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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 991 records · Page 55

Sublimation temperature sensor for temperature locale

The sublimation temperature sensor (or “sublime sensor”) provides a continuum of measurement locations in which certain maximum temperatures are achieved during a heat up/cool down cycle. A predetermined material is encapsulated within a vacuum-sealed, non-volatile long tube (i.e., both ends capped and L$\gg$ D). This assembly is then inserted and centered into a heated zone, such as a furnace, exhaust pipe, or reactor. As the temperature increases, the material will sublimate (i.e., a process of having both the solid and gaseous states of matter simultaneously present) and will begin to fill the void - moving outward in both directions toward the ends of the tube. Once beyond the elevated temperatures, the gas will de-sublimate (i.e., deposition) onto the inner wall of the tube. The desired result of the sensor is the ring of material that develops over a relatively short period of time. This material deposit can be equated with temperature at an exact location. There is no need to interpolate and/or extrapolate for the desired measurement. Accuracy has been recorded for temperature locations on the range of ±2 mm over a 1 m span. Likewise, the precision of the measurement is ±0.2% the overall sensor domain. Furthermore, individual tubes with unique materials and pressures can be bundled together to provide a complete temperature profile of the heated zone.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Wireless Sensor Modalities at a Nuclear Plant Site to Collect Vibration Data

One of the major contributors to the total operating costs of domestic nuclear fleet of reactors today is the operation and maintenance (O&M) costs. These include labor-intense preventive maintenance programs involving manually-performed inspection, calibration, testing, and maintenance of plant assets at periodic frequency and time-based replacement of assets at periodic frequency, irrespective of their conditions. This has resulted in a labor-centric business model to achieve high capacity factors. To build an optimal maintenance program, it’s time to transition from this labor-centric business model to a technology-centric business model. Fortunately, there are technologies (advanced sensor, data analytics, and risk assessment methodologies) that will support this transition. The technology-centric business model will result in significant plant life extension and reduction of time-based maintenance activities. This will drive down O&M costs as labor is a rising cost and technology is a declining cost. This approach will lay the foundation for real-time condition assessment of plant assets, allowing condition-based maintenance to enhance plant safety, reliability, and economics of operation. The goal of this project is to address challenges in the area of digital monitoring, i.e., the application of advanced sensor technologies (particularly wireless sensor technologies) and science-based data analytic capabilities to advance online monitoring and predictive maintenance in nuclear plants to improve plant performance (efficiency gain and economic competitiveness). To achieve the project goal, in partnership with Exelon Generating Company (Exelon), researchers from Idaho National Laboratory (INL) and Oak Ridge National Laboratory (ORNL) are performing research and development (R&D) to demonstrate application of wireless sensors using the distributed antenna system and advanced data analytics to achieve predictive maintenance. In the report, wireless vibration sensors, vibration data and its indicator are described. The wireless vibration sensors presented in this report support three types of wireless communication, namely, Wi-Fi, cellular, and 900 MHz. These wireless vibration sensors are considered by partner plant site for installation on plant asset to enable online vibration monitoring to replace periodic measurements. These vibration data along with other plant process data will be utilized to develop diagnostic and prognostic models.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Using sensor arrays to decode NO x /NH 3 /C 3 H 8 gas mixtures for automotive exhaust monitoring

In this work, an array of four mixed-potential sensors is employed to identify and quantify gases in complex mixtures of unknown composition which mimic diesel engine exhaust. The sensors use dense metal and metal oxide electrodes with a porous ceramic electrolyte, yttria-stabilized zirconia (YSZ). Since the sensors exhibit cross-specificity toward target gases, we develop a computational model for predicting gas concentrations in the mixtures. Our model is based on fundamental principles of gas-sensor interactions and, furthermore, takes into account the non-linearity of the observed sensor voltage response. Our approach enables accurate predictions of gas concentrations from the voltage output of the sensor array exposed to an extensive set of mixtures involving C 3 H 8 , NH 3 , NO and NO 2 . We find that our predictions remain accurate even if the model is trained using a reduced set of mixtures, or if the number of sensors is decreased to three or two. Finally, our experimental and computational framework can be used to decipher contents of complex gas mixtures of unknown composition in numerous industrial, automotive, and national security settings.

