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At least 1,009 records · Page 56

Manipulation of individual superconducting vortices and stick-slip motion in periodic pinning arrays

We numerically examine the manipulation of superconducting vortices interacting with a moving trap representing a magnetic force tip translating across a superconducting sample containing a periodic array of pinning sites. As a function of the tip velocity and coupling strength, we find five distinct dynamic phases, including a decoupled regime where the vortices are dragged a short distance within a pinning site, an intermediate coupling regime where vortices in neighboring pinning sites exchange places, an intermediate trapping regime where individual vortices are dragged longer distances and exchange modes of vortices occur in the surrounding pins, an intermittent multiple trapping regime where the trap switches between capturing one or two vortices, and a strong coupling regime in which the trap permanently captures and drags two vortices. In some regimes we observe the counterintuitive behavior that slow moving traps couple less strongly to vortices than faster moving traps; however, the fastest moving traps are generally decoupled. The different phases can be characterized by the distances the vortices are displaced and the force fluctuations exerted on the trap. We find different types of stick-slip motion depending on whether vortices are moving into and out of pinning sites, undergoing exchange, or performing correlated motion induced by vortices outside of the trap. Finally, our results are general to the manipulation of other types of particle-based systems interacting with periodic trap arrays, such as colloidal particles or certain types of frictional systems.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Wettability Effects on Primary Drainage Mechanisms and NAPL Distribution: A Pore-Scale Study

The pore-scale processes governing water drainage behavior in porous media have implications for geoscience multiphase scenarios including carbon capture and storage, contaminant site remediation, oil recovery, and vadose zone processes. However, few studies report directly observed pore-scale water drainage phenomena in 3-D soils. This knowledge gap limits our ability to verify assumptions underlying existing models and develop optimal solutions. As such, this paper utilizes synchrotron X-ray microtomography to present an experimental pore-scale examination of nonaqueous phase liquid (NAPL)/water distribution along a primary drainage front as dense NAPL was injected upward into water wetting (WW) and intermediate wetting (IW) sand-packed columns. Pore-network structures were extracted from imaged data sets and mapped onto segmented NAPL/water data sets which allowed quantitative examinations of wettability impacts on (a) the extent to which NAPL fills individual pore bodies and (b) relationships between pore size and the phase occupying the pore, with both considered as a function of distance (and capillary pressure) relative to the NAPL front. These results revealed that several hypotheses treating IW sand similarly to WW sands are simplistic. IW systems exhibited a sequence of pore filling that deviated from traditional capillary pressure-based model predictions: NAPL invades smaller pores, while larger, adjacent pores are bypassed leaving multipore residual water ganglia. NAPL pore saturations were close to 1 and did not change with capillary pressure in IW systems. Overall, the results illustrate how a relatively small change in operative contact angle alters NAPL distribution during water drainage, with important implications for geoscience multiphase flow scenarios.

58 GEOSCIENCES↗

Phase stability in the Hf-N and Zr-N systems

Hf and Zr nitrides are promising compounds for many technologically important areas, including high-temperature structural applications, quantum computing, and solar and optical applications. Here, this article reports on a comprehensive first-principles statistical mechanics study of phase stability in the Hf-N and Zr-N binary systems. A high solubility of nitrogen in the hcp forms of Hf and Zr is predicted. The rocksalt forms of HfN and ZrN can also tolerate a high degree of off-stoichiometry through the introduction of nitrogen and metal vacancies. The Hf-N binary favors a family of stacking faulted parent crystal structures at intermediate nitrogen concentrations that host a unique form of short-range order among nitrogen interstitials and vacancies. These phases can accommodate some degree of configurational entropy and remain ordered to temperatures as high as 1200 K.

