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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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Energy Systems Integration Facility Stewardship Summary: Fiscal Year 2025

A summary of NLR's stewardship of the nationally unique Energy Systems Integration Facility (ESIF) highlighting performance metrics, capability upgrades, and examples of R&D impact. 2025 brought a national focus on energy and ESIF is meeting the moment. All eyes are on data centers and domestic manufacturing and bringing the benefits of artificial intelligence to power system planning and operations. In step with national priorities, ESIF is building out capabilities that advance secure, reliable, and affordable power. ESIF hosted 190 multidisciplinary research projects, 855 high-performance computer users, and collaborated with 81 partners from industry, academia, research, and federal agencies. These research projects resulted in an AI method for detecting high-impedance faults with 90% accuracy, a grid controls demonstration in Connecticut, power quality validation of CorePower's flagship inductor, and a cybersecurity assessment of potential rogue capabilities in digitally connected energy devices. Facility infrastructure improvements enhanced the thermal research network, the SCADA system, the cyber range, power hardware-in-the-loop testing, and more. With support from the U.S Department of Energy (DOE), the ESIF laboratories continue to deliver leading solutions for secure, reliable, and affordable power.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Performance Improvements Through Advanced PV Backtracking on Uneven Terrain

The climatic sensitivity of new terrain-aware backtracking algorithms is evaluated across 800 locations in the continental USA on a representative synthetic rolling terrain. We find that a global optimization approach to backtracking results in climate-specific annual energy gains of 2.4%–3.2% relative to a traditional backtracking algorithm baseline. We identify a strong logarithmic correlation between local diffuse fraction and yield improvement, and highlight the effect of seasonal precipitation on performance gains. We also find that a backtracking approach, which approximates the terrain as constant, does not offer significant annual energy gains over the baseline on the synthetic terrain. Our findings suggest that specific yield from backtracking in the USA can be improved by as much as 88 kWh/kW by considering terrain when selecting a backtracking algorithm.

Backtracking↗

Energy-Efficient and Comfortable Buildings through Multivariate Integrated Control (ECoMIC)

