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At least 991 records · Page 55

Laboratory and astronomical identification of cyclopropenylidene, C3H2

Twenty-seven rotational lines of C3H2 have been identified in the laboratory or in astronomical sources, and the rotational and centrifugal distortion constants of this previously unobserved carbene ring determined to high accuracy. The assigned astronomical transitions include the strong, ubiquitous interstellar lines at 85,338 MHz and 18,343 MHz, which are the lowest lying transitions of ortho C3H2:2(12) to 1(01) and 1(10) to 1(01), respectively. Interstellar C3H2 can be rapidly formed by dissociative recombination of the very stable ion C3H3(+), which in turn can be produced from acetylene in only two stars. In standard molecular sources such as Ori A and Sgr B2, C3H2 is only moderately abundant, but in diffuse molecular clouds it may be one of the most abundant molecules. There is some radio spectroscopic evidence for two related molecules in Sgr B2 or TMC-1: ethynylmethylene HCCCH, a hypothetical carbon chain isomer, and cyclopropene, C3H4, a known, stable three-membered ring.

Thaddeus, P.↗

Application of Ni-63 photo and corona discharge ionization for the analysis of chemical warfare agents and toxic wastes

Over the past decade, advances in instrumental design and refinements in the understanding of ion molecule reactions at atmospheric pressure enabled the application of Ion Mobility Spectrometry (IMS) as a simple inexpensive and sensitive analytical method for the detection of organic trace compounds. Positive and negative gas-phase ions for ion mobility spectrometry have been produced by a variety of methods, including photo-ionization, laser multi photon ionization, surface ionization, corona discharge ionization. The most common ion source used in ion mobility spectrometry is a radioactive Ni-63 foil which is favored due to simplicity, stability, convenience, and high selectivity. If reactant ions like (H2O(n)H)(+) or (H2O(n)O2)(-) dominate in the reaction region, nearly all kinds of compounds with a given proton or electron affinity; are ionized. However, the radioactivity of the Ni-63 foil is one disadvantage of this ion source that stimulates the development and application of other ionization techniques. In this paper, we report analyses of old chemical warfare agents and toxic wastes using Bruker RAID ion mobility spectrometers. Due to the modular construction of the measuring cell, the spectrometers can be equipped with different ion sources. The combined use of Ni-63, photo- and corona discharge ionization allows the identification of different classes of chemical compounds and yields in most cases comparable results.

Stach, J.↗

Observations of 1E 1740.7-2942 with ROSAT and the VLA

We have observed the Galactic black hole candidate 1E 1740.7-2942 in X-rays with both the ROSAT high resolution imager (HRI) and position-sensitive proportional counter (PSPC) and at 1.5 and 4.9 GHz with the very large array (VLA). From the HRI observation we derive a position for 1E 1740.7-2942 of right ascension = 17(exp h) 43(exp m) 54.9(exp s), declination = -29 deg 44 min 45.3 sec (J2000), with a 90% confidence error circle of radius 8.5 sec. Thermal bremsstrahlung fits to the PSPC data yield a column density of 1.12 + 1.51 or -0.18 X 10(exp 23)/ sq cm, consistent with earlier X-ray measurements. The VLA observations of 4.9 GHz revealed two sources. Source A, which is the core of a double aligned radio jet source (Mirabel et al. 1992), lies within the ROSAT error circle, further confirming its identification with 1E 1740.7-2942.

Heindl, William A.↗

Observations of 1E 1740.7-2942 with ROSAT and the VLA

We have observed the Galactic black hole candidate 1E 1740.7-2942 in X-rays with both the ROSAT HRI and PSPC and at 1.5 and 4.9 GHz with the VLA. From the HRI observation we derive a position for 1E 1740.7-2942 of right ascension = 17 h 43 m 54.9 s, declination = -29 deg 44 min 45.3 sec (J2000), with a 90% confidence error circle of radius 8.5 min. Thermal bremsstrahlung fits to the PSPC data yield a column density of 1.12+1.51/-0.18 x 10(exp 23)/sq cm, consistent with earlier X-ray measurements. The VLA observation of 4.9 GHz revealed two sources. Source A, which is the core of a double aligned radio jet source (Mirabel et al. 1992), lies within the ROSAT error circle, further confirming its identification with 1E 1740.7-2942.

