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Sulfur Oxidation and Contrail Precursor Chemistry

Sulfuric acid (H2SO4), formed in commercial aircraft operations via Fuel-S (right arrow) SO2 + SO3 (right arrow) H2SO4, plays an important role in affecting the global climate change through atmospheric chemical reactions and radiative forcing. Measurement of the sulfur oxidation rates is critical to the understanding of the contrail formation. The principle reaction pathway is SO2 + O + M (right arrow) SO3 + M. Although there are many measurements for the rates of this reaction, it has never been measured in the temperature and pressure regime available to aircraft operation. In this investigation, a series of experiments were performed behind the reflected shock waves in a shock tube. OH radicals were produced in lean, shock heated SO2/H2/O2/Ar mixtures. The reaction progress was followed using OH absorption spectroscopy at 310 nm. The data were analyzed with the aid of computer modeling/simulation. The mean value of the rate coefficients of R21 determined is k(sub 21,0)/[M]= 3.9 x 10(exp 15) cm(sup 6) per square mole per second at T = 960 - 1150 K and rho = 16-30 micromole per cubic centimeter with uncertainty limits of plus or minus 30%. A non-Arrhenius fit to our data together with all existing data gives k(sub 21,0)/[M] = 1.3 x 10(exp 24) T (exp -2.5) exp(-2350 K/T) cm(sup 6) per square mole per second at T = 300 - 2500 K with the same uncertainty limits given above. The calculated conversion of S(IV)(SO2) to S(VI) (SO3 + H2SO4) was about 2% in our experimental conditions.

DeWitt, Kenneth↗

Precision X-ray Timing of RX J0806.3+1527 with CHANDRA: Evidence for Gravitational Radiation from an Ultracompact Binary

RX J0806.3+1527 is a candidate double degenerate binary with possibly the shortest known orbital period. The source shows an approximately equal to 100% X-ray intensity modulation at the putative orbital frequency of 3.11 mHz (321.5 s). If the system is a detached, ultracompact binary gravitational radiation should drive spin-up with a magnitude of nu(sup dot) approximately 10(exp -16) Hz per second. Efforts to constrain the X-ray frequency evolution to date have met with mixed success, principally due to the sparseness of earlier observations. Here we describe the results of the first phase coherent X-ray monitoring campaign on RX J0806.3+1527 with Chandra. We obtained a total of 70 ksec of exposure in 6 epochs logarithmically spaced over 320 days. With these data we conclusively show that the X-ray frequency is increasing at a rate of 3.77 plus or minus 0.8 x 10(exp -16) Hz per second. Using the ephemeris derived from the new data we are able to phase up all the earlier Chandra and ROSAT data and show they are consistent with a constant nu(sup dot) = 3.63 plus or minus 0.06 x 10(exp -16) Hz per second over the past decade. This value appears consistent with that recently derived by Israel et al. largely from monitoring of the optical modulation, and is in rough agreement with the solutions reported initially by Hakala et al., based on ground-based optical observations. The large and stable nu(sup dot) over a decade is consistent with gravitational radiation losses driving the evolution. An intermediate polar (IP) scenario where the observed X-ray period is the spin period of an accreting white dwarf appears less tenable because the observed nu(sup dot) requires an m(sup dot) approximately equal to 4 x 10 (exp -8) solar mass yr(sup -l), that is much larger than that inferred from the observed X-ray luminosity (although this depends on the uncertain distance and bolometric corrections), and it is difficult to drive such a high m(sup dot) in a binary system with parameters consistent with all the multiwavelength data. If the ultracompact scenario is correct, then the X-ray flux cannot be powered by stable accretion which would drive the components apart, suggesting a new type of energy source (perhaps electromagnetic) may power the X-ray flux.

