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A New Discrete Wavelength BUV Algorithm for Consistent Volcanic SO2 Retrievals from Multiple Satellite Missions

This paper describes a new discrete wavelength algorithm developed for retrieving volcanic sulfur dioxide (SO2) vertical column density (VCD) from UV observing satellites. The Multi-Satellite SO2 algorithm (MS_SO2) simultaneously retrieves column densities of sulfur dioxide, ozone, and Lambertian effective reflectivity (LER) and its spectral dependence. It is used operationally to process measurements from the heritage Total Ozone Mapping Spectrometer (TOMS) onboard NASA's Nimbus-7 satellite (N7/TOMS: 1978-1993) and from the current Earth Polychromatic Imaging Camera (EPIC) onboard Deep Space Climate Observatory (DSCOVR: 2015-) from the Earth-Sun Lagrange (L1) orbit. Results from MS_SO2 algorithm for several volcanic cases were assessed using the more sensitive principal component analysis (PCA) algorithm. The PCA is an operational algorithm used by NASA to retrieve SO2 from hyperspectral UV spectrometers, such as the Ozone Monitoring Instrument (OMI) onboard NASA's Earth Observing System Aura satellite and Ozone Mapping and Profiling Suite (OMPS) onboard NASA-NOAA Suomi National Polar Partnership (SNPP) satellite. For this comparative study, the PCA algorithm was modified to use the discrete wavelengths of the Nimbus-7/TOMS instrument, described in Sect. S1 of the Supplement. Our results demonstrate good agreement between the two retrievals for the largest volcanic eruptions of the satellite era, such as the 1991 Pinatubo eruption. To estimate SO2 retrieval systematic uncertainties, we use radiative transfer simulations explicitly accounting for volcanic sulfate and ash aerosols. Our results suggest that the discrete-wavelength MS_SO2 algorithm, although less sensitive than hyperspectral PCA algorithm, can be adapted to retrieve volcanic SO2 VCDs from contemporary hyperspectral UV instruments, such as OMI and OMPS, to create consistent, multi-satellite, long-term volcanic SO2 climate data records.

Bradford L Fisher↗

Algorithms and sensitivity analyses for Stratospheric Aerosol and Gas Experiment II water vapor retrieval

The operational inversion algorithm used for the retrieval of the water-vapor vertical profiles from the Stratospheric Aerosol and Gas Experiment II (SAGE II) occultation data is presented. Unlike the algorithm used for the retrieval of aerosol, O3, and NO2, the water-vapor retrieval algorithm accounts for the nonlinear relationship between the concentration versus the broad-band absorption characteristics of water vapor. Problems related to the accuracy of the computational scheme, the accuracy of the removal of other interfering species, and the expected uncertainty of the retrieved profile are examined. Results are presented on the error analysis of the SAGE II water vapor retrieval, indicating that the SAGE II instrument produced good quality water vapor data.

Chu, W. P.↗

Ice surface temperature retrieval from AVHRR, ATSR, and passive microwave satellite data: Algorithm development and application

During the first half of our second project year we have accomplished the following: (1) acquired a new AVHRR data set for the Beaufort Sea area spanning an entire year; (2) acquired additional ATSR data for the Arctic and Antarctic now totaling over seven months; (3) refined our AVHRR Arctic and Antarctic ice surface temperature (IST) retrieval algorithm, including work specific to Greenland; (4) developed ATSR retrieval algorithms for the Arctic and Antarctic, including work specific to Greenland; (5) investigated the effects of clouds and the atmosphere on passive microwave 'surface' temperature retrieval algorithms; (6) generated surface temperatures for the Beaufort Sea data set, both from AVHRR and SSM/I; and (7) continued work on compositing GAC data for coverage of the entire Arctic and Antarctic. During the second half of the year we will continue along these same lines, and will undertake a detailed validation study of the AVHRR and ATSR retrievals using LEADEX and the Beaufort Sea year-long data. Cloud masking methods used for the AVHRR will be modified for use with the ATSR. Methods of blending in situ and satellite-derived surface temperature data sets will be investigated.

