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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,009 records · Page 56

Effect of isovalent non-magnetic Fe-site doping on the electronic structure and spontaneous polarization of BiFeO{sub 3}

We report the results of our first-principles calculations on the effect of isovalent, non-magnetic, Al{sup 3+} ion doping on the electronic structure and spontaneous polarization of multiferroic BiFeO{sub 3}. Our calculations reveal that Al{sup 3+} doping in BiFeO{sub 3} results in the reduction of Fe–O–Fe bond angle, leading to the weakening of antiferromagnetic superexchange interaction, further substantiated by the reduction of exchange interaction constant with increasing doping level. Lowering of well-depth is suggestive of reduced switching potential and improved P-E loop with lowered coercivity. Chemical bonding analysis by electron localization function shows that cation–oxygen bonding is of mixed ionic–covalent character, with marginal increase in the covalent character with increasing doping concentration. Large spontaneous polarization of undoped BiFeO{sub 3} is retained with lower doping level (6.25%), while for higher doping content (31.25%), the spontaneous polarization is reduced, primarily due to larger c/a ratio at higher doping level.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

The theoretical foundation of 3D Alfvén resonances: normal modes

We consider the resonant coupling of fast and Alfvén magnetohydrodynamic (MHD) waves in a 3D equilibrium. Numerical solutions to normal modes (∝exp (−iωt)) are presented, along with a theoretical framework to interpret them. The solutions we find are fundamentally different from those in 1D and 2D. In 3D there exists an infinite number of possible resonant solutions within a “Resonant Zone,” and we show how boundary conditions and locally 2D regions can favor particular solutions. A unique feature of the resonance in 3D is switching between different permissible solutions when the boundary of the Resonant Zone is encountered. The theoretical foundation that we develop relies upon recognizing that, in 3D, the orientation of the resonant surface will not align in a simple fashion with an equilibrium coordinate. We present a method for generating the Alfvén wave natural frequencies for an arbitrarily oriented Alfvén wave, which requires a careful treatment of scale factors describing the background magnetic field geometry.

79 ASTRONOMY AND ASTROPHYSICS↗

Antiferromagnetic memory storage devices from magnetic transition metal dichalcogenides

Switchable antiferromagnetic (AFM) memory devices are provided based on magnetically intercalated transition metal dichalcogenides (TMDs) of the form AxMC2, where A is a magnetic element of stoichiometry x between 0 and 1, M is a transition metal of stoichiometry 1, and C is a chalcogen of stoichiometry 2. Memory storage is achieved by fabricating these materials into crosses of two or more bars and driving DC current pulses along the bars to rotate the AFM order to a fixed angle with respect to the current pulse. Application of current pulses along different bars can switch the AFM order between multiple directions. Standard resistance measurements can detect the orientation of the AFM order as high or low resistance states. The state of the device can be set by the input current pulses, and read-out by the resistance measurement, forming a non-volatile, AFM memory storage bit.

Analytis, James G.↗

Identifying Photoinduced Dipolar Polarization and Orbit–Orbit Interaction between Excitons in Organic–Inorganic Hybrid Perovskites

Abstract Photoinduced polarization and orbit–orbit interaction are important issues in hybrid perovskites toward developing optoelectronic functionalities. This paper identifies that photoinduced polarization occurs in hybrid perovskites with mixed‐cation methylammonium (MA)/formamidinium (FA) (MA x FA (1− x ) PbI 3 ) by measuring bulk polarization at 1 MHz in a magnetic field. Interestingly, when the internal dipole moment is increased upon increasing the MA:FA ratio, the photoinduced dipolar polarization can be substantially enhanced, clarifying the controversial issue of whether photoexcitation can induce a dielectric polarization within dipolar polarization regime in hybrid perovskites. Furthermore, upon increasing photoinduced dipolar polarization, it is found that the intrinsic orbit–orbit interaction between excitons can be increased, revealed by monitoring photocurrent change (Δ J sc ) upon switching the photoexcitation between linear and circular polarizations. This presents that organic cations are directly involved in the orbit–orbit interaction within band structures. Clearly, the studies provide an insightful understanding of the dipole moment effects on photoinduced dipolar polarization and orbit–orbit interaction between excitons in hybrid perovskites toward controlling the optoelectronic properties.

