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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 991 records · Page 55
All sourcesNASA NTRSDOE OSTI
DOE OSTI2015

VERY HIGH ENERGY γ-RAYS FROM THE UNIVERSE’S MIDDLE AGE: DETECTION OF THE z = 0.940 BLAZAR PKS 1441+25 WITH MAGIC

The flat-spectrum radio quasar PKS 1441+25 at a redshift of z = 0.940 is detected between 40 and 250 GeV with a significance of 25.5σ using the MAGIC telescopes. Together with the gravitationally lensed blazar QSO B0218+357 (z = 0.944), PKS 1441+25 is the most distant very high energy (VHE) blazar detected to date. The observations were triggered by an outburst in 2015 April seen at GeV energies with the Large Area Telescope on board Fermi. Multi-wavelength observations suggest a subdivision of the high state into two distinct flux states. In the band covered by MAGIC, the variability timescale is estimated to be 6.4 ± 1.9 days. Modeling the broadband spectral energy distribution with an external Compton model, the location of the emitting region is understood as originating in the jet outside the broad-line region (BLR) during the period of high activity, while being partially within the BLR during the period of low (typical) activity. The observed VHE spectrum during the highest activity is used to probe the extragalactic background light at an unprecedented distance scale for ground-based gamma-ray astronomy.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1980

Experiments on the amplification of optical activity

Chemical mechanisms for the amplification of small, abiotically produced enantiomeric excesses leading to the complete stereo specificity of all biochemical reactions observed in the present-day biosphere are investigated quantitatively. Partial copolymerization of a mixture of R- and S-leucine or R- and S-valine N-carboxy anhydrides containing a known excess of one enantiomer was induced and the enantiomeric composition of the resulting oligomer was analyzed by gas chromatography. It is found that the 50% polymerization of leucine mixtures having excesses of 8 to 70% of either enantiomer leads to a significant enhancement of the enantiomeric excess of the polymer, accompanied by a corresponding decrease in the enantiomeric excess of the unpolymerized residue. On the other hand, 25-50% polymerization of valine mixtures is observed to result in polymers showing a decreased enantiomeric excess relative to the starting mixture and corresponding increases in those of the residue. Results of the leucine polymerization are interpreted as supporting the theory of steric interactions between the monomer and the helical structure of the polymer leading to the enrichment of one enantiomer, and possible mechanisms for the reverse stereospecificity observed in valine are discussed.

Blair, N. E.↗
NASA NTRS2019

Assessing Dual-Polarization Radar Estimates of Extreme Rainfall During Hurricane Harvey

Hurricane Harvey hit the Texas Gulf Coast as a major hurricane on August 25, 2017 before exiting the state as a tropical storm on August 29, 2017. Left in its wake was historic flooding, with some locations measuring more than 60 inches of rain over a five-day period. The WSR-88D radar (KHGX) maintained operations for the entirety of the event. Rain gauge data from the Harris County Flood Warning System (HCFWS) was used for validation with the full radar data set to retrieve daily and event-total precipitation estimates for the period August 25-29, 2017. The KHGX precipitation estimates were then compared to the HCFWS gauges. Three different hybrid polarimetric rainfall retrievals were used, along with attenuation-based retrieval that employs the radar-observed differential propagation. An advantage of using a attenuation-based retrieval is its immunity to partial beam blockage and calibration errors in reflectivity and differential reflectivity. All of the retrievals are susceptible to changes in the observed Drop Size Distribution (DSD). No in situ DSD data were available over the study area, so changes in the DSD were interpreted by examining the observed radar data. We examined the parameter space of two key values in the attenuation retrieval to test the sensitivity of the rain retrieval. Selecting a value of α=0.015 and β=0.600 and β=0.625 provided the best overall results, relative to the gauges, but more work needs to be done to develop an automated technique to account for changes in the ambient DSD.

