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At least 1,009 records · Page 56

Energetic Electron Precipitation Driven by Electromagnetic Ion Cyclotron Waves from ELFIN’s Low Altitude Perspective

We review comprehensive observations of electromagnetic ion cyclotron (EMIC) wave-driven energetic electron precipitation using data collected by the energetic electron detector on the Electron Losses and Fields InvestigatioN (ELFIN) mission, two polar-orbiting low-altitude spinning CubeSats, measuring 50-5000 keV electrons with good pitch-angle and energy resolution. EMIC wave-driven precipitation exhibits a distinct signature in energy-spectrograms of the precipitating-to-trapped flux ratio: peaks at >0.5 MeV which are abrupt (bursty) (lasting ~17 s, or ΔL ~ 0.56) with significant substructure (occasionally down to sub-second timescale). We attribute the bursty nature of the precipitation to the spatial extent and structuredness of the wave field at the equator. Multiple ELFIN passes over the same MLT sector allow us to study the spatial and temporal evolution of the EMIC wave - electron interaction region. Case studies employing conjugate ground-based or equatorial observations of the EMIC waves reveal that the energy of moderate and strong precipitation at ELFIN approximately agrees with theoretical expectations for cyclotron resonant interactions in a cold plasma. Using multiple years of ELFIN data uniformly distributed in local time, we assemble a statistical database of ~50 events of strong EMIC wave-driven precipitation. Most reside at L ~ 5 – 7 at dusk, while a smaller subset exists at L ~ 8 – 12 at post-midnight. The energies of the peak-precipitation ratio and of the half-peak precipitation ratio (our proxy for the minimum resonance energy) exhibit an L-shell dependence in good agreement with theoretical estimates based on prior statistical observations of EMIC wave power spectra. The precipitation ratio’s spectral shape for the most intense events has an exponential falloff away from the peak (i.e., on either side of ~ 1.45 MeV). It too agrees well with quasi-linear diffusion theory based on prior statistics of wave spectra. It should be noted though that this diffusive treatment likely includes effects from nonlinear resonant interactions (especially at high energies) and nonresonant effects from sharp wave packet edges (at low energies). Sub-MeV electron precipitation observed concurrently with strong EMIC wave-driven >1 MeV precipitation has a spectral shape that is consistent with efficient pitch-angle scattering down to ~ 200-300 keV by much less intense higher frequency EMIC waves at dusk (where such waves are most frequent). At ~100 keV, whistler-mode chorus may be implicated in concurrent precipitation. These results confirm the critical role of EMIC waves in driving relativistic electron losses. Nonlinear effects may abound and require further investigation.

79 ASTRONOMY AND ASTROPHYSICS↗

Suppression of Void Nucleation in High-Purity Aluminum via Dynamic Recrystallization

The process of ductile fracture in metals often begins with void nucleation at second-phase particles and inclusions. Previous studies of rupture in high-purity face-centered-cubic metals, primarily aluminum (Al), concluded that second-phase particles are necessary for cavitation. A recent study of tantalum (Ta), a body-centered-cubic metal, demonstrated that voids nucleate readily at deformation-induced dislocation boundaries. These same features form in Al during plastic deformation. This study investigates why void nucleation was not previously observed at dislocation boundaries in Al. Here, we demonstrate that void nucleation is impeded in Al by room-temperature dynamic recrystallization (DRX), which erases these boundaries before voids can nucleate at them. If dislocation cells reform after DRX and before specimen separation by necking, voids nucleation is observed. These results indicate that dislocation substructures likely plays an important role in ductile rupture.

