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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,009 records · Page 56

Evaluating methods to reduce duration of near-threshold fatigue crack growth rate measurements for low-alloy steels in hydrogen gas

Measurement of the near-threshold fatigue crack growth rate (da/dN) vs. stress-intensity factor range (∆K) relationship in hydrogen gas is essential for maximizing the calculated design fatigue life of high-pressure hydrogen storage vessels. However, such measurements are rarely performed, since the low cyclic loading frequencies applied in standard practice lead to prohibitively protracted test durations. The objective of this study was to demonstrate two means for reducing test durations when measuring near-threshold da/dN vs. ΔK relationships under decreasing ΔK for low-alloy pressure vessel steels in hydrogen gas: 1) imposing steeper K-gradients relative to the recommended limits in standards such as ASTM E647, and 2) increasing cyclic loading frequency relative to typical values applied during fatigue crack growth testing of low-alloy steels in hydrogen gas. Recognizing that steeper K-gradients could amplify loading-history effects, test methods employing this approach were designed to mitigate such effects by either maintaining constant K max or gradually increasing the K-gradient as the threshold was approached. Although the varying K-gradient method was vulnerable to loading-history effects in the form of plasticity-induced crack closure, particularly at lower stress ratio (R) and higher starting K max values, these effects could be compensated by applying the adjusted compliance ratio (ACR) method. Here, it was demonstrated that steeper K-gradients in concert with increased cyclic loading frequency reduced the duration of near-threshold fatigue crack growth tests in hydrogen gas by more than 99% relative to standard practices.

Fatigue threshold↗

Progress in development of characterization capabilities to evaluate candidate materials for direct air capture applications

As part of U.S. national efforts to combat the detrimental effect of global climate change, the National Institute of Standards and Technology (NIST) was recently tasked to support efforts in direct air capture (DAC) of carbon dioxide research and deployment. In order to develop test procedures, materials, and documentary standards, key characterization methods relevant to DAC materials have been investigated and used to identify desirable properties for a potential Standard Reference Material (SRM). Select amine-supported materials that previously showed potential for DAC applications have been characterized using commonly available laboratory methods. Further insights into the adsorption characteristics have been gained from developing and applying more specialized characterization tools ideal for probing low concentrations of carbon dioxide. A broad suite of capabilities that examine relevant properties under appropriate conditions gives the most profound insights into a material's specific performance. We advocate for even more specialized capabilities to be developed and standardized to quantitatively monitor the interactions of CO 2 with molecular species in complex and often disordered systems to advance DAC and support carbon dioxide reduction (CDR) in general.

carbon dioxide↗

Zero-CO Residential Natural Gas Furnace

Residential natural gas furnaces are widely used in the US homes. Manufacturers dedicate significant design and testing resources to meet requirements of design standards. One area of these standards is controlling flue gas carbon monoxide (CO) emissions. To more effectively reduce CO emissions at the flue, we developed a novel catalyst-assisted approach that integrated a low Pt/Rh loading acidic gas reduction (AGR) catalyst with three-way catalyst (TWC) or diesel oxidation catalyst (DOC) components. Compact catalysts were fabricated and assembled into tubular components, which can be seamlessly incorporated into the primary heat exchanger of a representative commercially available condensing furnace. The retrofitted furnace was demonstrated and tested following ANSI/ASHRAE Standard 103-2017. Experimental results showed that both AGR/TWC and AGR/DOC configurations achieved near-zero CO emissions under steady-state and cold-start conditions, compared with up to 500 ppm at a cold start and 17 ppm in a steady state in the OEM furnace. The catalyst-assisted furnaces also exhibited an annual fuel utilization efficiency improvement of more than 1.5% relative to the baseline unit, with a manageable pressure drop of 2.0−2.5 in. of water column. These results demonstrate that the catalyst-assisted approach can effectively eliminate CO emissions and improve energy efficiency. The technology has broad applicability for residential and commercial gas-fired heating systems.

Gao, Zhiming [ORNL] (ORCID:0000000271397995)↗

Metrology and Standards Gaps and FY27 Work Focusing on Impact

This work focuses on the Heliostat Consortium (HelioCon) optical measurements and characterization, testing and modeling capabilities and infrastructure at NLR and Sandia supporting heliostat technology research, development, validation, and deployment in relevant industries. The development of standards in HelioCon requires a collective effort across the global heliostat community of industry, researchers, academia and other stakeholders.