This project aims to develop an integrated control solution for enhanced energy efficiency and user comfort in commercial buildings. The developed technology is a zone-based control framework that minimizes energy usage while maintaining occupants’ visual and thermal comfort through control of electric lights, motorized venetian blinds and thermostats. The control framework is designed following a modular, scalable and flexible architecture to facilitate easy integration with exiting building management systems. The control framework contains two key algorithms: 1) the lighting load balancing algorithm and 2) the thermostat control algorithm. The lighting load balancing algorithm adopts a model-based closed-loop control approach to determine the optimal electric light and venetian blind settings. It is formulated into an optimization problem with minimizing lighting-related energy consumptions as the objective and delivering adequate task light and preventing daylight glare as the constraints. The thermostat control algorithm is based on a well-established thermal comfort model and formulated as a root-finding problem to dynamically determine the optimal thermostat setpoint for both energy savings and improved thermal comfort. To address building-wide scalability, a system architecture was developed for the zone-based control technology. Three levels of services are defined in the architecture: external services, facility level services and zone level services. The zone-level service includes the control algorithms described above as well as the corresponding interfaces, profiles, sensors and actuators to realize the zone controller. The facility level services connect to the zones through a backbone network, handle supervisory level information and controls, and thus facilitate building-wide scalability. The external services provide communication capability to entities outside of the building for grid interaction and remote access. Various aspects of the developed control technology were evaluated and verified through both simulations and testbed implementations. Simulations coupling a DOE medium office reference building in EnergyPlus building simulation software and a prototype controller in Matlab were performed. During summer time in a mixed-humid climate zone, the simulations revealed reductions of 27% and 42% in electric lighting load and cooling load, respectively, when compared to an advanced base case with daylight dimming and blinds automatically tilted to block direct sun. Two single-room testbeds were established. The testbed at Philips Lighting business building (Rosemont, IL) was designed for quantifying energy performance of integrated controls. This particular implementation achieved 40% and 79% savings on lighting and HVAC energy, respectively, compared to a relatively simple base case operated on predefined schedules. While the resulting energy savings was very encouraging, it should be noted that there may be several caveats associated with it. 1) The test was run during late spring and early summer, and the savings numbers might not be directly used to extrapolate the annual energy savings. 2) Due to the needs for separate control and metering of the small-scale demonstrator within a large building, the HVAC system, hence the corresponding savings, did not represent a typical energy code-compliant design. 3) The light level in the control case was regulated at a particular setpoint, which was lower than then the full-on light level in the base case, and the savings resulted from tuning down the light level to the setpoint was not attributable to the contribution of the developed technology. The testbed at the Lawrence Berkeley National Laboratory (Berkeley, CA) specifically focused on glare control integration, and has demonstrated the feasibility and capability of the glare detection and prevention technique. While the short one-month test in this testbed provided a functional indication of the developed technology, and it would require at least a full solstice-to-solstice cycle to ruinously quantify the performance, which was not possible within the project timeframe. There are certain limitations inherited from the operational assumptions, which could potentially affect the effectiveness and applicability of the developed control technologies. The system takes a typical ceiling-mounting approach for the photosensor locations, and therefore, the control performance relies on proper commissioning or the built-in intelligence of the photosensor for pertinent task light level estimations. For spaces where daylight penetration diminishes significantly deeper into the zone, certain modification to the control algorithms is required to accommodate multiple lighting control subzones and the corresponding sensors for providing a more uniform light level across the entire zone. Integrated control of visual and thermal comfort requires the lighting control zone and thermal control zone to coincide with each other. In other words, the area illuminated by a lighting circuit needs to be the same area served by the thermostat. Thus, the original zoning will potentially constrain the applicability of this technology in retrofitting projects. This project demonstrated the technical feasibility of a zone-based integrated control technology. From the simulation results and testbed implementations, up to 60% lighting energy savings in daylit areas relative to a “no-controls” case can easily be achieved. A 20% reduction of whole building energy consumption is also attainable. In the aspect of occupant comfort, the testbed demonstrated the ability to maintain specified light level on the workplane while promptly mitigate daylight glare 90% of the time. The control system also managed to maintain the thermal environment at a comfortable level 90% of the time. The aspect of system scalability was guaranteed by the system architecture design, based on which the testbeds were instantiated. Analysis on the aspect of economic benefit has yielded an about 6-year payback time for a medium-sized building, including the installation of all hardware and software, such as motorized blinds and LED luminaires. The payback time can be significantly reduced if part of the hardware is already in place for retrofitting projects. It needs to be noted that since the payback analysis was partly based on the testbed performance results, it is constrained by the caveats associated with the testbed implementations. The main uncertainty lies in the contribution from the space conditioning energy savings as it was non-trivial to realistically configure a room-size HVAC system for directly extrapolating whole-building HVAC energy savings. It is recommended to further evaluate the developed technology at a larger scale, where the lighting and HVAC energy consumption can be realistically measured at the building level, to more rigorously quantify the performance potentials.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Nb3Sn Coating of Twin Axis Cavity for SRF Applications

The twin axis cavity with two identical accelerating beams has been proposed for Energy recovery linac (ERL) applications. Nb3Sn is a superconducting material with a higher critical temperature and a higher critical field as compared to Nb, which promises a lower operating cost due to higher quality factors. Two niobium twin axis cavities fabricated at JLab and were proposed to be coated with Nb3Sn. Due to their more complex geometry, the typical coating process used for basic elliptical cavities needs to be improved to coat these cavities. This devel-opment advances the current coating system at JLab for coating complex cavities. Two twin axis cavities were coated recently for the first time. This contribution dis-cusses initial results from coating of twin axis cavities, RF testing and witness sample analysis with an overview of the current challenges towards high performance Nb3Sn coated twin axis cavities.

Tiskumara, J.↗

Analysis of temperature effects on self-powered neutron detectors in a gamma field

Self-powered neutron detectors (SPND) are small, robust, in-core radiation sensors that have the potential to operate in high temperature environments (above 600°C). However, previous experiments indicated temperature related effects in the form of displacement currents. Given the recent irradiation at The Ohio State University Research Reactor using a delayed-response rhodium-based SPND alongside a prompt-response tantalum-based SPND, it was concluded that only low-energy electrons from gamma interactions were the cause of these temperature effects. A series of heated gamma irradiations with temperatures up to 750°C of SPNDs were performed at the Advanced Test Reactor Gamma Facility in order to better characterize these displacement currents. The results from the experiments demonstrated a strong relation between the displacement currents that occurred during temperature ramps to thermoluminescence (TL) glow peaks—the SPND with Al2O3 insulation has one glow peak within 750°C and the SPND with MgO has three. A demonstration was performed to calculate the trap energy levels of the displacement currents through TL glow peak analysis. Unfortunately, the methods employed provided inconsistent results, requiring an updated model based on ongoing irradiation instead of post-irradiation measurements.