Heindl, William A.↗

Human and Natural Influences on the Changing Thermal Structure of the Atmosphere

Since the late 1970s, satellite-based instruments have monitored global changes in atmospheric temperature. These measurements reveal multidecadal tropospheric warming and stratospheric cooling, punctuated by short-term volcanic signals of reverse sign. Similar long- and short-term temperature signals occur in model simulations driven by human-caused changes in atmospheric composition and natural variations in volcanic aerosols. Most previous comparisons of modeled and observed atmospheric temperature changes have used results from individual models and individual observational records. In contrast, we rely on a large multimodel archive and multiple observational datasets. We show that a human-caused latitude/altitude pattern of atmospheric temperature change can be identified with high statistical confidence in satellite data. Results are robust to current uncertainties in models and observations. Virtually all previous research in this area has attempted to discriminate an anthropogenic signal from internal variability. Here, we present evidence that a human-caused signal can also be identified relative to the larger "total" natural variability arising from sources internal to the climate system, solar irradiance changes, and volcanic forcing. Consistent signal identification occurs because both internal and total natural variability (as simulated by state-of-the-art models) cannot produce sustained global-scale tropospheric warming and stratospheric cooling. Our results provide clear evidence for a discernible human influence on the thermal structure of the atmosphere.

Santer, Benjamin D.↗

3DBFSVBF (3D BatFinder Smart Video BioFilter and Multi-class BatFinder Smart Video BioFilter) [SWR-22-88]

Bats are notoriously difficult to study, therefore, identifying specific behavioral trends and the precise environmental conditions at the time of collision requires a monitoring solution that can reliably collect relevant data. To date, thermal infrared video surveillance has been extensively applied to study bats and has proven to be a powerful yet cumbersome tool. Current analytical approaches are time consuming because data processing data has not been fully automated. In the past, steps have been taken to record avian and bat activity in conjunction with complicated image processing techniques that separate species from other moving objects within the field of view (i.e. clouds and portions of the wind turbine). Once the videos are collected, the post-processing does not allow real time monitoring and identification, leading to a delay in both studying the behavior of these species and determining the effectiveness of any impact reduction strategy being studied. Moreover, object identification capability is lacking, thus limiting the usefulness of video data. To resolve these issues, we are using open source 3D computer vision and machine learning techniques allowing for automatic detection of objects in real-time with the ability to correlate these objects with environmental variables and recording the flight paths of each object. The machine learning has been trained on 3D data and allows for automated real-time data collection, identification and tracking, thereby eliminating the need for long and tedious post-analysis processing of the videos. This machine learning model is an added feature to the previous BatFinder Smart Video BioFilter and increases the accuracy of that systems classification by increasing the accuracy of identifying bats (90% accuracy) and insects (69% accuracy) to a 97% accuracy. There are two object classifier machine learning models, Binary and multi-classification. Binary object classifier labeled BatFinder_Smart_Video_BioFilter.h5 distinguishes between biological objects and non-biological objects. The main goal of this object classifier is to ignore the turbine blades while detecting biological object flying withing the rotor swept area of the turbine. Non-biological objects have a probability of 0 and biological objects have a probability of 1. Multi-classifier labeled Multiclass_BatFinder_Smart_Video_BioFilter.h5 distinguishes between bats, birds, insects and non-biological.

Yarbrough, John↗

Uncertainty quantification of a physics-informed model based on sparse identification of a Thermal Energy Distribution System

