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At least 991 records · Page 55

Star formation in the cluster merger DLSCL J0916.2+2953

We investigate star formation in DLSCL J0916.2+2953, a dissociative merger of two clusters at z=0.53 that has progressed 1:1 +1.3 -0.4 Gyr since rst pass-through. We attempt to reveal the effects a collision may have had on the evolution of the cluster galaxies by tracing their star formation history. We probe current and recent activity to identify a possible star formation event at the time of the merger using EW(Hδ), EW([OII]), and Dn(4000) measured from the composite spectra of 64 cluster and 153 coeval eld galaxies. We supplement Keck DEIMOS spectra with DLS and HST imaging to determine the color, stellar mass, and morphology of each galaxy and conduct a comprehensive study of the populations in this complex structure. Spectral results indicate the average cluster and cluster red sequence galaxies experienced no enhanced star formation relative to the surrounding eld during the merger, ruling out a predominantly merger-quenched population. We nd that the average blue galaxy in the North cluster is currently active and in the South cluster is currently post-starburst having undergone a recent star formation event. While the North activity could be latent or long- term merger effects, a young blue stellar population and irregular geometry suggest the cluster was still forming prior the collision. While the South activity coincides with the time of the merger, the blue early-type population could be a result of secular cluster processes. The evidence suggests that the dearth or surfeit of activity is indiscernible from normal cluster galaxy evolution.

79 ASTRONOMY AND ASTROPHYSICS↗

The impact of feedback during massive star formation by core accretion

We study feedback during massive star formation using semi-analytic methods, considering the effects of disk winds, radiation pressure, photoevaporation, and stellar winds, while following protostellar evolution in collapsing massive gas cores. We find that disk winds are the dominant feedback mechanism setting star formation efficiencies (SFEs) from initial cores of ∼0.3–0.5. However, radiation pressure is also significant to widen the outflow cavity causing reductions of SFE compared to the disk-wind only case, especially for >100 M{sub ⊙} star formation at clump mass surface densities Σ{sub cl}≲0.3 g cm{sup −2}. Photoevaporation is of relatively minor importance due to dust attenuation of ionizing photons. Stellar winds have even smaller effects during the accretion stage. For core masses M{sub c}≃10–1000 M{sub ⊙} and Σ{sub cl}≃0.1–3 g cm{sup −2}, we find the overall SFE to be ε-bar {sub ∗f}=0.31(R{sub c}/0.1pc){sup −0.39}, potentially a useful sub-grid star formation model in simulations that can resolve pre-stellar core radii, R{sub c}=0.057(M{sub c}/60M{sub ⊙}){sup 1/2}(Σ{sub cl}/gcm{sup −2}){sup −1/2} pc. The decline of SFE with M {sub c} is gradual with no evidence for a maximum stellar-mass set by feedback processes up to stellar masses of m{sub ∗}∼300 M{sub ⊙}. We thus conclude that the observed truncation of the high-mass end of the IMF is shaped mostly by the pre-stellar core mass function or internal stellar processes. To form massive stars with the observed maximum masses of ∼150–300M{sub ⊙}, initial core masses need to be ≳500–1000 M{sub ⊙}. We also apply our feedback model to zero-metallicity primordial star formation, showing that, in the absence of dust, photoevaporation staunches accretion at ∼50 M{sub ⊙}. Our model implies radiative feedback is most significant at metallicities ∼10{sup −2}Z{sub ⊙}, since both radiation pressure and photoevaporation are effective in this regime.