36 MATERIALS SCIENCE↗

Microstructural Evolution of Al-1Fe (Weight Percent) Alloy During Accumulative Continuous Extrusion Forming

As a new microstructure refining method, accumulative continuous extrusion forming (ACEF) cannot only refine metal matrix but also refine the phases that exist in it. In order to detect the refinements of grain and second phase during the process, Al-1Fe (wt pct) alloy was processed by ACEF, and the microstructural evolution was analyzed by electron backscatter diffraction (EBSD) and transmission electron microscopy (TEM). Results revealed that the average grain size of Al-1Fe (wt pct) alloy decreased from 13 to 1.2 μm, and blocky Al{sub 3}Fe phase with an average length of 300 nm was granulated to Al{sub 3}Fe particle with an average diameter of 200 nm, after one pass of ACEF. Refinement of grain was attributed to continuous dynamic recrystallization (CDRX), and the granulation of Al{sub 3}Fe phase included the spheroidization resulting from deformation heat and the fragmentation caused by the coupling effects of strain and thermal effect. The spheroidization worked in almost the entire deformation process, while the fragmentation required strain accumulation. However, fragmentation contributed more than spheroidization. Al{sub 3}Fe particle stimulated the formation of substructure and retarded the migration of recrystallized grain boundary, but the effect of Al{sub 3}Fe phase on refinement of grain could only be determined by the contrastive investigation of Al-1Fe (wt pct) alloy and pure Al.

36 MATERIALS SCIENCE↗

Observational Study of Clogging Specimens from the Tundish Well Showing Origin and Growth of a Clog in an Al-Killed Ti-Alloyed Steel Cast

Post-mortem tundish skull samples of Ti-alloyed, Al-killed IF steel have been studied regarding the formation of clogging. By using modern characterization equipment and applied methods, we performed a detailed characterization of microstructures found in the tundish well. Aside from the primary metallographic examination, newly developed methods of particle size distribution analysis based on population density functions (PDF) and newly developed electron microscope EDS template mapping have been applied, allowing differentiation of complex particles according to phases and interphase contact relationships. Furthermore, detailed EDS analyses of individual inclusions with complex substructure regarding minor and trace elements within the alumina networks have been performed. These composite data on carefully selected clog microstructures allowed us to observe the presence of layering microstructures throughout the clog: “Coarse” layers (abundant microbubbles and internally complex alumina aggregates) and “Fine” layers (no microbubbles and complex alumina aggregates). Two populations of particles: Population I (2 to 5 µm) and a Population II (5 to 20 µm) build up the layers, both having lognormal PDF, in contrast to power-law PDF of secondary metallurgy inclusions. Coarse layers are further distinguished by selective concentrations of spinel with lognormal PDF as well as the occurrence of complex alumina particles with metal sub-inclusions often with elevated Cr, V, and Si content. Based on these observations, we derive a model for the origin and accumulation of the inclusions making up the clog, which suggests that the NMI of the two dominant populations do not come from the bulk steel, although secondary metallurgy-derived inclusions can be traced in the clog. Overall, microstructures show that the clog behaves as a coherent solid, and is able to displace and fracture.

36 MATERIALS SCIENCE↗

Microstructure Evolution and Mechanical Properties of High-Speed Friction Stir Welded Aluminum Alloy Thin Plate Joints

Sound friction stir welded (FSW) joints of 6061-T6 aluminum alloy sheets with an 0.8 mm thickness were obtained at conventional speed (2000 rpm, 300 mm/min) and high speed (11,000 rpm, 1500 mm/min). The recrystallization mechanism, precipitate evolution, mechanical properties and fracture behavior were investigated in detail. Microstructure analyses revealed that the grain structure evolution in the nugget zone (NZ) was dominated by continuous dynamic recrystallization. In the process of FSW, high speed facilitates the formation of finer equiaxed recrystallized grains, higher density of dislocations and substructures, and a larger number of precipitates in the NZ compared to the conventional speed, which further significantly improves the hardness and tensile strength of the joints. The maximum tensile strength was obtained with 292.6 MPa, 83.2% for the 6061-T6 aluminum alloy and 122.6% for the conventional-speed FSW joints. This work provides an effective method for preparing FSW aluminum alloy thin plate joints with excellent mechanical properties.