David B Wolff↗
NASA NTRS2019

Assessing Dual-Polarization Radar Estimates of Extreme Rainfall During Hurricane Harvey

Hurricane Harvey hit the Texas Gulf Coast as a major hurricane on 25 August 2017 before exiting the state as a tropical storm on 29 August 2017. Left in its wake was historic flooding, with some locations measuring more than 60 in. (150 cm) of rain over a 5-day period. The WSR-88D radar (KHGX) maintained operations for the entirety of the event. Rain gauge data from the Harris County Flood Warning System (HCFWS) was used for validation with the full radar dataset to retrieve daily and event-total precipitation estimates for the period 25–29 August2017. The KHGX precipitation estimates were then compared with the HCFWS gauges. Three different hybrid polarimetric rainfall retrievals were used, along with attenuation-based retrieval that employs the radar-observed differential propagation. An advantage of using a attenuation-based retrieval is its immunity to partial beam blockage and calibration errors in reflectivity and differential reflectivity. All of the retrievals are susceptible to changes in the observed drop size distribution (DSD). No in situ DSD data were available over the study area, so changes in the DSD were interpreted by examining the observed radar data. We examined the parameter space of two key values in the attenuation retrieval to test the sensitivity of the rain retrieval. Selecting a value ofa50.015 andb50.600 provided the best overall results, relative to the gauges, but more work needs to be done to develop an automated technique to account for changes in the ambient DSD.

David Billings Wolff↗
DOE OSTI2016

Avalanches, plasticity, and ordering in colloidal crystals under compression

Using numerical simulations we examine colloids with a long-range Coulomb interaction confined in a two-dimensional trough potential undergoing dynamical compression. As the depth of the confining well is increased, the colloids move via elastic distortions interspersed with intermittent bursts or avalanches of plastic motion. In these avalanches, the colloids rearrange to minimize their colloid-colloid repulsive interaction energy by adopting an average lattice constant that is isotropic despite the anisotropic nature of the compression. The avalanches take the form of shear banding events that decrease or increase the structural order of the system. At larger compression, the avalanches are associated with a reduction of the number of rows of colloids that fit within the confining potential, and between avalanches the colloids can exhibit partially crystalline or anisotropic ordering. The colloid velocity distributions during the avalanches have a non-Gaussian form with power law tails and exponents that are consistent with those found for the velocity distributions of gliding dislocations. We observe similar behavior when we subsequently decompress the system, and find a partially hysteretic response reflecting the irreversibility of the plastic events.

36 MATERIALS SCIENCE↗
NASA NTRS1976

On the existence of molecular hydrogen along lines of sight with low reddening

The existence of molecular hydrogen along lines of sight with low reddening (B-V color excesses not exceeding 0.03) is discussed for the stars HD 28497, Mu Col, Alpha Vir, Beta Cen, and Lambda Sco. The main observations are of the R(1) features, which for effective rotational temperatures above 200 K are the dominant source of H2 transitions. If the formation process for molecular hydrogen is similar to that for regions of greater reddening, the observations indicate that the neutral gas outside standard clouds may be partially in small clouds, though a more diffuse component seems to exist in some cases. Extremely high rotational temperatures are inferred for the H2 toward HD 28497. The possibility of formation of H2 through the reaction H(-) + H yields H2 + e(-) is briefly discussed. In any case, only small regions seem to contribute to the observed H2 column density.

York, D. G.↗
DOE OSTI2023

Experimental study on kinetic oxidation of graphite IG-110 by steam

Graphite is proposed for use in High-temperature Gas-cooled Reactors (HTGRs) as the fuel matrix, neutron moderator/reflector, and core structural material. One important property of nuclear grade graphite is their resistance to oxidation in high-temperature environment. Extensive investigation has been performed in the literature for graphite oxidation by air. However, available experimental data are still limited for graphite oxidation by steam under conditions comparable to a postulated steam ingress accident in HTGRs. In this study, the oxidation rate of graphite IG-110 by steam was measured at temperatures from 850 to 1100 °C with the steam partial pressure varying from 0.5 to 20.0 kPa and the hydrogen partial pressure varying from 0 to 2.0 kPa. Further analysis confirms the oxidation process in this present study is dominated by the chemical kinetics, which lends credit to the data for being used to develop numerical models. It was observed that the increase of the kinetic oxidation rate with the steam partial pressure tends to become less apparent if the steam partial pressure keeps increasing. In addition, it was found that the partitioning of hydrogen inhibits the graphite-steam reaction process even with the steam partial pressure up to 20.0 kPa. However, this inhibiting effect starts to become saturated when the hydrogen partial pressure exceeds 1.0 kPa. The oxidation rates were fitted to the conventional Langmuir-Hinshelwood (LH) and Boltzmann-enhanced Langmuir-Hinshelwood (BLH) models by a multivariable optimization algorithm. The BLH model exhibits a better accuracy than the LH model within the specified experimental conditions. The predicted oxidation rate using the BLH model shows a mean relative difference of about 24% with the maximum difference of about 55% when compared with our experimental data.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2014