79 ASTRONOMY AND ASTROPHYSICS↗

Observations of Lyα and O VI: signatures of cooling and star formation in a massive central cluster galaxy

We report new Hubble Space Telescope COS and Space Telescope Imaging Spectrograph spectroscopy of a star-forming region (∼100 M{sub ⊙} yr{sup −1}) in the center of the X-ray cluster RX J1532.9+3021 (z = 0.362), to follow-up the CLASH team discovery of luminous UV filaments and knots in the central massive galaxy. We detect broad (∼500 km s{sup −1}) Lyα emission lines with extraordinarily high equivalent widths (EQW ∼ 200 Å) and somewhat less broadened Hα (∼220 km s{sup −1}). Ultraviolet emission lines of N v and O vi are not detected, which constrains the rate at which gas cools through temperatures of 10{sup 6} K to be ≲10 M{sub ⊙} yr{sup −1}. The COS spectra also show a flat rest-frame UV continuum with weak stellar photospheric features, consistent with the presence of recently formed hot stars forming at a rate of ∼10 M{sub ⊙} yr{sup −1}, uncorrected for dust extinction. The slope and absorption lines in these UV spectra are similar to those of Lyman Break Galaxies at z≈3, albeit those with the highest Lyα equivalent widths and star formation rates. This high-EQW Lyα source is a high-metallicity galaxy rapidly forming stars in structures that look nothing like disks. This mode of star formation could significantly contribute to the spheroidal population of galaxies. The constraint on the luminosity of any O vi line emission is stringent enough to rule out steady and simultaneous gas cooling and star formation, unlike similar systems in the Phoenix Cluster and Abell 1795. The fact that the current star formation rate differs from the local mass cooling rate is consistent with recent simulations of episodic active galactic nucleus feedback and star formation in a cluster atmosphere.

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Predicting Quiescence: The Dependence of Specific Star Formation Rate on Galaxy Size and Central Density at 0.5 < z < 2.5

In this paper, we investigate the relationship between star formation and structure, using a mass-complete sample of 27,893 galaxies at 0.5 < z < 2.5 selected from 3D-HST. We confirm that star-forming galaxies are larger than quiescent galaxies at fixed stellar mass (M{sub ⋆}). However, in contrast with some simulations, there is only a weak relation between star formation rate (SFR) and size within the star-forming population: when dividing into quartiles based on residual offsets in SFR, we find that the sizes of star-forming galaxies in the lowest quartile are 0.27 ± 0.06 dex smaller than the highest quartile. We show that 50% of star formation in galaxies at fixed M{sub ⋆} takes place within a narrow range of sizes (0.26 dex). Taken together, these results suggest that there is an abrupt cessation of star formation after galaxies attain particular structural properties. Confirming earlier results, we find that central stellar density within a 1 kpc fixed physical radius is the key parameter connecting galaxy morphology and star formation histories: galaxies with high central densities are red and have increasingly lower SFR/M{sub ⋆}, whereas galaxies with low central densities are blue and have a roughly constant (higher) SFR/M{sub ⋆} at a given redshift. We find remarkably little scatter in the average trends and a strong evolution of >0.5 dex in the central density threshold correlated with quiescence from z ∼ 0.7–2.0. Neither a compact size nor high-n are sufficient to assess the likelihood of quiescence for the average galaxy; instead, the combination of these two parameters together with M{sub ⋆} results in a unique quenching threshold in central density/velocity.

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Accretion Disk Assembly During Common Envelope Evolution: Implications for Feedback and LIGO Binary Black Hole Formation

During a common envelope (CE) episode in a binary system, the engulfed companion spirals to tighter orbital separations under the influence of drag from the surrounding envelope material. As this object sweeps through material with a steep radial gradient of density, net angular momentum is introduced into the flow, potentially leading to the formation of an accretion disk. The presence of a disk would have dramatic consequences for the outcome of the interaction because accretion might be accompanied by strong, polar outflows with enough energy to unbind the entire envelope. Without a detailed understanding of the necessary conditions for disk formation during CE, therefore, it is difficult to accurately predict the population of merging compact binaries. This paper examines the conditions for disk formation around objects embedded within CEs using the “wind tunnel” formalism developed by MacLeod et al. We find that the formation of disks is highly dependent on the compressibility of the envelope material. Disks form only in the most compressible of stellar envelope gas, found in envelopes’ outer layers in zones of partial ionization. These zones are largest in low-mass stellar envelopes, but comprise small portions of the envelope mass and radius in all cases. We conclude that disk formation and associated accretion feedback in CE is rare, and if it occurs, transitory. The implication for LIGO black hole binary assembly is that by avoiding strong accretion feedback, CE interactions should still result in the substantial orbital tightening needed to produce merging binaries.