46 - INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AN↗

Advanced fuels campaign 2013 accomplishments

The mission of the Advanced Fuels Campaign (AFC) is to perform Research, Development, and Demonstration (RD&D) activities for advanced fuel forms (including cladding) to enhance the performance and safety of the nation’s current and future reactors; enhance proliferation resistance of nuclear fuel; effectively utilize nuclear energy resources; and address the longer-term waste management challenges. This includes development of a state-of-the art Research and Development (R&D) infrastructure to support the use of “goal-oriented science-based approach.” In support of the Fuel Cycle Research and Development (FCRD) program, AFC is responsible for developing advanced fuels technologies to support the various fuel cycle options defined in the Department of Energy (DOE) Nuclear Energy Research and Development Roadmap, Report to Congress, April 2010. Accomplishments made during fiscal year (FY) 2013 are highlighted in this report, which focuses on completed work and results. The process details leading up to the results are not included; however, the technical contact is provided for each section.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

On the Path to SunShot. Advancing Concentrating Solar Power Technology, Performance, and Dispatchability

This report examines the remaining challenges to achieving the competitive concentrating solar power (CSP) costs and large-scale deployment envisioned under the U.S. Department of Energy's SunShot Initiative. Although CSP costs continue to decline toward SunShot targets, CSP acceptance and deployment have been hindered by inexpensive photovoltaics (PV). However, a recent analysis found that thermal energy storage (TES) could increase CSP's value--based on combined operational and capacity benefits--by up to 6 cents/kWh compared to variable-generation PV, under a 40% renewable portfolio standard in California. Thus, the high grid value of CSP-TES must be considered when evaluating renewable energy options. An assessment of net system cost accounts for the difference between the costs of adding new generation and the avoided cost from displacing other resources providing the same level of energy and reliability. The net system costs of several CSP configurations are compared with the net system costs of conventional natural-gas-fired combustion-turbine (CT) and combined-cycle plants. At today's low natural gas prices and carbon emission costs, the economics suggest a peaking configuration for CSP. However, with high natural gas prices and emission costs, each of the CSP configurations compares favorably against the conventional alternatives, and systems with intermediate to high capacity factors become the preferred alternatives. Another analysis compares net system costs for three configurations of CSP versus PV with batteries and PV with CTs. Under current technology costs, the least-expensive option is a combination of PV and CTs. However, under future cost assumptions, the optimal configuration of CSP becomes the most cost-effective option.

14 SOLAR ENERGY↗

Fuzzy Linguistic Knowledge Based Behavior Extraction for Building Energy Management Systems

Significant portion of world energy production is consumed by building Heating, Ventilation and Air Conditioning (HVAC) units. Thus along with occupant comfort, energy efficiency is also an important factor in HVAC control. Modern buildings use advanced Multiple Input Multiple Output (MIMO) control schemes to realize these goals. However, since the performance of HVAC units is dependent on many criteria including uncertainties in weather, number of occupants, and thermal state, the performance of current state of the art systems are sub-optimal. Furthermore, because of the large number of sensors in buildings, and the high frequency of data collection, large amount of information is available. Therefore, important behavior of buildings that compromise energy efficiency or occupant comfort is difficult to identify. This paper presents an easy to use and understandable framework for identifying such behavior. The presented framework uses human understandable knowledge-base to extract important behavior of buildings and present it to users via a graphical user interface. The presented framework was tested on a building in the Pacific Northwest and was shown to be able to identify important behavior that relates to energy efficiency and occupant comfort.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Fundamental mechanistic insights into the catalytic reactions of Li-S redox by Co single-atom electrocatalysts via operando methods

Lithium-sulfur batteries represent an attractive option for energy storage applications. A deeper understanding of the multistep lithium-sulfur reactions and the electrocatalytic mechanisms are required to develop advanced, high-performance batteries. We have systematically investigated the lithium-sulfur redox processes catalyzed by a cobalt single-atom electrocatalyst (Co-SAs/NC) via operando confocal Raman microscopy and x-ray absorption spectroscopy (XAS). The real-time observations, based on potentiostatic measurements, indicate that Co-SAs/NC efficiently accelerates the lithium-sulfur reduction/oxidation reactions, which display zero-order kinetics. Under galvanostatic discharge conditions, the typical stepwise mechanism of long-chain and intermediate-chain polysulfides is transformed to a concurrent pathway under electrocatalysis. In addition, operando cobalt K-edge XAS studies elucidate the potential-dependent evolution of cobalt’s oxidation state and the formation of cobalt-sulfur bonds. Our work provides fundamental insights into the mechanisms of catalyzed lithium-sulfur reactions via operando methods, enabling a deeper understanding of electrocatalysis and interfacial dynamics in electrical energy storage systems.

