, and temperature stability
The Inductrack magnetic levitation system, developed at the Lawrence Livermore National Laboratory, is being studied for its possible use for launching rockets. Under NASA sponsorship, a small model system is being constructed at the Laboratory to pursue key technical aspects of this proposed application. The Inductrack is a passive magnetic levitation system employing special arrays of high-field permanent magnets (Halbach arrays) on the levitating carrier, moving above a "track" consisting of a close-packed array of shorted coils with which are interleaved with special drive coils. Halbach arrays produce a strong spatially periodic magnetic field on the front surface of the arrays, while canceling the field on their back surface. Relative motion between the Halbach arrays and the track coils induces currents in those coils. These currents levitate the carrier cart by interacting with the horizontal component of the magnetic field. Pulsed currents in the drive coils, synchronized with the motion of the carrier, interact with the vertical component of the magnetic field to provide acceleration forces. Motional stability, including resistance to both vertical and lateral aerodynamic forces, is provided by having Halbach arrays that interact with both the upper and the lower sides of the track coils. In its completed form the model system that is under construction will have a track approximately 100 meters in length along which the carrier cart will be propelled up to peak speeds of Mach 0.4 to 0.5 before being decelerated. Preliminary studies of the parameters of a full-scale system have also been made. These studies address the problems of scale-up, including means to simplify the track construction and to reduce the cost of the pulsed-power systems needed for propulsion.
The journey to Mars will require advancements in many existing technologies, including space power and energy storage systems. According to the 2015 NASA Technology Roadmaps, energy storage is a critical technology area to develop for both terrestrial as well as future long-term space missions. Currently, batteries represent one of the major areas in need of advancement, both in terms of energy density as well as safety. Recently, concerns regarding the fire safety of commercial lithium-ion batteries have prompted efforts to produce nonflammable battery components, namely the electrolyte and separator. Commercial lithium-ion batteries utilize polyolefin separators imbibed with a lithium salt dissolved in cyclic carbonates. This separator/electrolyte combination imparts good ionic conductivities in the range of 10(exp -2) to 10(exp -3) S/cm. However, the cyclic carbonates and polyolefin separator are inherently flammable. Room-temperature ionic liquids (RTILs) appear to be a safer alternative to cyclic carbonates. They offer good ionic conductivities, similar to those observed in cyclic carbonates, but are inherently nonvolatile and nonflammable giving them a safety advantage. Many promising RTILs for battery electrolytes are not compatible with commercial polyolefin separator materials. Polyimide aerogels possess an open-porous, fibrillar network architecture which offers a high degree of porosity (typically greater than 85 porous), required for lithium ion conduction, as well as good mechanical properties. Furthermore, these materials are compatible with all tested RTILs. By creating a polyimide gel and imbibing the gel with a RTIL containing a lithium salt instead of super critically drying them to form aerogels, a nonflammable separator/electrolyte system with conductivities in the range of 1x10(exp -3) S/cm has been demonstrated.
This chapter provides a basic guide to the flight testing of propulsion system operability and compatibility (O&C). For the purposes of establishing a frame of reference, O&C refers to the ability of the aircrew to establish and maintain the desired level of propulsion system net propulsive force throughout the operating envelope of the aircraft. For the purposes of definition, net propulsive force is used to refer to the vector resultant of all throttle dependant forces acting upon the aircraft. By limiting the discussion in this Section to flight testing of the O&C of the propulsion system, it should not be interpreted to mean that these are the only factors that need to be considered when conducting flight test to evaluate an aircraft propulsion system. Propulsion system structural interfaces, pneumatic interfaces, mechanical interfaces, hydraulic interfaces, thermodynamic interfaces and electrical interfaces must all be evaluated prior to or concurrently with the O&C test program in order to ensure a safe and effective flight test program of the aircraft and propulsion system.
The International Space Station (ISS) primary Electric Power System (EPS) was originally designed to use Nickel-Hydrogen (Ni-H2) batteries to store electrical energy. The electricity for the ISS is generated by its solar arrays, which charge batteries during insolation for subsequent discharge during eclipse. The Ni-H2 batteries were designed to operate at a 35 depth of discharge (DOD) maximum during normal operation in a Low Earth Orbit. In 2010, the ISS Program began the development of Lithium-Ion (Li-Ion) batteries to replace Ni-H2 batteries approaching the end of their useful life and concurrently funded a Li-Ion ORU (Orbital Replacement Unit) and cell life testing project. The first set of 6 Li-ion battery replacements was launched in December 2016 and deployed in January 2017. This paper will discuss the Li-ion battery on-orbit cycling and the status of the Li-Ion cell and ORU life cycle testing.