Integrated energy systems (IES)s are crucial for enhancing the economy and efficiency of power generation sources (e.g., nuclear energy) necessary to unleash American energy dominance. These systems can be integrated with thermal energy storage (TES) and intermittent renewable energies to optimize overall energy use, peak-load regulation, and demand-side responses. However, the stabilization of energy generation, transport, and utilization introduces operational complexities that exceed the challenges of managing each sub-component individually. Currently, though IESs rely on human operators for efficiency and stability, reducing human error risk and enhancing performance through automation is highly desirable. Recent advances at Idaho National Laboratory have demonstrated successful control of the Thermal Energy Distributed System (TEDS). However, the automatic control system depends on a deterministic Sparse Identification of Nonlinear Dynamics with Control (SINDyC) model, which are trained based on simulation data from physics-based simulations. Because of uncertainties in physics-based simulation, SINDyC model results in large discrepancies against experimental data and cannot be reliably used in automatic control. In this paper, we present an innovative approach to address these discrepancies by quantifying uncertainties and developing a more robust model. We first generated trajectories by using first-principles physics codes to encapsulate the experiment. Next, we trained thousands of models by randomly sampling these trajectories. We then collapsed all those models into one probabilistic SINDyC by fitting a multivariate Gaussian distribution onto the resulting coefficient’s distribution. Despite its simplicity, our approach successfully produced 95% confidence intervals that captured the experimental trajectories. It even did so with a higher probability and better U-pooling score across six of the seven relevant quantities of interest (QoIs), as compared to other classical approaches. In conclusion, ongoing research is focusing on generating new experimental trajectories to validate this approach, and on employing Bayesian calibration to refine parametric uncertainties and guide future model development efforts.

22 - GENERAL STUDIES OF NUCLEAR REACTORS↗

Spectroscopy of the extranuclear line-emitting regions associated with the gravitational lens system 2016 + 112

Moderate-resolution slit spectroscopy of the extended emission-line objects A1 and B1 located within 5 arcsec of the triple radio source 2016 + 112 shows that at least one is physically associated with the z = 3.273 quasar thought to be multiply imaged by a foreground galaxy. The data and theoretical models unanimously favor the identification of A1 and B1 with two separate clouds of ionized gas that lie within a few kiloparsecs of the primary A/B QSO and radio source. The available evidence does not support the view that they are multiple images of a single object or their classification as separate (companion) galaxies.

Schneider, D. P.↗

SHEEP: The Search for the High Energy Extragalactic Population

We present the SHEEP survey for serendipitously-detected hard X-ray sources in ASCA GIS images. In a survey area of approx. 40 sq deg, 69 sources were detected in the 5-10 keV band to a limiting flux of approx. 10(exp -13) erg/sq cm/s. The number counts agree with those obtained by the similar BeppoSAX HELLAS survey, and both are in close agreement with ASCA and BeppoSAX 2-10 keV surveys. Spectral analysis of the SHEEP sample reveals that the 2-10 and 5-10 keV surveys do not sample the same populations, however, as we find considerably harder spectra, with an average Gamma approx. 1.0 assuming no absorption. The implication is that the agreement in the number counts is coincidental, with the 5-10 keV surveys gaining approximately as many hard sources as they lose soft ones, when compared to the 2-10 keV surveys. This is hard to reconcile with standard AGN "population synthesis" models for the X-ray background, which posit the existence of a large population of absorbed sources. We find no evidence of the population hardening at faint fluxes, with the exception that the few very brightest objects are anomalously soft. 53 of the SHEEP sources have been covered by ROSAT in the pointed phase. Of these 32 were detected. An additional 3 were detected in the RASS. As expected the sources detected with ROSAT are systematically softer than those detected with ASCA alone, and of the sample as a whole. Although they represent a biased subsample, the ROSAT positions allow relatively secure catalog identifications to be made. We find associations with a wide variety of AGN and a few clusters and groups. At least two X-ray sources identified with high-z QSOs present very hard X-ray spectra indicative of absorption, despite the presence of broad optical lines. A possible explanation for this is that we are seeing relatively dust-free "warm absorbers" in high luminosity/redshift objects. Our analysis defines a new, hard X-ray selected sample of objects - mostly active galactic nuclei - which is less prone to bias due to obscuration than previous optical or soft X-ray samples. They are therefore more representative of the population of AGN in the universe in general, and the SHEEP survey should produce bright examples of the sources that make up the hard X-ray background, the majority of which has recently been resolved by Chandra. This should help elucidate the nature of the new populations.

