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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,009 records · Page 56
All sourcesNASA NTRSDOE OSTI
DOE OSTI2018

Effect of Annealing Temperature on Structural, Morphological, Optical and Magnetic Properties of NiFe{sub 2}O{sub 4} Thin Films

Nickel ferrite (NiFe{sub 2}O{sub 4}) thin films have been deposited on glass substrates by a chemical spray pyrolysis technique at 350 {sup ∘}C substrate temperature. The deposited films were annealed at four different temperatures (400, 450, 500 and 550 {sup ∘}C), and the effect of annealing temperature on the structural, morphological, optical and magnetic properties were studied. The annealed films were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), field emission scanning electron microscopy (FE-SEM), UV-visible spectroscopic analysis and vibrating sample magnetometer (VSM). XRD patterns showed that the NiFe{sub 2}O{sub 4} is oriented along (311) plane, which enhances peak intensity with respect to the annealing temperature. The analysis of XRD pattern revealed the formation of single-phase cubic spinel structure. The FT-IR spectrum of NiFe{sub 2}O{sub 4} thin films showed strong absorption peaks around 616 and 353 cm{sup − 1} which indicates the cubic spinel crystal structure of the films. FE-SEM micrographs show that the grain size increases with an increase in annealing temperature. The grain size varies between ∼ 19 and ∼ 28 nm, confirming the nanocrystalline nature of the prepared thin films. The optical properties of the films were studied by an absorbance spectrum in the range of 300 to 800 nm. The results showed that the energy band gap decreased with the increase of annealing temperature. Magnetic properties of NiFe{sub 2}O{sub 4} thin films exhibit a strong dependence on the annealing temperature. The saturation magnetization increases from ∼ 68.29 to ∼ 205.24 emu/cm{sup 3} with increasing annealing temperature, which is in favour of modern electronic device miniaturization.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1979

Elevated-temperature effects on strain gages on the YF-12A wing

A general study is made of the effects of structural heating on calibrated-strain-gage load measurements on the wing of a supersonic airplane. The primary emphasis is on temperature-induced effects as they relate to slope changes and thermal shifts of the applied load/strain relationships. These effects are studied by using the YF-12A airplane, a structural computer model, and subsequent analyses. Such topics as the thermal environment of the structure, the variation of load paths at elevated temperature, the thermal response characteristics of load equations, elevated-temperature load-measurement approaches, the thermal calibration of wings, and the correlation of strains are discussed. Ways are suggested to measure loads with calibrated strain gages in the supersonic environment.

Jenkins, J. M.↗
DOE OSTI2018

Effect of RF Power on Structural, Magnetic, and Optical Properties of CoFe{sub 2}O{sub 4} Thin Films

The thin films of CoFe{sub 2}O{sub 4} were deposited on glass substrates by radio-frequency (RF) sputtering. The effect of RF power variation from 60–120 W on the structure, magnetic, and optical properties of the as-deposited films and films annealed at 500 °C was studied. The magnetic parameters of the film, i.e., in-plane coercivity (H{sub c}), saturation magnetization (M{sub s}), and remanence (M{sub r}) increase as RF power is increased from 60 to 80 W followed by a decreasing trend with further increase in RF power to 120 W. Annealing of the film significantly improves the magnetic properties. The largest grain size and the best crystallinity of the film are obtained for the film deposited at 80 W of RF power. The thin films exhibited 70–80% optical transmittance. Optical band gap (E{sub g}) depends on the RF power and grain size, and it varies between 2.08 and 2.16 eV for the as-deposited films and between 2.16 and 2.30 eV for the annealed films. The study shows that RF power used for depositing the film has strong effect on the microstructure and properties of the film.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1997

Probabilistic Evaluation of Bolted Joints in Polymer Matrix Composites

Computational methods are described to probabilistically simulate fracture in bolted composite structures. Progressive fracture is simulated via an innovative approach independent of stress intensity factors and fracture toughness. The effect on structure damage of design variable uncertainties is quantified. The Fast Probability Integrator is used to assess the scatter in the composite structure response before and after damage. Sensitivity of the response to design variables is evaluated. The methods are demonstrated for bolted joint polymer matrix composite panels under end loads. The effects of fabrication process are included in the simulation of damage in the bolted panel. The results show that the most effective way to reduce the end displacement at fracture is to control the load and ply thickness.