47 OTHER INSTRUMENTATION↗

Methodology for Automated Detection of Degradation and Faults in Packaged Air Conditioners and Heat Pumps Using Only Two Sensors

The software was created in the process of developing a system known as the Smart Monitoring and Diagnostic System (SMDS) for packaged air conditioners and heat pumps used on commercial buildings (known as RTUs). The SMDS provides automated remote monitoring and detection of performance degradation and faults in these RTUs and could increase the awareness by building owners and maintenance providers of the condition of the equipment, the cost of operating it in degraded condition, and the quality of maintenance and repair service when it is performed. The SMDS provides these capabilities and would enable conditioned-based maintenance rather than the reactive and schedule-based preventive maintenance commonly used today, when maintenance of RTUs is done at all. Improved maintenance would help ensure persistent peak operating efficiencies, reducing energy consumption by an estimated 10% to 30%.

Source record↗

Analysis of Persistent Soiling Losses: Cooperative Research and Development (Final Report)

The Contractor will analyze data from sensors and equipment provided by Participant in order to provide the basis for understanding of the processes and rates for the formation of 'persistent' soiling (soiling not removed by rain). The resulting, data, technical report, and publications will provide the basis for Participant to improve it's predictive soiling model.

14 SOLAR ENERGY↗

Portable Luminescent Sensor Technologies for Economically Critical Metals

Presentation on the development of sensing materials and compact platforms for the photoluminescence-based detection of economically critical metals, including rare earth elements, cobalt, and aluminum. The important of detecting metals that interfere with critical metal processing, such as iron and aluminum, are also discussed. The presented results represent a significant step forward in reducing the economic and time costs associated with the characterization of metals during prospecting and downstream processing.

Crawford, Scott↗

Capacitance-Based Dimensional Change Sensors for In-Pile Materials Measurements

Advanced fuel compositions, such as accident tolerate fuels (ATF), are an active area of developing in the nuclear power industry. The long-term performance of these newly developed fuels is estimated through physics-based simulation models of irradiation-, temperature-, pressure-, etc.-induced material degradation. As these fuels are deployed in test reactors, measurement and characterization of the fuel pin evolution is used to validate prediction models. In-pile material evolution parameters, such as fuel rod pressurization, fuel stack and cladding elongation, and cladding diameter, are commonly measured using a linear voltage differential transformer (LVDT). However, LVDTs are bulky and limited to lower (350-500C) temperature operation. The high power density and small size of most experimental positions in high performance research reactors used for accelerated materials irradiation studies generally precludes the use of LVDTs in these reactors. There is a critical need for sensors that provide real-time data regarding material evolution under highly accelerated irradiation. These sensors would ideally have a small profile and the ability to withstand irradiation at extremely high dose rates and temperatures for extended periods of time. A capacitance-based sensor is currently under development at the University of Tennessee to provide a direct measurement of in-pile dimensional change during irradiation. Sensor response was simulated using AutoCAD Electromagnetic field simulator (EMS) for a variety of sensor materials and configurations and fuel pin swelling conditions. Initial results of these simulations are summarized and areas of ongoing research and development are discussed.

Naughton, Tyler↗

Fast response High Altitude Laser Optical Sensor (HALOS) for atmospheric water and temperature measurements

Advanced instrumentation and sensing methods are the key factor in the determination of many climate science research problems. In this Phase I STTR a laser-based diagnostic system for atmospheric temperature and water concentrations measurements was developed, this system, HALOS – High Altitude Laser Optical Sensor, employs a mid-infrared (MIR) quantum cascade laser (QCL) of the distributed feedback variety (DFB) powered by a 100 kHz rep rate ramp modulated current profile which enables spectral profiling. Measurements made during Phase I showed that HALOS can surpass the available hygrometers refresh rates while offering superior accuracy (<4%) from the low Frost Point (Tfrost) of -110°C to dew points (Tdew) at 35°C while being able to encompass sub ppm concentration at altitude and supersaturated conditions at ground level. Readings from HALOS include temperature sensitivity on the order of 0.2°C and absolute humidity sensitivity (AH) on the order of 0.010 μmol/m 3 (0.18 mg/m 3 ) at a data output rate exceeding 1 kHz. HALOS can be easily integrable in existing Department of Energy (DOE) or National Oceanic and Atmospheric Administration (NOAA) conventional or remote operated aircraft having either a fixed or rotary wing.

