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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 991 records · Page 55
All sourcesNASA NTRSDOE OSTI
DOE OSTI2014

Studies on structural, dielectric, and transport properties of Ni{sub 0.65}Zn{sub 0.35}Fe{sub 2}O{sub 4}

We report the crystal structure, dielectric, transport, and magnetic properties of Ni{sub 0.65}Zn{sub 0.35}Fe{sub 2}O{sub 4}. Rietveld refinement results of X-ray diffraction patterns confirm the phase formation of the material with cubic crystal structure (Fd3{sup ¯}m). The frequency dependent ac conductivity behavior obeys the Jonscher's power law and is explained using the jump relaxation model. The observed behavior of temperature dependent bulk conductivity is attributed to the variable-range hopping of localized polarons. The correlation of polaron conduction and high permittivity behavior of NZFO is established on the basis of long range and short range conduction mechanisms. The complex impedance spectra clearly show the contribution of both grain and grain boundary effect on the electrical properties.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2014

Recombination dynamics of excitons with low non-radiative component in semi-polar (10-11)-oriented GaN/AlGaN multiple quantum wells

Optical properties of GaN/Al{sub 0.2}Ga{sub 0.8}N multiple quantum wells grown with semi-polar (10-11) orientation on patterned 7°-off Si (001) substrates have been investigated. Studies performed at 8 K reveal the in-plane anisotropic behavior of the QW photoluminescence (PL) intensity for this semi-polar orientation. The time resolved PL measurements were carried out in the temperature range from 8 to 295 K to deduce the effective recombination decay times, with respective radiative and non-radiative contributions. The non-radiative component remains relatively weak with increasing temperature, indicative of high crystalline quality. The radiative decay time is a consequence of contribution from both localized and free excitons. We report an effective density of interfacial defects of 2.3 × 10{sup 12} cm{sup −2} and a radiative recombination time of τ{sub loc} = 355 ps for the localized excitons. This latter value is significantly larger than those reported for the non-polar structures, which we attribute to the presence of a weak residual electric field in the semi-polar QW layers.

36 MATERIALS SCIENCE↗
DOE OSTI2016

Structural and optical characterization of terbium doped ZnGa{sub 2}O{sub 4} thin films deposited by RF magnetron sputtering

Tb{sup 3+} doped ZnGa{sub 2}O{sub 4} nanophosphor (21 nm) has been synthesized via low temperature polyol route and subsequently thin films of the same were deposited on glass and ITO substrates by RF magnetron sputtering. The films were characterized by X-ray Diffraction and luminescence measurements. The XRD pattern showed that Tb{sup 3+} doped ZnGa{sub 2}O{sub 4} nanophosphor has a cubic spinel phase. Luminescence behavior of the nanophosphor and as deposited sputtered film was investigated. The PL emission spectra of nanophosphor gave a broad ZnGa{sub 2}O{sub 4} host emission band along with a strong terbium emission and the thin films showed only broad host emission band and there was no terbium ion emission.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2016

Edge cracks in nickel and aluminium single crystals: A molecular dynamics study

A molecular dynamics study of edge cracks in Ni and Al single crystals under mode-I loading conditions is presented. Simulations are performed using embedded-atom method potentials for Ni and Al at a temperature of 0.5 K. The results reveal that Ni and Al show different fracture mechanisms. Overall failure behavior of Ni is brittle, while fracture in Al proceeds through void nucleation and coalescence with a zig-zag pattern of crack growth. The qualitative nature of results is discussed in the context of vacancy-formation energies and surface energies of the two FCC metals.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2013

Utilizing a simple CT dosimetry phantom for the comprehension of the operational characteristics of CT AEC systems