Chamis, C. C.↗
DOE OSTI2019

Effect of Synthesis Temperature on Structural, Optical, and Magnetic Properties of ZnO Nanoparticles Synthesized by Combustion Method

ZnO nanoparticles at different temperatures were synthesized by using the combustion method. The effect of synthesis temperature on the properties of the nanoparticles was studied by using XRD, FESEM, EDS, TEM, photoluminescence (PL), Raman, diffuse reflectance spectra (DRS), and VSM characterization techniques. The XRD results reveal that the grown nanoparticles have a hexagonal wurtzite structure without any impurities and agreed with EDS results. FESEM and TEM micrographs show that the ZnO nanoparticles possess a spherical shape with agglomeration free, and the size increases with increase of synthesis temperature. From DRS studies, it was noticed that the band gap decreases with increase of synthesis temperature. In PL studies, blue peak at 465 nm may be due to defect-related transitions. A sharp intense peak in Raman spectra at 485 cm{sup −1} represents E{sub 2}H mode is a characteristic of a hexagonal wurtzite structure. The magnetic studies show that the magnetization decreases from 0.0172 to 0.0042 emu/g as the synthesis temperature increases from 400 to 550 °C. ZnO synthesized at 500 °C has a large squareness ratio. These materials are potential candidates for memory devices.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2018

Effect of Zn coprecipitation on the structure of layered Mn oxides

Mn oxides (MnOx) are a group of ubiquitous metal oxides in the environment and can significantly affect the biogeochemical cycles of metals, nutrients, and contaminants. Due to their negative surface charge across a wide range of environmental conditions, metal cations have strong affinities for MnOx, and the presence of metal cations during or after the formation of MnO x might significantly affect their structure and reactivity. This study systematically investigates the effects of Zn 2+ presence during mineral formation (i.e. coprecipitation) on the structure of acid birnessite and delta-MnO 2 , two synthetic analogs that are structurally similar to fresh biogenic MnO x but with different crystallinity. For both acid birnessite and delta-MnO 2 , Zn 2+ existed as surface adsorbed species at vacancy sites, interrupted layer stacking along c axis, and caused reductions of the lateral particle size. Zn 2+ also reduced Mn(III) contents in delta-MnO 2 layers, leaving more vacancy sites (capped by adsorbed Zn 2+ ). The reduction of layer stacking was more obvious for acid birnessite, while the modification of layer structure was more significant for delta-MnO 2 . These structural changes will likely lead to modified reactivity of MnO x in natural systems.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Structural and thermal properties of Eu 2 Ga 11 Sn 35

Clathrates have been reported to form in a variety of different structure types; however, inorganic clathrate-I materials with a low-cation concentration have yet to be investigated. Furthermore, tin-based compositions have been much less investigated as compared to silicon or germanium analogs. We report the temperature-dependent structural and thermal properties of single-crystal Eu 2 Ga 11 Sn 35 revealing the effect of structure and composition on the thermal properties of this low-cation clathrate-I material. Specifically, low-temperature heat capacity, thermal conductivity, and synchrotron single-crystal x-ray diffraction reveal a departure from Debye-like behavior, a glass-like phonon mean-free path for this crystalline material, and a relatively large Grüneisen parameter due to the dominance of low-frequency Einstein modes. In conclusion, our analyses indicate thermal properties that are a direct result of the structure and composition of this clathrate-I material.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Delineating the Effects of Counterions on the Structural and Vibrational Properties of U(IV) Lindqvist Polyoxometalate Complexes

Herein we conducted a full investigation into the fundamental structural and vibrational properties of uranium(IV) Peacock−Weakley-type lacunary Lindqvist (W 10 ) polyoxometalate (POM) complexes. We recently demonstrated the importance of the secondary lattice elements in tuning the distortion of the D 4d symmetry in W 10 POM complexes, and here, we synthesized eight UW 10 complexes with different alkali metal counterions and evaluated how the composition and packing of counterion species affected complex structural and vibrational properties. Single-crystal X-ray diffraction analysis on complexes 1−8 revealed changes in structural distortion parameters as a function of differences in counterion configurations, while far-infrared and Raman spectra for 1−8 also demonstrated that vibrational mode frequencies were sensitive to changes in counterion composition and packing. To more effectively compare different counterion configurations, we developed counterion effective ionic radius (eIR) as a new structural parameter, and comparisons between structural distortion parameters and eIR values strongly suggested that modulation by the secondary lattice elements can affect structural and vibrational manifolds within POM complexes. Partial least squares (PLS) analysis was used to quantitatively evaluate correlations observed within this investigation, and PLS statistical models showed a strong correlation between counterion eIR and both structural distortion parameters and vibrational mode frequencies.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2019

Nucleon and nuclear structure functions with nonperturbative and higher order perturbative QCD effects