Modeling active region transient brightenings observed with X-ray telescope as multi-stranded loops

Strong evidence exists that coronal loops as observed in extreme ultraviolet and soft X-rays may not be monolithic isotropic structures, but can often be more accurately modeled as bundles of independent strands. Modeling the observed active region transient brightenings (ARTBs) within this framework allows for the exploration of the energetic ramifications and characteristics of these stratified structures. Here we present a simple method of detecting and modeling ARTBs observed with the Hinode X-Ray Telescope (XRT) as groups of zero-dimensional strands, which allows us to probe parameter space to better understand the spatial and temporal dependence of strand heating in impulsively heated loops. This partially automated method can be used to analyze a large number of observations to gain a statistical insight into the parameters of coronal structures, including the number of heating events required in a given model to fit the observations. In this article, we present the methodology and demonstrate its use in detecting and modeling ARTBs in a sample data set from Hinode/XRT. These initial results show that, in general, multiple heating events are necessary to reproduce observed ARTBs, but the spatial dependence of these heating events cannot yet be established.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2019

Time-resolved imaging of atoms and molecules in laser-produced uranium plasmas

Gas-phase oxidation of uranium (U), plume chemistry, and its impact on optical emission features of the uranium plasma are investigated. Plasmas were produced via nanosecond laser ablation of a natural uranium target in a chamber where uranium oxidation was controlled by varying the oxygen partial pressure within argon cover gas. Monochromatic imaging of uranium atoms and monoxide molecules was performed using narrowband optical filters, which clearly reveals the spatio-temporal evolution of these species in the plasma. Uranium oxides are found to be formed at the plasma edges, where lower temperatures favor molecular recombination. Segregation between the distribution of uranium atoms and monoxide species is observed at later times of plasma evolution, and is more apparent at lower oxygen partial pressures. At higher oxygen partial pressures, significant variation in plume morphology is noticed for UO species, which is attributed to higher rate of oxide (UxOy) formation at the plume edges. The monochromatic images of U atoms and molecules and corresponding spectral features at various oxygen partial pressures presented here provide a unique insight into gas-phase, high-temperature uranium oxidation, and its chemistry and have implications for a wide range of nuclear applications, from stand-off detection of radioisotopes to forensics and safeguards.

(140.3440) Laser-induced breakdown, (280.4788) Opt↗
NASA NTRS1984

Dynamic thermal episodes in the protosolar nebula: Development of models from observations on CAI's

Evaluation of earlier observations indicated that layered rims on coarse-grained Allende CAI's were possibly the result of partial melting by ablation/drag-heating and reaction of CAI exteriors with a gas or gases of non-solar composition. Bunch and Chang reported the common occurrence of thin, fine-grained, matrix-like bands that at least partially surround rims of CAI's. Although material in these bands in general appears to be similar to matrix, SEM observations show them to be dissimilar in volatile element content, mineral composition, and grain morphology. Moreover, they appear to be related in time of formation with rim development and Na-metasomatism of CAI's. Observations indicate a short-lived but intense heating episode followed by radid cooling as the mechanism responsible for these CAI features.

Bunch, T. E.↗
DOE OSTI2015

Detecting the companions and ellipsoidal variations of RS CVn primaries. I. σ Geminorum

To measure the properties of both components of the RS Canum Venaticorum binary σ Geminorum (σ Gem), we directly detect the faint companion, measure the orbit, obtain model-independent masses and evolutionary histories, detect ellipsoidal variations of the primary caused by the gravity of the companion, and measure gravity darkening. We detect the companion with interferometric observations obtained with the Michigan InfraRed Combiner at Georgia State University’s Center for High Angular Resolution Astronomy Array with a primary-to-secondary H-band flux ratio of 270 ± 70. A radial velocity curve of the companion was obtained with spectra from the Tillinghast Reflector Echelle Spectrograph on the 1.5 m Tillinghast Reflector at Fred Lawrence Whipple Observatory. We additionally use new observations from the Tennessee State University Automated Spectroscopic and Photometric Telescopes (AST and APT, respectively). From our orbit, we determine model-independent masses of the components (M{sub 1}=1.28±0.07 M{sub ⊙}, M{sub 2}=0.73±0.03 M{sub ⊙}), and estimate a system age of 5∓1 Gyr. An average of the 27 year APT light curve of σ Gem folded over the orbital period (P=19.6027±0.0005 days) reveals a quasi-sinusoidal signature, which has previously been attributed to active longitudes 180° apart on the surface of σ Gem. With the component masses, diameters, and orbit, we find that the predicted light curve for ellipsoidal variations due to the primary star partially filling its Roche lobe potential matches well with the observed average light curve, offering a compelling alternative explanation to the active longitudes hypothesis. Measuring gravity darkening from the light curve gives β<0.1, a value slightly lower than that expected from recent theory.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