Monte Carlo methods↗

Impact of fragment formation on shear viscosity in the nuclear liquid-gas phase transition region

Within the improved quantum molecular dynamics (ImQMD) model we follow the evolution of nuclear matter for planar Couette flow in a periodic box. We focus on the region of liquid-gas phase transition and extract the shear viscosity coefficient from the local stress tensor, directly following the viscosity definition. Here, by switching on and off the mean field and thus inducing the phase transition, we are able to observe the impact of clumping in the phase transition region on the viscosity.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Anti-phase boundaries at the SrTiO{sub 3}/Si(001) interface studied using aberration-corrected scanning transmission electron microscopy

In this work, the atomic structure of anti-phase boundary defects at the SrTiO{sub 3}/Si (001) interface is investigated by aberration-corrected scanning transmission electron microscopy. Atomic-resolution images reveal an abrupt SrTiO{sub 3}/Si interface with no intermediate oxide layer. Both single and double Si atomic columns (“dumbbells”) from different terraces of the Si(001) surface are visible at the interface. Anti-phase boundaries (APB) consisting of two adjacent TiO{sub 2} planes in the SrTiO{sub 3} (STO) film resulting either from Si surface steps or from the merging of crystalline domains from different surface nucleation sites are identified. These APBs occur on either {110} or {010} planes and both types have displacement vectors of a{sub STO}/2〈110〉.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Sensitivity analysis of simulated SOA loadings using a variance-based statistical approach: SENSITIVITY ANALYSIS OF SOA

We investigate the sensitivity of secondary organic aerosol (SOA) loadings simulated by a regional chemical transport model to 7 selected tunable model parameters: 4 involving emissions of anthropogenic and biogenic volatile organic compounds, anthropogenic semi-volatile and intermediate volatility organics (SIVOCs), and NOx, 2 involving dry deposition of SOA precursor gases, and one involving particle-phase transformation of SOA to low volatility. We adopt a quasi-Monte Carlo sampling approach to effectively sample the high-dimensional parameter space, and perform a 250 member ensemble of simulations using a regional model, accounting for some of the latest advances in SOA treatments based on our recent work. We then conduct a variance-based sensitivity analysis using the generalized linear model method to study the responses of simulated SOA loadings to the tunable parameters. Analysis of SOA variance from all 250 simulations shows that the volatility transformation parameter, which controls whether particle-phase transformation of SOA from semi-volatile SOA to non-volatile is on or off, is the dominant contributor to variance of simulated surface-level daytime SOA (65% domain average contribution). We also split the simulations into 2 subsets of 125 each, depending on whether the volatility transformation is turned on/off. For each subset, the SOA variances are dominated by the parameters involving biogenic VOC and anthropogenic SIVOC emissions. Furthermore, biogenic VOC emissions have a larger contribution to SOA variance when the SOA transformation to non-volatile is on, while anthropogenic SIVOC emissions have a larger contribution when the transformation is off. NOx contributes less than 4.3% to SOA variance, and this low contribution is mainly attributed to dominance of intermediate to high NOx conditions throughout the simulated domain. The two parameters related to dry deposition of SOA precursor gases also have very low contributions to SOA variance. This study highlights the large sensitivity of SOA loadings to the particle-phase transformation of SOA volatility, which is neglected in most previous models.

Shrivastava, Manish↗

Unsteady Extinction of Opposed Jet Ethylene/Methane HIFiRE Surrogate Fuel Mixtures vs Air

A unique idealized study of the subject fuel vs. air systems was conducted using an Oscillatory-input Opposed Jet Burner (OOJB) system and a newly refined analysis. Extensive dynamic-extinction measurements were obtained on unanchored (free-floating) laminar Counter Flow Diffusion Flames (CFDFs) at 1-atm, stabilized by steady input velocities (e.g., U(sub air)) and perturbed by superimposed in-phase sinusoidal velocity inputs at fuel and air nozzle exits. Ethylene (C2H4) and methane (CH4), and intermediate 64/36 and 15/85 molar percent mixtures were studied. The latter gaseous surrogates were chosen earlier to mimic ignition and respective steady Flame Strengths (FS = U(sub air)) of vaporized and cracked, and un-cracked, JP-7 "like" kerosene for a Hypersonic International Flight Research Experimentation (HIFiRE) scramjet. For steady idealized flameholding, the 100% C2H4 flame is respectively approx. 1.3 and approx.2.7 times stronger than a 64/36 mix and CH4; but is still 12.0 times weaker than a 100% H2-air flame. Limited Hot-Wire (HW) measurements of velocity oscillations at convergent-nozzle exits, and more extensive Probe Microphone (PM) measurements of acoustic pressures, were used to normalize Dynamic FSs, which decayed linearly with pk/pk U(sub air) (velocity magnitude, HW), and also pk/pk P (pressure magnitude, PM). Thus Dynamic Flame Weakening (DFW) is defined as % decrease in FS per Pascal of pk/pk P oscillation, namely, DFW = -100 d(U(sub air)/U(sub air),0Hz)/d(pkpk P). Key findings are: (1) Ethylene flames are uniquely strong and resilient to extinction by oscillating inflows below 150 Hz; (2) Methane flames are uniquely weak; (3) Ethylene / methane surrogate flames are disproportionately strong with respect to ethylene content; and (4) Flame weakening is consistent with limited published results on forced unsteady CFDFs. Thus from 0 to approx. 10 Hz and slightly higher, lagging diffusive responses of key species led to progressive phase lags (relative to inputs) in the oscillating flames, and caused maximum weakening. At 20 to 150 Hz, diffusion-rate-limited effects diminished, causing flames to "regain strengnth," and eventually become completely insensitive beyond 300 Hz. Detailed mechanistic understanding is needed. Overall, ethylene flames are remarkably resilient to dynamic extinction by oscillating inflows. They are the strongest, with the notable exception of H2. For HIFiRE tests, the 64%/36% surrogate disproportionally retains the high dynamic FS of ethylene, so the potential for loss of scramjet flameholding (flameout) due to low frequency oscillations is significantly mitigated.

