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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,009 records · Page 56
All sourcesNASA NTRSDOE OSTI
NASA NTRS1986

Review of measurements of the RF spectrum of radiation from lightning

A review is presented of the measurements reported in the literature of the spectrum of electromagnetic radiation from lightning in the frequency range from 1 kHz to 1 GHz. Measurements have been made either by monitoring the power received at individual frequencies using a narrow bandwidth recording device tuned to the frequencies under investigation or by recording the transient (time dependent) radiation with a wide bandwidth device and then Fourier transforming the waveform to obtain a spectrum. Measurements of the first type were made extensively in the 1950’s and 1960’s and several composite spectra have been deduced by normalizing the data of different investigators to common units of bandwidth and distance. The composite spectra tend to peak near 5 kHz and then decrease roughly as (frequency).’ upto nearly 100 MHz where scatter in the data make the behaviour uncertain. Measurements of the second type have been reported for return strokes, the stepped leader and for some intracloud processes. The spectrum of first return strokes obtained in this manner is very similar to the composite spectra obtained from the narrowband measurements.

Lightning Spectrum↗
NASA NTRS2000

Vertical Distributions of PH3 in Saturn from Observations of Its 1-0 and 3-2 Rotational Lines

Far-infrared Fourier-transform spectrometer measurements of the 1-0 and 3-2 PH3 transitions in Saturn's disk near 267 and 800 GHz (8.9 and 26.7/cm), respectively, were analyzed simultaneously to derive a global mean profile for the PH3 vertical mixing ratio between 100 and 600 mbar total pressure. The far-infrared spectrum is relatively free from spectral interlopers, suffers minimal absorption or scattering by atmospheric particulates, and contains intrinsically weak PH3 lines that are sensitive to a range of atmospheric depths. The combined spectra are inconsistent with a uniform tropospheric mixing ratio, even with a stratospheric cut-off. They are consistent with a volume mixing ratio of PH3 that drops from 1.2 x 10(exp -5) at 645 mbar pressure to a value of 4.1 x 10(exp -7) at 150 mbar pressure, a decrease that is linear is log abundance vs log pressure. The mixing ratio could drop even more quickly at atmospheric pressures below 150 mbar and still be consistent with the data. The mixing ratio may well remain constant with depth for pressures above 630 mbar. The maximum PH3 mixing ratio in this model is consistent with a [P]/[H] ratio in the deep atmosphere that is about a factor of 10 higher than solar composition. Such a model is consistent with rapid mixing up to the radiative-convective boundary and transport by, for example, vertical waves just above this boundary. In the best fitting model, the eddy diffusion coefficient is approximately 10(exp 4) sq cm near 630 mbar, and it must increase with altitude. The predominant PH3 loss mechanisms are direct photolysis by UV radiation and scavenging by H atoms produced by the photolysis.

Orton, G. S.↗
NASA NTRS1999

Measuring Directional Wave Spectra and Wind Speed with a Scanning Radar Altimeter

The geometry for the NASA Scanning Radar Altimeter (SRA) is shown. It transmits a 8-ns duration pulse at Ka-band (8.3 mm) and measures time of flight as it scans a 1 degree (two-way) beam from left to right across the aircraft ground track. The most recent configuration determines the surface elevation at 64 points spaced at uniform angular intervals of about 0.7 across a swath whose width is about 0.8 times the aircraft altitude. The system generates these raster lines of the surface topography beneath the aircraft at about a 10 Hz rate. In postflight processing the SRA wave topographic data are transformed with a two-dimensional Fast Fourier Transformation (FFT) and Doppler corrected to produce directional wave spectra. The SRA is not absolutely calibrated in power, but by measuring the relative fall-off of backscatter with increasing incidence angle, the SRA can also determine the mean square slope (mss) of the sea surface, a surrogate for wind speed. For the slope-dependent specular point model of radar sea surface scattering, an expression approximated by a geometric optics form, for the relative variation with incidence angle of the normalized backscatter radar cross section would be sigma (sup 0) (sub rel) = sec (exp 4) theta exp (-tan squared theta/mss) where theta is the off-nadir incidence angle.