Strohymayer, Tod E.↗

Development of a Spectral Model Based on Charge Transport for the Swift/BAT 32K CdZnTe Detector Array

The properties of 32K CdZnTe (4 x 4 sq mm large, 2 mm thick) detectors have been studied in the pre-flight calibration of the Burst Alert Telescope (BAT) on-board the Swift Gamma-ray Burst Explorer (scheduled for launch in November 2004). In order to understand the energy response of the BAT CdZnTe array, we first quantify the mobility-lifetime (mu tau) products of carriers in individual CdZnTe detectors, which produce a position dependency in the charge induction efficiency and results in a low energy tail in the energy spectrum. Based on a new method utilizing (57)Co spectra obtained at different bias voltages, the mu tau for electrons ranges from 5.0 x 10(exp -4) to 1.0 x 10(exp -2) sq cm/V while the mu tau for holes ranges from 1.3 x 10(exp -5 to 1.8 x 10(exp -4) sq cm/V. We find that this wide distribution of mu tau products explains the large diversity in spectral shapes between CdZnTe detectors well. We also find that the variation of mu tau products can be attributed to the difference of crystal ingots or manufacturing harness. We utilize the 32K sets of extracted mu tau products to develop a spectral model of the detector. In combination with Monte Carlo simulations, we can construct a spectral model for any photon energy or any incident angle.

Sato, Goro↗

External and Internal Reconnection in Two Filament-Carrying Magnetic-Cavity Solar Eruptions

We observe two near-limb solar filament eruptions, one of 2000 February 26 and the other of 2002 January 4. For both we use 195 Angstroms, Fe XII images from the Extreme-Ultraviolet Imaging Telescope (EIT) and magnetograms from the Michelson Doppler Imager (MDI), both of which are on the Solar arid Heliospheric Observatory (SOHO). For the earlier event we also use soft X-ray telescope (SXT), hard X-ray telescope (HXT), and Bragg Crystal Spectrometer (BCS) data from the Yohkoh satellite, and hard X-ray data from the BATSE experiment on the Compton Gamma Ray Observation, (CGRO). Both events occur in quadrupolar magnetic regions, and both have coronal features that we infer belong to the same magnetic cavity structures as the filaments. In both cases, the cavity and filament first rise slowly at approximately 10 kilometers per second prior to eruption and then accelerate to approximately 100 kilometers per second during the eruption, although the slow-rise movement for the higher altitude cavity elements is clearer in the later event. We estimate that both filaments and both cavities contain masses of approximately 10(exp 14)-10(exp 15) and approximately 10(exp 15)-10(exp 16)g, respectively. We consider whether two specific magnetic reconnection-based models for eruption onset, the tether cutting and the breakout models, are consistent with our observations. In the earlier event, soft X-rays from SXT show an intensity increase during the 12 minute interval over which fast eruption begins, which is consistent with tether-cutting-model predictions. Substantial hard X-rays, however, do not occur until after fast eruption is underway, and so this is a constraint the tether-cutting model must satisfy. During the same 12 minute interval over which fast eruption begins, there are brightenings and topological changes in the corona indicative of high-altitude reconnection early in the eruption, and this is consistent with breakout predictions. In both eruptions, the state of the overlying loops at the time of onset of the fast-rise phase of the corresponding filament can be compared with expectations from the breakout model, thereby setting constraints that the breakout model must meet. Our findings are consistent with both runaway tether-cutting-type reconnection and fast breakout-type reconnection, occurring early in the fast phase of the February eruption and with both types of reconnection being important in unleashing the explosion, but we are not able to say which, if either, type of reconnection actually triggered the fast phase. In any case, we have found specific constraints that either model, or any other model, must satisfy if correct.

Sterling, Alphonse C.↗

Tropospheric Carbon Monoxide Measurements from the Scanning High-resolution Interferometer Sounder on 7 September 2000 in Southern Africa during SAFARI 2000

Retrieved tropospheric carbon monoxide (CO) column densities are presented for more than 9000 spectra obtained by the University of Wisconsin-Madison (UWis) Scanning High-Resolution Interferometer Sounder (SHIS) during a flight on the NASA ER-2 on 7 September 2000 as part of the Southern African Regional Science Initiative (SAFARI 2000) dry season field campaign. Enhancements in tropospheric column CO were detected in the vicinity of a controlled biomass burn in the Timbavati Game Reserve in northeastern South Africa and over the edge of the river of smoke in south central Mozambique. Relatively clean air was observed over the far southern coast of Mozambique. Quantitative comparisons are presented with in situ measurements from five different instruments flying on two other aircraft: the University of Washington Convair-580 (CV) and the South African Aerocommander JRB in the vicinity of the Timbavati fire. Measured tropospheric CO columns (extrapolated from 337 to 100 mb) of 2.1 x 10(exp 18) per square centimeter in background air and up to 1.5 x 10(exp 19) per square centimeter in the smoke plume agree well with SHIS retrieved tropospheric CO columns of (2.3 plus or minus 0.25) x 10(exp 18) per square centimeter over background air near the fire and (1.5 plus or minus 0.35) x 10(exp 19) per square centimeter over the smoke plume. Qualitative comparisons are presented with three other in situ CO profiles obtained by the South African JRA aircraft over Mozambique and northern South Africa showing the influence of the river of smoke.