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Constraining Formation Models of Binary Black Holes with Gravitational-wave Observations

Gravitational waves (GWs) from binary black hole (BBH) mergers provide a new probe of massive-star evolution and the formation channels of binary compact objects. By coupling the growing sample of BBH systems with population synthesis models, we can begin to constrain the parameters of such models and glean unprecedented knowledge about the inherent physical processes that underpin binary stellar evolution. In this study, we apply a hierarchical Bayesian model to mass measurements from a synthetic GW sample to constrain the physical prescriptions in population models and the relative fraction of systems generated from various channels. We employ population models of two canonical formation scenarios in our analysis—isolated binary evolution involving a common-envelope phase and dynamical formation within globular clusters—with model variations for different black hole natal kick prescriptions. We show that solely with chirp mass measurements, it is possible to constrain natal kick prescriptions and the relative fraction of systems originating from each formation channel with O(100) of confident detections. This framework can be extended to include additional formation scenarios, model parameters, and measured properties of the compact binary.

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PHAT. XIX. The Ancient Star Formation History of the M31 Disk

We map the star formation history across M31 by fitting stellar evolution models to color–magnitude diagrams of each 83″ × 83″ (0.3 × 1.4 kpc, deprojected) region of the Panchromatic Hubble Andromeda Treasury (PHAT) survey outside of the innermost 6{sup ′}×12{sup ′} portion. We find that most of the star formation occurred prior to ∼8 Gyr ago, followed by a relatively quiescent period until ∼4 Gyr ago, a subsequent star formation episode about 2 Gyr ago, and a return to relative quiescence. There appears to be little, if any, structure visible for populations with ages older than 2 Gyr, suggesting significant mixing since that epoch. Finally, assuming a Kroupa initial mass function from 0.1 to 100 M {sub ⊙}, we find that the total amount of star formation over the past 14 Gyr in the area over which we have fit models is 5 × 10{sup 10} M {sub ⊙}. Fitting the radial distribution of this star formation and assuming azimuthal symmetry, (1.5 ± 0.2) × 10{sup 11} M {sub ⊙} of stars has formed in the M31 disk as a whole, (9 ± 2) × 10{sup 10} M {sub ⊙} of which has likely survived to the present after accounting for evolutionary effects. This mass is about one-fifth of the total dynamical mass of M31.

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Stellar Absorption Line Analysis of Local Star-forming Galaxies: The Relation between Stellar Mass, Metallicity, Dust Attenuation, and Star Formation Rate

We analyze the optical continuum of star-forming galaxies in the Sloan Digital Sky Survey by fitting stacked spectra with stellar population synthesis models to investigate the relation between stellar mass, stellar metallicity, dust attenuation, and star formation rate. We fit models calculated with star formation and chemical evolution histories that are derived empirically from multi-epoch observations of the stellar mass–star formation rate and the stellar mass–gas-phase metallicity relations, respectively. We also fit linear combinations of single-burst models with a range of metallicities and ages. Star formation and chemical evolution histories are unconstrained for these models. The stellar mass–stellar metallicity relations obtained from the two methods agree with the relation measured from individual supergiant stars in nearby galaxies. These relations are also consistent with the relation obtained from emission-line analysis of gas-phase metallicity after accounting for systematic offsets in the gas-phase metallicity. We measure dust attenuation of the stellar continuum and show that its dependence on stellar mass and star formation rate is consistent with previously reported results derived from nebular emission lines. However, stellar continuum attenuation is smaller than nebular emission line attenuation. The continuum-to-nebular attenuation ratio depends on stellar mass and is smaller in more massive galaxies. Our consistent analysis of stellar continuum and nebular emission lines paves the way for a comprehensive investigation of stellar metallicities of star-forming and quiescent galaxies.