The spacesuit boots that will be used on Artemis lunar south pole surface missions will be exposed to extremely cold temperatures (down to ~50 K). To assess the performance of the government’s Exploration Extravehicular Mobility Unit (xEMU) lunar boot in these permanently shadowed regions, testing was performed at the Jet Propulsion Lab (JPL) in the Cryogenic Ice Transfer, Acquisition Development, and Excavation Laboratory (CITADEL) thermal vacuum (TVAC) chamber. This paper documents the data analysis, thermal boot model correlation, and operational predictions conducted using data from the xEMU CITADEL TVAC test. Expected thermal conductances within the boot and between the boot and environment were calculated from test data, which was then used as an initial guess for conductances within a Thermal Desktop (TD) model. Correlation of the TD model using the internal SOLVER feature was performed across 10 different test points which varied external temperature, internal boot ventilation flowrate, and contact pressure. Operational performance at the lunar south pole was then predicted using results from the correlated model. While the predictions provide evidence for acceptable performance of the boots at the 100K environment test point, there is still substantial uncertainty in performance, especially at the 48K test point. This uncertainty is due in part to testing limitations such as contacting the foot to a hard metal plate rather than granular regolith, and model limitations such as the lack of a realistic foot model. These limitations and their impacts are addressed in detail in this paper. The results of this test series and model correlation underscore the importance of additional improved testing and modeling for characterizing the expected thermal resistance between the outside of the boot and the lunar surface.
Successful design of open rotor propulsors requires effective analysis across multiple disciplines, including aerodynamics, acoustics, and structures. A viable design must not only be efficient but must also produce an acceptable level of noise and meet all static and dynamic structural requirements. For design and optimization, this is especially challenging because running high fidelity analyses is resource-intensive, and optimizing a design may require many thousands of cases to be analyzed. For this reason, the NASA team has applied design methodology that utilizes low-cost aerodynamic methods, machine learning models, and high-fidelity analyses when necessary. This includes standard two-dimensional methods such as throughflow analysis and quasi-3D blade-to-blade CFD, as well as some newly developed methods. Optimization using 3D CFD is necessary to maximize performance, and this is considered as well. All optimizations are carried out subject to structural constraints evaluated using finite element analysis. Doing this accurately requires a robust trunnion design, capable of pitching the blade between cruise and takeoff conditions while maintaining acceptable factor of safety. Hot to cold analysis must also be applied in order to correctly determine the as-manufactured shape. For acoustics, the unsteady pressures on the blade surfaces must be predicted, and this can be done either through full-annulus unsteady CFD or through a nonlinear harmonic method (NLH). NLH can run much faster, allowing some acoustic considerations to be made earlier in the design process. The design process is ongoing, and this presentation will review the current status and planned next steps. This part of the talk will focus on aerodynamic performance and be followed by a talk on structures and acoustics.
An essential phase of the Explorer XIII development was a thermal study and design to provide an acceptable temperature environment for the electronics components and external surfaces of the satellite during ascent and in orbit. It was necessary to establish by preflight analysis and tests that tolerable temperatures could be maintained in three regimes of flight. In the first regime (from launch until release of the heat shield) the satellite was subjected to radiative and conductive heat from the shield. In the second regime, after release of the shield at 350,000 feet, the satellite was heated by free molecular flow. In the third regime - the orbit phase - it was necessary that temperatures within limits for a 1-year lifetime be established. In addition to these three regimes, a study was made to investigate the effect of elevated rocket-motor temperatures during launch and after burnout. This chapter will deal with some pertinent preflight estimates and correlation of these estimates with flight data.
