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At least 991 records · Page 55

Low dislocation density InAlN/AlN/GaN heterostructures grown on GaN substrates and the effects on gate leakage characteristics

This paper reports on the electrical characterization of Ni/Au Schottky diodes fabricated on InAlN high-electron-mobility transistor (HEMT) structures grown on low dislocation density free-standing GaN substrates. InAlN HEMT structures were grown on sapphire and GaN substrates by metal-organic vapor phase epitaxy, and the effects of threading dislocation density on the leakage characteristics of Ni/Au Schottky diodes were investigated. Threading dislocation densities were determined to be 1.8 × 10{sup 4 }cm{sup −2} and 1.2 × 10{sup 9 }cm{sup −2} by the cathodoluminescence measurement for the HEMT structures grown on GaN and sapphire substrates, respectively. Leakage characteristics of Ni/Au Schottky diodes were compared between the two samples, and a reduction of the leakage current of about three to four orders of magnitude was observed in the forward bias region. For the high reverse bias region, however, no significant improvement was confirmed. We believe that the leakage current in the low bias region is governed by a dislocation-related Frenkel–Poole emission, and the leakage current in the high reverse bias region originates from field emission due to the large internal electric field in the InAlN barrier layer. Our results demonstrated that the reduction of dislocation density is effective in reducing leakage current in the low bias region. At the same time, it was also revealed that another approach will be needed, for instance, band modulation by impurity doping and insertion of insulating layers beneath the gate electrodes for a substantial reduction of the gate leakage current.

36 MATERIALS SCIENCE↗

Effects of substrate orientation on the growth of InSb nanostructures by molecular beam epitaxy

In this work, the effects of substrate orientation on InSb quantum structure growth by molecular beam epitaxy (MBE) are presented. Motivated by the observation that (411) evolves naturally as a stable facet during MBE crystal growth, comparison studies have been carried out to investigate the effects of the crystal orientation of the underlying GaSb substrate on the growth of InSb by MBE. By depositing InSb on a number of different substrate orientations, namely: (100), (311), (411), and (511), a higher nanostructure density was observed on the (411) surface compared with the other orientations. This result suggests that the (411) orientation presents a superior surface in MBE growth to develop a super-flat GaSb buffer surface, naturally favorable for nanostructure growth.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Characterization of reclaimed GaAs substrates and investigation of reuse for thin film InGaAlP LED epitaxial growth

This study reports a method to reuse GaAs substrates with a batch process for thin film light emitting diode (TF-LED) production. The method is based on an epitaxial lift-off technique. With the developed reclaim process, it is possible to get an epi-ready GaAs surface without additional time-consuming and expensive grinding/polishing processes. The reclaim and regrowth process was investigated with a one layer epitaxial test structure. The GaAs surface was characterized by an atomic force microscope directly after the reclaim process. The crystal structure of the regrown In{sub 0.5}(Ga{sub 0.45}Al{sub 0.55}){sub 0.5}P (Q{sub 55}) layer was investigated by high resolution x-ray diffraction and scanning transmission electron microscopy. In addition, a complete TF-LED grown on reclaimed GaAs substrates was electro-optically characterized on wafer level. The crystal structure of the epitaxial layers and the performance of the TF-LED grown on reclaimed substrates are not influenced by the developed reclaim process. This process would result in reducing costs for LEDs and reducing much arsenic waste for the benefit of a green semiconductor production.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Nickel enhanced graphene growth directly on dielectric substrates by molecular beam epitaxy

The efficacy of Ni as a surfactant to improve the crystalline quality of graphene grown directly on dielectric Al{sub 2}O{sub 3}(0001) substrates by molecular beam epitaxy is examined. Simultaneously exposing the substrate to a Ni flux throughout C deposition at 950 °C led to improved charge carrier mobility and a Raman spectrum indicating less structural disorder in the resulting nanocrystalline graphene film. X-ray photoelectron spectroscopy confirmed that no residual Ni could be detected in the film and showed a decrease in the intensity of the defect-related component of the C1s level. Similar improvements were not observed when a lower substrate temperature (850 °C) was used. A close examination of the Raman spectra suggests that Ni reduces the concentration of lattice vacancies in the film, possibly by catalytically assisting adatom incorporation.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Low energy electron irradiation induced carbon etching: Triggering carbon film reacting with oxygen from SiO{sub 2} substrate