We have studied the nucleon structure functions F EM iN (x,Q 2 ), i = 1, 2, by including contributions due to the higher order perturbative QCD effect up to next-to-next-to-leading order (NNLO) and the nonperturbative effects due to the kinematical and dynamical higher twist (HT) effects. The numerical results for F EM iN (x,Q 2 ) are obtained using Martin, Motylinski, Harland-Lang, Thorne 2014 NLO and NNLO nucleon parton distribution functions (PDFs). The dynamical HT correction has been included following the renormalon approach as well as the phenomenological approach, and the kinematical HT effect is incorporated using the works of Schienbein et al. These nucleon structure functions have been used as an input to calculate the nuclear structure functions F EM iN (x,Q 2 ). In a nucleus, the nuclear corrections arise because of the Fermi motion, binding energy, nucleon correlations, mesonic contribution, and shadowing and antishadowing effects. These nuclear corrections are taken into account in the numerical calculations to obtain the nuclear structure functions F EM iN (x,Q 2 ), for the various nuclear targets such as 12 C, 27 Al, 56 Fe, 64 Cu, 118 Sn, 197 Au, and 208 Pb which are of experimental interest. The effect of isoscalarity correction for nonisoscalar nuclear targets has also been studied. The results for the F EM iN (x,Q 2 ) are compared with nCTEQ nuclear PDFs parametrization as well as with the experimental results from JLab, SLAC, and NMC in the kinematic region of 0.1 ≤ x ≤ 0.8 for several nuclei. We have also calculated the ratio R A (x,Q 2 ) = F 2A (x,Q 2 )/2x F 1A (x,Q 2 ) in the moderate Q 2 region for various nuclei and compared the results with the available experimental data from JLab to examine the validity of the Callan-Gross relation in the nuclei. We also make predictions for the nuclear structure functions in 12 C, 64 Cu, and 197 Au in the kinematic region of the proposed experiment at JLab.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
NASA NTRS1984

Structures and Properties of Polymers Important to Their Wear Behavior

The wear and transfer of various semicrystalline polymers sliding against smooth steel or glass surfaces were examined. The effects of structures, and properties of polymers on their wear behavior are discussed. It is found that the high wear characteristics of PTFE is due to the easy destruction of the banded structure of PTFE. The size of spherulites and the molecular profile are closely related to the magnitude of wear rates of typical semicrystalline polymers. The effects of these factors on the wear rate on the basis of the destruction or melting of spherulites at the frictional surface are discussed. Although the fatigue theory of wear indicates that some mechanical properties are important to wear behavior, it is shown that the theory does not always explain the experimental result obtained on a smooth surface.

Tanaka, K.↗
NASA NTRS1986

Ceramic-ceramic shell tile thermal protection system and method thereof

A ceramic reusable, externally applied composite thermal protection system (TPS) is proposed. The system functions by utilizing a ceramic/ceramic upper shell structure which effectively separates its primary functions as a thermal insulator and as a load carrier to transmit loads to the cold structure. The composite tile system also prevents impact damage to the atmospheric entry vehicle thermal protection system. The composite tile comprises a structurally strong upper ceramic/ceramic shell manufactured from ceramic fibers and ceramic matrix meeting the thermal and structural requirements of a tile used on a re-entry aerospace vehicle. In addition, a lightweight high temperature ceramic lower temperature base tile is used. The upper shell and lower tile are attached by means effective to withstand the extreme temperatures (3000 to 3200F) and stress conditions. The composite tile may include one or more layers of variable density rigid or flexible thermal insulation. The assembly of the overall tile is facilitated by two or more locking mechanisms on opposing sides of the overall tile assembly. The assembly may occur subsequent to the installation of the lower shell tile on the spacecraft structural skin.

Riccitiello, Salvatore R.↗
DOE OSTI2018

Influence of rotational symmetry breaking on topological insulators

This article describes influence of symmetry breaking in topological insulators. In this study, we examined the effect of spatial symmetry breaking on the time-reversal invariant topological insulators with a rhombohedral crystal structure. This effect was verified by means of the Green function method. Breakdown of spatial symmetry brings the change of the topological number of the bulk. Accordingly, surface changes singular to nonsingular interface. In this process, fully gapped states are realized by violating the time-reversal symmetry, which leads to mass gap. Our results indicated that the surface acted as the interface of a topological phase transition.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2021

Unveiling the mechanism of phase and morphology selections during the devitrification of Al-Sm amorphous ribbon