McMillan, W. W.↗

Sea Ice

Sea ice covers vast areas of the polar oceans, with ice extent in the Northern Hemisphere ranging from approximately 7 x 10(exp 6) sq km in September to approximately 15 x 10(exp 6) sq km in March and ice extent in the Southern Hemisphere ranging from approximately 3 x 10(exp 6) sq km in February to approximately 18 x 10(exp 6) sq km in September. These ice covers have major impacts on the atmosphere, oceans, and ecosystems of the polar regions, and so as changes occur in them there are potential widespread consequences. Satellite data reveal considerable interannual variability in both polar sea ice covers, and many studies suggest possible connections between the ice and various oscillations within the climate system, such as the Arctic Oscillation, North Atlantic Oscillation, and Antarctic Oscillation, or Southern Annular Mode. Nonetheless, statistically significant long-term trends are also apparent, including overall trends of decreased ice coverage in the Arctic and increased ice coverage in the Antarctic from late 1978 through the end of 2003, with the Antarctic ice increases following marked decreases in the Antarctic ice during the 1970s. For a detailed picture of the seasonally varying ice cover at the start of the 21st century, this chapter includes ice concentration maps for each month of 2001 for both the Arctic and the Antarctic, as well as an overview of what the satellite record has revealed about the two polar ice covers from the 1970s through 2003.

Parkinson, Claire L.↗

External and Internal Reconnection in Two Filament-Carrying Magnetic-Cavity Solar Eruptions

We observe two near-limb solar filament eruptions, one of 2000 February 26 and the other of 2002 January 4. For both we use 195 A Fe XII images from the Extreme-Ultraviolet Imaging Telescope (EIT) and magnetograms from the Michelson Doppler Imager (MDI), both of which are on the Solar and Heliospheric Observatory (SOHO). For the earlier event we also use soft X-ray telescope (SXT), hard X-ray telescope (HXT), and Bragg Crystal Spectrometer (BCS) data from the Yohkoh satellite, and hard X-ray data from the BATSE experiment on the Compton Gamma Ra.v Observatory (CGRO). Both events occur in quadrupolar magnetic regions, and both have coronal features that we infer belong to the same magnetic cavity structures as the filaments. In both cases, the cavity and filament first rise slowly at approx.10 km/s prior to eruption and then accelerate to approx.100 km/s during the eruption, although the slow-rise movement for the higher altitude cavity elements is clearer in the later event. We estimate that both filaments and both cavities contain masses of approx.10(exp 14)-10(exp 15) and approx.10(exp 15)-10(exp 16) g, respectively. We consider whether two specific magnetic reconnection-based models for eruption onset, the "tether cutting" and the "breakout" models, are consistent with our observations. In the earlier event, soft X-rays from SXT show an intensity increase during the 12 minute interval over which fast eruption begins, which is consistent with tether- cutting-model predictions. Substantial hard X-rays, however, do not occur until after fast eruption is underway, and so this is a constraint the tether-cutting model must satisfy. During the same 12 minute interval over which fast eruption begins, there are brightenings and topological changes in the corona indicative of high-altitude reconnection early in the eruption, and this is consistent with breakout predictions. In both eruptions, the state of the overlying loops at the time of onset of the fast-rise phase of the corresponding filament can be compared with expectations from the breakout model, thereby setting constraints that the breakout model must meet. Our findings are consistent with both runaway tether-cutting-type reconnection and fast breakout-type reconnection, occurring early in the fast phase of the February eruption and with both types of reconnection being important in unleashing the explosion, but we are not able to say which, if either, type of reconnection actually triggered the fast phase. In any case, we have found specific constraints that either model, or any other model, must satisfy if correct.