Walsh, E. J.↗
DOE OSTI2023

Metal–Carbodithioate-Based 3D Semiconducting Metal–Organic Framework: Porous Optoelectronic Material for Energy Conversion

Solar energy conversion requires the working compositions to generate photoinduced charges with high potential and the ability to deliver charges to the catalytic sites and/or external electrode. These two properties are typically at odds with each other and call for new molecular materials with sufficient conjugation to improve charge conductivity but not as much conjugation as to overly compromise the optical band gap. In this work, we developed a semiconducting metal-organic framework (MOF) prepared explicitly through metal-carbodithioate"(-CS 2 ) n M" linkage chemistry, entailing augmented metal-linker electronic communication. The stronger ligand field and higher covalent character of metal-carbodithioate linkages-when combined with spirofluorene-derived organic struts and nickel-(II) ion-based nodes-provided a stable, semiconducting 3D-porous MOF, Spiro-CS 2 Ni. This MOF lacks long-range ordering and is defined by a flexible structure with non-aggregated building units, as suggested by reverse Monte Carlo simulations of the pair distribution function obtained from total scattering experiments. The solvent-removed "closed pore"material recorded a Brunauer-Emmett-Teller area of similar to 400m 2 /g, where the "open pore" form possesses90 wt % solvent-accessible porosity. Electrochemical measurements suggest that Spiro-CS 2 Ni possesses a band gap of 1.57 eV(sigma = 10 -7 S/cm at -1.3 V bias potential),which can be further improved by manipulating the d-electron configuration through an axial coordination (ligand/substrate), the latter of which indicates usefulness as an electrocatalyst and/or a photoelectrocatalyst(upon substrate binding). Transient-absorption spectroscopy reveals a long-lived photo-generated charge-transfer state (τ CR = 6.5 mu s) capable of chemical transformation under a biased voltage. Spiro-CS 2 Ni can endure a compelling range of pH(1-12 for weeks) and hours of electrochemical and photoelectrochemical conditions in the presence of water and organic acids. We believe this work provides crucial design principles for low-density, porous,light-energy-conversion materials.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Building Neutron Scattering Infrastructure in Louisiana for Advanced Materials (Final Report)

The main objective of the Louisiana Consortium for Neutron Scattering (LaCNS) is to build a major neutron scattering infrastructure capable of treating both soft and hard materials. The goal is to create a sustainable effort having the quality, breadth, and depth necessary to produce competitive proposals including collaborative and center type proposals. Our scientific aim is to understand the role of coupling in emergent complex materials and its impact on the structure/property relationship and to explore how to tune the key couplings to guide the design of materials with the desired properties. This naturally includes building a base of users of the Spallation Neutron Source (SNS) and the High Flux Isotope Reactor (HFIR) in Louisiana; to train highly talented graduate and post-doctoral students in synthesis, neutron scattering, and simulation and modeling techniques, thereby helping to produce the next generation of scientist who use neutron scattering techniques as a crucial part of their research. The goal of our hard matter program is to understand the interplay between spin, charge, orbital, and lattice degrees of freedom in carefully selected complex materials. We have made considerable progress on number of complex systems including the oxide Sr3(Ru1-xMnx)2O7 where short-range magnetic ordering with anisotropic spin texture is initiated at the metal-insulator transition that clearly indicates a strong spin-charge coupling. Another critical area is in quantum materials. For example, in the topological semimetal BaMnSb2, we found a 3D canted antiferromagnetic Weyl semimetal with a 2D electronic structure and a nontrivial Berry phase. In addition, in the hexagonal chiral Mn1/3NbS2 system, we found soliton/soliton and soliton/antisoliton domain walls where the application of small fields or small currents can be used to control nanoscopic magnetic domains where the control of domain walls is crucially important for information storage. In addition, chemical transformation investigations were performed on the VISION instrument at Spallation Neutron Source (SNS). The soft matter effort was focused on understanding the role of non-covalent interactions on the structure and dynamics of fluid-based soft matter. One key focus was on sequence-defined (SD) amphiphilic peptoid polymers that allow encoding of molecular interactions and thereby systematic investigations of how charge directs the solution self-assembly of amphiphilic polymers in water. Another important area was on the dynamics of lipids self-assembled into membranes for exploring the permeability and mechanical using both neutron spin echo (NSE) spectroscopy and quasielastic neutron scattering (QENS) to distinguished between viscoelasticity and permeability at the molecular scale. Overall, the LaCNS project was quite successful, generating 145 publications and 245 presentations. Our graduate and post-doctoral students were well trained resulting in positions in national laboratories (Oak Ridge National Laboratory (ORNL), Argonne National Laboratory and Los Alamos National Laboratory), major research universities, and industry. We also developed a uniaxial pressure cell along with ORNL for SNS. A critical goal of this project was to establish a foundation for competing nationally in federally funded research programs. To this end, we were quite successful in generating over twenty-two federally and non-federally funded grants including awards from NSF, DOE, and DOD, and two early career awards. Equally important, we were able to secure a key major piece of instrumentation via a large ARO grant for a state-of-the-art electron microscope.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Improved Cr ii log(gf) values and abundance determinations in the photospheres of the sun and metal-poor star HD 84937

