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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 991 records · Page 55
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Chemical Imaging of Atmospheric Biomass Burning Particles from North American Wildfires

The effects of biomass burning aerosols (BBA) on radiative forcing and cloud formation depend on chemical composition and the internal structures of individual particles within smoke plumes. To improve our understanding of the chemical and physical properties of BBA emitted at different times of the day and their evolution during atmospheric aging, we conducted a study as a part of the Fire Influence on Regional to Global Environments and Air Quality field campaign. Particle samples were collected onboard a research aircraft from smoke plumes from a wildfire in eastern Oregon during late afternoon and nighttime flights on August 28, 2019. A time-resolved aerosol collector was used to collect samples on substrates for offline spectromicroscopic imaging to investigate the single-particle characteristics of BBA particles. Approximately 20,400 individual particles from 10 selected samples were analyzed using computer-controlled scanning electron microscopy coupled with energy-dispersive X-ray microanalysis, revealing their elemental composition, morphology, and viscosity. Elemental microanalysis indicated that aged potassium is likely found in the form of K 2 SO 4 , KNO 3 , and possible K-organic salts. Further chemical speciation and carbon bonding mapping within individual particles were conducted using synchrotron-based scanning transmission X-ray microscopy (STXM) coupled with near edge X-ray absorption fine structure (NEXAFS) spectroscopy. Real-time, water-soluble light absorption measurements were acquired using a particle-into-liquid sampler instrument coupled to a liquid waveguide capillary cell and total organic analyzer. In the late afternoon samples, 65% of the total particle number population consisted entirely of organic components, compared to 46% in the nighttime particles. These differences were attributed to discrepancies in composition at the time of emission and to the daytime condensation and accumulation of photochemically formed secondary organic material on existing BBA particles, a process that halts at night. Microscopy images indicated that particle viscosity was lower in the nighttime particles (<10 1 Pa·s), likely due to increased relative humidity and a higher contribution from hygroscopic inorganic components. The chemical heterogeneity of individual particles was quantified using STXM-derived mixing state parameters. The nature of carbon bonding within individual particles was inferred from the extent of carbon sp 2 hybridization derived from NEXAFS spectra. Average percentages of sp 2 hybridization range between 40% and 60%, with no noticeable differences between late afternoon and nighttime flights. These findings were compared with the online optical properties of both late afternoon and nighttime smoke plumes, providing valuable insights into the complex relationship between chemical composition and optical properties of BBA particles at different times of the day.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Taxonomic and environmental distribution of bacterial amino acid auxotrophies

Abstract Many microorganisms are auxotrophic—unable to synthesize the compounds they require for growth. With this work, we quantify the prevalence of amino acid auxotrophies across a broad diversity of bacteria and habitats. We predicted the amino acid biosynthetic capabilities of 26,277 unique bacterial genomes spanning 12 phyla using a metabolic pathway model validated with empirical data. Amino acid auxotrophy is widespread across bacterial phyla, but we conservatively estimate that the majority of taxa (78.4%) are able to synthesize all amino acids. Our estimates indicate that amino acid auxotrophies are more prevalent among obligate intracellular parasites and in free-living taxa with genomic attributes characteristic of ‘streamlined’ life history strategies. We predicted the amino acid biosynthetic capabilities of bacterial communities found in 12 unique habitats to investigate environmental associations with auxotrophy, using data compiled from 3813 samples spanning major aquatic, terrestrial, and engineered environments. Auxotrophic taxa were more abundant in host-associated environments (including the human oral cavity and gut) and in fermented food products, with auxotrophic taxa being relatively rare in soil and aquatic systems. Overall, this work contributes to a more complete understanding of amino acid auxotrophy across the bacterial tree of life and the ecological contexts in which auxotrophy can be a successful strategy.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2022

Reaction–drift–diffusion models from master equations: application to material defects

We present a general method to produce well-conditioned continuum reaction–drift–diffusion equations directly from master equations on a discrete, periodic state space. We assume the underlying data to be kinetic Monte Carlo models (i.e. continuous-time Markov chains) produced from atomic sampling of point defects in locally periodic environments, such as perfect lattices, ordered surface structures or dislocation cores, possibly under the influence of a slowly varying external field. Our approach also applies to any discrete, periodic Markov chain. Here, the analysis identifies a previously omitted non-equilibrium drift term, present even in the absence of external forces, which can compete in magnitude with the reaction rates, thus being essential to correctly capture the kinetics. To remove fast modes which hinder time integration, we use a generalized Bloch relation to efficiently calculate the eigenspectrum of the master equation. A well conditioned continuum equation then emerges by searching for spectral gaps in the long wavelength limit, using an established kinetic clustering algorithm to define a proper reduced, Markovian state space.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Bar rejuvenation in S0 galaxies?