54 ENVIRONMENTAL SCIENCES↗

Identification and characterization of the dominant thermal resistance in lithium-ion batteries using operando 3-omega sensors

Poor thermal transport within lithium-ion batteries fundamentally limits their performance, safety, and lifetime, in spite of external thermal management systems. All prior efforts to understand the origin of batteries' mysteriously high thermal resistance have been confined to ex situ measurements without understanding the impact of battery operation. Here, we develop a frequency-domain technique that employs sensors capable of measuring spatially resolved intrinsic thermal transport properties within a live battery while it is undergoing cycling. Our results reveal that the poor battery thermal transport is due to high thermal contact resistance between the separator and both electrode layers and worsens as a result of formation cycling, degrading total battery thermal transport by up to 70%. We develop a thermal model of these contact resistances to explain their origin. These contacts account for up to 65% of the total thermal resistance inside the battery, leading to far-reaching consequences for the thermal design of batteries. Finally, our technique unlocks new thermal measurement capabilities for future battery research.

25 ENERGY STORAGE↗

INSPIRE Phase I Development

Sandia National Laboratories (Sandia) and Makel Engineering, Inc developed a pathway towards an advanced multi-modal sensor system suitable for in-situ analysis of exhaled volatile organic compounds (VOCs) for pilots, divers and field patients. Our proposed In-Mask Sensors for Physiological Investigation of Respiratory Exhalation - INSPIRE, will combine micro-gas chromatograph (microGC) and miniature ion mobility spectrometer (IMS) for detection of trace amounts of exhaled breath VOCs with miniature solid state sensors for inorganic compounds found in breath such as oxygen, carbon dioxide, moisture and the inert gases nitrogen, argon and helium. To develop clear developmental pathway towards that goal Sandia demonstrated a new version of its ion-mobility spectrometer detection technology for VOC detection, while Makel demonstrated detection of inorganics and concepts for mask integration. Sandia demonstrated detection of many compounds from the EPA TO-15 Test Mixture, which is representative of many classes of compounds found in air, and can be purchased as a gas standard from a variety of suppliers. The work demonstrated for phase I was sufficient to move the team into phase II of the program, where a full prototype unit will be developed. This CRADA provided clear value to the taxpayer by allowing a US small business to continue to phase II of a competitive STTR proposal for the Air Force. This process will help to transition Sandia’s technology into the marketplace to address a clear DoD requirement.

Moorman, Matthew↗

Rational Design of Capacitive Pressure Sensors Based on Pyramidal Microstructures for Specialized Monitoring of Biosignals

Abstract There is an increasing demand for specialized pressure sensors in various applications. Previously, capacitive pressure sensors have been shown to have wide versatility in use, with a high degree of potential tuning possible through manipulating the geometry or material selection of the dielectric layer. However, in order to make sensors that are tunable and predictable, the design and fabrication method first needs to be developed. Presented here is an improved fabrication method to achieve tunable, consistent, and reproducible pressure sensors by using a pyramid microstructured dielectric layer along with a lamination layer. The as‐produced sensor performance is able to match predicted trends. Further, a simple model based on this system is developed and its efficacy is experimentally confirmed. Then, the model to predict a wide range of material and microstructure geometric properties prior to device fabrication is used to provide trends on sensor performance. Finally, it is demonstrated that the new method can be used to targetedly design a pressure sensor for a specific application—in vitro pulse sensing.