Sterling, Alphonse C.↗

Measurement of the Specific Heat Using a Gravity Cancellation Approach

The specific heat at constant volume C(sob V) of a simple fluid diverges near its liquid-vapor critical point. However, gravity-induced density stratification due to the divergence of isothermal susceptibility hinders the direct comparison of the experimental data with the predictions of renormalization group theory. In the past, a microgravity environment has been considered essential to eliminate the density stratification. We propose to perform specific heat measurements of He-3 on the ground using a method to cancel the density stratification. A He-3 fluid layer will be heated from below, using the thermal expansion of the fluid to cancel the hydrostatic compression. A 6% density stratification at a reduced temperature of 10(exp -5) can be cancelled to better than 0.1% with a steady 1.7 micro K temperature difference across a 0.05 cm thick fluid layer. A conventional AC calorimetry technique will be used to determine the heat capacity. The minimized bulk density stratification with a relaxation time 6500 sec at a reduced temperature of 10(exp -5) will stay unchanged during 1 Hz AC heating. The smear of the specific heat divergence due to the temperature difference across the cell is about 0.1% at a reduced temperature of 10(exp -6). The combination of using High Resolution Thermometry with a 0.5 n K temperature resolution in the AC technique and the cancellation of the density stratification will enable C(sub V) to be measured down to a reduced temperature of 10(exp -6) with less than a 1% systematic error.

Zhong, Fang↗

Ultra-High-Temperature Ceramics Evaluated for Aeropropulsion Use

Ultra-high-temperature ceramics (UHTC) are a group of materials consisting of zirconium diboride (ZrB2) or hafnium diboride (HfB2) plus silicon carbide (SiC), and in some instances, carbon (C). They offer a combination of properties that make them candidates for airframe leading edges on sharp-bodied reentry vehicles. These UHTCs perform well in the environment for such applications (i.e., air at low pressures). The purpose of this study at the NASA Glenn Research Center was to examine three of these materials under conditions more representative of a propulsion environment: that is, higher oxygen partial pressure and total pressure. Relatively long, multiple-exposure cycles were emphasized. We completed an in-house study of ZrB2 plus 20 vol% SiC (abbreviated as ZS), ZrB2 plus 14 vol% SiC and 30 vol% C (ZSC), and SCS-9a SiC fiber-reinforced ZrB2 plus 20 vol% SiC (ZSS). HfB2-based compositions were not included in the study because of their high cost. The capability of UHTC for propulsion applications must be compared with that of mature, available, and commercially used ceramics such as silicon nitride (e.g., AS-800) to put things in proper perspective. In terms of mechanical properties, UHTCs fall short in terms of strength and fracture toughness. At about 1300 C, the creep resistance of ZS appears to be superior to the creep resistance reported for AS-800. However, the stress rupture life for Si3N4 under stress and temperature conditions similar to those used in this study is measured in hundreds of hours. Because of oxidation, ZS could not achieve such lives. In terms of oxidation resistance, acceptable amounts of material recession in 1 hour to thousands of hours, depending on the specific propulsion application, are on the order of 100 to 300 mm. This converts to an acceptable range of parabolic recession rate constants kp" of approximately less than or equal to 10(exp -1) to 10(exp -2) square millimeters per hour for a 1-hr application. For a 100-hr application, an acceptable range of kp" would be less than or equal to those values divided by 100. For the more oxidation resistant ZS material, measured parabolic recession rate constants were 4.7 x 10(exp -3) millimeters per hour at 1327 C, 7.8 x 10(exp -2) square millimeters per hour at 1627 C, and 1.3 millimeters per hour at 1927 C. Thus, recession rate constants for ZS are acceptable at 1327 C for a 1-hr application, but here silicon nitride is a superior material. At 1627 C, ZS oxidation is marginal for a 1-hr application, but dimensional growth would be an issue. In a 100-hr application, ZS cannot be considered at any temperature. Our cursory examination of thermal shock, both from a theoretical and experimental viewpoint, indicated that the ZS and ZSC UHTCs are inferior to AS-800 silicon nitride. On the basis of this limited study, UHTCs are not ready to be considered as aeropropulsion materials for any applications longer than a few minutes. Current materials suffer from aggressive oxidation and moisture attack (Quynhgiao Nguyen, NASA Glenn, and Raymond C. Robinson, QSS Group, Inc., Cleveland, OH, 2002, private communication), and they are susceptible to thermal shock. For long-term propulsion applications, major improvements in environmental durability are needed. Work is in progress to improve the oxidation resistance of UHTC materials.