New emission branching fraction (BF) measurements for 183 lines of the second spectrum of chromium (Cr ii) and new radiative lifetime measurements from laser-induced fluorescence for 8 levels of Cr{sup +} are reported. The goals of this study are to improve transition probability measurements in Cr ii and reconcile solar and stellar Cr abundance values based on Cr i and Cr ii lines. Eighteen spectra from three Fourier Transform Spectrometers supplemented with ultraviolet spectra from a high-resolution echelle spectrometer are used in the BF measurements. Radiative lifetimes from this study and earlier publications are used to convert the BFs into absolute transition probabilities. These new laboratory data are applied to determine the Cr abundance log ε in the Sun and metal-poor star HD 84937. The mean result in the Sun is 〈logε(Cr II)〉 = 5.624 ± 0.009 compared to 〈logε(Cr I)〉 = 5.644 ± 0.006 on a scale with the hydrogen abundance log ε(H) = 12 and with the uncertainty representing only line-to-line scatter. A Saha (ionization balance) test on the photosphere of HD 84937 is also performed, yielding 〈logε(Cr II)〉 = 3.417 ± 0.006 and 〈log ε(Cr i, lower level excitation potential E. P. > 0 eV)〉 = 3.374 ± 0.011 for this dwarf star. We find a correlation of Cr with the iron-peak element Ti, suggesting an associated nucleosynthetic production. Four iron-peak elements (Cr along with Ti, V, and Sc) appear to have a similar (or correlated) production history—other iron-peak elements appear not to be associated with Cr.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2026

Highly Crystalline and Porous Borocarbonitrides as Metal‐Free Catalysts for Boosted N‐Heterocycle Dehydrogenation

Safe and efficient hydrogen storage is pivotal for enabling a clean hydrogen economy. Liquid organic hydrogen carriers (LOHCs) offer a practical solution, but their deployment is hindered by the lack of highly active and economical dehydrogenation catalysts. In this work, we report a metal‐free catalyst design that overcomes the long‐standing trade‐off between crystallinity and surface area in two‐dimensional frameworks for highly efficient dehydrogenation of LOHCs. A flux‐assisted reconstruction strategy transforms amorphous borocarbonitrides (AM‐BCN) into highly crystalline, defect‐rich BCN nanosheets (C‐BCN) with large surface area and accessible porosity, as confirmed by complementary spectroscopic, x‐ray, and neutron analyses. C‐BCN catalyzes the acceptor‐less dehydrogenation of aza‐fused LOHCs with quantitative hydrogen release under mild conditions, outperforming AM‐BCN and previously reported metal‐free scaffolds. Mechanistic insights from x‐ray, neutron scattering, and theoretical calculations identify open C‐B‐N and N‐B‐N defect motifs as the primary active sites. This work establishes a generalizable strategy to engineer crystalline, porous, defect‐rich two‐dimensional lattices and demonstrates a highly active metal‐free platform for LOHC dehydrogenation with high‐purity H 2 generation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Unique Conductivity Behavior in Water-In-Salt Electrolytes Driven by Ion Clusters