Nandra, K.↗

Uranium-Bearing Evaporite Mineralization Influencing Plume Persistence. Literature Review and DOE-LM Site Surveys

This report on evaporite mineralization was completed as an Ancillary Work Plan for the Applied Studies and Technology program under the U.S. Department of Energy (DOE) Office of Legacy Management (LM). This study reviews all LM sites under Title I and Title II of the Uranium Mill Tailings Radiation Control Act (UMTRCA) and one Decontamination and Decommissioning site to provide (1) a summary of which sites have evaporite deposits, (2) any available quantitative geochemical and mineralogical analyses, and (3) references to relevant reports. In this study, “evaporite” refers to any secondary mineral precipitate that occurs due to a loss of water through evaporative processes. This includes efflorescent salt crusts, where this term refers to a migration of dissolved constituents to the surface with a resulting salt crust, where “salt” can refer to any secondary precipitate, regardless of constituents. The potential for the formation of evaporites at LM sites has been identified, and may have relevance to plume persistence issues. Evaporite deposits have the potential to concentrate and store contaminants at LM sites that could later be re-released. These deposits can also provide a temporary storage mechanism for carbonate, chloride, and sulfate salts along with uranium and other contaminants of concern (COCs). Identification of sites with evaporites will be used in a new technical task plan (TTP), Persistent Secondary Contaminant Sources (PeSCS), for any proposed additional sampling and analyses. This additional study is currently under development and will focus on determining if the dissolution of evaporites has the potential to hinder natural flushing strategies and impact plume persistence. This report provides an initial literature review on evaporites followed by details for each site with identified evaporites. The final summary includes a table listing of all relevant LM sites regardless of evaporite identification.

54 ENVIRONMENTAL SCIENCES↗

Analytical Identification Method of Generalized Short‐Circuit Ratio Using Phasor Measurement Units

This paper introduces a novel analytical approach for the identification of the admittance matrix and the generalized short-circuit ratio (gSCR) in power systems integrated with renewable energy sources. The proposed method leverages voltage and current measurements from phasor measurement units (PMUs) to construct a least squares objective function, which is then solved using matrix calculus and partial derivatives. Unlike conventional optimization algorithms, this approach provides an analytical solution that substantially reduces data requirements, enabling the efficient and accurate identification of the gSCR with smaller datasets. Additionally, its fixed computational complexity allows for real-time updates as new data are collected, ensuring continuous refinement of the system of equations and enabling rapid, precise gSCR calculations. The method also exhibits strong robustness against measurement noise, making it well-suited for practical applications in dynamic power systems. The combination of reduced data requirements, real-time adaptability, noise robustness and fixed computational load establishes this method as a highly efficient and reliable tool for real-time power system stability analysis. Case studies on an EPRI 36-bus system demonstrate the method's effectiveness, highlighting its accuracy in closely matching true gSCR values, even under diverse disturbances and noisy conditions.

Han, Zelei [Hohai University, Nanjing (China)] (OR↗

Discovery of 3.6-s X-ray pulsations from 4U0115+63

SAS 3 observations reveal a pulsation period of 3.61 sec for the transient X-ray source 4U0115+63. Positional measurement is accurate to approximately 30 arc s, and has led to the likely identification of an optical counterpart. The intensity of the pulses, as reported on 5.9 January 1978, is given as approximately 1.7 times that of the Crab Nebula (1-27 keV). Spectral information was also obtained from the ratios of counting rates in the first three energy channels of the center slat collimator detector (1-27 keV). Two classes of models are proposed to explain the transient nature of the X-ray sources: (1) episodic mass transfer in a binary system, and (2) eccentric binary orbits.

Cominsky, L.↗

Acoustic Research under the Source Physics Experiment

The Source Physics Experiment series is a long-term research and development (R&D) effort under the U.S. Department of Energy’s National Nuclear Security Administration focused on improving the physical understanding of how chemical explosions generate seismoacoustic signals. Beginning in 2011, a series of subsurface chemical explosions in two different and highly contrasting geologies were conducted at the Nevada National Security Site in Nevada, USA with the objective of improving simulation and modeling approaches to explosion identification, yield estimation and other monitoring applications. The two executed phases of the series provide new explosion signature source data from a wide range of geophysical diagnostic equipment; recorded data from the test series is now openly available to the broader seismoacoustic community. This manuscript details the executed test series, deployed seismoacoustic networks, and summarizes major scientific achievements utilizing recorded signatures from the explosive tests.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Improved position and new optical candidate for A0538-66