Vaden, Sarah N.↗

Covariant phase space with boundaries

The covariant phase space method of Iyer, Lee, Wald, and Zoupas gives an elegant way to understand the Hamiltonian dynamics of Lagrangian field theories without breaking covariance. The original literature however does not systematically treat total derivatives and boundary terms, which has led to some confusion about how exactly to apply the formalism in the presence of boundaries. In particular the original construction of the canonical Hamiltonian relies on the assumed existence of a certain boundary quantity “B”, whose physical interpretation has not been clear. We here give an algorithmic procedure for applying the covariant phase space formalism to field theories with spatial boundaries, from which the term in the Hamiltonian involving B emerges naturally. Our procedure also produces an additional boundary term, which was not present in the original literature and which so far has only appeared implicitly in specific examples, and which is already nonvanishing even in general relativity with sufficiently permissive boundary conditions. The only requirement we impose is that at solutions of the equations of motion the action is stationary modulo future/past boundary terms under arbitrary variations obeying the spatial boundary conditions; from this the symplectic structure and the Hamiltonian for any diffeomorphism that preserves the theory are unambiguously constructed. We show in examples that the Hamiltonian so constructed agrees with previous results. We also show that the Poisson bracket on covariant phase space directly coincides with the Peierls bracket, without any need for non-covariant intermediate steps, and we discuss possible implications for the entropy of dynamical black hole horizons.

36 MATERIALS SCIENCE↗

Stabilization of Photocatalytically Active Uranyl Species in a Uranyl–Organic Framework for Heterogeneous Alkane Fluorination Driven by Visible Light

When photoactivated, the uranyl ion is a robust oxidant capable of abstracting hydrogen atoms from nonactivated C–H bonds. Yet, the highly reactive singly reduced [U V O 2 ] + intermediate is unstable with respect to disproportionation to the uranyl dication and insoluble tetravalent uranium phases, which limits the usage of uranyl ions as robust photocatalysts. Herein, we demonstrate that photoactivated uranyl ions can be stabilized by immobilizing and separating them spatially in a uranyl–organic framework heterogeneous catalyst, NU-1301. The visible-light-photoactivated uranyl ions in NU-1301 demonstrated longer-lived U(V) and radicals than those in homogeneous counterparts, as evidenced by X-ray photoelectron spectroscopy and time-dependent electron paramagnetic resonance, leading to higher turnovers and enhanced stability for the fluorination of nonactivated alkanes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Guiding Electrochemical Carbon Dioxide Reduction toward Carbonyls Using Copper Silver Thin Films with Interphase Miscibility

Steering the selectivity of Cu-based electrochemical CO2 reduction (CO2R) catalysts toward targeted products will serve to improve the technoeconomic outlook of technologies based on this process. Using physical vapor deposition as a tool to overcome thermodynamic miscibility limitations, CuAg thin films with nonequilibrium Cu/Ag alloying were prepared for CO2R performance evaluation. In comparison to pure Cu, the CuAg thin films showed significantly higher activity and selectivity toward liquid carbonyl products, including acetaldehyde and acetate. Suppressed activity and selectivity toward hydrocarbons and the competing hydrogen evolution were also demonstrated on CuAg thin films, with a greater degree of suppression observed at increasing nominal Ag compositions. Compositional-dependent CO2R trends coupled with physical characterization and density functional theory suggest that significant miscibility of Ag into the Cu-rich phase of the catalyst underpinned the observed CO2R trends through tuning of adsorbate and reaction intermediate binding energies on the surface.