Levine, Stanley R.↗

Gravitational Wave Detection on the Moon and the Moons of Mars

The Moon and the moons of Mars should be extremely quiet seismically and could therefore become sensitive gravitational wave detectors, if instrumented properly. Highly sensitive displacement sensors could be deployed on these planetary bodies to monitor the motion induced by gravitational waves. A superconducting displacement sensor with a 10-kg test mass cooled to 2 K will have an intrinsic instrument noise of 10(exp -16) m Hz(exp -1/2). These sensors could be tuned to the lowest two quadrupole modes of the body or operated as a wideband detector below its fundamental mode. An interesting frequency range is 0.1 to approx. 1 Hz, which will be missed by both the ground detectors on the Earth and LISA and would be the best window for searching for stochastic background gravitational waves. Phobos and Deimos have their lowest quadrupole modes at 0.2 to approx. 0.3 Hz and could offer a sensitivity h(sub min) = 10(exp -22) Hz(exp -1/2) within their resonance peaks, which is within two orders of magnitude from the goal of the Big Bang Observer (BBO). The lunar and Martian moon detectors would detect many interesting foreground sources in a new frequency window and could serve as a valuable precursor for BBO.

Paik, Ho Jung↗

A Chandra ACIS Observation of the X-ray Luminous SN 1988Z

SN 1988Z is the most luminous X-ray-emitting supernova, initially detected in 1995 using the ROSAT HRI with the luminosity of approx. 8x10(exp 40) erg/s . Its high luminosity was ascribed to expansion of the blast wave into an especially dense circumstellar medium. In this paper, we describe a recent observation of SN 1988Z using the ACIS detector on CHANDRA. We readily detect SN 1988Z, obtaining approx. 30 net counts which corresponds to a 0.2-2.0 keV luminosity of approx. 3.2x10(exp 39) erg/s. The calculated quantiles for the extracted counts allow a broad range of temperatures, but require a temperature hotter than 5 keV if there is no intrinsic absorption. The X-ray luminosity indicates that the emitting region has a high density (>10(exp 5)/cu cm)and that the density profile is not consistent with a constant mass loss stellar wind during the approx. 5,000 years before the explosion. If the circumstellar medium is due to progenitor mass loss, then the mass loss rate is extremely high (approx.10(exp -3) Solar Mass/yr(V(sub omega)/10 km/s)). The X-ray results are compared with the predictions of models of SN 1988Z.

Schlegel, Eric M.↗

Spatial Correlation Function of the Chandra Selected Active Galactic Nuclei

We present the spatial correlation function analysis of non-stellar X-ray point sources in the Chandra Large Area Synoptic X-ray Survey of Lockman Hole Northwest (CLASXS). Our 9 ACIS-I fields cover a contiguous solid angle of 0.4 deg(exp 2) and reach a depth of 3 x 10(exp -15) erg/square cm/s in the 2-8 keV band. We supplement our analysis with data from the Chandra Deep Field North (CDFN). The addition of this field allows better probe of the correlation function at small scales. A total of 233 and 252 sources with spectroscopic information are used in the study of the CLASXS and CDFN fields respectively. We calculate both redshift-space and projected correlation functions in co-moving coordinates, averaged over the redshift range of 0.1 < z < 3.0, for both CLASXS and CDFN fields for a standard cosmology with Omega(sub Lambda) = 0.73,Omega(sub M) = 0.27, and h = 0.71 (H(sub 0) = 100h km/s Mpc(exp -1). The correlation function for the CLASXS field over scales of 3 Mpc< s < 200 Mpc can be modeled as a power-law of the form xi(s) = (S/SO)(exp - gamma), with gamma = 1.6(sup +0.4 sub -0.3) and S(sub o) = 8.0(sup +.14 sub -1.5) Mpc. The redshift-space correlation function for CDFN on scales of 1 Mpc< s < 100 Mpc is found to have a similar correlation length so = 8.55(sup +0.74 sub -0.74) Mpc, but a shallower slope (gamma = 1.3 +/- 0.1). The real-space correlation functions derived from the projected correlation functions, are found to be tau(sub 0 = 8.1(sup +1.2 sub -2.2) Mpc, and gamma = 2.1 +/- 0.5 for the CLASXS field, and tau(sub 0) = 5.8(sup +.1.0 sub -1.5) Mpc, gamma = 1.38(sup +0.12 sub -0.14 for the CDFN field. By comparing the real- and redshift-space correlation functions in the combined CLASXS and CDFN samples, we are able to estimate the redshift distortion parameter Beta = 0.4 +/- 0.2 at an effective redshift z = 0.94. We compare the correlation functions for hard and soft spectra sources in the CLASXS field and find no significant difference between the two groups. We have also found that the correlation between X-ray luminosity and clustering amplitude is weak, which, however, is fully consistent with the expectation using the simplest relations between X-ray luminosity, black hole mass, and dark halo mass. We study the evolution of the AGN clustering by dividing the samples into 4 redshift bins over 0.1 Mpc< z <3.0 Mpc. We find a very mild evolution in the clustering amplitude, which show the same evolution trend found in optically selected quasars in the 2dF survey. We estimate the evolution of the bias, and find that the bias increases rapidly with redshift (b(z = 0.45) = 0.95 +/- 0.15 and b(z = 2.07) = 3.03 +/- 0.83): The typical mass of the dark matter halo derived from the bias estimates show little change with redshift. The average halo mass is found to be log (M(sub halo)/M(sun))approximates 12.1. Subject headings: cosmology: observations - large-scale structure of the universe - x-rays: diffuse background - galaxies: nuclei