Purpose: To investigate the utility of the nested polymethylacrylate (PMMA) phantom (which is available in many CT facilities for CTDI measurements), as a tool for the presentation and comparison of the ways that two different CT automatic exposure control (AEC) systems respond to a phantom when various scan parameters and AEC protocols are modified.Methods: By offsetting the two phantom's components (the head phantom and the body ring) half-way along their longitudinal axis, a phantom with three sections of different x-ray attenuation was created. Scan projection radiographs (SPRs) and helical scans of the three-section phantom were performed on a Toshiba Aquilion 64 and a Philips Brilliance 64 CT scanners, with different scan parameter selections [scan direction, pitch factor, slice thickness, and reconstruction interval (ST/RI), AEC protocol, and tube potential used for the SPRs]. The dose length product (DLP) values of each scan were recorded and the tube current (mA) values of the reconstructed CT images were plotted against the respective Z-axis positions on the phantom. Furthermore, measurements of the noise levels at the center of each phantom section were performed to assess the impact of mA modulation on image quality.Results: The mA modulation patterns of the two CT scanners were very dissimilar. The mA variations were more pronounced for Aquilion 64, where changes in any of the aforementioned scan parameters affected both the mA modulations curves and DLP values. However, the noise levels were affected only by changes in pitch, ST/RI, and AEC protocol selections. For Brilliance 64, changes in pitch affected the mA modulation curves but not the DLP values, whereas only AEC protocol and SPR tube potential selection variations affected both the mA modulation curves and DLP values. The noise levels increased for smaller ST/RI, larger weight category AEC protocol, and larger SPR tube potential selection.Conclusions: The nested PMMA dosimetry phantom can be effectively utilized for the comprehension of CT AEC systems performance and the way that different scan conditions affect the mA modulation patterns, DLP values, and image noise. However, in depth analysis of the reasons why these two systems exhibited such different behaviors in response to the same phantom requires further investigation which is beyond the scope of this study.

61 RADIATION PROTECTION AND DOSIMETRY↗
DOE OSTI2025

User-based I/O Profiling for Leadership Scale HPC Workloads

I/O constitutes a significant portion of most of the application run-time. Spawning many such applications concurrently on an HPC system leads to severe I/O contention. Thus, understanding and subsequently reducing I/O contention induced by such multi-tenancy is critical for the efficient and reliable performance of the HPC system. In this study, we demonstrate that an application’s performance is influenced by the command line arguments passed to the job submission. We model an application’s I/O behavior based on two factors: past I/O behavior within a time window and user-configured I/O settings via command-line arguments. We conclude that I/O patterns for well-known HPC applications like E3SM and LAMMP are predictable, with an average uncertainty below 0.25 (A probability of 80%) and near zero (A probability of 100%) within a day. However, I/O pattern variance increases as the study time window lengthens. Additionally, we show that for 38 users and at least 50 applications constituting approximately 93000 job submissions, there is a high correlation between a submitted command line and the past command lines made within 1 to 10 days submitted by the user. We claim the length of this time window is unique per user.

Yazdani, Ahmad Hossein [Virginia Tech, Blacksburg]↗
DOE OSTI2018

Visualizing Clustering and Uncertainty Analysis with Multivariate Longitudinal Data

Multivariate time-series datasets are intrinsic to the study of dynamic, naturalistic behavior, such as in the applications of finance and motion video analysis. Statistical models provide the ability to identify event patterns in these data under conditions of uncertainty, but researchers must be able to evaluate how well a model uses available information in a dataset for clustering decisions and for uncertainty information. The Hidden Markov Model (HMM) is an established method for clustering time-series data, where the hidden states of the HMM are the clusters. We develop novel methods for quantifying the uncertainty of the performance of and for visualizing the clustering performance and uncertainty of fitting a HMM to multivariate time-series data. We explain the usefulness of uncertainty quantification and visualization with evaluating the performance of clustering models, as well as how information exploitation of time-series datasets can be enhanced. We implement our methods to cluster patterns of scanpaths from raw eye tracking data.

97 MATHEMATICS AND COMPUTING↗
NASA NTRS1980

Cusp region particle precipitation and ion convection for northward interplanetary magnetic field

Data from Atmosphere Explorer D for periods of strong northward interplanetary magnetic field show the following characteristic behavior in the dayside magnetospheric cusp region: energy-time spectrograms of suprathermal positive ion fluxes exhibit a characteristic 'V' pattern as the spacecraft moves toward higher latitudes; that is, with the peak in the energy spectrum falling in energy and then rising again. Convection velocities follow this pattern closely with strong east-west flows (with antisunward components) occurring in the equatorward half of the 'V' and significant sunward flows occurring in the poleward half of the 'V'. These patterns can be understood qualitatively in terms of a model of ionospheric electric potential produced by the known dependence of Birkeland current densities on magnetic activity.