10 SYNTHETIC FUELS↗

Direct visualization of hydrogen absorption dynamics in individual palladium nanoparticles

Many energy storage materials undergo large volume changes during charging and discharging. The resulting stresses often lead to defect formation in the bulk, but less so in nanosized systems. Here, we capture in real time the mechanism of one such transformation—the hydrogenation of single-crystalline palladium nanocubes from 15 to 80 nm—to better understand the reason for this durability. First, using environmental scanning transmission electron microscopy, we monitor the hydrogen absorption process in real time with 3 nm resolution. Then, using dark-field imaging, we structurally examine the reaction intermediates with 1 nm resolution. The reaction proceeds through nucleation and growth of the new phase in corners of the nanocubes. As the hydrogenated phase propagates across the particles, portions of the lattice misorient by 1.5%, diminishing crystal quality. Once transformed, all the particles explored return to a pristine state. As a result, the nanoparticles’ ability to remove crystallographic imperfections renders them more durable than their bulk counterparts.

36 MATERIALS SCIENCE↗

Polytype selection in the antisolvent-free crystallization of formamidinium lead iodide using alkylammonium chlorides

This work presents a systematic study of how the size of the C 0 –C 4 alkylammonium chloride additive directs the crystallization pathway in antisolvent-free FAPbI 3 films. We find that larger cations promote the intermediate formation of hexagonal polytypes, correlating with enhanced film crystallinity. Understanding the nucleation, crystallization, and phase transition mechanisms in perovskite thin films produced without antisolvent quenching is crucial for improving phase stability and optoelectronic performance at scale. By means of in situ grazing incidence wide-angle X-ray scattering experiments, we show that the nature of alkylammonium chloride (RACl) additives significantly influences the crystallization dynamics and temperature-dependent stability of formamidinium lead iodide (FAPbI 3 ) perovskite films formed using antisolvent-free processes. The in situ experiments reveal that the effective radius of the RA + cation and the vapor pressure of the RA 0 conjugate base are critical factors affecting the crystallization pathway and film morphology. C 2 –C 3 additives with moderate chain lengths may strike a balance between promoting the early crystallization of the cubic 3C phase while suppressing unwanted phases. This balance promotes the formation of highly crystalline cubic perovskite phase with well-oriented structure and better optoelectronic properties. These findings provide guidance regarding the design of additives to crystallize more stable and efficient perovskite films for optoelectronic applications.

Marchezi, Paulo E↗

Gen3 Gas Phase System Development and Demonstration (Final Technical Report)

Work undertaken in this project seeks to transform the current baseline technology – which is a collection of related but separately developed components and concepts – into a unified and operating test facility and an accompanying preliminary commercial design. This project is motivated by the primary goal of developing a system to absorb concentrated solar energy and deliver it into thermal energy storage at temperatures above 700°C, thereby enabling integration with a high-efficiency supercritical carbon dioxide (sCO 2 ) power cycle to achieve or exceed a levelized cost of electricity (LCOE) target of 6 ¢ per kilowatt-hour electric (kW e -hr). The proposed baseline solution utilizes a high-temperature gas phase (GP) system interfacing with a two-tank particle thermal energy storage (TES) and intermediate heat exchangers to supply sCO 2 at 20-25 megapascals (MPa) and 700°C at the turbine inlet.