14 SOLAR ENERGY↗

Electrospun porous La–Sr–Co–Ni–O nanofibers for highly sensitive non-enzymatic glucose detection

Glucose biosensors are widely used for clinical, industrial, and environmental applications. Nonenzymatic electrochemical glucose biosensors based on metal oxides with a perovskite structure have exhibited high sensitivity, excellent stability, and cost efficiency. In this work, porous La–Sr–Co–Ni–O (LSCNO) nanofibers, with an ABO 3 -type perovskite structure, were prepared through optimizing the A-site and B-site elements by electrospinning, followed with calcination at 700 °C for 5 h. Characterized by scanning and transmission electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy, fabricated nanofibers were confirmed to be porous and nanosized polycrystalline grains with high crystallinity. A novel La 0.75 Sr 0.25 Co 0.5 Ni 0.5 O 3 -based nonenzymatic electrochemical biosensor was developed, which is sensitive to glucose because of an electrochemically catalytic mechanism, a mediated electron transfer involving Ni(II)/Ni(III) or Co(II)/Co(III), accompanying with gluconic acid complexation. The glucose biosensor presented a linear response in the range of 0.1–1.0 mM with a calibration sensitivity of 924 ± 28 μA mM –1 , a proportion of the variance of 0.9926, and a lower limit of detection of 0.083 mM, respectively, demonstrating an outstanding analytical performance. The biosensor showed no response to the most widely used anionic surfactant, sodium dodecyl sulfate, and low sensitivity to other biomolecules, such as fructose, lactose, galactose, mannose, dopamine, and ascorbic acid. A urine sample was tested by this novel nonenzymatic electrochemical biosensor by standard addition method, suggesting a potential application for clinical test.

36 MATERIALS SCIENCE↗

Development and implementation of an in-situ cable condition monitoring method for nuclear power plants - 130

The sustainability of the existing fleet of nuclear power reactors depends on utilities' ability to manage the aging of key components that cannot easily or economically be replaced or upgraded. Cables, metals, and concrete structures are among the major and key components that the industry and government are working on to ensure the long term reliability and safety of nuclear plants. To ensure that these key components continue to meet their performance requirements, new testing and condition monitoring technologies must be developed that are capable of identifying and quantifying degradation in these materials. The work presented in this paper focuses on the development and implementation of an in-situ condition monitoring method for nuclear power plant cables. This cable condition monitoring method is based on the frequency domain reflectometry (FDR) technique, which is a non-destructive in-situ electrical test that uses the principle of transmission line theory to locate and quantify impedance changes in a cable circuit. Through extensive research, development, and validation, the FDR test technique has been adapted as a cable condition monitoring method that trends with increasing cable degradation. In addition, the FDR data has been correlated to the industry standard elongation at break (EAB) test to quantify the degree of localized degradation in nuclear plant cable insulation material caused by long term exposure to high temperatures and radiation. By correlating FDR to EAB, the aging condition of cables routed through harsh environments can be better understood in relation to its ability to perform its intended function. (authors)

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Power Hardware-in-the-Loop-Based Anti-Islanding Evaluation and Demonstration

The National Renewable Energy Laboratory (NREL) teamed with Southern California Edison (SCE), Clean Power Research (CPR), Quanta Technology (QT), and Electrical Distribution Design (EDD) to conduct a U.S. Department of Energy (DOE) and California Public Utility Commission (CPUC) California Solar Initiative (CSI)-funded research project investigating the impacts of integrating high-penetration levels of photovoltaics (PV) onto the California distribution grid. One topic researched in the context of high-penetration PV integration onto the distribution system is the ability of PV inverters to (1) detect islanding conditions (i.e., when the distribution system to which the PV inverter is connected becomes disconnected from the utility power connection) and (2) disconnect from the islanded system within the time specified in the performance specifications outlined in IEEE Standard 1547. This condition may cause damage to other connected equipment due to insufficient power quality (e.g., over-and under-voltages) and may also be a safety hazard to personnel that may be working on feeder sections to restore service. NREL teamed with the Florida State University (FSU) Center for Advanced Power Systems (CAPS) to investigate a new way of testing PV inverters for IEEE Standard 1547 unintentional islanding performance specifications using power hardware-in-loop (PHIL) laboratory testing techniques.