ABSTRACT Based on the colour measurements from a multiband, multicomponent 2D decompositions of S0 and spiral galaxies using SDSS images, we found that bars are bluer in S0 galaxies compared to the spiral galaxies. Most of the S0s in our sample have stellar masses ∼L* galaxies. The environment might have played an important role as most of the S0s with bluer bars are in the intermediate-density environment. The possibility of minor mergers and tidal interactions that occurs frequently in the intermediate-density environment might have caused either a bar to form and/or induce star formation in the barred region of S0 galaxies. The underlying discs show the usual behaviour being redder in S0s compared to spiral galaxies while the bulges are red and old for both S0 and spiral galaxies. The finding of bluer bars in S0 galaxies is a puzzling issue and poses an interesting question at numerical and theoretical studies most of which shows that the bars are long-lived structures with old stellar populations.

Barway, Sudhanshu↗
DOE OSTI2021

Star-forming S0 galaxies in the SDSS-IV MaNGA survey

ABSTRACT To investigate star-forming activities in early-type galaxies, we select a sample of 52 star-forming S0 galaxies (SFS0s) from the SDSS-IV MaNGA survey. We find that SFS0s have smaller stellar masses compared to normal S0s in MaNGA. After matching the stellar mass to select the control sample, we find that the mean Sérsic index of SFS0 bulges (1.76 ± 0.21) is significantly smaller than that of the control sample (2.57 ± 0.20), suggesting the existence of pseudo-bulges in SFS0s. After introducing the environmental information, SFS0s show smaller spin parameters in the field than in groups, while the control sample has no obvious difference in different environments, which may suggest different dynamical processes in SFS0s. Furthermore, with derived N/O and O/H abundance ratios, SFS0s in the field show nitrogen enrichment, providing evidence for the accretion of metal-poor gas in the field environment. To study the star-formation relation, we show that the slope of the spatially resolved star-formation main sequence is nearly 1.0 with MaNGA integral field unit data, confirming the self-regulation of star-formation activity on kpc scales.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Editors’ Choice—Natural Convection Boundary Layer Thickness at Elevated Chloride Concentrations and Temperatures and the Effects on a Galvanic Couple

The natural convection boundary layer ( δ n c ) and its influence on cathodic current in a galvanic couple under varying electrolytes as a function of concentration (1 − 5.3 M NaCl) and temperature (25 °C−45 °C) were understood. Polarization scans were obtained under quiescent conditions and at defined boundary layer thicknesses using a rotating disk electrode on platinum and stainless steel 304L (SS304L); these were combined to determine δ n c . With increasing chloride concentration and temperature, δ n c decreased. Increased mass transport (Sherwood number) results in a decrease in δ n c , providing a means to predict this important boundary. Using Finite Element Modeling, the cathodic current was calculated for an aluminum alloy/SS304L galvanic couple as a function of water layer ( WL ) thickness and cathode length. Electrolyte domains were delineated, describing (i) dominance of ohmic resistance over mass transport under thin WL , (ii) the transition from thin film to bulk conditions at δ n c , and (iii) dominance of mass transport under thick WL . With increasing chloride concentration, cathodic current decreased due to decreases in mass transport. With increasing temperature, increased cathodic current was related to increases in mass transport and solution conductivity. This study has implications for sample sizing and corrosion prediction under changing environments.