Key, Jeff↗

Optimal Aerosol Parameterization for Remote Sensing Retrievals

We have developed a new algorithm for the retrieval of aerosol and gases from SAGE It1 solar transmission measurements. This algorithm improves upon the NASA operational algorithm in several key aspects, including solving the problem non-linearly and incorporating a new methodology for separating the contribution of aerosols and gases. In order to extract aerosol information we have built a huge database of aerosol models for both stratospheric and tropospheric aerosols, and polar stratospheric cloud particles. This set of models allows us to calculate a vast range of possible extinction spectra for aerosols. and from these, derive a set of eigenvectors which then provide the basis set used in our inversion algorithm. Our aerosol algorithm and retrievals are described in several articles (listed in References Section) published under this grant. In particular they allow us to analyze the spectral properties of aerosols and PSCs and ultimately derive their microphysical properties. We have found some considerable differences between our spectra and the ones derived from the SAGE III operational algorithm. These are interesting as they provide an independent check on the validity of published aerosol data and, in particular, on their associated uncertainties. In order to understand these differences, we are assembling independent aerosol data from other sources with which to make comparisons. We have carried out extensive comparisons of our ozone retrievals with both SAGE III and independent lidar, ozonesonde, and satellite measurements (Polyakov et al., 2004). These show very good agreement throughout the stratosphere and help to quantify differences which can be attributed to natural variation in ozone versus that produced by algorithmic differences. In the mid - upper stratosphere, agreement with independent data was generally within 5 - 20%. but in the lower stratosphere the differences were considerably larger. We believe that a large proportion of this discrepancy in the lower stratosphere is attributable to natural variation, and is also seen in comparisons between lidar and ozonesonde measurements. NO2 profiles obtained with our algorithm were compared to those obtained through the SAGE III operational algorithm and exhibited differences of 20 - 40%. Our retrieved profiles agree with the HALOE NO2 measurements significantly better than those of the operational retrieval. In other work (described below), we are extending our aerosol retrievals into the infrared regime and plan to perform retrievals from combined uv-visible-infrared spectra. This work will allow us to use the spectra to derive the size and composition of aerosols, and we plan to employ our algorithms in the analysis of PSC spectra. We are presently also developing a limb-scattering algorithm to retrieve aerosol data from limb measurements of solar scattered radiation.

Newchurch, Michael J.↗

Algorithm for NO2 Vertical Column Retrieval from the Ozone Monitoring Instrument

We describe the operational algorithm for the retrieval of stratospheric, tropospheric, and total column densities of nitrogen dioxide NO2 from earthshine radiances measured by the Ozone Monitoring Instrument (OMI), aboard the EOS-Aura satellite. The algorithm uses the DOAS method for the retrieval of slant column NO densities. Air mass factors (AMFs) calculated from a stratospheric NO2 profile are used to make initial estimates of the vertical column density. Using data collected over a 24-h period, a smooth estimate of the global stratospheric field is constructed. Where the initial vertical column densities exceed the estimated stratospheric field, we infer the presence of tropospheric NO2, and recalculate the vertical column density (VCD) using an AMF calculated from an assumed tropospheric NO2 profile. The parameters that control the operational algorithm were selected with the aid of a set of data assembled from stratospheric and tropospheric chemical transport models. We apply the optimized algorithm to OMI data and present global maps of NO2 VCDs for the first time.

Bucsela, Eric J.↗

Merging of the Case 2 Regional Coast Colour and Maximum‑Peak Height Chlorophyll‑a Algorithms: Validation and Demonstration of Satellite‑derived Retrievals Across US Lakes