Dou, Yixuan↗

Fabrication of Gamma Detectors Based on Magnetic Ag:Er Microcalorimeters

This report discusses the photolithographic fabrication of ultra-high resolution gamma-ray detectors based on magnetic microcalorimeters (MMCs). The MMC uses a novel Er-doped silver sensor (Ag:Er) that is expected to have higher sensitivity than the Er-doped gold (Au:Er) sensors currently in use. The MMC also integrates the first-stage SQUID preamplifier on the same chip as the MMC gamma detector to increase its signal-to-noise ratio. In addition, the MMC uses a passive Ta-Nb heat switch to replace one of the common long-term failure points in earlier detectors. This report discusses the fabrication process we have developed to implement the proposed improvements.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

TIMING OBSERVATIONS OF PSR J1023+0038 DURING A LOW-MASS X-RAY BINARY STATE

Transitional millisecond pulsars (tMSPs) switch, on roughly multi-year timescales, between rotation-powered radio millisecond pulsar (RMSP) and accretion-powered low-mass X-ray binary (LMXB) states. The tMSPs have raised several questions related to the nature of accretion flow in their LMXB state and the mechanism that causes the state switch. The discovery of coherent X-ray pulsations from PSR J1023+0038 (while in the LMXB state) provides us with the first opportunity to perform timing observations and to compare the neutron star’s spin variation during this state to the measured spin-down in the RMSP state. Whereas the X-ray pulsations in the LMXB state likely indicate that some material is accreting onto the neutron star’s magnetic polar caps, radio continuum observations indicate the presence of an outflow. The fraction of the inflowing material being ejected is not clear, but it may be much larger than that reaching the neutron star’s surface. Timing observations can measure the total torque on the neutron star. We have phase-connected nine XMM-Newton observations of PSR J1023+0038 over the last 2.5 years of the LMXB state to establish a precise measurement of spin evolution. We find that the average spin-down rate as an LMXB is 26.8 ± 0.4% faster than the rate (−2.39 × 10{sup −15} Hz s{sup −1}) determined during the RMSP state. This shows that negative angular momentum contributions (dipolar magnetic braking, and outflow) exceed positive ones (accreted material), and suggests that the pulsar wind continues to operate at a largely unmodified level. We discuss implications of this tight observational constraint in the context of possible accretion models.

79 ASTRONOMY AND ASTROPHYSICS↗

Optical Helicity-Manipulated Photocurrents and Photovoltages in Organic Solar Cells

The performance of an organic functional device can be effectively improved through external field manipulation. In this study, we experimentally demonstrate the optical polarization manipulation of the photocurrent or photovoltage in organic solar cells. Through switching the incident light from a linearly polarized light to a circularly polarized one, we find a pronounced change in the photocurrent, which is not observable in normal inorganic cells. There are two competing hypotheses for the primary process underlying the circular polarization-dependent phenomena in organic materials, one involving the inverse Faraday effect (IFE) and the other a direct photon spin–electron spin interaction. By way of ingenious device design and external magnetic field-induced stimuli, it is expected that the organic IFE can be a powerful experimental tool in revealing and elucidating excited-state processes occurring in organic spintronic and optoelectronic devices. Therefore, we believe that our results will potentially lead to the development of new multifunctional organic devices with integrated electronic, optical, and magnetic properties for energy conversion, optical communication, and sensing technologies.

14 SOLAR ENERGY↗

Ion Migration Studies in Exfoliated 2D Molybdenum Oxide via Ionic Liquid Gating for Neuromorphic Device Applications

The formation of an electric double layer in ionic liquid (IL) can electrostatically induce charge carriers and/or intercalate ions in and out of the lattice which can trigger a large change of the electronic, optical, and magnetic properties of materials and even modify the crystal structure. Here, we present a systematic study of ionic liquid gating of exfoliated 2D molybdenum trioxide (MoO 3 ) devices and correlate the resultant electrical properties to the electrochemical doping via ion migration during the IL biasing process. A nearly 9 orders of magnitude modulation of the MoO 3 conductivity is obtained for the two types of ionic liquids that are investigated. In addition, notably rapid on/off switching was realized through a lithium-containing ionic liquid whereas much slower modulation was induced via oxygen extraction/intercalation. Time of flight–secondary ion mass spectrometry confirms the Li intercalation. Density functional theory (DFT) calculations have been carried out to examine the underlying metallization mechanism. Results of short-pulse tests show the potential of these MoO 3 devices as neuromorphic computing elements due to their synaptic plasticity.