25 ENERGY STORAGE↗
DOE OSTI2020

Applicability of Public Dose Limits to Individuals on the Nevada National Security Site

Historically all persons working on the Nevada National Security Site (NNSS) were considered subject to worker dose limits when calculations of potential dose from the air pathway were conducted to demonstrate compliance with Title 42 United States Code (USC) Chapter 85, “The Clean Air Act,” and Title 40 Code of Federal Regulations (CFR) Part 61, Subpart H, “National Emission Standards for Hazardous Air Pollutants (NESHAP).” Calculations were also conducted for the all-pathways potential dose to demonstrate compliance with U.S. Department of Energy (DOE) Order DOE O 458.1 Chg. 3, “Radiation Protection of the Public and the Environment.” The need to evaluate environmental air sampling locations and past regulator questions about the existence of persons potentially subject to public dose limits being on the NNSS drove this assessment (letter from EPA [U.S. Environmental Protection Agency] Region 9 to DOE/Nevada Operations Office, dated September 3, 1999). This assessment also supports determining those persons subject to public dose limits from the all pathways perspective. A person that is a member of the public is subject to public dose limits.

61 RADIATION PROTECTION AND DOSIMETRY↗
DOE OSTI2019

Deep Unsaturated Zone Contributions to Carbon Cycling in Semiarid Environments, Journal of Geophysical Research

This data package contains core sample organic carbon (OC) and inorganic carbon (IC) , pore water dissolved organic carbon (DOC) and dissolved inorganic carbon (DIC), temperature depth profiles, subsurface carbon dioxide fluxes, 13C , depth and season-dependent respiration rates from incubated samples. This field‐based study spans a depth of 7 meters through the unsaturated zone into groundwater, and was done to explore depth-resolved carbon fluxes. Dissolved organic carbon flux and other environmental mechanisms are characteristic of arid‐ and semiarid climate regions, and can be incorporated to improve carbon flux predictions.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Tellurium Corrosion of Type 304/304L Stainless Steel, Iron, Chromium, and Nickel in High-Temperature Liquid Sodium

Investigating tellurium (Te) corrosion on structural materials is crucial for sodium-cooled fast reactors (SFRs) due to radionuclide presence and knowledge gaps. In this study, Type 304/304L stainless steel (SS304), chromium (Cr), iron (Fe), and nickel (Ni) samples were immersed in low-oxygen environments with Te in liquid sodium at 773 K for 30 days. At 10 ppm oxygen, SS304 showed multiple oxide layers, including a compact NaCrO 2 interlayer and porous Na-Fe-Ni-O outer layers. Tellurium penetrated through the porous layers but was hindered by the NaCrO 2 interlayer. At 0.01 ppm oxygen, Cr had no oxide layer, while Fe and Ni had unstable ones. Tellurium-induced pitting was deeper in Fe and Ni compared to Cr. Oxygen levels and Cr composition are critical factors affecting stable oxide compound layer formation and mitigating Te-induced pitting.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Detection of a Superluminous Spiral Galaxy in the Heart of a Massive Galaxy Cluster

It is well established that brightest cluster galaxies (BCGs), residing in the centers of galaxy clusters, are typically massive and quenched galaxies with cD or elliptical morphology. An optical survey suggested that an exotic galaxy population, superluminous spiral and lenticular galaxies, could be the BCGs of some galaxy clusters. Because the cluster membership and the centroid of a cluster cannot be accurately determined based solely on optical data, we followed up a sample of superluminous disk galaxies and their environments using XMM-Newton X-ray observations. Specifically, we explored seven superluminous spiral and lenticular galaxies that are candidate BCGs. We detected massive galaxy clusters around five superluminous disk galaxies and established that one superluminous spiral, 2MASX J16273931+3002239, is the central BCG of a galaxy cluster. The temperature and total mass of the cluster are ${{kT}}_{500}={3.55}_{-0.20}^{+0.18}$ keV and M 500 = (2.39 ± 0.19) × 10 14 M ⊙ . We identified the central galaxies of the four clusters that do not host superluminous disk galaxies at their cores, and established that the centrals are massive elliptical galaxies. However, for two of the clusters, the offset superluminous spirals are brighter than the central galaxies, implying that the superluminous disk galaxies are the brightest cluster galaxies. Our results demonstrate that superluminous disk galaxies are rarely the central systems of galaxy clusters. This is likely because galactic disks are destroyed by major mergers, which are more frequent in high-density environments. We speculate that the disks of superluminous disk galaxies in cluster cores may have been reformed due to mergers with gas-rich satellites.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1975