36 MATERIALS SCIENCE↗

Advancing microelectronics through nanoscale science: A perspective on needs and opportunities from the nanoscale science research centers

Microelectronics are the cornerstone of the modern world, enhancing our daily lives by providing services such as communications and datacenters. These resources are accessible thanks to the continual pursuit of a deeper understanding of the chemical and physical phenomena underlying the materials synthesis approaches and fabrication processes used to create microelectronic components and subsequently the components' responses to electrical, optical, and other stimuli that are utilized within microelectronic systems. Today, further development of microelectronics requires multidisciplinary expertise across scientific disciplines and fields of study—synthesis, materials characterization, nanoscale fabrication, and performance characterization—with focus placed on comprehending the nanoscale forms and features of microelectronic components. The Nanoscale Science Research Centers (NSRCs) are Department of Energy, Office of Science user facilities that support the international scientific community in advancing nanoscale science and technology. As a key component of the U.S. Government's National Nanotechnology Initiative, the NSRCs enable transformative discoveries by providing world-class facilities, expertise, and collaborative opportunities. Here, in this perspective, we showcase a non-exhaustive cross-section of the capabilities housed at and developed by the NSRCs and their user communities to address fundamental synthesis, metrology, fabrication, and performance considerations toward advancing the development of new microelectronics. Finally, we provide a timely outlook on the next major areas of necessary development in nanoscale sciences to continue the innovation of microelectronics into the next generation.

2D materials↗

Spatial resolution measurements of the advanced radiographic capability x-ray imaging system at energies relevant to Compton radiography

Compton radiography provides a means to measure the integrity, ρR and symmetry of the DT fuel in an inertial confinement fusion implosion near peak compression. Upcoming experiments at the National Ignition Facility will use the ARC (Advanced Radiography Capability) laser to drive backlighter sources for Compton radiography experiments and will use the newly commissioned AXIS (ARC X-ray Imaging System) instrument as the detector. AXIS uses a dual-MCP (micro-channel plate) to provide gating and high DQE at the 40–200 keV x-ray range required for Compton radiography, but introduces many effects that contribute to the spatial resolution. Experiments were performed at energies relevant to Compton radiography to begin characterization of the spatial resolution of the AXIS diagnostic.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

2014 Radiological Monitoring Results Associated with the Advanced Test Reactor Complex Cold Waste Pond

This report summarizes radiological monitoring performed of the Idaho National Laboratory Site’s Advanced Test Reactor Complex Cold Waste wastewater prior to discharge into the Cold Waste Pond and of specific groundwater monitoring wells associated with the Industrial Wastewater Reuse Permit (#LA-000161-01, Modification B). All radiological monitoring is performed to fulfill Department of Energy requirements under the Atomic Energy Act.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

The NASA Advanced Space Power Systems Project

The goal of the NASA Advanced Space Power Systems Project is to develop advanced, game changing technologies that will provide future NASA space exploration missions with safe, reliable, light weight and compact power generation and energy storage systems. The development effort is focused on maturing the technologies from a technology readiness level of approximately 23 to approximately 56 as defined in the NASA Procedural Requirement 7123.1B. Currently, the project is working on two critical technology areas: High specific energy batteries, and regenerative fuel cell systems with passive fluid management. Examples of target applications for these technologies are: extending the duration of extravehicular activities (EVA) with high specific energy and energy density batteries; providing reliable, long-life power for rovers with passive fuel cell and regenerative fuel cell systems that enable reduced system complexity. Recent results from the high energy battery and regenerative fuel cell technology development efforts will be presented. The technical approach, the key performance parameters and the technical results achieved to date in each of these new elements will be included. The Advanced Space Power Systems Project is part of the Game Changing Development Program under NASAs Space Technology Mission Directorate.

batteries↗

Understanding of the Dynamics of the Stirling Convertor Advanced by Structural Testing