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The Chemical Abundance Structure of the Inner Milky Way: A Signature of “Upside-down” Disk Formation

We present a model for the [α/Fe]--[Fe/H] distribution of stars in the inner Galaxy, 3 kpc<R<5 kpc, measured as a function of vertical distance |z| from the midplane by Hayden et al. (H15). Motivated by an “upside-down” scenario for thick disk formation, in which the thickness of the star-forming gas layer contracts as the stellar mass of the disk grows, we combine one-zone chemical evolution with a simple prescription in which the scale-height of the stellar distribution drops linearly from z{sub h}=0.8 kpc to z{sub h}=0.2 kpc over a timescale t {sub c}, remaining constant thereafter. We assume a linear-exponential star formation history, M-dot {sub ∗}(t)∝te{sup −t/t{sub s}{sub f}}. With a star formation efficiency timescale τ{sub ∗}=M{sub g}(t)/ M-dot {sub ∗}(t)=2 Gyr, an outflow mass-loading factor η= M-dot {sub out}(t)/ M-dot {sub ∗}(t)=1.5, t{sub sf}=3 Gyr, and t{sub c}=2.5 Gyr, the model reproduces the observed locus of inner disk stars in [α/Fe]--[Fe/H] and the metallicity distribution functions (MDFs) measured by H15 at |z|=0--0.5 kpc, 0.5--1 kpc, and 1--2 kpc. Substantial changes to model parameters lead to disagreement with the H15 data; for example, models with t{sub c}=1 Gyr or t{sub sf}=1 Gyr fail to match the observed MDF at high-|z| and low-|z|, respectively. The inferred scale-height evolution, with z {sub h}(t) dropping on a timescale t{sub c}∼t{sub sf} at large lookback times, favors upside-down formation over dynamical heating of an initially thin stellar population as the primary mechanism regulating disk thickness. The failure of our short-t {sub c} models suggests that any model in which thick disk formation is a discrete event will not reproduce the continuous dependence of the MDF on |z| found by H15. Our scenario for the evolution of the inner disk can be tested by future measurements of the |z|-distribution and the age–metallicity distribution at R=3--5 kpc.

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ALMA Reveals Sequential High-mass Star Formation in the G9.62+0.19 Complex

Stellar feedback from high-mass stars (e.g., H ii regions) can strongly influence the surrounding interstellar medium and regulate star formation. Our new ALMA observations reveal sequential high-mass star formation taking place within one subvirial filamentary clump (the G9.62 clump) in the G9.62+0.19 complex. The 12 dense cores (MM1–MM12) detected by ALMA are at very different evolutionary stages, from the starless core phase to the UC H ii region phase. Three dense cores (MM6, MM7/G, MM8/F) are associated with outflows. The mass–velocity diagrams of the outflows associated with MM7/G and MM8/F can be well-fit by broken power laws. The mass–velocity diagram of the SiO outflow associated with MM8/F breaks much earlier than other outflow tracers (e.g., CO, SO, CS, HCN), suggesting that SiO traces newly shocked gas, while the other molecular lines (e.g., CO, SO, CS, HCN) mainly trace the ambient gas continuously entrained by outflow jets. Five cores (MM1, MM3, MM5, MM9, MM10) are massive starless core candidates whose masses are estimated to be larger than 25 M {sub ☉}, assuming a dust temperature of ≤20 K. The shocks from the expanding H ii regions (“B” and “C”) to the west may have a great impact on the G9.62 clump by compressing it into a filament and inducing core collapse successively, leading to sequential star formation. Our findings suggest that stellar feedback from H ii regions may enhance the star formation efficiency and suppress low-mass star formation in adjacent pre-existing massive clumps.