Water quality monitoring is relevant for protecting the designated, or beneficial uses, of water such as drinking, aquatic life, recreation, irrigation, and food supply that support the economy, human well-being, and aquatic ecosystem health. Managing finite water resources to support these designated uses requires information on water quality so that managers can make sustainable decisions. Chlorophyll-a (chl-a, µg L−1) concentration can serve as a proxy for phytoplankton biomass and may be used as an indicator of increased anthropogenic nutrient stress. Satellite remote sensing may present a complement to in situ measures for assessments of water quality through the retrieval of chl-a with in-water algorithms. Validation of chl-a algorithms across US lakes improves algorithm maturity relevant for monitoring applications. This study compares performance of the Case 2 Regional Coast Colour (C2RCC) chl-a retrieval algorithm, a revised version of the Maximum-Peak Height (MPH(P)) algorithm, and three scenarios merging these two approaches. Satellite data were retrieved from the MEdium Resolution Imaging Spectrometer (MERIS) and the Ocean and Land Colour Instrument (OLCI), while field observations were obtained from 181 lakes matched with U.S. Water Quality Portal chl-a data. The best performance based on mean absolute multiplicative error (MAEmult) was demonstrated by the merged algorithm referred to as C15−M10 (MAEmult = 1.8, biasmult = 0.97, n = 836). In the C15−M10 algorithm, the MPH(P) chl-a value was retained if it was > 10 µg L−1; if the MPH(P) value was ≤ 10 µg L−1, the C2RCC value was selected, as long as that value was < 15 µg L−1. Time-series and lake-wide gradients compared against independent assessments from Lake Champlain and long-term ecological research stations in Wisconsin were used as complementary examples supporting water quality reporting requirements. Trophic state assessments for Wisconsin lakes provided examples in support of inland water quality monitoring applications. This study presents and assesses merged adaptations of chl-a algorithms previously reported independently. Additionally, it contributes to the transition of chl-a algorithm maturity by quantifying error statistics for a number of locations and times.

Satellite↗

Reduced Dimensionality Analysis of TEMPO Ozone Profile Retrievals Using the Compact Phase Space (CPSR) Algorithm

TEMPO ozone (O 3 ) profile retrievals are expected to have fidelity in the troposphere due the sensitivities of the associated averaging kernels. However, those averaging kernels are severely rank deficiency meaning that a visual inspection of the vertical structure of the averaging kernel profile sensitivities is misleading due linear dependencies in the profile. The Compact Phase Space Retrieval (CPSR) algorithm use singular value decompositions of the averaging kernels and the ‘compressed’ retrieval solution error covariance to project the transformed averaging kernels into a space that removes the linear dependencies and accounts for the solution error uncertainties. In this oral presentation and poster, we apply the CPSR dimensional reduction analysis to TEMPO and TROPOMI O 3 profile retrievals for 13:45 UTC March 29, 2024 to study the phase space characteristics of the transformed averaging kernels as a function of latitude for North America. Our results show that TEMPO generally has more phase space vertical structure in the troposphere than TROPOMI. TEMPO has four to five dominant modes, and TROPOMI has five to six dominant modes. That means that dimensional reduction can reduce the TEMPO resource requirements by ~77% and the TROPOMI requirements by ~81%. Finally, we found that after removing linear dependences and after accounting for solution uncertainties TEMPO still has sensitivities throughout the troposphere.

TEMPO↗

The Time Series Technique for Aerosol Retrievals over Land from MODIS: Algorithm MAIAC