Yang, Y.↗

The electron excited ultraviolet spectrum of HD : cross sections and transition probabilities

We have analyzed the high-resolution ultraviolet (UV) emission spectrum of molecular deuterium hydride (HD) excited by electron impact at 100 eV under optically thin, single-scattering experimental conditions. The high-resolution spectrum (FWHM=160 mA) spans the wavelength range from 900 to 1650 A and contains the two Rydberg series of HD: (sup 1)Sigma(sub u)(sup +)1s(sigma), np(si n=2, 3, 4) --> X(sup 1)Sigma(sub g)(sup +) and (sup 1)Pi(sub u)(sup +)1s(sigma), np(pi)(C,D,D',D'', n=2, 3, 4, 5) -->X(sup 1)Sigma(sub g)(sup +). A model spectrum of HD, based on newly calculated tra rovibrational coupling for the strongest band systems, B (sup 1)Sigma(sub u)(sup +)-X(sup 1)Sigma(sub g)(sup +),B'(sup 1)Sigma(sub g)(sup +)-X(sup 1)Sigma(sub g)(sup +),C(sup 1)Pi(sub u)-X(sup 1)Sigm sections for direct excitation at 100 eV of the B (sup 1)Sigma(sub u)(sup +), B' (sup 1)Sigma(sub u)(sup +), C(sup 1)Pi(sub u), and D(sup 1)Pi(sub u) states were derived from a model analysis of the state. The absolute cross section values for excitation to the B (sup 1)Sigma(sub u)(sup +), B' (sup 1)Sigma(sub u)(sup +), C(sup 1)Pi(sub u), and D(sup 1)Pi(sub u) states were found to be (2.57+/-0. and (0.17+/-0.04)x10(exp -17) sq cm, respectively. We have also determined the dissociative excitation cross sections at 100 eV for the emission of Ly(alpha) at 1216 A and Ly(Beta) at 1025 A lines, which are (7.98+/-1.12)x10(exp -18) and (0.40+/-0.10)x10(exp -18) sq cm, respectively. The summed excitation function of the closely spaced pair of lines, H Ly(alpha) and D Ly(Beta), resulting from excitation of HD, has been measured from the threshold to 800 eV and is analytically modeled with a semiempirical relation. The model cross sections are in good agreement with the corrected Ly(alpha) cross sections of Mohlmann et al. up to 2 keV. Based on measurements of H, D (2s) production cross section values by Mohlmann et al., the H, D (n=2) cross section is estimated to be 1.6 x 10(exp -17) sq cm at 100 eV.

molecular data↗

Post Irradiation Evaluation of Thermal Control Coatings and Solid Lubricants to Support Fission Surface Power Systems