We report low-energy (50–200 eV) electron irradiation induced etching of thin carbon films on a SiO{sub 2} substrate. The etching mechanism was interpreted that electron irradiation stimulated the dissociation of the carbon film and SiO{sub 2}, and then triggered the carbon film reacting with oxygen from the SiO{sub 2} substrate. A requirement for triggering the etching of the carbon film is that the incident electron penetrates through the whole carbon film, which is related to both irradiation energy and film thickness. This study provides a convenient electron-assisted etching with the precursor substrate, which sheds light on an efficient pathway to the fabrication of nanodevices and nanosurfaces.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Growth of L1{sub 0}-ordered crystal in FePt and FePd thin films on MgO(001) substrate

Formation of L1{sub 0}-oredered structure from disordered A1 phase has been investigated for FePt and FePd films on MgO(001) substrates employing a two-step method consisting of low temperature deposition at 200 °C followed by high-temperature annealing at 600 °C. L1{sub 0}-(001) variant crystal with the c-axis perpendicular to the substrate grows preferentially in FePd films whereas L1{sub 0}-(100), (010) variants tend to be mixed with the L1{sub 0}-(001) variant in FePt films. The structure analysis by X-ray diffraction indicates that a difference in A1 lattice strain is the influential factor that determines the resulting L1{sub 0}-variant structure in ordered thin films. Misfit dislocations and anti-phase boundaries are observed in high-resolution transmission electron micrographs of 10 nm-thick Fe(Pt, Pd) film consisting of L1{sub 0}-(001) variants which are formed through atomic diffusion at 600 °C in a laterally strained FePt/PeFd epitaxial thin film. Based on the experimental results, a nucleation and growth model for explaining L1{sub 0}-variant formation is proposed, which suggests a possibility in tailoring the L1{sub 0} variant structure in ordered magnetic thin films by controlling the alloy composition, the layer structure, and the substrate material.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Water at the graphene–substrate interface: interaction with short laser pulses

We have investigated the role of adsorption water in the local transformation of multilayer graphene deposited on an oxidised silicon substrate, which was exposed to nanosecond low-intensity focused laser radiation with a wavelength of 532 nm in the air. Experimental data obtained for a laser energy density E = 0.04 J cm{sup -2} suggest that the formation of micropits (craters) is a consequence of the multipulse removal of the layer of a water adsorbate, which is intercalated between graphene and the substrate, from the zone of laser irradiation of the graphene sheet. The energy threshold of graphene damage in the regions devoid of water was found to be higher in comparison with the initial one (0.058 against 0.048 J cm{sup -2}). According to computer simulations of the heating dynamics of the sample and the heat distribution in the substrate – adsorbate – graphene multilayer system, at energy densities corresponding to the experimental ones the water adsorbate layer heats to a temperature sufficiently high to form an increased-pressure vapour cavity under the graphene film. (interaction of laser radiation with matter)

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Mid-IR reflectance spectrum of multilayer graphene: Influence of adsorbate at the graphene – substrate interface

Water adsorbate at the interface between graphene and SiO{sub 2}/Si substrate is found to affect the reflectance spectra of (3 – 6)-layer graphene in the mid-IR range (λ = 2 – 16 μm). The sample under study was previously kept in acetone vapour to remove water adsorbate from the graphene – substrate interface. The graphene reflectance in the range of 8 – 16 μm tends to decrease with recovery of water adsorbate layer at the graphene – substrate interface at room temperature and relative air humidity RH = 40 % – 60 %. The observed effect is most likely caused by the blue shift of the absorption edge at interband transitions due to the change in the Fermi level position in the graphene valence band under the influence of the charge induced in graphene by the water adsorbate film. (paper)