Atmospheric aerosols interact with sun light by scattering and absorbing radiation. By changing irradiance of the Earth surface, modifying cloud fractional cover and microphysical properties and a number of other mechanisms, they affect the energy balance, hydrological cycle, and planetary climate [IPCC, 2007]. In many world regions there is a growing impact of aerosols on air quality and human health. The Earth Observing System [NASA, 1999] initiated high quality global Earth observations and operational aerosol retrievals over land. With the wide swath (2300 km) of MODIS instrument, the MODIS Dark Target algorithm [Kaufman et al., 1997; Remer et al., 2005; Levy et al., 2007] currently complemented with the Deep Blue method [Hsu et al., 2004] provides daily global view of planetary atmospheric aerosol. The MISR algorithm [Martonchik et al., 1998; Diner et al., 2005] makes high quality aerosol retrievals in 300 km swaths covering the globe in 8 days. With MODIS aerosol program being very successful, there are still several unresolved issues in the retrieval algorithms. The current processing is pixel-based and relies on a single-orbit data. Such an approach produces a single measurement for every pixel characterized by two main unknowns, aerosol optical thickness (AOT) and surface reflectance (SR). This lack of information constitutes a fundamental problem of the remote sensing which cannot be resolved without a priori information. For example, MODIS Dark Target algorithm makes spectral assumptions about surface reflectance, whereas the Deep Blue method uses ancillary global database of surface reflectance composed from minimal monthly measurements with Rayleigh correction. Both algorithms use Lambertian surface model. The surface-related assumptions in the aerosol retrievals may affect subsequent atmospheric correction in unintended way. For example, the Dark Target algorithm uses an empirical relationship to predict SR in the Blue (B3) and Red (B1) bands from the 2.1 m channel (B7) for the purpose of aerosol retrieval. Obviously, the subsequent atmospheric correction will produce the same SR in the red and blue bands as predicted, i.e. an empirical function of 2.1. In other words, the spectral, spatial and temporal variability of surface reflectance in the Blue and Red bands appears borrowed from band B7. This may have certain implications for the vegetation and global carbon analysis because the chlorophyll-sensing bands B1, B3 are effectively substituted in terms of variability by band B7, which is sensitive to the plant liquid water. This chapter describes a new recently developed generic aerosol-surface retrieval algorithm for MODIS. The Multi-Angle Implementation of Atmospheric Correction (MAIAC) algorithm simultaneously retrieves AOT and surface bi-directional reflection factor (BRF) using the time series of MODIS measurements.

Lyapustin, Alexei↗

Retrieval of Aerosol Optical Properties Using MERIS Observations: Algorithm and Some First Results

The MEdium Resolution Imaging Spectrometer (MERIS) instrument on board ESA Envisat made measurements from 2002 to 2012. Although MERIS was limited in spectral coverage, accurate Aerosol Optical Thickness (AOT) from MERIS data are retrieved by using appropriate additional information. We introduce a new AOT retrieval algorithm for MERIS over land surfaces, referred to as eXtensible Bremen AErosol Retrieval (XBAER). XBAER is similar to the dark-target (DT) retrieval algorithm used for Moderate-resolution Imaging Spectroradiometer (MODIS), in that it uses a lookup table (LUT) to match to satellite-observed reflectance and derive the AOT. Instead of a global parameterization of surface spectral reflectance, XBAER uses a set of spectral coefficients to prescribe surface properties. In this manner, XBAER is not limited to dark surfaces (vegetation) and retrieves AOT over bright surface (desert, semiarid, and urban areas). Preliminary validation of the MERIS-derived AOT and the ground-based Aerosol Robotic Network (AERONET) measurements yield good agreement, the resulting regression equation is y (0.92 x +/- 0.07) + (0.05 +/- 0.01) and Pearson correlation coefficient of R 0.78. Global monthly means of AOT have been compared from XBAER, MODIS and other satellite-derived datasets.

satellite retrievals↗

Global Retrieval of Cloud Particle Size and Optical Thickness Using ISCCP Data

The primary thrust of this investigation is to develop an algorithm to retrieve cloud particle sizes using ISCCP data. The research under this grant has been successful in obtaining initial results of global distribution of ice-particle sizes. Further research about possible problems caused by nonsphericity of ice particle sizes is currently underway. An algorithm of retrieving ice-cloud particle sizes using ISCCP CX data has been developed. The first survey of ice-particle size in a near-global scale has been completed. Comparison with in situ measurements of ice crystal sizes during FIRE I shows good agreement. The initial results show that the global mean size of ice crystals (De) is about 60 micron. This result is consistent with the range of in situ measurements all over the world if definitions of effective particle size are unified (see next section). The survey also shows that there is no distinct difference of ice-particle sizes between continental and maritime ice-clouds. There are many different definitions of effective particle size used in ice-cloud research. Simple comparisons between values of in situ measurement and satellite remote sensing are misleading and may lead to incorrect conclusions. We reviewed different definitions of effective particle sizes used in the literature and compared their relative magnitudes.