The development of a nuclear power system for space missions, such as the Jupiter Icy Moons Orbiter or a lunar outpost, requires substantially more compact reactor design than conventional terrestrial systems. In order to minimize shielding requirements and hence system weight, the radiation tolerance of component materials within the power conversion and heat rejection systems must be defined. Two classes of coatings, thermal control paints and solid lubricants, were identified as material systems for which limited radiation hardness information was available. Screening studies were designed to explore candidate coatings under a predominately fast neutron spectrum. The Ohio State Research Reactor Facility staff performed irradiation in a well characterized, mixed energy spectrum and performed post irradiation analysis of representative coatings for thermal control and solid lubricant applications. Thermal control paints were evaluated for 1 MeV equivalent fluences from 10(exp 13) to 10(exp 15) n per square centimeters. No optical degradation was noted although some adhesive degradation was found at higher fluence levels. Solid lubricant coatings were evaluated for 1 MeV equivalent fluences from 10(exp 15) to 10(exp 16) n per square centimeters with coating adhesion and flexibility used for post irradiation evaluation screening. The exposures studied did not lead to obvious property degradation indicating the coatings would have survived the radiation environment for the previously proposed Jupiter mission. The results are also applicable to space power development programs such as fission surface power for future lunar and Mars missions.

Bowman, Cheryl L.↗

Microthrust Propulsion of the LISA Mission

We present the most recent propulsion requirements for the Laser Interferometer Space Antenna (LISA) Mission and describe potential microth ruster technology that can meet these requirements. LISA consists of three spacecraft in heliocentric orbits, forming a triangle with 5x l 0 (exp 6) km sides that are the arms of three Michelson-type interferometers. Reflective proof masses provide the reference surfaces at the end of the interferometer arms as part of the Gravitational Referenc e Sensor (GRS) designed to detect gravitational waves. The microthrus t propulsion system will be part of the Disturbance Reduction System (DRS), which is responsible for maintaining each spacecraft position w ithin approximately 10 nm around the proof masses. To provide the nec essary sensitivity, the GRS must not experience spurious acceleration s >15 (exp -10) m/ s(exp 2) in the 0.1 mHz to 1 Hz bandwidth, requiring precision formation flying and drag-free operation of the LISA spa cecraft. This leads to the following microthruster performance requir ements: a thrust range of 2-30 Micro N, a thrust resolution < 0.1 Mic ro N, and thrust noise <0.1 Hz(exp -1/2) over the LISA measurement bandwidth. The microthruster must provide this performance for 5 years c ontinuously, contain 10 years worth of propellant, and not disrupt th e science measurements. Potential microthruster technologies include Colloid, Field Emission Electric Propulsion (FEEP), and precision cold gas microthrusters. Each of these technologies is described in detai l with focus on the NASA microthruster development of the Busek Collo id Micro-Newton Thruster (CMNT).

Field Emission Electric Propulsion (FEEP)↗

Warm Molecular Gas Traced with CO J = 7 --> 6 in the Galaxy's Central 2 Parsecs: Dynamical Heating of the Circumnuclear Disks

We present an 11" resolution map of the central 2 pc of the Galaxy in the CO J = 7 --> 6 rotational transition. The CO emission shows rotation about Sgr A* but also evidence for noncircular turbulent motion and a clumpy morphology. We combine our data set with available CO measurements to model the physical conditions in the disk. We find that the molecular gas in the region is both warm and dense, with T approx. 200-300 K and n(sub H2) approx. (5-7) x 10(exp 4) cm(exp -3). The mass of warm molecular gas we measure in the central 2 pc is at least 2000 M(solar), about 20 times the UV-excited atomic gas mass, ruling out a UV heating scenario for the molecular material. We compare the available spectral tracers with theoretical models and conclude that molecular gas is heated with magnetohydrodynamic shocks with v approx. 10-20 km s(exp -1) and B approx. 0.3- 0.5 mG. Using the conditions derived with the CO analysis, we include the other important coolants, neutral oxygen and molecular hydrogen, to estimate the total cooling budget of the molecular material. We derive a mass-to-luminosity ratio of approx. 2-3 M(solar)(L(solar)exp -1), which is consistent with the total power dissipated via turbulent decay in 0.1 pc cells with v(sub rms) approx. 15 kilometers per second. These size and velocity scales are comparable to the observed clumping scale and the velocity dispersion. At this rate, the material near Sgr A* is dissipating its orbital energy on an orbital timescale and cannot last for more than a few orbits. Our conclusions support a scenario in which the features near Sgr A* such as the circumnuclear disk and northern arm are generated by infalling clouds with low specific angular momentum.