2D materials↗

Antiferromagnetic metal phase in an electron-doped rare-earth nickelate

Long viewed as passive elements, antiferromagnetic materials have emerged as promising candidates for spintronic devices due to their insensitivity to external fields and potential for high-speed switching. Recent work exploiting spin and orbital effects has identified ways to electrically control and probe the spins in metallic antiferromagnets, especially in non-collinear or non-centrosymmetric spin structures. The rare-earth nickelate NdNiO 3 is known to be a non-collinear antiferromagnet in which the onset of antiferromagnetic ordering is concomitant with a transition to an insulating state. In this work, we find that for low electron doping, the magnetic order on the nickel site is preserved, whereas electronically, a new metallic phase is induced. We show that this metallic phase has a Fermi surface that is mostly gapped by an electronic reconstruction driven by bond disproportionation. Furthermore, we demonstrate the ability to write to and read from the spin structure via a large zero-field planar Hall effect. Our results expand the already rich phase diagram of rare-earth nickelates and may enable spintronics applications in this family of correlated oxides.

36 MATERIALS SCIENCE↗

Time- and power-dependent operation of a parametric spin-wave amplifier

We present the experimental observation of the localized amplification of externally excited, propagating spin waves in a transversely in-plane magnetized Ni{sub 81}Fe{sub 19} magnonic waveguide by means of parallel pumping. By employing microfocussed Brillouin light scattering spectroscopy, we analyze the dependency of the amplification on the applied pumping power and on the delay between the input spin-wave packet and the pumping pulse. We show that there are two different operation regimes: At large pumping powers, the spin-wave packet needs to enter the amplifier before the pumping is switched on in order to be amplified while at low powers the spin-wave packet can arrive at any time during the pumping pulse.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Vertical oscillations of dust particles in a strongly magnetized plasma sheath induced by horizontal laser manipulation

Experimental studies are presented where dust particles are suspended in the lower sheath region of an argon rf discharge at a strong vertical magnetic field from B = 1.5 T up to 2.27 T. There the particles arranged in an ordered pattern imposed by the upper mesh electrode. It is observed that the particles jump to a new equilibrium position, where they exhibit self-excited vertical oscillations when illuminated by a horizontal laser beam. Furthermore, the dust motion is weakly damped during an upward jump and strongly damped during the return to the equilibrium after the laser is switched off. A model based on delayed charging is presented that can describe the observed behavior.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Half-ice, half-fire-driven ultranarrow phase crossover in one-dimensional decorated 𝑞-state Potts ferrimagnets: An AI-co-led exploration

OpenAI’s reasoning model o3-mini-high was used to carry out an exact analytic study of one-dimensional ferrimagnetic site- and bond-decorated 𝑞-state Potts models. We demonstrate that the finite-temperature ultranarrow phase crossover (UNPC), driven by a hidden “half-ice, half-fire” state recently discovered in the 𝑞=2 case (Ising model), persists for 𝑞>2. Moreover, we identify unique features for 𝑞>2, including the dome structure in the field-temperature phase diagram, and for large 𝑞 a secondary high-temperature UNPC to the fully disordered paramagnetic state. As the UNPC quickly approaches a genuine transition by enhancing 𝐽, the interaction between the backbone spins, two distinct behaviors emerge: In the site-decorated Potts model, 𝑇 0 is independent of 𝐽 and thus remains unchanged (Type-I UNPC), and in the bond-decorated Potts model with 𝑞>2, 𝑇 0 depends on 𝐽 and quickly shifts toward a finite temperature as 𝐽 increases (Type-II UNPC). These results establish a versatile framework for engineering controlled fast state-flipping switches in low-dimensional systems. Our nine-dan artificial intelligence (AI)-contribution framework assigns AI the meritorious status of AI-co-led discovery in this work.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Inductively Driven, 3D Liner Compression of a Magnetized Plasma to Megabar Energy Densities