Welch, Ronald M.↗

Ice surface temperature retrieval from AVHRR, ATSR, and passive microwave satellite data: Algorithm development and application

One essential parameter used in the estimation of radiative and turbulent heat fluxes from satellite data is surface temperature. Sea and land surface temperature (SST and LST) retrieval algorithms that utilize the thermal infrared portion of the spectrum have been developed, with the degree of success dependent primarily upon the variability of the surface and atmospheric characteristics. However, little effort has been directed to the retrieval of the sea ice surface temperature (IST) in the Arctic and Antarctic pack ice or the ice sheet surface temperature over Antarctica and Greenland. The reason is not one of methodology, but rather our limited knowledge of atmospheric temperature, humidity, and aerosol vertical, spatial and temporal distributions, the microphysical properties of polar clouds, and the spectral characteristics of snow, ice, and water surfaces. Over the open ocean the surface is warm, dark, and relatively homogeneous. This makes SST retrieval, including cloud clearing, a fairly straightforward task. Over the ice, however, the surface within a single satellite pixel is likely to be highly heterogeneous, a mixture of ice of various thicknesses, open water, and snow cover in the case of sea ice. Additionally, the Arctic is cloudy - very cloudy - with typical cloud cover amounts ranging from 60-90 percent. There are few observations of cloud cover amounts over Antarctica. The goal of this research is to increase our knowledge of surface temperature patterns and magnitudes in both polar regions, by examining existing data and improving our ability to use satellite data as a monitoring tool. Four instruments are of interest in this study: the AVHRR, ATSR, SMMR, and SSM/I. Our objectives are as follows. Refine the existing AVHRR retrieval algorithm defined in Key and Haefliger (1992; hereafter KH92) and applied elsewhere. Develop a method for IST retrieval from ATSR data similar to the one used for SST. Further investigate the possibility of estimating surface temperature from passive microwave data (in conjunction with AVHRR clear sky samples) through the use of 'effective emissivities' and physical relationships between skin temperature and subsurface temperature. Use the general method outlined in MK93 to calculate a 12-year record of clear sky equivalent surface temperatures, or possibly all-sky snow-ice interface physical temperatures, from SMMR and SSM/I, compare these temperatures to climatologies, ECMWF modeled surface temperatures, and surface temperatures predicted by a 2-D ice model. And intercompare several ice surface retrieval methods and validate them against ground measurements from the Swiss Camp on the Greenland ice sheet. Additionally, we intend to develop a surface temperature product based on AVHRR data and possibly blended with drifting buoy and meteorological station temperatures.

Key, Jeff↗

Aerosol Retrieval and Atmospheric Correction Algorithms for EPIC

EPIC is a multi-spectral imager onboard planned Deep Space Climate ObserVatoRy (DSCOVR) designed for observations of the full illuminated disk of the Earth with high temporal and coarse spatial resolution (10 km) from Lagrangian L1 point. During the course of the day, EPIC will view the same Earth surface area in the full range of solar and view zenith angles at equator with fixed scattering angle near the backscattering direction. This talk will describe a new aerosol retrieval/atmospheric correction algorithm developed for EPIC and tested with EPIC Simulator data. This algorithm uses the time series approach and consists of two stages: the first stage is designed to periodically re-initialize the surface spectral bidirectional reflectance (BRF) on stable low AOD days. Such days can be selected based on the same measured reflectance between the morning and afternoon reciprocal view geometries of EPIC. On the second stage, the algorithm will monitor the diurnal cycle of aerosol optical depth and fine mode fraction based on the known spectral surface BRF. Testing of the developed algorithm with simulated EPIC data over continental USA showed a good accuracy of AOD retrievals (10-20%) except over very bright surfaces.