Understanding and predicting ion transport in aqueous electrolytes are crucial for advanced energy storage and biophysics, and many emergent technologies yet remain elusive. Herein, we introduce a unified framework to quantitatively describe and predict electrolyte conductivity that shifts from conventional molar concentration-based metrics to a volume fraction-based approach. Through analyzing a variety of electrolyte solutions via this perspective, we observe a universal conductivity peak at a 37% volume fraction. Small-angle X-ray scattering (SAXS) and molecular dynamics (MD) simulations reveal that nanometer-scale ion clusters drive this general behavior. Moreover, key geometric features of the ion transport pathwayssuch as pore size, tortuosity, and connectivityfollow a consistent dependence with respect to the volume fraction, reinforcing the argument for the universal conductivity trend. This paradigm shift opens new avenues for designing high-performance electrolytes and provides transformative insights for advancing studies in many fields, wherein molecular aggregates dictate transport properties.

Nguyen, Huong T. D.↗
DOE OSTI2014

Electromagnetic nonlinear gyrokinetics with polarization drift

A set of new nonlinear electromagnetic gyrokinetic Vlasov equation with polarization drift and gyrokinetic Maxwell equations is systematically derived by using the Lie-transform perturbation method in toroidal geometry. For the first time, we recover the drift-kinetic expression for parallel acceleration [R. M. Kulsrud, in Basic Plasma Physics, edited by A. A. Galeev and R. N. Sudan (North-Holland, Amsterdam, 1983)] from the nonlinear gyrokinetic equations, thereby bridging a gap between the two formulations. This formalism should be useful in addressing nonlinear ion Compton scattering of intermediate-mode-number toroidal Alfvén eigenmodes for which the polarization current nonlinearity [T. S. Hahm and L. Chen, Phys. Rev. Lett. 74, 266 (1995)] and the usual finite Larmor radius effects should compete.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2026

pyDiSCaMB : enabling the use of multipolar scattering factors in Phenix

Multipolar scattering models, such as the transferable aspherical atom model, account for atomic chemical interactions and provide a more accurate representation of experimental data. However, the simpler independent atom model (IAM), which assumes non-interacting atoms, is the only model available in the most widely used macromolecular refinement programs. This is primarily because IAM offers a hard-to-beat combination of computational efficiency and modelling power at typical macromolecular resolutions. By contrast, more accurate multipolar modelling has historically been limited due to its computational cost and the absence of an interface between software capable of calculating structure factors and gradients based on multipolar models and software designed for macromolecular refinement. This work introduces pyDiSCaMB , a Python software package designed to integrate between the computational crystallography toolbox ( cctbx ) and the quantum crystallography library DiSCaMB ( Densities in Structural Chemistry and Molecular Biology ), thus enabling multipolar scattering models in Phenix 's toolkit. The implementation, features and capabilities of pyDiSCaMB are presented, the runtimes for the calculation of structure factor and target gradients with respect to atomic parameters are explored, and Fourier images of electrostatic potential, electron density and deformation maps are computed as illustrative examples. The pyDiSCaMB library will make multipolar modelling widely available to the structural biology community, potentially transforming refinement and model-building for both crystallography and cryogenic electron microscopy (cryoEM).

MATTS data bank↗
DOE OSTI2015

Atomic substitution effects on the structural and vibrational properties of Ni{sub x}Pb{sub 1-x}TiO{sub 3}: X-ray diffraction and Raman scattering investigations

The effects of the atomic substitution of Pb by Ni in the PbTiO{sub 3} ferroelectric perovskite on the vibrational and structural properties was studied using x-ray diffraction and Raman scattering. It was observed that for Ni concentrations between 0.0 and 0.4, there is the formation of a solid solution with reduction of the Raman wavenumber of the E(TO1) soft mode and the tetragonallity factor, which influence directly the temperature of the tetragonal ferroelectric to cubic paraelectric phase transition, the Curie temperature. For concentrations greater than 0.4, it is observed the formation of a PbTiO{sub 3} and NiTiO{sub 3} composite, denounced by the recovering of the both, tetragonallity factor and the E(TO1) soft mode wavenumber. The values of the Curie temperatures were estimated by the Raman scattering measurements for temperatures ranging from 300 to 950 K.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Institute for Quantum Matter