14 SOLAR ENERGY↗

Fuel Matrix Degradation Model Development Update: Alloy Corrosion Rates and Hydrogen Generation

This work is being performed as part of the DOE NE Spent Fuel and Waste Science and Technology Campaign, Argillite and Crystalline Rock R&D work packages: SF-19AN01030101 and SF-19AN01030201. This document meets the milestone M4SF-19AN010301013 for Argillite R&D and the milestone M4SF-19AN010302013 for Crystalline R&D. The fuel matrix degradation (FMD) model calculates the degradation rate of spent UO2 fuel based on fundamental electrochemical theory and thermodynamics. The model provides the quantitative basis for radionuclide source term predictions in the generic disposal system analysis (GDSA) performance assessment (PA) model. The FMD model has been implemented in a manner that facilitates its integration with the GDSA-PA code and a preliminary, integrated FMD-GDSA model has been successfully tested (Jerden et al., 2017). The specific focus of on-going work is to accurately and quantitatively represent the generation of H2 in a breached waste package and its effect on the spent fuel degradation rate so that this key process can be accurately represented in PA models. It has been shown experimentally that millimolar concentrations of dissolved H2 in contact with spent fuel will inhibit oxidative dissolution and decrease the fuel degradation rates by as much as three orders of magnitude (e.g., Röllin et al., 2001, Ollila, 2008). This will lead to a significant decrease in the radionuclide source term values used in repository PA models. Sensitivity studies using the FMD model have shown that the dissolved H2 concentration is the dominant environmental variable affecting the UO2 spent fuel dissolution rate as long as a source of H2 persists in the breached waste package (Jerden et al., 2015). Therefore, on-going experimental and modeling efforts focus on H2 production, accumulation and interfacial reactions within a breached waste package. The anoxic corrosion of metallic engineering materials within a breached waste package will be the main source of H2 in crystalline and argillite rock repository systems. The most important H2-producing alloys present within a waste package include stainless steel, carbon steel, and aluminum alloys and the Zircaloy fuel cladding. A steel corrosion module was added to the FMD model to account for these H2 sources and couple the H2 generation rate with fuel degradation processes (Jerden et al., 2017). As discussed below, there is a need for experimental data from electrochemical corrosion tests to quantify the H2 generation rates due to the corrosion of these waste package alloys as a function of key environmental variables (Eh, pH, groundwater chemistry). This report presents results from series of electrochemical corrosion tests with materials present in waste packages that provide information needed to parameterize and validate the FMD model. The alloys tested include 316L stainless steel (316SS), AISI 4320 carbon steel (C-steel) and Zircaloy-4 fuel cladding (unirradiated). Potentiodynamic polarization and potentiostatic polarization tests were performed in buffer solutions at pH 4, 7 and 10 with NaCl concentrations of 0, 4 and 100 millimolar (mM). The potentiostatic tests were performed at voltages varying from 0.5 volts down to -0.66 volts, vs the standard hydrogen electrode (SHE), and all tests were performed at laboratory ambient temperatures (~22 °C). The corrosion rates measured during the electrochemical tests were used as direct input to a new FMD/in-package chemistry model that is being developed to provide accurate long-term spent fuel degradation rates as chemical conditions (Eh, pH, speciation) evolve within a breached waste package. This new model was developed by coupling the FMD model with the reactive transport code X1t, which is a module within the Geochemist’s Workbench (GWB) reaction path modeling code (Jerden et al., 2019). The reactive transport model consists of a 1D domain discretized with 21 reaction diffusion cells and includes a single waste packag

Jerden, James↗

Software development infrastructure for the HYBRID modeling and simulation project

One of the goals of the HYBRID modeling and simulation project is to assess the economic viability of hybrid systems in a market that contains renewable energy sources like wind. The idea is that it is possible for the nuclear plant to sell non-electric energy cushions, which absorb (at least partially) the volatility introduced by the renewable energy sources. This system is currently modeled in the Modelica programming language. To assess the economics of the system, an optimization procedure is trying to find the minimal cost of electricity production. The RAVEN code is used as a driver for the whole problem. It is assumed that at this stage, the HYBRID modeling and simulation framework can be classified as non-safety “research and development” software. The associated quality level is Quality Level 3 software. This imposes low requirements on quality control, testing and documentation. The quality level could change as the application development continues.Despite the low quality requirement level, a workflow for the HYBRID developers has been defined that include a coding standard and some documentation and testing requirements. The repository performs automated unit testing of contributed models. The automated testing is achieved via an open-source python script called BuildingsP from Lawrence Berkeley National Lab. BuildingsPy runs Modelica simulation tests using Dymola in an automated manner and generates and runs unit tests from Modelica scripts written by developers. In order to assure effective communication between the different national laboratories a biweekly videoconference has been set-up, where developers can report their progress and issues. In addition, periodic face-face meetings are organized intended to discuss high-level strategy decisions with management. A second means of communication is the developer email list. This is a list to which everybody can send emails that will be received by the collective of the developers and managers involved in the project. Thirdly, to exchange documents quickly, a SharePoint directory has been set-up. SharePoint allows teams and organizations to intelligently share, and collaborate on content from anywhere.