Wang, Yujie↗

NASA Satellite Monitoring of Water Clarity in Mobile Bay for Nutrient Criteria Development

This project has demonstrated feasibility of deriving from MODIS daily measurements time series of water clarity parameters that provide coverage of a specific location or an area of interest for 30-50% of days. Time series derived for estuarine and coastal waters display much higher variability than time series of ecological parameters (such as vegetation indices) derived for land areas. (Temporal filtering often applied in terrestrial studies cannot be used effectively in ocean color processing). IOP-based algorithms for retrieval of diffuse light attenuation coefficient and TSS concentration perform well for the Mobile Bay environment: only a minor adjustment was needed in the TSS algorithm, despite generally recognized dependence of such algorithms on local conditions. The current IOP-based algorithm for retrieval of chlorophyll a concentration has not performed as well: a more reliable algorithm is needed that may be based on IOPs at additional wavelengths or on remote sensing reflectance from multiple spectral bands. CDOM algorithm also needs improvement to provide better separation between effects of gilvin (gelbstoff) and detritus. (Identification or development of such algorithm requires more data from in situ measurements of CDOM concentration in Gulf of Mexico coastal waters (ongoing collaboration with the EPA Gulf Ecology Division))

Blonski, Slawomir↗

Retrieval of Aerosol Optical Properties From GOCI-II Observations: Continuation of Long-Term Geostationary Aerosol Monitoring Over East Asia

Since the Geostationary Ocean Color Imager (GOCI) was successfully launched in 2010, the GOCI Yonsei aerosol retrieval (YAER) algorithm has been continuously updated to retrieve hourly aerosol optical properties. GOCI-II has 4 more channels including UV, finer spatial resolution (250 m), and daily full disk coverage as compared to GOCI, and was launched in February 2020, onboard the GEO-KOMPSAT-2B (GK-2B) satellite. In this study, we extended the YAER algorithm to GOCI-II data based on its improved performance in many aspects and present the first results of aerosol optical properties retrieved from GOCI-II data. Utilizing the overlapping period between the GOCI-II and GOCI in geostationary Earth orbit, we present GOCI-II aerosol retrievals for high aerosol-loading cases over East Asia and show that these have a consistent spatial distribution with those from GOCI. Furthermore, GOCI-II provides AOD at an even higher spatial resolution, revealing finer changes in aerosol concentrations. Validation results for one year data show that the GOCI-II AOD has a correlation coefficient of 0.83 and a ratio within the expected error (EE) of 59.4 % when compared with the aerosol robotic network (AERONET) data. We compared statistical metrics for the GOCI and GOCI-II AODs to assess the consistency between the two datasets. In addition, it was found that there is a strong correlation between the two datasets from the comparison of gridded GOCI and GOCI-II AOD products. It is expected that data from GOCI-II will continue long-term aerosol records with high accuracy that can be used to address air-quality issues over East Asia.

AOD↗

Validating MODIS Above-Cloud Aerosol Optical Depth Retrieved from Color Ratio Algorithm Using Direct Measurements Made by NASA's Airborne AATS and 4STAR Sensors

We present the validation analysis of above-cloud aerosol optical depth (ACAOD) retrieved from the color ratio method applied to MODIS cloudy-sky reflectance measurements using the limited direct measurements made by NASAs airborne Ames Airborne Tracking Sunphotometer (AATS) and Spectrometer for Sky-Scanning, Sun-Tracking Atmospheric Research (4STAR) sensors. A thorough search of the airborne database collection revealed a total of five significant events in which an airborne sun photometer, coincident with the MODIS overpass, observed partially absorbing aerosols emitted from agricultural biomass burning, dust, and wildfires over a low-level cloud deck during SAFARI-2000, ACE-ASIA 2001, and SEAC4RS 2013 campaigns, respectively. The co-located satellite-airborne match ups revealed a good agreement (root-mean-square difference less than 0.1), with most match ups falling within the estimated uncertainties associated with the MODIS retrievals (about -10 to +50 ). The co-retrieved cloud optical depth was comparable to that of the MODIS operational cloud product for ACE-ASIA and SEAC4RS, however, higher by 30-50% for the SAFARI-2000 case study. The reason for this discrepancy could be attributed to the distinct aerosol optical properties encountered during respective campaigns. A brief discussion on the sources of uncertainty in the satellite-based ACAOD retrieval and co-location procedure is presented. Field experiments dedicated to making direct measurements of aerosols above cloud are needed for the extensive validation of satellite based retrievals.