79 ASTRONOMY AND ASTROPHYSICS↗

Equation of State Dependent Dynamics and Multi-messenger Signals from Stellar-mass Black Hole Formation

We investigate axisymmetric black hole (BH) formation and its gravitational wave (GW) and neutrino signals with self-consistent core-collapse supernova simulations of a non-rotating 40 M ⊙ progenitor star using the isotropic diffusion source approximation for the neutrino transport and a modified gravitational potential for general relativistic effects. We consider four different neutron star (NS) equations of state (EoS): LS220, SFHo, BHBΛ$\phi$, and DD2, and study the impact of the EoS on BH formation dynamics and GW emission. We find that the BH formation time is sensitive to the EoS from 460 to >1300 ms and is delayed in multiple dimensions for ~100–250 ms due to the finite entropy effects. Depending on the EoS, our simulations show the possibility that shock revival can occur along with the collapse of the proto-neutron star (PNS) to a BH. The gravitational waveforms contain four major features that are similar to previous studies but show extreme values: (1) a low-frequency signal (~300–500 Hz) from core-bounce and prompt convection, (2) a strong signal from the PNS g-mode oscillation among other features, (3) a high-frequency signal from the PNS inner-core convection, and (4) signals from the standing accretion shock instability and convection. The peak frequency at the onset of BH formation reaches to ~2.3 kHz. Thus, the characteristic amplitude of a 10 kpc object at peak frequency is detectable but close to the noise threshold of the Advanced LIGO and KAGRA, suggesting that the next-generation GW detector will need to improve the sensitivity at the kHz domain to better observe stellar-mass BH formation from core-collapse supernovae or failed supernovae.

79 ASTRONOMY AND ASTROPHYSICS↗

Cold Filamentary Accretion and the Formation of Metal-poor Globular Clusters and Halo Stars

We propose that cold filamentary accretion in massive galaxies at high redshifts can lead to the formation of star-forming clumps in the halos of these galaxies without dark matter substructure. In certain cases, these clumps can be the birthplaces of metal-poor globular clusters (MP GCs). Using cosmological simulations, we show that narrow streams of dense gas feeding massive galaxies from the cosmic web can fragment, producing star-forming clumps. We then derive an analytical model for the properties of streams as a function of halo mass and redshift, and assess when these are gravitationally unstable, when this can lead to collapse and star formation in the halo, and when it may result in the formation of MP GCs. For stream metallicities $\gtrsim 0.01{Z}_{\odot }$, this is likely to occur at $z\gt 4.5$. At $z\sim 6$, the collapsing clouds have masses of $\sim (5\mbox{--}10)\times {10}^{7}\,{M}_{\odot }$, and the average stream pressure is $\sim {10}^{6}\,{\mathrm{cm}}^{-3}\,{\rm{K}}$. The conditions for GC formation are met in the extremely turbulent "eyewall" at $\sim 0.3{R}_{{\rm{v}}}$, where counter-rotating streams can collide, driving very large densities. Our scenario can account for the observed kinematics and spatial distribution of MP GCs, the correlation between their mass and metallicity, and the mass ratio between the GC system and the host halo. For MW-mass halos, we infer that $\sim 30 \% $ of MP GCs could have formed in this way, with the remainder likely accreted in mergers. Our predictions for GC formation along circumgalactic filaments at high redshift are testable with JWST.

79 ASTRONOMY AND ASTROPHYSICS↗

H I Gas and Star Formation in Major Galaxy Pairs from the FAST All Sky H I Survey (FASHI)

Atomic hydrogen (H I ) plays a fundamental role in fueling star formation in galaxies. However, the behavior of H I gas in interacting systems, particularly galaxy pairs, remains elusive. In this work, we investigate the H I content of major mergers by crossmatching the extragalactic H I catalog from the Five-hundred-meter Aperture Spherical radio Telescope (FAST) All-Sky H I Survey with a previously established sample of isolated galaxy pairs. With the superior sensitivity of FAST, we have constructed the largest sample of major mergers with H I detections, consisting of 440 galaxy pairs: 364 spiral-spiral (S+S) and 76 spiral-elliptical (S+E) systems. We examine the H I gas fraction (f H I ), star formation rate (SFR), and H I star formation efficiency (SFE H I = SFR/M H I ) for individual galaxies in pairs. The control sample is matched in both stellar mass and redshift. We find that paired galaxies, particularly those in pairs with small projected separations (d p < 50 h −1 kpc), exhibit systematically lower (by 8.8%) H I gas fractions compared to the control galaxies. The SFR is enhanced for galaxies in the S+S pairs. The SFE H I is ∼15% higher for galaxies in the S+S pairs than in the control galaxies, while spiral galaxies in the S+E pairs show no significant difference in SFE H I compared to the control sample. These findings suggest that the merger process triggers efficient H I gas depletion and enhances star formation, especially in close S+S pairs. Notably, our sample includes 26 red spirals in paired systems. These galaxies exhibit H I deficiency and suppressed star formation activity compared to the isolated galaxies, indicating that interactions may affect quiescent spirals differently, potentially due to mechanisms similar to those of ellipticals.