97 MATHEMATICS AND COMPUTING↗

Performance of Windows in Walls With Continuous Insulation

Window openings in walls are a significant contributor to poor thermal performance because of thermal bridging through the framing members (e.g., studs, joists, plates, bracing) and because windows lack the thermal properties of insulation. Window installation guidance for walls with continuous insulation (CI) is critical for continued market growth of this energy efficiency technology. This research project offers window manufacturers a starting point and a potential path toward developing installation instructions for windows over CI. The objectives of the research include evaluating the common method for installing windows in walls with CI, as well as establishing acceptance criteria for evaluating the performance of windows installed in walls with and without CI. The research measures: 1. The performance characteristics (e.g., water management, structural integrity) of windows in walls without CI. 2. The performance of different thicknesses and types of CI used in walls. 3. The performance of different types of window assemblies (e.g., double-hung windows, mulled double-hung windows, mulled casement windows, and slider windows) installed over CI. 4. The performance of window flange types (e.g., rigid mounting and less robust flanges) installed over CI. 5. Installing windows over CI using baseline installation instructions versus window manufacturer installation instructions. The project’s sequential testing protocol consists of the following: • A water penetration resistance testing adapted from two ASTM standards: E331 (uniform static air pressure in four steps) and E547 (cyclic static air pressure) • A temperature cycling adapted from ASTM E2264 Method B (convective hot air) • A service condition wind loading test adapted from ASTM E330 • A six-month vertical displacement observation phase prior to the structural performance testing • A final water penetration resistance test after vertical displacement observation • A structural performance test adapted from ASTM E330. Key research findings include: • The criterion for passing a water penetration resistance test is that there is no water overflowing at the interior face of the studs. If there is any bubbling or slight pooling of water at the sill, then it must recede after the pressure is removed. Excessive leakage and/or water leaking to the interior face of the framing around the window constitutes a failure. • All single double-hung windows installed directly to lumber or over oriented strand board passed all test protocols. • For most wall specimens, the test results showed that the use of foam sheathing did not affect the performance of the window for water leakage. • All wall specimens underwent temperature cycling. The results indicated that temperature cycling had little to no effect on windows installed over foam sheathing. • For wall specimens that underwent six-month vertical displacement monitoring, the results showed that windows installed over foam sheathing do not sag over time. • The single-hung and double-hung windows installed using window manufacturer installation instructions passed the structural performance test, compared to failures observed in windows that were installed using generic installation instructions. The generic and manufacturer installation methods differed on the following construction details: type of fasteners, fastening patterns on the flanges, and window shimming details. • Additional testing is required to determine methods to improve structural pressure performance of slider windows. Potential solutions that would require additional testing may include fastener spacing, different types of fasteners, masonry window clips, construction adhesive, foam sealant, stronger window flange material, and/or straps.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Long Term Creep Behavior of a CoCrFeNiMn High Entropy Alloy

The potential of high entropy alloys (HEAs) to meet or exceed austenitic stainless-steel performance with the additional benefit of improved hot corrosion/oxidation resistance makes FCC HEAs attractive for use in energy applications. While shorter term creep tests have been reported in the literature on HEAs, not all methodologies utilize repeatable techniques. This manuscript reports on over 23,500 accumulated hours of tensile creep testing with adherence to ASTM standards on a melt solidified ingot of CoCrFeNiMn HEA converted to wrought plate using conventional thermo-mechanical processing techniques. The typical standard creep analyses are reported, i.e., Larson-Miller parameter, Monkman-Grant relationship, activation energy for creep, and creep stress exponents were calculated and compared to previously reported short-term creep tests. Additionally, characteristics of creep fracture and microstructural evolution are reported with cursory dislocation mechanisms investigated.