14 SOLAR ENERGY↗

TOI–1278 B: SPIRou Unveils a Rare Brown Dwarf Companion in Close-in Orbit around an M Dwarf

We present the discovery of an 18.5 ± 0.5 M {sub Jup} brown dwarf (BD) companion to the M0V star TOI–1278. The system was first identified through a percent-deep transit in Transiting Exoplanet Survey Satellite photometry; further analysis showed it to be a grazing transit of a Jupiter-sized object. Radial velocity (RV) follow-up with the SPIRou near-infrared high-resolution velocimeter and spectropolarimeter in the framework of the 300-night SPIRou Legacy Survey carried out at the Canada–France–Hawaii Telescope led to the detection of a Keplerian RV signal with a semi-amplitude of 2306 ± 10 m s{sup -1} in phase with the 14.5 day transit period, with a slight but nonzero eccentricity. The intermediate-mass ratio (M {sub ·}/M {sub comp} ~ 31) is unique for having such a short separation (0.095 ± 0.001 au) among known M-dwarf systems. Interestingly, M-dwarf–BD systems with similar mass ratios exist with separations of tens to thousands of astronomical unit.

47 OTHER INSTRUMENTATION↗

PULSATION-TRIGGERED MASS LOSS FROM AGB STARS: THE 60 DAY CRITICAL PERIOD

Low- and intermediate-mass stars eject much of their mass during the late, red giant branch (RGB) phase of evolution. The physics of their strong stellar winds is still poorly understood. In the standard model, stellar pulsations extend the atmosphere, allowing a wind to be driven through radiation pressure on condensing dust particles. Here, we investigate the onset of the wind, using nearby RGB stars drawn from the Hipparcos catalog. We find a sharp onset of dust production when the star first reaches a pulsation period of 60 days. This approximately coincides with the point where the star transitions to the first overtone pulsation mode. Models of the spectral energy distributions show stellar mass-loss rate suddenly increasing at this point, by a factor of ∼10 over the existing (chromospherically driven) wind. The dust emission is strongly correlated with both pulsation period and amplitude, indicating stellar pulsation is the main trigger for the strong mass loss, and determines the mass-loss rate. Dust emission does not strongly correlate with stellar luminosity, indicating radiation pressure on dust has little effect on the mass-loss rate. RGB stars do not normally appear to produce dust, whereas dust production by asymptotic giant branch stars appears commonplace, and is probably ubiquitous above the RGB-tip luminosity. We conclude that the strong wind begins with a step change in mass-loss rate and is triggered by stellar pulsations. A second rapid mass-loss-rate enhancement is suggested when the star transitions to the fundamental pulsation mode at a period of ∼300 days.

79 ASTRONOMY AND ASTROPHYSICS↗

A shock isolator for diode laser operation on a closed-cycle refrigerator

A device developed to isolate the diode laser from impact shocks delivered during the expansion phase of the Solvay cycle of a helium refrigerator is briefly described. The device uses intermediate cold stations in the stand-off, which permit the stand-off to be short and rigid while minimizing the thermal load at the diode mount.

Jennings, D. F.↗

Interface of the transport systems research vehicle monochrome display system to the digital autonomous terminal access communication data bus

An upgrade of the transport systems research vehicle (TSRV) experimental flight system retained the original monochrome display system. The original host computer was replaced with a Norden 11/70, a new digital autonomous terminal access communication (DATAC) data bus was installed for data transfer between display system and host, while a new data interface method was required. The new display data interface uses four split phase bipolar (SPBP) serial busses. The DATAC bus uses a shared interface ram (SIR) for intermediate storage of its data transfer. A display interface unit (DIU) was designed and configured to read from and write to the SIR to properly convert the data from parallel to SPBP serial and vice versa. It is found that separation of data for use by each SPBP bus and synchronization of data tranfer throughout the entire experimental flight system are major problems which require solution in DIU design. The techniques used to accomplish these new data interface requirements are described.

Easley, W. C.↗

The structure, energetics and evolution of the dominant frequency-dependent three-dimensional atmospheric modes

The three-dimensional structure of the dominant modes of wintertime variability are examined, and the mode structures are determined by an EOF analysis of the coupled vertical mean and shear streamfunction fields for a wide range of time-scale classes. The time mean energy conversions are determined from a two-layer quasigeostrophic model. Lag-cross correlations between the dominant low-frequency modes tend to be small and/or symmetric about zero, the high frequency modes are found to show highly asymmetric sinusoidal cross correlation functions similar to traveling waves, and some intermediate and short-time scale modes exhibit correlations indicating an association with the decaying phases of blocking in the Pacific. It is suggested that the mean flow barotropic (baroclinic) instabilities are an important source of variance for some of the lowest (highest) fluctuations considered.

Schubert, S. D.↗