Yan, Shulan 淑澜鄢 [Xiamen University (China); SDSS C↗

Prompt planetesimal formation beyond the snow line

We develop a simple model to predict the radial distribution of planetesimal formation. The model is based on the observed growth of dust to millimeter-sized particles, which drift radially, pile-up, and form planetesimals where the stopping time and dust-to-gas ratio intersect the allowed region for streaming instability-induced gravitational collapse. Using an approximate analytic treatment, we first show that drifting particles define a track in metallicity–stopping time space whose only substantial dependence is on the disk’s angular momentum transport efficiency. Prompt planetesimal formation is feasible for high particle accretion rates (relative to the gas, M-dot {sub p}/ M-dot ≳3×10{sup −2} for α=10{sup −2}), which could only be sustained for a limited period of time. If it is possible, it would lead to the deposition of a broad and massive belt of planetesimals with a sharp outer edge. Numerically including turbulent diffusion and vapor condensation processes, we find that a modest enhancement of solids near the snow line occurs for centimeter-sized particles, but that this is largely immaterial for planetesimal formation. We note that radial drift couples planetesimal formation across radii in the disk, and suggest that considerations of planetesimal formation favor a model in which the initial deposition of material for giant planet cores occurs well beyond the snow line.

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An Imperfectly Passive Nature: Bright Submillimeter Emission from Dust-obscured Star Formation in the z = 3.717 “Passive” System, ZF 20115

The identification of high-redshift, massive galaxies with old stellar populations may pose challenges to some models of galaxy formation. However, to securely classify a galaxy as quiescent, it is necessary to exclude significant ongoing star formation, something that can be challenging to achieve at high redshifts. In this Letter, we analyze deep ALMA/870 μm and SCUBA-2/450 μm imaging of the claimed “post-starburst” galaxy ZF 20115 at z = 3.717 that exhibits a strong Balmer break and absorption lines. The rest-frame far-infrared imaging identifies a luminous starburst 0.″4 ± 0.″1 (∼3 kpc in projection) from the position of the ultraviolet/optical emission and is consistent with lying at the redshift of ZF 20115. The star-forming component, with an obscured star formation rate of 100{sub −70}{sup +15} M{sub ⊙} yr{sup −1}, is undetected in the rest-frame ultraviolet but contributes significantly to the lower angular resolution photometry at rest-frame wavelengths ≳3500 Å. This contribution from the obscured starburst, especially in the Spitzer/IRAC wavebands, significantly complicates the determination of a reliable stellar mass for the ZF 20015 system, and we conclude that this source does not pose a challenge to current models of galaxy formation. The multi-wavelength observations of ZF 20115 unveil a complex system with an intricate and spatially varying star formation history. ZF 20115 demonstrates that understanding high-redshift obscured starbursts will only be possible with multi-wavelength studies that include high-resolution observations, available with the James Webb Space Telescope, at mid-infrared wavelengths.

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Compact Steep Spectrum Radio Sources with Enhanced Star Formation Are Smaller Than 10 kpc

Compact steep spectrum (CSS) radio sources are active galactic nuclei (AGN) that have radio jets propagating only on galactic scales, defined as having projected linear size (LS) of up to 20 kpc. CSS sources are generally hosted by massive early-type galaxies with little ongoing star formation; however, a small fraction are known to have enhanced star formation. Using archival data from the Faint Images of the Radio Sky at Twenty cm survey, the Very Large Array Sky Survey, and the Sloan Digital Sky Survey, we identify a volume-limited sample of 166 CSS sources at z < 0.2 with L 1.4 GHz > 10 24 W Hz -1 . Comparing the star formation rates and linear sizes of these CSS sources, we find that the ≈14% of CSS sources with specific star formation rates above 0.01 Gyr -1 all have LS < 10 kpc. We discuss the possible mechanisms driving this result, concluding that it is likely the excess star formation in these sources occurred in multiple bursts and ceased prior to the AGN jet being triggered.