An analysis of HEAO 1 modulation collimator data leading to an improved position determination and a new optical counterpart candidate for the transient X-ray source A0538-66 is reported. Data obtained during five outbursts, all of which were separated by 16.7 days or a small multiple thereof, indicates that the outbursts, although of varying duration, intensity, and hardness ratio originated from the same source, at a position of 5 h 35 min 42.7 sec RA and 66 deg 53 arcmin 44 arcsec dec. The improved position determination is found to exclude the previously suggested optical counterpart, and a search of archive plates of the Large Magellanic cloud in the refined error regions has lead to the tentative identification of a B-type star with an observed B variability of 1 mag with the X-ray source.

Johnston, M. D.↗

Spectroscopic identification of 2,3-dimethylbut-2-ene transients in 2,3-dimethylbut-2-ane flames

Combustion reactions provide the principal energy source of the world yet they are creating a burden through pollution. A detailed understanding of the complicated chemistry of flames is essential for optimizing energy output while minimizing detrimental side effects. Here, we present a measurement technique based on time domain, resonance-enhanced multiphoton ionization via Rydberg states followed by laser-induced plasma backscattering of microwaves and demonstrate this non-intrusive, in-situ technique by selectively identifying 2,3-dimethylbut-2-ene in a complex 2,3-dimethylbut-2-ane flame environment.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

High resolution identification and quantification of diffuse deep groundwater discharge in mountain rivers using continuous boat-mounted helium measurements

Discharge of deeply sourced groundwater to streams is difficult to locate and quantify, particularly where both discrete and diffuse discharge points exist, but diffuse discharge is one of the primary controls on solute budgets in mountainous watersheds. The noble gas helium is a unique identifier of deep groundwater discharge because groundwater with long residence times is commonly enriched in helium. In this study, a portable mass spectrometer was used to measure longitudinal variation in dissolved helium concentrations in two mountainous rivers at high spatial resolution not feasible with traditional sampling techniques. Helium profiles were then simulated using a mass-balance model to quantify longitudinal variation in groundwater discharge to the receiving rivers. Results indicate helium concentrations were enriched by multiple orders of magnitude above atmospheric equilibrium in both rivers and that this persisted for up to 18 km below observed pulse inputs in the Colorado River. Helium mass-balance models match observed longitudinal patterns with the exception of sharp initial increases in helium observed in the rivers. Increased longitudinal groundwater discharge rates correspond to mapped geologic structures in both watersheds that likely transport deep geothermal water. Models show variable sensitivity to spatial assignment of input variables representing the groundwater source, illustrating the importance of collecting data from discrete groundwater discharges where possible. The methodology shows promise for field experiments designed to assess air–water exchange rates and to quantify total groundwater discharge from a combination of discrete and diffuse sources.

Deep groundwater↗

Contamination Control in Hybrid Microelectronic Modules. Part 1: Identification of Critical Process and Contaminants

Various hybrid processing steps, handling procedures, and materials are examined in an attempt to identify sources of contamination and to propose methods for the control of these contaminants. It is found that package sealing, assembly, and rework are especially susceptible to contamination. Moisture and loose particles are identified as the worst contaminants. The points at which contaminants are most likely to enter the hybrid package are also identified, and both general and specific methods for their detection and control are developed. In general, the most effective controls for contaminants are: clean working areas, visual inspection at each step of the process, and effective cleaning at critical process steps. Specific methods suggested include the detection of loose particles by a precap visual inspection, by preseal and post-seal electrical testing, and by a particle impact noise test. Moisture is best controlled by sealing all packages in a clean, dry, inert atmosphere after a thorough bake-out of all parts.

Himmel, R. P.↗

The identification of H2311 + 77 with HD220140, a probable RS CVn star

H2311 + 77, one of the bright soft X-ray sources in the sky originally detected with HEAO 1, has been identified in an Exosat imaging observation with a 7.7-mag late-type star, HD220140. The X-ray luminosity and the optical characteristics of this star indicate that it is probably an RS CVn binary system.

Pravdo, S. H.↗