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Substrate Preferences and Catalytic Parameters Determined by Structural Characteristics of Sterol 14[alpha]-Demethylase (CYP51) from Leishmania infantum

Leishmaniasis is a major health problem that affects populations of {approx}90 countries worldwide, with no vaccine and only a few moderately effective drugs. Here we report the structure/function characterization of sterol 14{alpha}-demethylase (CYP51) from Leishmania infantum. The enzyme catalyzes removal of the 14{alpha}-methyl group from sterol precursors. The reaction is essential for membrane biogenesis and therefore has great potential to become a target for antileishmanial chemotherapy. Although L. infantum CYP51 prefers C4-monomethylated sterol substrates such as C4-norlanosterol and obtusifoliol (V{sub max} of {approx}10 and 8 min{sup -1}, respectively), it is also found to 14{alpha}-demethylate C4-dimethylated lanosterol (V{sub max} = 0.9 min{sup -1}) and C4-desmethylated 14{alpha}-methylzymosterol (V{sub max} = 1.9 min{sup -1}). Binding parameters with six sterols were tested, with K{sub d} values ranging from 0.25 to 1.4 {mu}m. Thus, L. infantum CYP51 is the first example of a plant-like sterol 14{alpha}-demethylase, where requirements toward the composition of the C4 atom substituents are not strict, indicative of possible branching in the postsqualene portion of sterol biosynthesis in the parasite. Comparative analysis of three CYP51 substrate binding cavities (Trypanosoma brucei, Trypanosoma cruzi, and L. infantum) suggests that substrate preferences of plant- and fungal-like protozoan CYP51s largely depend on the differences in the enzyme active site topology. These minor structural differences are also likely to underlie CYP51 catalytic rates and drug susceptibility and can be used to design potent and specific inhibitors.

59 BASIC BIOLOGICAL SCIENCES↗

System-wide Studies of N-Lysine Acetylation in Rhodopseudomonas palustris Reveals Substrate Specificity of Protein Acetyltransferases

Background: Protein acetylation is widespread in prokaryotes. Results: Six new acyl-CoA synthetases whose activities are controlled by acetylation were identified, and their substrate preference established. A new protein acetyltransferase was also identified and its substrate specificity determined. Conclusion: Protein acetyltransferases acetylate a conserved lysine residue in protein substrates. Significance: The R. palustris Pat enzyme specifically acetylates AMP-forming acyl-CoA synthetases and regulates fatty acid metabolism.

59 BASIC BIOLOGICAL SCIENCES↗

Controllable corrosion-assisted fabrication of Au–Ag alloyed hollow nanocrystals for highly efficient and environmentally-stable SERS substrates

Surface enhanced Raman scattering (SERS) substrates with both high activity and long term chemical-stability have been expected in the practical application of the SERS-based detection. In this paper, Au–Ag bimetal nanocrystals are fabricated based on the template-etching reaction in the Ag nanocubes-contained cetylpyridinium chloride (CPC) aqueous solution via adding the HAuCl 4 solution. The obtained nanocrystals are Au–Ag alloyed and hollow in structure. Further, it has been found that with the increasing Au/Ag molar ratio, the shape of the alloyed nanocrystals evolve from the truncated nanocubes to the hollow boxes and then nanocages, showing the ever red-shifting surface plasmon resonance from the visible to the infrared region. The formation of the alloyed hollow nanocrystals is attributed to the preferential dissolution of the Ag nanocubes induced by CPC selective adsorption and the three to one galvanic replacement reaction between Ag and Au atoms. Importantly, such Au–Ag alloyed hollow nanocrystals, especially the ones with a low Au/Ag atomic ratio, show both high SERS activity and long term environmental stability compared with pure Ag or Au nanocrystals, and are the ideal candidate for the SERS substrate with practical application value. As a result, this work not only demonstrates the nanofabrication route to the alloyed hollow nanocrystals with controllable shapes and tunable optical properties in a large region, but also presents highly active and chemically-stable SERS substrates for the practical SERS-based detection.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Towards a III-V Solar Cell with a Metamorphic Graded Buffer Directly Grown on V-Groove Si Substrates