The NASA Glenn Research Center, the U.S. Department of Energy, and the Stirling Technology Company (STC) are developing a highly efficient, long-life, free-piston Stirling convertor for use as an advanced spacecraft power system for future NASA missions, including deep-space and Mars surface applications. As part of this development, four structural dynamic test programs were recently performed on Stirling Technology Demonstration Convertors (TDC's) that were designed and built by STC under contract to the Department of Energy. This testing was performed in Glenn's Structural Dynamics Laboratory and Microgravity Emissions Laboratory. The first test program, in November and December 1999, demonstrated that the Stirling TDC could withstand the harsh random vibration experienced during a typical spacecraft launch and survive with no structural damage or functional power performance degradation. This was a critical step in enabling the use of Stirling convertors for future spacecraft power systems. The most severe test was a 12.3grms random vibration test, with test durations of 3 min per axis. The random vibration test levels were chosen to simulate, with margin, the maximum anticipated launch vibration conditions. The Microgravity Emissions Laboratory is typically used to measure the dynamics produced by operating space experiments and the resulting impact to the International Space Station's microgravity environment. For the second Stirling dynamic test program, performed in January 2001, the Microgravity Emissions Laboratory was used to characterize the structure-borne disturbances produced by the normal operation of a pair of Stirling convertors. The forces and moments produced by the normal operation of a Stirling system must be recognized and controlled, if necessary, so that other nearby spacecraft components, such as cameras, are not adversely affected. The Stirling convertor pair emitted relatively benign tonal forces at its operational frequency and associated harmonics. Therefore, Stirling power systems will not disturb spacecraft science experiments if minimal appropriate mounting efforts are made. The third test program, performed in February and May 2001, resulted in a modal characterization of a Stirling convertor. Since the deflection of the TDC piston rod, under vibration excitation, was of particular interest, the outer pressure shell was removed to allow access to the rod. Through this testing, the Stirling TDC's natural frequencies and modes were identified. This knowledge advanced our understanding of the successful 1999 vibration test and may be utilized to optimize the output power of future Stirling designs. The fourth test program, in April 2001, was conducted to characterize the structural response of a pair of Stirling convertors, as a function of their mounting interface stiffness. The test results provide guidance for the Stirling power package interface design. Properly designed, the interface may lead to increased structural capability and power performance beyond what was demonstrated in the successful 1999 vibration test. Dynamic testing performed to date at Glenn has shown that the Stirling convertors can withstand liftoff random vibration environments and meet "good neighbor" vibratory emission requirements. Furthermore, the future utilization of the information obtained during the tests will allow the corporation selected to be the Stirling system integrator to optimize their convertor and system interfaces designs. Glenn's Thermo-Mechanical Systems Branch provides Stirling technology expertise under a Space Act Agreement with the Department of Energy. Additional vibration testing by Glenn's Structural Systems Dynamics Branch is planned to continue to demonstrate the Stirling power system's vibration capability as its technology and flight system designs progress.

Hughes, William O.↗

W.A. Parish Post-Combustion CO{sub 2} Capture and Sequestration Project Phase 1 Definition

For a secure and sustainable energy future, the United States (U.S.) must reduce its dependence on imported oil and reduce its emissions of carbon dioxide (CO{sub 2}) and other greenhouse gases (GHGs). To meet these strategic challenges, the U.S. wiU have to create fundamentally new technologies with performance levels far beyond what is now possible. Developing advanced post-combustion clean coal technologies for capturing CO{sub 2} from existing coal-fired power plants can play a major role in the country's transition to a sustainable energy future, especially when coupled with CO{sub 2}-enhanced oil recovery (CO{sub 2}-EOR). Pursuant to these goals, NRG Energy, Inc. (NRG) submitted an application and entered into a cost-shared collaboration with the U.S. Department of Energy (DOE) under Round 3 of the Clean Coal Power Initiative (CCPI) to advance low-emission coal technologies. The objective of the NRG W A Parish Post-Combustion CO{sub 2} Capture and Sequestration Demonstration Project is to establish the technical feasibility and economic viability of post-combustion CO{sub 2} capture using flue gas from an existing pulverized coal-fired boiler integrated with geologic sequestration via an enhanced oil recovery (EOR) process. To achieve these objectives, the project will be executed in three phases. Each phase represents a distinct aspect of the project execution. The project phases are: • Phase I. Project Definition/Front-End Engineering Design (FEED) • Phase ll. Detailed Engineering, Procurement & Construction • Phase III. Demonstration and Monitoring The purpose of Phase I is to develop the project in sufficient detail to facilitate the decision-making process in progressing to the next stage of project delivery. Phase n. This report provides a complete summary of the FEED study effort, including pertinent project background information, the scope of facilities covered, decisions, challenges, and considerations made regarding configuration and performance of the facility, along with the conceptual design and estimate results. The findings of this report should be considered conceptual in nature and are conditioned on the statements contained herein. The cost of preparing this report (including the FEED study described herein) was funded in part by a $167-million grant provided by the U.S. DOE.