Hotspot testing of glass/backsheet and glass/glass PV modules pre-stressed in extended thermal cycling

This paper investigates the effect of hotspot (HS) stress endurance of two of the latest designs of monocrystalline modules: a half-cell glass/backsheet (G/B) module and a full-cell glass/glass (G/G) module. These modules have already been pre-stressed in extended thermal cycling with 600 cycles per the IEC 61215 standard to represent field-stressed modules. This study differs from the other conventional studies wherein only fresh modules are subjected to hotspot endurance stress. The G/G module reached a maximum temperature of approximately 200 °C at a cell shading of 25 %, 55 °C higher than the maximum hotspot temperature of 145 °C in the G/B module. A significant burn mark, without glass shattering, was observed in the hotspot-stressed cell of the G/G module due to the current mismatch induced by partial shading. Most of the cells in the G/G module appear to be severely damaged (severe dark areas), as observed in the electroluminescence (EL) image, while the dark regions were rarely present in the G/B module. The EL image also illustrates multiple cell cracks that resist current flow and eventually contribute to the full-cell module degradation. About 8.3 % degradation in maximum power was observed for the G/G module and 1.3 % for the G/B module after the sequential stress tests. The lower degradation in the G/B module can potentially be attributed to its design, which comprises of two parallel strings, each having 72-half-cells and benefits from lower heat dissipation. Furthermore, this indicates that the half-cell design could potentially minimize the hotspot degradation and failures in crystalline-silicon modules.

14 SOLAR ENERGY↗
DOE OSTI2016

Microsensor and transcriptomic signatures of oxygen depletion in biofilms associated with chronic wounds: Biofilms and oxygen

Polymicrobial biofilms have been implicated in delayed wound healing, although the mechanisms by which biofilms impair wound healing are poorly understood. Many species of bacteria produce exotoxins and exoenzymes that may inhibit healing. In addition, oxygen consumption by biofilms may impede wound healing. In this study, we used oxygen microsensors to measure oxygen transects through in vitro-cultured biofilms, biofilms formed in vivo in a diabetic (db/db) mouse model, and ex vivo human chronic wound specimens. The results show that oxygen levels within both euthanized and live mouse wounds had steep gradients that reached minima ranging from 19 to 61% oxygen partial pressure, compared to atmospheric oxygen levels. The oxygen gradients in the mouse wounds were similar to those observed for clinical isolates cultured in vitro and for human ex vivo scabs. No oxygen gradients were observed for heat-killed scabs, suggesting that active metabolism by the viable bacteria contributed to the reduced oxygen partial pressure of the wounds. To characterize the metabolic activities of the bacteria in the mouse wounds, we performed transcriptomics analyses of Pseudomonas aeruginosa biofilms associated with the db/db mice wounds using Affymetrix microarrays. The results demonstrated that the bacteria expressed genes for metabolic activities associated with cell growth. Interestingly, the transcriptome results indicated that the bacteria within the wounds also experienced oxygen-limitation stress. Among the bacterial genes that were expressed in vivo were genes associated with the Anr-mediated hypoxia-stress response. Other bacterial stress response genes highly expressed in vivo were genes associated with stationary-phase growth, osmotic stress, and RpoH-mediated heat shock stress. Overall, the results support the hypothesis that the metabolic activities of bacteria in biofilms act as oxygen sinks in chronic wounds and that the depletion of oxygen contributes to the detrimental impact of biofilms on wound healing.

bacterial biofilms↗
DOE OSTI2016

Visualizing Redox Dynamics of a Single Ag/AgCl Heterogeneous Nanocatalyst at Atomic Resolution