airborne sun photometer↗

The Ocean Colour Climate Change Initiative: III. A Round-Robin Comparison on In-Water Bio-Optical Algorithms

Satellite-derived remote-sensing reflectance (Rrs) can be used for mapping biogeochemically relevant variables, such as the chlorophyll concentration and the Inherent Optical Properties (IOPs) of the water, at global scale for use in climate-change studies. Prior to generating such products, suitable algorithms have to be selected that are appropriate for the purpose. Algorithm selection needs to account for both qualitative and quantitative requirements. In this paper we develop an objective methodology designed to rank the quantitative performance of a suite of bio-optical models. The objective classification is applied using the NASA bio-Optical Marine Algorithm Dataset (NOMAD). Using in situ Rrs as input to the models, the performance of eleven semianalytical models, as well as five empirical chlorophyll algorithms and an empirical diffuse attenuation coefficient algorithm, is ranked for spectrally-resolved IOPs, chlorophyll concentration and the diffuse attenuation coefficient at 489 nm. The sensitivity of the objective classification and the uncertainty in the ranking are tested using a Monte-Carlo approach (bootstrapping). Results indicate that the performance of the semi-analytical models varies depending on the product and wavelength of interest. For chlorophyll retrieval, empirical algorithms perform better than semi-analytical models, in general. The performance of these empirical models reflects either their immunity to scale errors or instrument noise in Rrs data, or simply that the data used for model parameterisation were not independent of NOMAD. Nonetheless, uncertainty in the classification suggests that the performance of some semi-analytical algorithms at retrieving chlorophyll is comparable with the empirical algorithms. For phytoplankton absorption at 443 nm, some semi-analytical models also perform with similar accuracy to an empirical model. We discuss the potential biases, limitations and uncertainty in the approach, as well as additional qualitative considerations for algorithm selection for climate-change studies. Our classification has the potential to be routinely implemented, such that the performance of emerging algorithms can be compared with existing algorithms as they become available. In the long-term, such an approach will further aid algorithm development for ocean-colour studies.

Phytoplankton↗

Retrieve Optically Thick Ice Cloud Microphysical Properties by Using Airborne Dual-Wavelength Radar Measurements

An algorithm to retrieve optically thick ice cloud microphysical property profiles is developed by using the GSFC 9.6 GHz ER-2 Doppler Radar (EDOP) and the 94 GHz Cloud Radar System (CRS) measurements aboard the high-altitude ER-2 aircraft. In situ size distribution and total water content data from the CRYSTAL-FACE field campaign are used for the algorithm development. To reduce uncertainty in calculated radar reflectivity factors (Ze) at these wavelengths, coincident radar measurements and size distribution data are used to guide the selection of mass-length relationships and to deal with the density and non-spherical effects of ice crystals on the Ze calculations. The algorithm is able to retrieve microphysical property profiles of optically thick ice clouds, such as, deep convective and anvil clouds, which are very challenging for single frequency radar and lidar. Examples of retrieved microphysical properties for a deep convective clouds are presented, which show that EDOP and CRS measurements provide rich information to study cloud structure and evolution. Good agreement between IWPs derived from an independent submillimeter-wave radiometer, CoSSIR, and dual-wavelength radar measurements indicates accuracy of the IWC retrieved from the two-frequency radar algorithm.

Wang, Zhien↗

Development of a prototype algorithm for the operational retrieval of height-resolved products from GOME

Global ozone monitoring experiment (GOME) level 2 products of total ozone column amounts have been generated on a routine operational basis since July 1996. These products and the level 1 radiance products are the major outputs from the ERS-2 ground segment GOME data processor (GDP) at DLR in Germany. Off-line scientific work has already shown the feasibility of ozone profile retrieval from GOME. It is demonstrated how the retrievals can be performed in an operational context. Height-resolved retrieval is based on the optimal estimation technique, #and cloud-contaminated scenes are treated in an equivalent reflecting surface approximation. The prototype must be able to handle GOME measurements routinely on a global basis. Requirements for the major components of the algorithm are described: this incorporates an overall strategy for operational height-resolved retrieval from GOME.

Spurr, Robert J. D.↗