The complex interplay between energetic and kinetic factors that governs the phase and morphology selections can originate at the earliest stage of crystallization in the amorphous parent phases. Because of the extreme difficulties in capturing the microscopic nucleation process, a detailed picture of how initial disordered structures affect the transformation pathway remains unclear. Here, we report the experimental observation of widely varying phase selection and grain size evolution during the devitrification of a homogeneous melt-spun glassy ribbon. Two different crystalline phases, θ-Al 5 Sm and ε-Al 60 Sm 11 , are found to form in the different regions of the same metallic glass ribbon during the devitrification. The grain size of ε-Al 60 Sm 11 phase shows a strong spatial heterogeneity. Coarse-grained ε-Al 60 Sm 11 phase coupled with the small volume fraction of θ-Al 5 Sm phase is preferably formed close to wheel side of the melt-spun ribbon. Combining experimental characterization and computational simulations, we show that phase selection and microstructure evolution can be traced back to different types and populations of atomic clusters that serve as precursors for the nucleation of different crystalline phases. Inhomogeneous cooling rates cause different structure orders across the glass sample during the quenching process. Our findings provide direct insight into the effect of structural order on the crystallization pathways during the devitrification of metallic glass. It also opens an avenue to study the detailed nucleation process at the atomic level using the metallic glass as a platform and suggests the opportunity of microstructure and property design via controlling the cooling process.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
NASA NTRS1992

Instantaneous response of elastic thin-walled structures with arbitrary open cross section to rapid heating

A generalized modeling and analysis approach of thermally-induced coupled vibrations of elastic thin-walled configurations with arbitrary open cross sections are presented in conjunction with a unified implicit transient methodology. Limited research appears in literature which takes into account the influence of rapid thermal heating effects on structures involving various forms of coupling. As a consequence, the dynamic response of such thin-walled structures of arbitrary open cross section due to rapid heating are described here. Effects involving triple, double, and no coupling between bending and torsional vibrations caused by sudden heating on these structures are examined. Numerical test cases are presented which describe the influence of sudden heating on elastic thin-walled structures of arbitrary open cross sections.

Chen, Xiaoqin↗
DOE OSTI2023

Fundamental aspects of Spacetime and Quantum Fields

The proposal contained two goals: firstly, placing fundamental bound on thermalization in Quantum Field Theories (QFTs) and, secondly, developing our understanding of emergent spacetime from matrices through concrete models. Since the previous reporting period, in collaboration with Sean Hartnoll we have continued our study of entanglement edge modes in matrix quantum mechanics (MQM). This has resulted in two papers. The first applies our construction for the Matrix Quantum Hall system first to fuzzy sphere states known to correspond to stringy M2-branes in MQM. Entanglement in these states using machine learning methods have also been studied by Sean Hartnoll and Xizhi Han in previous work done under this grant. Our construction builds on this work, and further demonstrates how area laws on fuzzy geometries emerge from strongly coupled systems. The second paper generalizes this construction to all noncommutative geometries with curvature much larger than the noncommutativity parameter. We demonstrate that despite UV/IR mixing effects, the structure of entanglement edge mode irreducible representations is determined by the boundary area of subsystems. On manifolds without global symmetries, we have demonstrated that nonlocal effects inherent to noncommutative geometries resum into a change of frame of the metric structure, similar to the change from string frame to Einstein frame for entanglement entropies calculated in string theory. These advancements lay the groundwork for future progress in the understanding of emergent geometry from large-N theories. Using these techniques, we are currently working on applying our methods to noncom mutative geometries whose construction is not so well understood, such as the fuzzy 5-sphere. Despite their opacity these objects are quite important, as string physics in the bulk of holographic systems bears many features of noncommutative geometry. We have also laid the groundwork of applying our methods to tensor networks, one of the most powerful models for understanding how geometry emerges from entanglement.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
NASA NTRS1991

The zeroes of controlled structures - Sensor/actuator attributes and structural modelling

The effects of sensor/actuator design and modeling decisions on the zero frequencies of single input single output structural systems are explored. A zero definition based on the high gain closed loop character of the poles of a system is used to study parametrically zeroes as a function of sensor and actuator location. An infinite order model is adopted so that the effects of finite order modeling are removed. Examples focus on point or localized actuators and sensors and simple uniform structures. The sensitivity of the zero frequencies to changes in the sensor and actuator location for both collocated and non-collocated cases are presented. Non-minimum phase behavior is visible in only certain non-collocated situations. In addition to the sensor/actuator attributes, the zeroes are shown to be a function of the truncation and discretization used to model the structural response for collocated and dual systems. Methods for improving the zero predictions in the control bandwidth are suggested.

Fleming, Farla M.↗
NASA NTRS1991

Vibration sensing in flexible structures using a distributed-effect modal domain optical fiber sensor

Modal domain optical fiber sensors have recently been employed in the implementation of system identification algorithms and the closed-loop control of vibrations in flexible structures. The mathematical model of the modal domain optical fiber sensor used in these applications, however, only accounted for the effects of strain in the direction of the fiber's longitudinal axis. In this paper, we extend this model to include the effects of arbitrary stress. Using this sensor model, we characterize the sensor's sensitivity and dynamic range.

Reichard, Karl M.↗