The use of LANDSAT-1 imagery for water quality studies in southern Scandinavia

The possibilities of using LANDSAT-1 images for environmental studies, with special references to water quality studies, were investigated by selecting test areas in southern Scandinavia. The MSS images of different bands are compared under the magnification of an Interpretoscope and densitometric analyses are performed in a Schnell-photometer. The possibility of tracing pollution plumes is studied in the Oresund outside Copenhagen. The effect of different sewers and the circulation of the polluted water is analyzed in various situations. The variation in reflectivity of a great number of lakes in South and Middle Sweden is studied by means of densitometric analyses and significant regional differences are found. The correlation with in situ measurements of water quality (turbidity and secchi disc transparency) of the sampled lakes (made by the National Swedish Environment Protection Board) is fairly good.

Hellden, U.↗
NASA NTRS1976

The Lewis Research Center geomagnetic substorm simulation facility

A simulation facility was established at the NASA-Lewis Research Center to determine the response of typical spacecraft materials to the geomagnetic substorm environment and to evaluate instrumentation that will be used to monitor spacecraft system response to this environment. Space environment conditions simulated included the thermal-vacuum conditions of space, solar simulation, geomagnetic substorm electron fluxes and energies, and the low energy plasma environment. Measurements for spacecraft material tests included sample currents, sample surface potentials, and the cumulative number of discharges. Discharge transients were measured by means of current probes and oscilloscopes and were verified by a photomultiplier.

Berkopec, F. D.↗
NASA NTRS1977

The Lewis Research Center geomagnetic substorm simulation facility

A simulation facility was established to determine the response of typical spacecraft materials to the geomagnetic substorm environment and to evaluate instrumentation that will be used to monitor spacecraft system response to this environment. Space environment conditions simulated include the thermal-vacuum conditions of space, solar simulation, geomagnetic substorm electron fluxes and energies, and the low energy plasma environment. Measurements for spacecraft material tests include sample currents, sample surface potentials, and the cumulative number of discharges. Discharge transients are measured by means of current probes and oscilloscopes and are verified by a photomultiplier. Details of this facility and typical operating procedures are presented.

Berkopec, F. D.↗
NASA NTRS1977

Volatile products from the interaction of KCl(g) with Cr2O3 and LaCrO3 in oxidizing environments

Cooled target collection techniques and high pressure mass spectrometric sampling were used to measure the relative rates of oxidative vaporization and to identify the volatile products emanating from samples of chromia and Mg-doped lanthanum chromite. The materials were exposed to partial pressures of KCl with and without H2O in one atmosphere of slowly flowing oxygen at elevated temperatures. Chromia and fresh samples of lanthanum chromite exhibited enhanced rates of oxidative vaporization upon exposure to these reactants. Mass spectrometric identification showed that the enhancements resulted from the heterogeneous formation of complex molecules of the type KCl sub 1,2,3 CrO3 and KOH sub l,2 CrO3. Lanthanum chromite that had undergone prolonged oxidative vaporization exhibited no enhanced oxidation upon exposure to the reactants.

Kohl, F. J.↗
NASA NTRS1983

Polymers in solar energy utilization

A laser photoacoustic technique (LPAT) has been verified for performing accelerated life testing of outdoor photooxidation of polymeric materials used in solar energy applications. Samples of the material under test are placed in a chamber with a sensitive microphone, then exposed to chopped laser radiation. The sample absorbs the light and converts it to heat by a nonradiative deexcitation process, thereby reducing pressure fluctuations within the cell. The acoustic signal detected by the microphone is directly proportional to the amount of light absorbed by the specimen. Tests were performed with samples of ethylene/methylacrylate copolymer (EMA) reprecipitated from hot cyclohexane, compressed, and molded into thin (25-50 microns) films. The films were exposed outdoors and sampled by LPAT weekly. The linearity of the light absorbed with respect to the acoustic signal was verified.Correlations were established between the photoacoustic behavior of the materials aged outdoors and the same kinds of samples cooled and heated in a controlled environment reactor. The reactor tests were validated for predicting outdoor exosures up to 55 days.

Liang, R. H.↗