Burch, J. L.↗
NASA NTRS1981

Proposed three-phase modeling of Be stars from combined UV and visual observations

Far ultraviolet observations of the behavior of wind velocity and superionization values as a function of the phase of the (Be, B shell, B normal) pattern established by visual observations for gamma Cas and 59 Cyg are translated into a crude atmospheric model for the Be phase and several kinds of mass flux variability across the three phases.

Doazan, V.↗
NASA NTRS1988

Laser velocimeter measurements of the flow downstream of the Space Shuttle Main Engine high pressure oxidizer turbopump first-stage turbine nozzle

A laser two-focus velocimeter was used in an open-loop water test facility in order to map the flowfield downstream of the SSME's high-pressure oxidizer turbopump first-stage turbine nozzle; attention was given to the effects of the upstream strut-downstream nozzle configuration on the flow at the rotor inlet, in order to estimate dynamic loads on the first-stage rotor blades. Velocity and flow angles were plotted as a function of circumferential position, and were found to clearly display the periodic behavior of the wake flow field. The influence of the upstream centerbody-supporting struts on the vane nozzle wake pattern was evident.

Ferguson, T. V.↗
NASA NTRS1990

Identification of the connections in biologically inspired neural networks

We developed an identification method to find the strength of the connections between neurons from their behavior in small biologically-inspired artificial neural networks. That is, given the network external inputs and the temporal firing pattern of the neurons, we can calculate a solution for the strengths of the connections between neurons and the initial neuron activations if a solution exists. The method determines directly if there is a solution to a particular neural network problem. No training of the network is required. It should be noted that this is a first pass at the solution of a difficult problem. The neuron and network models chosen are related to biology but do not contain all of its complexities, some of which we hope to add to the model in future work. A variety of new results have been obtained. First, the method has been tailored to produce connection weight matrix solutions for networks with important features of biological neural (bioneural) networks. Second, a computationally efficient method of finding a robust central solution has been developed. This later method also enables us to find the most consistent solution in the presence of noisy data. Prospects of applying our method to identify bioneural network connections are exciting because such connections are almost impossible to measure in the laboratory. Knowledge of such connections would facilitate an understanding of bioneural networks and would allow the construction of the electronic counterparts of bioneural networks on very large scale integrated (VLSI) circuits.

Demuth, H.↗
NASA NTRS1995

Circinus X-1 revisited: Fast-timing properties in relation to spectral state

We have studied the X-ray spectral and fast-timing variations of Cir X-1 by performing a homogenous analysis of all EXOSAT ME data on this source using X-ray hardness-intensity diagrams (HIDs), color-color diagrams (CDs), and power spectra. Cir X-1 exhibits a wide range of power spectral shapes and a large variety in X-ray spectral shapes. At different epochs the power spectra variously resemble those of an atoll source, a Z source, a black-hole candidate, or are unlike any of these. At some epochs one-dimensional connected-branch patterns are seen in HID and CD, and at other times more complex structures are found. We interpret the complex behavior of Cir X-1 in terms of a model where accretion rate, orbital phase and epoch are the main determinants of the source behavior, and where the unique properties of the source are due to two special circumstances: (1) the source is the only known atoll source (accreting neutron star with a very low magnetic field) that can reach the Eddington critical accretion rate, and (2) it has a unique, highly eccentric and probably precessing orbit. Property (1) makes Cir X-1 a very important source for our understanding of the similarities in the observable properties of neutron stars and black holes as it allows to separate out black hole signatures from properties that are merely due to the presence of accretion compact with a low magnetic field.

Oosterbroek, T.↗
NASA NTRS1998

Radiative Ignition and Transition to Spread Investigation (RITSI)