The mission of the Institute for Quantum Matter (IQM) Energy Frontier Research Center was to discover and understand emergent properties in material systems with the potential for transformative impacts on energy and information technologies.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Searching for topological Fermi arcs via quasiparticle interference on a type-II Weyl semimetal MoTe2

Abstract Weyl semimetals display a novel topological phase of matter where the Weyl nodes emerge in pairs of opposite chirality and can be seen as either a source or a sink of Berry curvature. The exotic effects in Weyl semimetals, such as surface Fermi arcs and the chiral anomaly, make them a new playground for exploring novel functionalities. Further exploiting their potential applications requires clear understanding of their topological electronic properties. Here we report a Fourier transform scanning tunneling spectroscopy (FT-STS) study on a type-II Weyl semimetal candidate MoTe 2 whose Weyl points are predicated to be located above Fermi level. Although its electronic structure below the Fermi level has been identified by angle resolved photo emission spectroscopy, by comparing our experimental data with first-principles calculations, we are able to identify the origins of multiple scattering channels both below and above Fermi level. Our calculations also show the existence of both trivial and topological arc-like states above the Fermi energy. In the FT-STS experiments, we have observed strong signals from intra-arc scatterings as well as from the scattering between the arc-like surface states and the projected bulk states. A detailed comparison between our experimental observations and calculated results reveals the trivial and non-trivial scattering channels are difficult to distinguish in this compound. Interestingly, we find that the broken inversion symmetry changes the terminating states on the two inequivalent surfaces, which in turn changes the relative strength of the scattering channels observed in the FT-STS images on the two surfaces.

Iaia, Davide↗
NASA NTRS2016

Physical State and Distribution of Materials at the Surface of Pluto from New Horizons LEISA Imaging Spectrometer

From Earth based observations Pluto is known to be the host of N2, CH4 and CO ices and also a dark red material. Very limited spatial distribution information is available from rotational visible and near-infrared spectral curves obtained from hemispheric measurements. In July 2015 the New Horizons spacecraft reached Pluto and its satellite system and recorded a large set of data. The LEISA spectro-imager of the RALPH instruments are dedicated to the study of the composition and physical state of the materials composing the surface. In this paper we report a study of the distribution and physical state of the ices and non-ice materials on Pluto's illuminated surface and their mode and degree of mixing. Principal Component analysis as well as various specific spectral indicators and correlation plots are used on the first set of 2 high resolution spectro-images from the LEISA instrument covering the whole illuminated face of Pluto at the time of the New Horizons encounter. Qualitative distribution maps have been obtained for the 4 main condensed molecules, N2, CH4, CO, H2O as well as for the visible-dark red material. Based on specific spectral indicators, using either the strength or the position of absorption bands, these 4 molecules are found to indicate the presence of 3 different types of ices: N2-rich:CH4:CO ices, CH4-rich(:CO:N2?) ices and H2O ice. The mixing lines between these ices and with the dark red material are studied using scatter plots between the various spectral indicators. CH4 is mixed at the molecular level with N2, most probably also with CO, thus forming a ternary molecular mixture that follows its phase diagram with low solubility limits. The occurrence of a N2-rich - CH4-rich ices mixing line associated with a progressive decrease of the CO/CH4 ratio tells us that a fractionation sublimation sequence transforms one type of ice to the other forming either a N2-rich - CH4-rich binary mixture at the surface or an upper CH4-rich ice crust that may hide the N2-rich ice below. The strong CH4-rich - H2O mixing line witnesses the subsequent sublimation of the CH4-rich ice lag left behind by the N2:CO sublimation (N spring-summer), or a direct condensation of CH4 ice on the cold H2O ice (S autumn). The weak mixing line between CH4-containing ices and the dark red material and the very sharp spatial transitions between these ices and this non-volatile material are probably due to thermal incompatibility. Finally the occurrence of a H2O ice - red material mixing line advocates for a spatial mixing of the red material covering H2O ice, with possibly a small amount intimately mixed in water ice. From this analysis of the different materials distribution and their relative mixing lines, H2O ice appears to be the substratum on which other ices condense or non-volatile organic material is deposited from the atmosphere. N2-rich ices seem to evolve to CH4-dominated ices, possibly still containing traces of CO and N2, as N2 and CO sublimate away. The spatial distribution of these materials is very complex. The high spatial definition of all these composition maps, as well as those at even higher resolution that will be soon available, will allow us to compare them with Pluto's geologic features observed by LORRI panchromatic and MVIC multispectral imagers to better understand the geophysical processes in action at the surface of this astonishingly active frozen world.