Rozman, Kyle A.↗

Improving energy performance metrics to maximize the benefits of disruptive technologies

Advances in appliance and equipment systems' technologies also cause changes in their technical characteristics that can affect energy consumption and associated greenhouse gas emissions. Energy performance evaluation methods that use testing and metrics can evolve to account for energy consumption contributed from new technological characteristics. However, there is no systematic effort to enable the advancement of test procedures and performance metrics to maximize the energy, climate, and financial benefits of disruptive technologies. Therefore, it is important for countries to regularly update their energy-efficiency policy programs, such as standards and labels, by improving test procedures and metrics to reflect the innovation in emerging technologies as well as to mitigate the risk of deploying obsolete technology. This paper shows how energy performance metrics have been improving in selected appliances and equipment and provides insights to design a systematic effort to improve metrics and test procedures at the speed of ongoing changes in technologies and markets.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Do atoms age?

Time evolution generically entangles a quantum state with environmental degrees of freedom. The resulting increase in entropy changes the properties of that quantum system leading to “aging”. It is interesting to ask if this familiar property also applies to simple, single particle quantum systems such as the decay of a radioactive particle. We propose a test of such aging in an ion clock setup where we probe for temporal changes to the energies of the electronic state of an ion containing a radioactive nucleus. Such effects are absent in standard quantum mechanics and this test is thus a potent null test for violations of quantum mechanics. As a proof of principle, we show that these effects exist in causal non-linear modifications of quantum mechanics.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

A scalable real-time framework for Thomson scattering analysis: Application to NSTX-U

A detailed description of a prototype setup for real-time (RT) Thomson scattering (TS) analysis is presented and implemented in the multi-point Thomson scattering (MPTS) diagnostic system at the National Spherical Torus Experiment Upgrade (NSTX-U). The data acquisition hardware was upgraded with RT capable electronics (RT-analog digital converters and a RT server) that allow for fast digitization of the laser pulse signal of eight radial MPTS channels. In addition, a new TS spectrum analysis software for a rapid calculation of electron temperature ( T e ) and electron density ( n e ) was developed. Testing of the RT hardware and data analysis software was successfully completed and benchmarked against the standard, post-shot evaluation. Timing tests were performed showing that the end-to-end processing time was reproducibly below 17 ms for the duration of at least 5 s, meeting a 60 Hz deadline by the laser pulse repetition rate over the length of a NSTX-U discharge. The presented RT framework is designed to be scalable in system size, i.e., incorporation of additional radial channels by solely adding additional RT capable hardware. In conclusion, it is scalable in its operation duration and was continuously running for up to 30 min, making it an attractive solution for machines with long discharges such as advanced, non-inductive tokamaks or stellarators.

47 OTHER INSTRUMENTATION↗

Impact Behavior of Polyester GFRP for Naval Applications: Influence of the Clamping Device and Fluid–Material Interaction

The low-velocity impact behavior of polyester glass fiber composite laminates has been investigated under different clamping conditions, by wetting the specimens surface with fluids having different densities. Unidirectional composite laminates, based on polymer resin and fibers of naval interest, with different thicknesses have been manufactured by resin transfer molding process in order to have a high control of the final properties and a high fiber volume fraction. Impact tests in air have been, first, performed up to penetration on all manufactured composites having four different thicknesses to get information on the material impact behavior. The effect of the clamping conditions and the interaction of the laminates with two fluids different in density, i.e., water and paraffin oil, have been investigated, then, only on the thickest laminates that showed a lower tendency to impact damage. In particular, the impact tests have been performed by impacting the front surface of the sample and by wetting the back surface of the composite samples under unclamped and clamped conditions, replicating the boundary constraints suggested by ASTM D7136 Standard for the conventional impact tests. Experimental results showed a lower initial rigidity, higher absorbed energy and deflection for specimens exposed to liquids with respect to those exposed to air, confirming the need of taking into account the fluid interaction in the case of marine composite applications.

36 MATERIALS SCIENCE↗

Securing Solar for the Grid (S2G) (Final Project Report) [Slides]

This is the final technical report for the SETO-funded project Securing Solar for the Grid (S2G) from FY22-24. The project scope included development and dissemination of standards' requirements, best practices, equipment testing procedures, assessment tools, as well as education and training materials for cyber defense, posture and maturity tailored to solar technologies. The outcomes for this work include: co-led the development of cybersecurity certification standard (UL2941), co-led the development of cybersecurity guide (IEEE1547.3), development of recommendations for supply chain cybersecurity, and development of cybersecurity risk profiles and recommendations for DERMS.

14 SOLAR ENERGY↗