A total of 25 experiments was conducted in the Glovebox Facility on the Third United States Microgravity payload (USMP3) mission to study the behavior of both flaming and smoldering ignition events, the transition from ignition to the flame/smoldering spread, and the flame/smoldering growth pattern in air. Twenty one of the 25 experiments were flaming experiments and the remainder were smoldering experiments. Ignition was initiated by a heated wire across a thermally thin filter paper in the middle of the sample for the two-dimensional configuration and by a focused beam from a halogen/tungsten lamp at the center of the sample for the three-dimensional configuration. The external air flow velocity was varied from 0 cm/s to 6.5 cm/s. The ignition and subsequent flame spread events were recorded by a video camera, a 35 mm camera, and 6 thermocouples (2 in the gas phase and 4 in the sample). The results indicate that non-piloted radiative ignition of the paper by external thermal radiation tends to occur more easily than in normal gravity. In the two-dimensional configuration, the transition from ignition to downstream flame spread never occurred; only the transition to upstream spread took place. In the three-dimensional configuration, a char growth pattern emerged in the shape of a fan, with the ignited area as the center of the fan and the fan spreading in the upstream direction. The internal angle of the fan increased with an increase in external flow velocity (higher flow velocity gave a more opened fan pattern). At an external flow velocity of 5 cm/s, the flame was horseshoe-shaped and the char pattern became an elongated semicircle toward upstream. It appears that the peak upstream flame spread rate was reached at a higher external velocity than for the two-dimensional flame front. Flame spread much faster along open edges of the sample paper than along the sample face, presumably due to there being larger supply of oxygen and energy feedback at the open edges than at the surface. These results indicate the possible importance of the effect of the flame front shape such as the curvature of the flame front on spread rate and flame strength. A complex, unexpected finger-shaped char growth pattern was observed during the smoldering experiment. Higher external flow velocity increased the number of localized smoldering fronts, of the char fingers they left behind, and frequency of bifurcations from the fingers. At present, it is not clear what caused such a complex char growth pattern.

Kashiwagi, Takashi↗
NASA NTRS1992

VA/Q distribution during heavy exercise and recovery in humans: implications for pulmonary edema

Ventilation-perfusion (VA/Q) inequality has been shown to increase with exercise. Potential mechanisms for this increase include nonuniform pulmonary vasoconstriction, ventilatory time constant inequality, reduced large airway gas mixing, and development of interstitial pulmonary edema. We hypothesized that persistence of VA/Q mismatch after ventilation and cardiac output subside during recovery would be consistent with edema; however, rapid resolution would suggest mechanisms related to changes in ventilation and blood flow per se. Thirteen healthy males performed near-maximal cycle ergometry at an inspiratory PO2 of 91 Torr (because hypoxia accentuates VA/Q mismatch on exercise). Cardiorespiratory variables and inert gas elimination patterns were measured at rest, during exercise, and between 2 and 30 min of recovery. Two profiles of VA/Q distribution behavior emerged during heavy exercise: in group 1 an increase in VA/Q mismatch (log SDQ of 0.35 +/- 0.02 at rest and 0.44 +/- 0.02 at exercise; P less than 0.05, n = 7) and in group 2 no change in VA/Q mismatch (n = 6). There were no differences in anthropometric data, work rate, O2 uptake, or ventilation during heavy exercise between groups. Group 1 demonstrated significantly greater VA/Q inequality, lower vital capacity, and higher forced expiratory flow at 25-75% of forced vital capacity for the first 20 min during recovery than group 2. Cardiac index was higher in group 1 both during heavy exercise and 4 and 6 min postexercise. However, both ventilation and cardiac output returned toward baseline values more rapidly than did VA/Q relationships. Arterial pH was lower in group 1 during exercise and recovery. We conclude that greater VA/Q inequality in group 1 and its persistence during recovery are consistent with the hypothesis that edema occurs and contributes to the increase in VA/Q inequality during exercise. This is supported by observation of greater blood flows and acidosis and, presumably therefore, higher pulmonary vascular pressures in such subjects.

NASA Discipline Cardiopulmonary↗
DOE OSTI2019

Weak Ferroelectricity and Leakage Current Behavior of Multiferroic CoCr{sub 2}O{sub 4} Nanomaterials

Multiferroic CoCr{sub 2}O{sub 4} is synthesized by low-temperature sol-gel auto combustion technique. High energy synchrotron x-ray diffraction pattern confirms the single-phase cubic structure with space group Fd3m. Average crystallite size (17.91 nm) and negative micro-strain (9.86 × 10{sup −4}) are estimated by Williamson–Hall (W-H) plot. FTIR confirms the formation of spinel metal oxide-based cobalt chromites. The strong decrease in ε′ and tan δ at higher frequency can be interpreted by Maxwell-Wagner-type interfacial polarization. Weak ferroelectricity is mainly attributed to the partial reversal of polarization. J-E characteristic reveals the Ohmic (I–V) and Child’s square law (I–V{sup 2}) behavior observed in CoCr{sub 2}O{sub 4} nanomaterials with slope value ~ 1.04 and ~ 1.6, respectively. The conduction process for the leakage current density is interpreted using the space-charge limited current (SCLC) mechanism.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2014