galatic nuclei↗

Structural Modeling for the Terrestrial Planet Finder Mission

We present the most recent propulsion requirements for the Laser Interferometer Space Antenna (LISA) Mission and describe potential microth ruster technology that can meet these requirements. LISA consists of three spacecraft in heliocentric orbits, forming a triangle with 5x l o6 km sides that are the arms of three Michelson-type interferometers. Reflective proof masses provide the reference surfaces at the end of the interferometer arms as part of the Gravitational Reference Senso r (GRS) designed to detect gravitational waves. The microthrust propu lsion system will be part of the Disturbance Reduction System (DRS), which is responsible for maintaining each spacecraft position within approximately 10 nm around the proof masses. To provide the necessary sensitivity, the GRS must not experience spurious accelerations > 10 (exp -15) m/s(exp 2)# Hz (exp -1/2) in the 0.1 mHz to 1 Hz bandwidth, requiring precision formation flying and drag-free operation of the L ISA spacecraft. This leads to the following microthruster performance requirements: a thrust range of 2-30 microN, a thrust resolution < O .1 micro N, and thrust noise <0.1 micro N Hz (exp -1/2) over the LISA measurement bandwidth. The microthruster must provide this performanc e for 5 years continuously, contain 10 years worth of propellant, and not disrupt the science measurements. Potential microthruster techno logies include Colloid, Field Emission Electric Propulsion (FEEP), and precision cold gas microthrusters. Each of these technologies is des cribed in detail with focus on the NASA microthruster development of the Busek Colloid Micro-Newton Thruster (CMNT).

coronagraphs↗

Experimental Impacts into Chondritic Targets: Disruption of an L6 Chondrite by Multiple Impacts - Part 1

A fragment of an L6 chondrite (ALH 85017,13) with an initial mass (M(sub 0)) of 464.1 g was the target in a series of experimental impacts in which the largest remaining fragment (M(sub R)) after each shot was impacted by a 3.18-mm ceramic sphere at a nominal speed of 2 km/s. This continued until the mass of the largest remaining piece was less than half the mass of the target presented to that shot (M(sub S)). Two chunks of Bushveldt gabbro with similar initial masses were also impacted under the same conditions until M(sub R) was less than half M(sub 0). The two gabbro targets required a total of 1.51x10(exp 7) and 1.75x10(exp 7) erg/g to attain 0.27 and 0.33 M(sub R)/M(sub 0), respectively; the chondrite, however, was considerably tougher, reaching 0.40 and 0.21 M(sub R)/M(sub 0) only after receiving 2.37x10(exp 7) and 3.10x10(exp 7) erg g-1, respectively. The combined ejecta and spallation products from the gabbro impacts were coarser than those from the chondrite and in sufficient quantities that the new surface areas exceeded those from the meteorite until the fifth shot in the chondrite series, which was the number of impacts required to disrupt each gabbro target (i.e., MR/M0 = 0.5). Unlike the behavior shown in previous regolith-evolution series, neither gabbro target produced an enhancement in the size fraction reflecting the mean size of the crystals composing the rock (about 3 mm), an effect possibly related to the width of the shock pulse. The original chondrite was so fine-grained and fractured, and the variance in its grain-size distribution so large, that effects related to grain-size were relegated to the <63- m fraction. Impacts into ALH 85017 produced abundant, fine-grained debris, but otherwise the slopes of its size distributions were comparable to those from other experiments involving natural and fabricated terrestrial targets. The characteristic slopes of the chondrite's size distributions, however, were notably more constant over the entire nine-impact series than those from any of the terrestrial targets, a testament to the control over comminution apparently exerted by pre-existing fractures and other, microscopic damage in the meteorite. The enhancement in the finer fraction of debris from ALH 85017 indicates that ordinary chondrites in solar orbit would be very efficient contributors to the cosmic-dust complex. At the same time, the greater resistance to disruption displayed by ordinary chondrites relative to that exhibited by igneous rocks indicates that a selection effect could be operative between the annealed, ordinary-chondritic breccias and relatively weaker, differentiated meteorites. Preferential survival from their time in the regoliths of their parent bodies through their transit to Earth and passage through the atmosphere suggests that meteorite collections could be biased in favor of the ordinary chondrites.

Cintala, Mark J.↗