Schmitt, B.↗
DOE OSTI2022

Synchrotron X-ray based particle image velocimetry to measure multiphase streamflow and densitometry

Synchrotron-based radiation techniques are increasingly used in the field of flow condition measurements. As a complicated multiphase flow, cavitation has been investigated in a wide variety of industrial fields, to prevent damages on spillways at large dams or intensify the bacteria eradication rate during water treatments. To control the detrimental effects of cavitating flows, the dynamics of and mechanisms affecting cavitation development shall be visualized and identified in real-time. Due to the large reflection and scattering effects of multiphase flow, standard visible-light imaging technologies cannot penetrate vapor bubbles and provide extremely limited information. In this study, the synchrotron source emitted high-flux X-ray pulses are used to capture flow motion and visualize internal structures with sufficiently high spatial and temporal resolutions. The image processing procedures on raw x-ray images are developed using 2D Fourier transform (FT) and wavelet transform (WT) to implement the contrast enhancement and de-noising. Through the edge detection algorithm, tracking either seeded particles or phase interfaces inside the opaque multiphase flow can be achieved to perform the particle image velocimetry. Further, with decomposing particle-only and particle-eliminated subplots from the X-ray phase-contrast image, the time-resolved velocity and void fraction fields are obtained simultaneously, paving a way for further flow condition analysis such as densitometry.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2015

Highly orientated growth and characterization of La{sub 0.7}Sr{sub 0.3}MnO{sub 3} thin films with different orientations on SrTiO{sub 3} substrates by chemical solution deposition method

La{sub 0.7}Sr{sub 0.3}MnO{sub 3} (LSMO) thin films were successfully prepared on (100), (110), and (111) oriented SrTiO{sub 3} substrates by chemical solution deposition method. The structural, magnetic, and magnetotransport properties were systematically studied. X-ray diffraction θ-2θ and ϕ-scan measurements results show that all the films have perfect crystalline orientation and in-plane alignment. Both the Curie temperature and metal-insulator transition temperature are almost the same for all the three orientations, about 339 K. The magnetoresistance value (MR value, defined as (R{sub M} − R{sub 0})/R{sub 0} × 100%, where R{sub M} and R{sub 0} are the resistivity with and without applied magnetic field) for the films reaches maximum near the Curie temperature. Both the magnetization and MR value for (100) direction LSMO are the largest, and meanwhile for (111) direction are the smallest. The saturation magnetization decreases approximately proportional to T{sup 2} at low temperature (T < T{sub c}/2) for all the oriented film. Inversely, the resistivity increases proportional to T{sup 2} in the same temperature range, which can be attributed to the electron-electron scattering.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2017

Gravitational wave from dark sector with dark pion

In this work, we investigate the spectra of gravitational waves produced by chiral symmetry breaking in dark quantum chromodynamics (dQCD) sector. The dark pion (π) can be a dark matter candidate as weakly interacting massive particle (WIMP) or strongly interacting massive particle (SIMP). For a WIMP scenario, we introduce the dQCD sector coupled to the standard model (SM) sector with classical scale invariance and investigate the annihilation process of the dark pion via the 2π → 2 SM process. For a SIMP scenario, we investigate the 3π → 2π annihilation process of the dark pion as a SIMP using chiral perturbation theory. We find that in the WIMP scenario the gravitational wave background spectra can be observed by future space gravitational wave antennas. On the other hand, when the dark pion is the SIMP dark matter with the constraints for the chiral perturbative limit and pion-pion scattering cross section, the chiral phase transition becomes crossover and then the gravitational waves are not produced.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