20 FOSSIL-FUELED POWER PLANTS↗

An Efficient Rechargeable Aluminium–Amine Battery Working Under Quaternization Chemistry

Rechargeable aluminium (Al) batteries (RABs) have long-been pursued due to the high sustainability and three-electron-transfer properties of Al metal. However, limited redox chemistry is available for rechargeable Al batteries, which restricts the exploration of cathode materials. Herein, we demonstrate an efficient Al–amine battery based on a quaternization reaction, in which nitrogen (radical) cations (R 3 N .+ or R 4 N + ) are formed to store the anionic Al complex. The reactive aromatic amine molecules further oligomerize during cycling, inhibiting amine dissolution into the electrolyte. Consequently, the constructed Al–amine battery exhibits a high reversible capacity of 135 mAh g -1 along with a superior cycling life (4000 cycles), fast charge capability and a high energy efficiency of 94.2 %. Moreover, the Al–amine battery shows excellent stability against self-discharge, far beyond conventional Al–graphite batteries. Our findings pave an avenue to advance the chemistry of RABs and thus battery performance.

25 ENERGY STORAGE↗

Unified architecture for data-driven metadata tagging of building automation systems

This article presents a Unified Architecture (UA) for automated point tagging of Building Automation System (BAS) data, based on a combination of data-driven approaches. Advanced energy analytics applications—including fault detection and diagnostics and supervisory control—have emerged as a significant opportunity for improving the performance of our built environment. Effective application of these analytics depends on harnessing structured data from the various building control and monitoring systems, but typical BAS implementations do not employ any standardized metadata schema. While standards such as Project Haystack and Brick Schema have been developed to address this issue, the process of structuring the data, i.e., tagging the points to apply a standard metadata schema, has, to date, been a manual process. This process is typically costly, labor-intensive, and error-prone. In this work we address this gap by proposing a UA that automates the process of point tagging by leveraging the data accessible through connection to the BAS, including time-series data and the raw point names. The UA intertwines supervised classification and unsupervised clustering techniques from machine learning and leverages both their deterministic and probabilistic outputs to inform the point tagging process. Furthermore, we extend the UA to embed additional input and output data-processing modules that are designed to address the challenges associated with the real-time deployment of this automation solution. We test the UA on two datasets for real-life buildings: (i) commercial retail buildings and (ii) office buildings from the National Renewable Energy Laboratory (NREL) campus. We report the proposed methodology correctly applied 85–90% and 70–75% of the tags in each of these test scenarios, respectively for two significantly different building types used for testing UA's fully-functional prototype. The proposed UA, therefore, offers promising approach for automatically tagging BAS data as it reaches close to 90% accuracy. Further building upon this framework to algorithmically identify the equipment type and their relationships is an apt future research direction to pursue.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Design of surface protective layer of LiF/FeF 3 nanoparticles in Li-rich cathode for high-capacity Li-ion batteries

Advanced lithium-ion batteries for renewable energy storage applications have become a major research interest in recent years. Much better performance can be realized by improvements in the material surface design, especially for the cathode materials. Here, we present a new design for a surface protective layer formed via a facile aqueous solution process in which a nano-architectured layer of LiF/FeF 3 is epitaxially grown on bulk hierarchical Li-rich cathode Li[Li 0.2 Ni 0.2 Mn 0.6 ]O 2 . Coin cell tests of this material in the voltage range of 2–4.8 V indicated a high reversible capacity (260.1 mA h g -1 at 0.1 C), superior rate performance (129.9 mA h g -1 at 20 C), and excellent capacity retention. Differential scanning calorimetry showed good thermal stability. The enhanced capacity and cycling stability are attributed to the suppression of interfacial side reactions as well as the conversion reaction resulting from the introduction of LiF/FeF 3 as a surface protective layer.

Iron fluoride↗