Ruth, Sara Rachel Arussy↗

Low-Power, Flexible Sensor Arrays with Solderless Board-to-Board Connectors for Monitoring Soil Deformation and Temperature: Supporting Data

This dataset was used to assess the potential of a Soil Deformation and Temperature Monitoring System developed and presented in the article named "Low-Power, Flexible Sensor Arrays with Solderless Board-to-Board Connectors for Monitoring Soil Deformation and Temperature" and published in Sensors. There are 21 comma-delimited data files (.csv). 14 files contain current measurements performed in a lab setting, enabling the electrical evaluation of the sensor probe. These files are generated by the Keithley DMM6500 multimeter, and list the measured supply current (first column) as a function of time (3rd column). Another set of 6 files is also acquired in lab experiments, but contain soil temperature an deformation measurements, enabling an assessment of the developed device's accuracy. In these files, the first column contains the time (UTC), followed by the sensor's battery voltage and temperature and acceleration values (X, Y, Z) in subsequent columns. The measurements were acquired every 5 seconds. Another .csv file contains field data in a similar format (time, temperature, acceleration) collected at the Teller road (mile 27) site near Nome, Alaska with one probe. The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research. The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska. Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗

Collider Physics Instrumentation

We are developing new technologies for particle tracking. These include 3D silicon sensors and devices for calibration and dosimetry in the HL-LHC fluence regime. We collaborate in the development of a new model for radiation damage in silicon - this is immediately relevant to extrapolations about the future of LHC tracker hardware. We lead radiation damage campaigns on behalf of many collaborating LHC institutes as well as ourselves, and we apply the results of these to development of new techniques for particle beam monitoring and operation of silicon detectors in variable environmental conditions.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Advanced In-situ Diagnostics for Multicomponent Gas Analysis and Material Aging

Current methods of detecting material aging rely heavily on accelerated aging studies expensive, bulky, and resource-hungry diagnostics. We are developing compact gas analysis methods based on sensor platforms such as quartz crystal microbalances (QCM), using nanoporous metals and Metal-Organic Frameworks (MOFs), which enhance sensitivity and impart selectivity to analytes. Targeted analytes are O2 and other volatile analytes. In FY16 we installed and tested a new QCM system coupled to a commercial gas mixing system. This instrumentation provides a new multi-use capability that: 1) allows evaluation of detection of novel materials to enable selective detection of volatile species relevant to Enhanced Surveillance; 2) accelerates development of new thin film deposition methods for depositing these materials on sensing devices; and 3) enables in-situ monitoring, with sub-monolayer sensitivity, of the interaction of volatile species with material surfaces subject to aging or corrosion.

36 MATERIALS SCIENCE↗

Heterogeneous Integration Technologies for High-temperature, High-density, Low-profile Power Modules of Wide Bandgap Devices in Electric Drive Applications (Final Technical Report)

The goal of this project is to develop packaging technologies for making high-temperature, high-density, and low-profile wide-bandgap (WBG) power electronics modules for electric drives. These modules are aimed at enabling the DOE’s University Consortium to reach its 2025 inverter targets of ≥ 100 kW/L and ≤ 2.7 $/kW. The specific objectives are to: design and fabricate SiC half-bridge power modules with double-sided cooling and parasitic inductances < 5 nH, heat flux density > 400 W/cm 2 , and working junction temperature of 200 o C; design, fabricate, and deliver a gate driver with double-sided cooled modules for the construction of a 100 kW/L inverter at Oak Ridge National Lab; and design and prototype intelligent gate drivers with integrated current sensor and a low-profile DC-DC power supply with air-core transformer for testing power modules at 200 o C junction temperature. We followed an iterative technical approach of design, simulation, fabrication, and testing of various versions of modules, current sensors, and power supply. The state-of-the-art silicon carbide devices rated at 1.2 kV and 149 A were packaged by sintered-silver bonding on an aluminum nitride direct-bond-copper substrate for high thermal conductivity, high working temperature, and high joint reliability. Porous silver posts were used to interconnect the device’s source pads to the other direct-bond-copper substrate for low mechanical stresses, ease of manufacturing, and double-sided cooling. A current sensor based on package parasitic inductance was developed to measure switching current. A dynamic feedback scheme was developed to compensate the effect of parasitic resistance and temperature variation. A constant-current class-E dc-dc converter with air-core transformer was developed. Air-core transformer was used due to the unavailability of magnetic core at high temperatures. Gate driver and power supply were integrated with the double-side cooled, high temperature SiC power modules for testing the modules at 200 o C junction temperature. Double-pulse and continuous testing of the integrated technologies validated the design and fabrication of the three component technologies. Throughout the project, we overcame the challenge for design verification caused by low prototyping yield, which then helped train the graduate students, the future workforce, to learn the engineering know-how for low-cost manufacturing of reliable products. Below is a summary of the major accomplishments of this project: development of a prototyping process for fabricating double-side cooled (1200 V, 149 A) SiC phase-leg modules capable of working to 200 o C Tj; simulation and experimental verification of the improvement of thermo-mechanical reliability of the double-side cooled SiC phase-leg module by using rigid encapsulant; design and experimental validation of a current sensor based on package parasitic inductance and a compensation solution for eliminating the effect of parasitic resistance; design and experimental validation of a low-profile power supply with six-output air-core transformer for gate driver; functional demonstration of a SiC phase-leg module integrated with its gate driver, current sensor, and an air-core power supply at 200 o C Tj in a double-pulse switching test setup and Buck converter continuous test setup; successful completion of six PhD and two MS students who are or will work at Apple Inc., Tesla Inc., Wolfspeed Inc., Microchip Inc., Monolithic Power Systems Inc., and LG Magna Inc.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