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Experimental observations of detached bow shock formation in the interaction of a laser-produced plasma with a magnetized obstacle

The magnetic field produced by planets with active dynamos, like the Earth, can exert sufficient pressure to oppose supersonic stellar wind plasmas, leading to the formation of a standing bow shock upstream of the magnetopause, or pressure-balance surface. Scaled laboratory experiments studying the interaction of an inflowing solar wind analog with a strong, external magnetic field are a promising new way to study magnetospheric physics and to complement existing models, although reaching regimes favorable for magnetized shock formation is experimentally challenging. This paper presents experimental evidence of the formation of a magnetized bow shock in the interaction of a supersonic, super-Alfvenic plasma with a strongly magnetized obstacle at the OMEGA laser facility. The solar wind analog is generated by the collision and subsequent expansion of two counter- propagating, laser-driven plasma plumes. The magnetized obstacle is a thin wire, driven with strong electrical currents. Hydrodynamic simulations using the FLASH code predict that the colliding plasma source meets the criteria for bow shock formation. Spatially resolved, optical Thomson scat- tering measures the electron number density, and optical emission lines provide a measurement of the plasma temperature, from which we infer the presence of a fast magnetosonic shock far upstream of the obstacle. Proton images provide a measure of large-scale features in the magnetic field topology, and reconstructed path-integrated magnetic field maps from these images suggest the formation of a bow shock upstream of the wire and as a transient magnetopause. We compare features in the reconstructed fields to two-dimensional MHD simulations of the system.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Understanding Solid-Electrolyte Interphase Formation at the Lithium Metal Anode of Lithium-Sulfur Batteries

Lithium-sulfur (Li-S) batteries are one of the most promising chemistries for the next generation of energy storage devices. In a standard Li-S cell, the metallic lithium anode is an essential component of the battery due to its low density, extremely high theoretical specific capacity, and very low negative electrochemical potential. However, several challenges related to the use of Li metal have prevented this battery technology from becoming commercially available. For instance, Li-anodes are highly reactive, which results in the continuous decomposition of the electrolyte and the formation of the solid-electrolyte interphase (SEI) layer. This, combined with the non-uniform deposition of Liions during plating at the anode surface, can seriously affect the performance, cycling, and safety of the battery. In addition, it has been suggested that a controlled SEI formation at the metallic Li anode can yield enhanced battery performance. Hence, a comprehensive understanding of how the SEI layer is formed can help elucidate improvements in this battery technology. In this work, the formation of the SEI layer in Li-S batteries is investigated using density functional theory (DFT) and ab initio molecular dynamics (AIMD) simulations. The stability of liquid organic-based electrolyte components, salt concentration, electron-rich environments, and the use of inorganic solid-state electrolyte (SSE) materials are explored in order to provide molecular-level fundamental insights into how the nature and composition of the electrolyte can alter the initial stages of the SEI formation. The products of electrolyte decomposition and electro-/chemical reaction pathways of liquid electrolyte component such as solvent and salts are predicted from AIMD simulations of electrolyte-anode interfaces. Energetics of reactions from DFT ground-state optimizations are also presented to confirm the decomposition mechanisms. Some significant differences are then drawn regarding the use of low and high salt concentrations. Simulations under electron-rich environments show additional multielectron electrochemical reactions of solvent and salt decomposition taking place due to the excess of electrons and the presence of radical anions in the solution. Finally, the initial stages of formation, stability, and main constituents of interfaces between Li-metal and Sbased electrodes with sulfide-based SSEs are characterized in detail.

25 ENERGY STORAGE↗