In the exploration of destinations outside of Earth's neighborhood, specifically Mars, scientific and engineering inquiries have occurred by two means; observations from satellites and observations by landed spacecraft. Satellite observations (Mariner, MRO, Mars Odyssey, provide global-scale spatial and temporal data while landed spacecraft (Viking, Mars Pathfinder, Spirit, Opportunity, Phoenix Mars Lander) investigate highly localized areas of the surface of the planet. In preparation for human exploration, extensive knowledge of the surface and atmospheric environments should be known before the first human leaves Earth. The primary goal of performing reconnaissance on Mars on a sub-global scale is to know as much as possible about the environment to which crews will be subjected. At the current rate of launching and landing probes to Mars, it will take a very long time to understand the surface and atmospheric conditions associated with the regions where prospective crews may land. Meanwhile electronics and electrical systems are rapidly getting smaller. One can argue that to acquire the knowledge of the region, one must take hundreds, maybe thousands of measurements simultaneously. One means to perform such a task is to deploy a swarm of sensors. Such a swarm would perform an in-situ assessment of the region. Imagine a close flyby mission to Mars for example, where mini- to micro-sensors are deposited into the atmosphere over half an orbit or more. The sensors, captured by the atmospheric drag and Martian gravity slowly descend buffeted about by Martian winds and weather until they settle on the surface a great time later (think of how long dust takes to settle). As they descend they communicate a vast array of data; temperature, chemistry, pressure, radiation dose, electric or magnetic properties from a region of the planet and an individual sensor need not measure the same quantity as its neighbors. Initially, they could move at the whim of the environment but later versions could have locomotion or propulsion mechanisms. Humans wouldn't need to decide where the sensors go, the sensors do that for themselves. This is a key strength of a sensor swarm. The intelligence relies on the group not on a decision maker on earth. Real time sensor inputs direct what the swarm considers most interesting to investigate resulting in emergent behavior. We issued a $20,000 challenge to the global innovators to provide solutions as to how such a swarm could be initialized and by what protocols and methodologies by which they operate. Over 400 innovators from 49 countries took a look at the problem, with three receiving partial awards for solutions.
In recent years, metal combustion studies at the University of Colorado have focused on the effects of gravity (g) on the ignition and burning behavior of bulk metals. The impetus behind this effort is the understanding of the ignition conditions and flammability properties of structural metals found in oxygen (O,sub>2 ) systems for space applications. Since spacecraft are subjected to higher-than-1g loads during launch and reentry and to a zero-gravity environment while in orbit, the study of ignition and combustion of bulk metals at different gravitational accelerations is of great practical concern. From the scientific standpoint, studies conducted under low gravity conditions provide simplified boundary conditions, since buoyancy is removed, and make possible the identification of fundamental ignition and combustion mechanisms. This investigation is intended to provide experimental verification of the influence of natural convection on the burning behavior of metals. In addition, the study offers the first findings of the influence of gravity on ignition of bulk metals and on the combustion mechanism and structure of metal-oxygen, vapor-phase diffusion flames in a buoyancy-free environment. Titanium (Ti) and magnesium (Mg) metals were chosen because of their importance as elements of structural materials and their simple chemical composition-pure metals instead of multicomponent alloys to simplify chemical and spectroscopic analyses. In addition, these elements present the two different combustion modes observed in metals: heterogeneous or surface burning (for Ti) and homogeneous or gas-phase reaction (for Mg). Finally, Mg, Ti, and their oxides exhibit a wide range of thermophysical and chemical properties. Metal surface temperature profiles, critical and ignition temperatures, propagation rates, burning times, and spectroscopic measurements are obtained under normal and reduced gravity. Visual evidence of all phenomena is provided by high-speed photography.
Understanding the coastal zone of the Antarctic Ice Sheet, where it interacts with the Southern Ocean and warmer air masses, is crucial for predicting Antarctica's influence on the global climate. This region has multiple tipping mechanisms that could trigger large, rapid, and potentially irreversible changes in the coming centuries. The Antarctic Ice Sheet remains the largest source of uncertainty in future sea-level projections. Insufficient knowledge of bed topography beneath the ice shelves and the coastal ice sheet is not yet well documented, but is a major source of this uncertainty. This review assesses current knowledge of the coastal zone and highlights methods to investigate it, including aerogeophysical surveys, ground- and ship-based measurements, satellite observations, and computer modeling. An ensemble analysis of published bed topography datasets identifies significant data gaps and their regional distribution, framed in the context of current ice-sheet behavior and potential instability. We propose scientific priorities and guidelines for future aerogeophysical surveys, advocating for a comprehensive, coordinated international effort to build a next-generation dataset of Antarctic bed properties. Such an initiative would significantly advance understanding of the role of coastal processes in ice-sheet dynamics, reducing uncertainties in sea-level rise projections and enhancing predictions of future ocean and climate changes.
High energy anode and cathode development, electrolyte encapsulation, tape activation, and parasitic operation techniques for dry tape battery concept
High energy anode and cathode for dry tape battery - incapsulation of electrolyte - manufacturing and testing of device