DIRECT SIMULTANEOUS MEASUREMENT OF PARTICULATE MATTER AND AMMONIA STORAGE ON COMBINED SELECTIVE CATALYTIC REDUCTION FILTER SYSTEMS USING RADIO FREQUENCY SENSORS

Tightening global emissions regulations are motivating interest in the development and implementation of Selective Catalytic Reduction + Filtration (SCRF) systems, which are designed to reduce the concentration of tailpipe particulate matter (PM) and NO x emissions. These systems allow designers to combine the NO x reduction capability of an SCR with the filtration capability of a particulate filter on a single unit. Practical implementation of these systems requires reliable measurement and diagnosis of their state – both with respect to trapped particulate matter as well as adsorbed ammonia. Currently, these systems rely on a variety of gas sensors, mounted upstream or downstream of the system, that only provide an indirect inference of the operation state. In this study, a single radio frequency (RF) sensor was used to perform simultaneous measurements of soot loading and ammonia inventory on an SCRF. Several SCRF core samples were tested at varying soot and ash loads in a catalyst reactor bench. Soot levels were measured by monitoring changes in the bulk dielectric properties within the catalyst using the sensor, while ammonia levels were determined by feeding selected regions of the RF spectrum into a pretrained generalized regression neural network model. Results show the RF sensor is able to directly measure the instantaneous ammonia inventory, while simultaneously providing soot loading measurements within 0.5 g/L. These results confirm that simultaneous measurements of both the PM and ammonia loading state of an SCRF are possible using a single RF sensor via analysis of specific features in the full RF spectrum. The results indicate significant potential to remove the control barriers typically associated with the implementation of advanced SCRF systems.

Ragaller, Paul↗

Calibration, measurement, and characterization of soil moisture dynamics in a central Amazonian tropical forest

Soil moisture plays a key role in hydrological, biogeochemical, and energy budgets of terrestrial ecosystems. Accurate soil moisture measurements in remote ecosystems such as the Amazon are difficult and limited because of logistical constraints. Time domain reflectometry (TDR) sensors are widely used to monitor soil moisture and require calibration to convert the TDR's dielectric permittivity measurement (K a ) to volumetric water content (θ v ). In this study, our objectives were to develop a field-based calibration of TDR sensors in an old-growth upland forest in the central Amazon, to evaluate the performance of the calibration, and then to apply the calibration to determine the dynamics of soil moisture content within a 14.2 -m-deep vertical soil profile. Depth-specific TDR calibration using local soils in a controlled laboratory setting yielded a novel K a –θ v third-degree polynomial calibration. The sensors were later installed to their specific calibration depth in a 14.2-m pit. The widely used K a –θ v relationship (Topp model) underestimated the site-specific θ v by 22–42%, indicating significant error in the model when applied to these well-structured, clay-rich tropical forest soils. The calibrated wet- and dry-season θ v data showed a variety of depth and temporal variations highlighting the importance of soil textural differentiation, root uptake depths, as well as event to seasonal precipitation effects. Data such as these are greatly needed for improving our understanding of ecohydrological processes within tropical forests and for improving models of these systems in the face of changing environmental conditions.

54 ENVIRONMENTAL SCIENCES↗