To take advantage of the smaller scale, higher density regime of fusion an efficient method for achieving the compressional heating required to reach fusion gain conditions must be found. What is proposed is a more flexible metallic liner compression scheme that minimizes the kinetic energy required to reach fusion. It is believed that it is possible to accomplish this at sub-megajoule energies. This however will require operation at very small scale. To have a realistic hope of inexpensive, repetitive operation, it is essential to have the liner kinetic energy under a megajoule which allows for the survivability of the vacuum and power systems. At small scale the implosion speed must be reasonably fast to maintain the magnetized plasma (FRC) equilibrium during compression. For limited liner kinetic energy, it becomes clear that the thinnest liner imploded to the smallest radius consistent with the requirements for FRC equilibrium lifetime is desired. The proposed work is directed toward accomplishing this goal. Typically an axial (Z) current is employed for liner compression. There are however several advantages to using a θ-pinch coil. With the θ-pinch the liner currents are inductively driven which greatly simplifies the apparatus and vacuum system, and avoids difficulties with the post implosion vacuum integrity. With fractional flux leakage, the foil liner automatically provides for the seed axial compression field. To achieve it with optimal switching techniques, and at an accelerated pace however will require additional funding. This extra expense is well justified as the compression technique that will be enabled by this funding is unique in the ability to implode individual segments of the liner at different times. This is highly advantageous as the liner can be imploded in a manner that maximizes the energy transfer to the FRC. Production of shaped liner implosions for additional axial compression can thus be readily accomplished with the modified power modules. The additional energy and switching capability proposed will thus provide for optimal utilization of the liner energy. The following tasks were outlined for the three year effort: (1) Design and assemble the foil liner compression test structure and chamber including the compression bank and test foils [Year 1]. (2) Perform foil liner compression experiments and obtain performance data over a range on liner dimensions and bank parameters [Year 2]. (3) Carry out compression experiments of the FRC plasma to Megagauss fields and measure key fusion parameters [Year 3]. (4) Develop numerical codes and analyze experimental results, and determine the physics and scaling for future work [Year 1-3]. The principle task of the project was to design and assemble the foil liner FRC formation chamber, the full compression test structure and chamber including the compression bank. This task was completed successfully. The second task was to test foils in the test facility constructed in year one and characterize the performance obtained from liner compression. These experimental measurements were then compared with analytical predictions, and numerical code results. The liner testing was completed and compared with both the analytical results as well as the code work performed with the 3D structural dynamics package of ANSYS Metaphysics®. This code is capable of modeling the dynamic behavior of materials well into the non-linear regime (e.g. a bullet hit plate glass). The liner dynamic behavior was found to be remarkably close to that predicted by the 3D structural dynamics results. Incorporating a code that can also include the magnetics and plasma physics has also made significant progress at the UW. The remaining test bed construction and assembly task is was completed, and the FRC formation and merging experiments were carried out as planned. The liner compression of the FRC to Megagauss fields was not performed due to not obtaining a sufficiently long lived FRC during the final year of the grant. Modifications planned to correct this deficiency included a larger FRC source as well as a much larger liner driver energy storage system. Due to discontinuation of the grant neither of these improvements were carried out.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

The Fano-type transmission and field enhancement in heterostructures composed of epsilon-near-zero materials and truncated photonic crystals

The Fano-type interference effect is studied in the heterostructure composed of an epsilon-near-zero (ENZ) material and a truncated photonic crystal for transverse magnetic polarized light. In the Fano-type interference effect, the ENZ material provides narrow reflection pathway and the photonic crystal provides broadband reflection pathway. The boundary condition across the ENZ interface and the confinement effect provided by the photonic crystal can enhance the electric fields in the ENZ material greatly. The field enhancements, together with the asymmetric property of Fano-type spectrum, possess potential applications for significantly lowering the threshold of nonlinear processes such as optical switching and bistability.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Bit patterned media optimization at 1 Tdot/in{sup 2} by post-annealing