Operando characterization of gas solid reactions at the atomic scale is of great importance for determining the mechanism of catalysis. This is especially true in the study of heterostructures because of structural correlation between the different parts. However, such experiments are challenging and have rarely been accomplished. In this work, atomic scale redox dynamics of Ag/AgCl heterostructures have been studied using in situ environmental transmission electron microscopy (ETEM) in combination with density function theory (DFT) calculations. The reduction of Ag/AgCl to Ag is likely a result of the formation of Cl vacancies while Ag+ ions accept electrons. The oxidation process of Ag/AgCl has been observed: rather than direct replacement of Cl by O, the Ag/AgCl nanocatalyst was first reduced to Ag, and then Ag was oxidized to different phases of silver oxide under different O-2 partial pressures. Ag2O formed at low O-2 partial pressure, whereas AgO formed at atmospheric pressure. By combining in situ ETEM observation and DFT calculations, this structural evolution is characterized in a distinct nanoscale environment.

Ag/AgCl heterogeneous nanocatalyst↗
NASA NTRS2019

Using solar eclipse events to validate VIIRS reflective solar band calibration at multiple radiance levels

The VIIRS instruments aboard the SNPP and NOAA-20 (N20) satellites have 14 reflective solar bands (RSB) covering a spectral range from 412 nm to 2250 nm. The radiance of each VIIRS RSB is calculated from a quadratic function of the background-subtracted digital count, 𝑑𝑛, with the quadratic coefficients determined during pre-launch testing. On orbit, calibration is maintained using observations of a sunlit solar diffuser (SD), which views the Sun every orbit through a fixed attenuation screen. The SD observations, which are at nearly the same radiance level every orbit, provide a time varying overall calibration adjustment factor, the F-factor. But there is no designed on-orbit mechanism for calibration at multiple radiance levels, so the relative strengths of the quadratic coefficients continue to be fixed at the pre-launch values. On a few rare occasions, the VIIRS instruments have passed through a partial solar eclipse during the part of the satellite orbit when the SD is illuminated by the Sun (near the South Pole). As of August 2019, the SNPP and N20 VIIRS SDs have observed five and three partial solar eclipses, respectively. While these events are rare, they offer a unique opportunity to test the RSB calibration using the SD at different radiance levels. In this paper, we compare the reduction in the measured SD signals during an eclipse to the predicted radiance reduction based on the Sun-Moon geometry and a solar radiance model. We find good agreement between the data and model for all events, indicating that the VIIRS RSB gain linearity has remained fairly stable on-orbit. The most significant deviation is for the N20 short-wave infrared bands, which had non-linearity concerns during pre-launch testing. We also investigate the SNPP results using different versions of the prelaunch quadratic gain coefficients.

solar eclipse↗
NASA NTRS1990

Estimability of geodetic parameters from space VLBI observables

The feasibility of space very long base interferometry (VLBI) observables for geodesy and geodynamics is investigated. A brief review of space VLBI systems from the point of view of potential geodetic application is given. A selected notational convention is used to jointly treat the VLBI observables of different types of baselines within a combined ground/space VLBI network. The basic equations of the space VLBI observables appropriate for convariance analysis are derived and included. The corresponding equations for the ground-to-ground baseline VLBI observables are also given for a comparison. The simplified expression of the mathematical models for both space VLBI observables (time delay and delay rate) include the ground station coordinates, the satellite orbital elements, the earth rotation parameters, the radio source coordinates, and clock parameters. The observation equations with these parameters were examined in order to determine which of them are separable or nonseparable. Singularity problems arising from coordinate system definition and critical configuration are studied. Linear dependencies between partials are analytically derived. The mathematical models for ground-space baseline VLBI observables were tested with simulation data in the frame of some numerical experiments. Singularity due to datum defect is confirmed.

Adam, Jozsef↗
NASA NTRS1993

Venus resurfacing rates: Constraints provided by 3-D Monte Carlo simulations

A 3-D Monte Carlo model that simulates the evolving surface of Venus under the influence of a flux of impacting objects and a variety of styles of volcanic resurfacing was implemented. For given rates of impact events and resurfacing, the model predicts the size-frequency and areal distributions of surviving impact craters as a function of time. The number of craters partially modified by volcanic events is also calculated as the surface evolves. It was found that a constant, global resurfacing rate of approximately 0.4 km(sup 3)/yr is required to explain the observed distributions of both the entire crater population, and the population of craters partially modified by volcanic processes.

Bullock, M. A.↗