Superconductivity and metallic behavior in Pb{sub x}C{sub y}O{sub δ} structures prepared by focused electron beam induced deposition

Focused electron beam induced deposition as a direct-write approach possesses great potential to meet the demands for superconducting nanostructure fabrication especially regarding its 3D patterning capabilities combined with the high resolution in the nanometer regime. So far, however, it was not possible to fabricate superconducting structures with this technique. In this work, we present a lead-based superconductor prepared by focused electron beam induced deposition by dissociation of the precursor tetraethyllead. The as-grown structures exhibit metallic behavior and a minimum resistivity in the normal state of ρ = 16 μΩcm at T = 9 K followed by a superconducting transition at T{sub c} = 7.2 K.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2019

Modeling the formation of double rolls from heterogeneously patterned gels

Both stimuli-responsive gels and growing biological tissue can undergo pronounced morphological transitions from two-dimensional (2D) layers into 3D geometries. We derive an analytical model that allows us to quantitatively predict the features of 2D-to-3D shape changes in polymer gels that encompasses different degrees of swelling within the sample. We analyze a particular configuration that emerges from a flat rectangular gel that is divided into two strips (bistrips), where each strip is swollen to a different extent in solution. The final configuration yields double rolls that display a narrow transition layer between two cylinders of constant radii. To characterize the rolls' shapes, we modify the theory of thin incompatible elastic sheets to account for the Flory-Huggins interaction between the gel and the solvent. This modification allows us to derive analytical expressions for the radii, the amplitudes, and the length of the transition layer within a given roll. Furthermore, our predictions agree quantitatively with available experimental data. In addition, we carry out numerical simulations that account for the complete nonlinear behavior of the gel and show good agreement between the analytical predictions and the numerical results. Our solution sheds light on a stress focusing pattern that forms at the border between two dissimilar soft materials. Moreover, models that provide quantitative predictions on the final morphology in such heterogeneously swelling hydrogels are useful for understanding growth patterns in biology as well as accurately tailoring the structure of gels for various technological applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2014

In-Situ MVA of CO 2 Sequestration Using Smart Field Technology

Capability of underground carbon dioxide storage to confine and sustain injected CO 2 for a long period of time is the main concern for geologic CO 2 sequestration. If a leakage from a geological CO 2 sequestration site occurs, it is crucial to find the approximate amount and the location of the leak, in a timely manner, in order to implement proper remediation activities. An overwhelming majority of research and development for storage site monitoring has been concentrated on atmospheric, surface or near surface monitoring of the sequestered CO 2 . This study aims to monitor the integrity of CO 2 storage at the reservoir level. This work proposes developing in-situ CO 2 Monitoring and Verification technology based on the implementation of Permanent Down-hole Gauges (PDG) or “Smart Wells” along with Artificial Intelligence and Data Mining (AI&DM). The technology attempts to identify the characteristics of the CO 2 leakage by de-convolving the pressure signals collected from Permanent Down-hole Gauges (PDG). Citronelle field, a saline aquifer reservoir, located in the U.S. was considered as the basis for this study. A reservoir simulation model for CO 2 sequestration in the Citronelle field was developed and history matched. PDGs were installed, and therefore were considered in the numerical model, at the injection well and an observation well. Upon completion of the history matching process, high frequency pressure data from PDGs were generated using the history matched numerical model using different CO 2 leakage scenarios. Since pressure signal behaviors were too complicated to de-convolute using any existing mathematical formulations, a Machine Learning-based technology was introduced for this purpose. An Intelligent Leakage Detection System (ILDS) was developed as the result of this effort using the machine learning and pattern recognition technologies. The ILDS is able to detect leakage characteristics in a short period of time (less than a day from its occurrence) demonstrating the capability of the system in quantifying leakage characteristics subject to complex rate behaviors. The performance of ILDS is examined under different conditions such as multiple well leakages, cap rock leakage, availability of an additional monitoring well, presence of pressure drift and noise in the pressure sensor and uncertainty in the reservoir model.

54 ENVIRONMENTAL SCIENCES↗