V-groove Si substrates offer a promising route for the direct growth of III-V solar cells on low-cost, photovoltaic-grade Si. In this work, we develop a method for coalescing GaP nucleated on V-groove substrates into thin films suitable for the growth of III-V solar cells. We demonstrate the ability to suppress nucleation-related defects by modifying the V-groove substrate to cover the (0 0 1)-oriented Si V-groove tops with SiN x . A threading dislocation density (TDD) of 5 × 10 7 cm -2 was measured with electron channeling contrast imaging. Continuing work will focus on further reducing the TDD and the growth of a GaAs solar cell on a GaP on V-groove Si template.

41 EE - Solar Energy Technologies Office (EE-4S)↗

Glancing angle deposition of Ge nanorod arrays on Si patterned substrates

A periodic arrangement of Ge nanorods on a Si(111) substrate was realized by glancing angle deposition (GLAD) onto honeycomb-like arranged Au hillocks formed using a self-assembled monolayer of polystyrene nanospheres as an evaporation mask. Additionally, a honeycomb-like arrangement of Au dots was used as an etch mask in a reactive ion beam etching process for pattern transfer procedure. Resulting honeycomb patterns consisting of Si hillocks within the Si(111) substrates were utilized to deposit Ge nanorods. Effective morphological variations in shape and dimension of GLAD-grown nanorods on honeycomb-like patterned substrates with both Au dot and Si dot arrays are strongly influenced by interseed distances, seed heights, and consequently shadowing lengths. For a large pattern period, it was observed that the usual triangular shape of the nanorod changed to a hexagonal shape as an effect of additional particle flux that reached the growing nanorod from the direction of second and third-nearest neighbors due to inadequate shadowing lengths and increased interseed condensation.

36 MATERIALS SCIENCE↗

Effect of target-substrate distance on properties of flexible InZnSnO films grown by linear facing target sputtering

The authors have investigated the effect of target-to-substrate distance (TSD) on the electrical, optical, and structural properties of flexible InZnSnO (IZTO) films grown on polyethylene terephthalate substrates using linear facing target sputtering (LFTS) at room temperature. The electrical and optical properties of IZTO film grown by LFTS were significantly influenced by TSD while the structural and surface properties of IZTO film were not affected by TSD, unlike conventional magnetron sputtering. Regardless of TSD, all IZTO film showed completely amorphous structure with very low root mean square roughness of 0.33 nm, due to the low kinetic energy of sputtered IZTO atoms and a substrate position that did not directly face the targets. Based on the figure of merit value, the optimized TSD for deposition of flexible IZTO films is 2.5 cm. At optimized conditions, the IZTO film showed a sheet resistance of 23.1 {Omega}/sq and an optical transmittance of 80%.

36 MATERIALS SCIENCE↗

Evolution of morphology and structure of Pb thin films grown by pulsed laser deposition at different substrate temperatures

Pb thin films were prepared by pulsed laser deposition on a Si (100) substrate at different growth temperatures to investigate their morphology and structure. The morphological analysis of the thin metal films showed the formation of spherical submicrometer grains whose average size decreased with temperature. X-ray diffraction measurements confirmed that growth temperature influences the Pb polycrystalline film structure. A preferred orientation of Pb (111) normal to the substrate was achieved at 30 °C and became increasingly pronounced along the Pb (200) plane as the substrate temperature increased. These thin films could be used to synthesize innovative materials, such as metallic photocathodes, with improved photoemission performances.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Impact of surface morphology of Si substrate on performance of Si/ZnO heterojunction devices grown by atomic layer deposition technique