We report on the fabrication of 1 Tdot/in{sup 2} bit patterned media with high coercivity (H{sub C}) and narrow intrinsic switching field distribution (iSFD) based on nanoimprint from a master pattern formed by e-beam guided block copolymer assembly onto a carbon hard mask and subsequent pattern transfer via etching into a thin CoCrPt perpendicular anisotropy recording layer. We demonstrate that an additional vacuum annealing step after pattern transfer into the CoCrPt layer and after Carbon hard mask removal not only yields recovery from undesired damage of the island edges, but actually transforms the islands into a magnetically more favorable compositional phase with higher H{sub C}, lower iSFD/H{sub C}, and three-fold increased thermal stability. Energy filtered transmission electron microscopy analysis reveals that the diffusion of Cr from the island cores to the periphery of the islands during post-annealing is responsible for the transformation of the magnetic bits into a more stable state.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Depinning transition of a domain wall in ferromagnetic films

Here, we report first principle numerical study of domain wall (DW) depinning in two-dimensional magnetic film, which is modeled by 2D random-field Ising system with the dipole-dipole interaction. We observe non-conventional activation-type motion of DW and reveal the fractal structure of DW near the depinning transition. We determine scaling functions describing critical dynamics near the transition and obtain universal exponents establishing connection between thermal softening of pinning potential and critical dynamics. In addition, we observe that tuning the strength of the dipole-dipole interaction switches DW dynamics between two different universality classes, corresponding to two distinct dynamic regimes characterized by non-Arrhenius and conventional Arrhenius-type DW motions.

36 MATERIALS SCIENCE↗

Novel hard, tough HfAlSiN multilayers, defined by alternating Si bond structure, deposited using modulated high-flux, low-energy ion irradiation of the growing film

Hf{sub 1−x−y}Al{sub x}Si{sub y}N (0 ≤ x ≤ 0.14, 0 ≤ y ≤ 0.12) single layer and multilayer films are grown on Si(001) at 250 °C using ultrahigh vacuum magnetically unbalanced reactive magnetron sputtering from a single Hf{sub 0.6}Al{sub 0.2}Si{sub 0.2} target in mixed 5%-N{sub 2}/Ar atmospheres at a total pressure of 20 mTorr (2.67 Pa). The composition and nanostructure of Hf{sub 1−x−y}Al{sub x}Si{sub y}N films are controlled by varying the energy E{sub i} of the ions incident at the film growth surface while maintaining the ion-to-metal flux ratio constant at eight. Switching E{sub i} between 10 and 40 eV allows the growth of Hf{sub 0.78}Al{sub 0.10}Si{sub 0.12}N/Hf{sub 0.78}Al{sub 0.14}Si{sub 0.08}N multilayers with similar layer compositions, but in which the Si bonding state changes from predominantly Si–Si/Si–Hf for films grown with E{sub i} = 10 eV, to primarily Si–N with E{sub i} = 40 eV. Multilayer hardness values, which vary inversely with bilayer period Λ, range from 20 GPa with Λ = 20 nm to 27 GPa with Λ = 2 nm, while fracture toughness increases directly with Λ. Multilayers with Λ = 10 nm combine relatively high hardness, H ∼ 24 GPa, with good fracture toughness.

36 MATERIALS SCIENCE↗

Numerical electromagnetic frequency domain analysis with discrete exterior calculus

In this paper, we perform a numerical analysis in frequency domain for various electromagnetic problems based on discrete exterior calculus (DEC) with an arbitrary 2-D triangular or 3-D tetrahedral mesh. We formulate the governing equations in terms of DEC for 3-D and 2-D inhomogeneous structures, and also show that the charge continuity relation is naturally satisfied. Then we introduce a general construction for signed dual volume to incorporate material information and take into account the case when circumcenters fall outside triangles or tetrahedrons, which may lead to negative dual volume without Delaunay triangulation. Then we examine the boundary terms induced by the dual mesh and provide a systematical treatment of various boundary conditions, including perfect magnetic conductor (PMC), perfect electric conductor (PEC), Dirichlet, periodic, and absorbing boundary conditions (ABC) within this method. An excellent agreement is achieved through the numerical calculation of several problems, including homogeneous waveguides, microstructured fibers, photonic crystals, scattering by a 2-D PEC, and resonant cavities. - Highlights: • The formulation of 2D and 3D electromagnetic equations with DEC are presented. • Characteristic Hodge stars are constructed without well-centered triangulation or Delaunay triangulation. • Systematical treatment of various boundary conditions, including PMC, PEC, periodic, and absorbing boundary conditions. • Switching between E to H field can change PEC from essential boundary condition to natural boundary condition. • Quality factor of an open dielectric sphere is considered.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