In this paper, the authors have investigated the structural, optical, and electrical characteristics of silicon nanowire (SiNW)/zinc oxide (ZnO) core–shell nanostructure heterojunctions and compared their characteristics with Si/ZnO planar heterojunctions to investigate the effect of surface morphology of Si substrate in the characteristics of Si/ZnO heterojunction devices. In this work, ZnO thin film was conformally deposited on both p-type 〈100〉 planar Si substrate and substrate with vertically aligned SiNW arrays by atomic layer deposition (ALD) method. The x-ray diffraction spectra show that the crystalline structures of Si/ZnO heterojunctions are having (101) preferred orientation, whereas vertically oriented SiNW/ZnO core–shell heterojunctions are having (002)-oriented wurtzite crystalline structures. The photoluminescence (PL) spectra of Si/ZnO heterojunctions show a very sharp single peak at 377 nm, corresponding to the bandgap of ZnO material with no other defect peaks in visible region; hence, these devices can have applications only in UV region. On the other hand, SiNW/ZnO heterojunctions are having band-edge peak at 378 nm along with a broad emission band, spreading almost throughout the entire visible region with a peak around 550 nm. Therefore, ALD-grown SiNW/ZnO heterojunctions can emit green and red light simultaneously. Reflectivity measurement of the heterojunctions further confirms the enhancement of visible region peak in the PL spectra of SiNW/ZnO heterojunctions, as the surface of the SiNW/ZnO heterojunctions exhibits extremely low reflectance (<3%) in the visible wavelength region compared to Si/ZnO heterojunctions (>20%). The current–voltage characteristics of both Si/ZnO and SiNW/ZnO heterojunctions are measured with large area ohmic contacts on top and bottom of the structure to compare the electrical characteristics of the devices. Due to large surface to-volume ratio of SiNW/ZnO core–shell heterojunction devices, the output current rating is about 130 times larger compared to their planar version at 2 V forward bias voltage. This higher output current rating can be exploited for fabricating high-performance nanoelectronic and optoelectronic devices in near future.

42 ENGINEERING↗

Highly (001) oriented L1{sub 0}-CoPt/TiN multilayer films on glass substrates with perpendicular magnetic anisotropy

To obtain strong perpendicular magnetic anisotropy (PMA) based on L1{sub 0} structure for magnetic storage devices, costly single crystalline substrates are generally required to achieve (001) texture. Recently, various studies also have focused on depositing different kinds of seed layers on glass or other amorphous substrates to promote (001) preferred orientation of L1{sub 0} CoPt and FePt. TiN is a very promising seed layer material because of its cubic crystalline structure (similar to MgO) and excellent diffusion barring property even at high temperatures. In the present work, highly (001) oriented L1{sub 0}-CoPt/TiN multilayer films have been successfully deposited on glass substrates. After annealing at 700 °C, the film exhibits PMA, and a strong (001) peak is detected from the x-ray diffraction profiles, indicating the ordering transformation of CoPt layers from fcc (A1) to L1{sub 0} structure. It also is found that alternate deposition of cubic TiN and CoPt effectively improves the crystallinity and (001) preferred orientation of CoPt layers. This effect is verified by the substantial enhancement of (001) reflection and PMA with increasing the period number of the multilayer films.

36 MATERIALS SCIENCE↗

Growth optimization and characterization of GaN epilayers on multifaceted (111) surfaces etched on Si(100) substrates

The four nearest Si(111) multifaceted sidewalls were exposed inside an array of 3 μm-wide square holes patterned on an Si(100) substrate, and this patterned Si(100) substrate was used as a substrate for the deposition of a gallium nitride (GaN) epilayer. Subsequently the effect that the growth pressure, the etched-hole profiles, and the etched-hole arrangement had upon the quality of the as-grown GaN was investigated. The coalescence of the as-grown GaN epilayer on the exposed Si(111) facets was observed to be enhanced with reduced growth pressure from 120 to 90 Torr. A larger Si(001) plane area at the bottom of the etched holes resulted in bidirectional GaN domains, which resulted in poor material quality. The bidirectional GaN domains were observed as two sets of six peaks via a high-resolution x-ray diffraction phi scan of the GaN(10-11) reflection. It was also shown that a triangular array of etched holes was more desirable than square arrays of etched holes for the growth high-quality and continuous GaN films.

42 ENGINEERING↗