36 MATERIALS SCIENCE↗

High-Temperature Low-Cycle Fatigue Behavior of HS80H Ferritic–Martensitic Steel Under Dynamic Strain Aging

In this work, low-cycle fatigue tests were performed on HS80H ferritic–martensitic steel with the strain amplitudes ranging from 0.5 to 2.0% at room temperature and 350 °C. The cyclic stress response at 350 °C was found to be different from that at room temperature due to the effect of dynamic strain aging and showed a significant secondary hardening when the strain values were 0.5 and 0.7%. Furthermore, the dynamic strain aging effect also resulted in an abnormal increase in fatigue life when the strain was 0.7%, which was due to the change in elastic strain. Additionally, the elastic strain and fatigue life were bilinear relations in the double logarithmic coordinates. Finally, the transmission electron microscope observations showed that the dynamic strain aging led to the change in substructure, while the grain was refined.

36 MATERIALS SCIENCE↗

Characterization of a Cast Duplex Stainless Steel with 3.0%Cu and Modeling of Precipitation Hardening

Duplex stainless steels (DSSs) are corrosion-resistant alloys extensively used in aggressive environments. Cast DSSs may be selected for pipes, valves and pumps in chemical, petrochemical and nuclear industries. The grade steel ASTM A890 1B is an example of cast DSS with 2.7-3.3%Cu addition. Copper increases the resistance to many types of corrosion, especially in non-oxidizing environments. When the copper content is higher than 2%, the steel can be precipitation-hardened. In this work, the precipitation hardening of a DSS ASTM A890 1B steel with 3.0%Cu was studied and modeled for aging temperatures in the 450-600 °C range. Copper precipitates in the ferrite phase, but remains in solid solution in the austenite. The age hardening curves were modeled by ΔH = K(t){sup n} model, where ΔH is the increase in hardness, t is the aging time, and K and n are constants to be determined. The microstructure and substructure were investigated by scanning electron and transmission electron microscopes.

36 MATERIALS SCIENCE↗

The Application of Canned Deformation to a Hard-Deformed Spray-Deposited Al-Zn-Mg-Cu Alloy

A wide variety of industrial applications require Al-Zn-Mg-Cu alloys with high strength and ductility. However, Zn-rich Al-Zn-Mg-Cu alloys prepared by rapid solidification methods usually show excellent strength but poor formability, which restricts their wide application in complex forming. In this study, we developed a new deformation method for the spray-deposited Zn-rich Al-Zn-Mg-Cu alloy to avoid crack formation and achieve isotropic properties. The microstructure evolution and crystallographic textures were analyzed and compared with the results of a normal deformation process. Crack-free forgings with the ultimate tensile strength (UTS), yield strength (YS) and elongation of 727 ± 5 MPa, 690 ± 3 MPa, 5.0 ± 0.7% along the radial direction and 735 ± 2 MPa, 693 ± 3 MPa, 6.3 ± 0.2% along the tangential direction were finally obtained. The improvement in the mechanical properties can be attributed to the larger amount of subgrains and substructures generated in the canned deformed alloy. The results of this study show excellent advantages and potential application prospects of the canned deformation to hard-deformed Al-Zn-Mg-Cu alloys.

36 MATERIALS SCIENCE↗

Microstructures and Impact Wear Behavior of Al-Alloyed High-Mn Austenitic Cast Steel After Aging Treatment

The microstructural evolution and impact wear behavior of Al-alloyed ultra-high-Mn austenitic cast steel were investigated after different heat treatments, including quenching (Q) and quenching + aging (Q + A). Another ultra-high-Mn austenitic cast steel without Al was compared under the same experimental condition. After Q + A, Al addition contributed to the precipitation of κ-carbides which improves the yield strength and wear resistance of the austenite matrix. However, the mechanical properties and wear resistance of the Al-free steel were strongly deteriorated due to the precipitation of plate-like M{sub 3}C-type carbides, as well as the worn surface of the Al-free steel had the feature of micro-scratches. After Q + A (2 h), the Al-alloyed steel obtained optimal wear resistance and the main wear feature was strain fatigue. But, excessive aging time (4 h) would lead to a large fragile peeling from the worn surface and the wear resistance was decreased. Also, the worn subsurface microstructures with different heat treatments were observed by transmission electron microscopy (TEM). These results show that the deformation microstructures of the Al-free steel contained stacking faults, dislocation tangle and deformation twins. The deformation character of Al-alloyed steel is dominated by planar glide, and with increase in the aging time, planar dislocation substructures gradually evolved, relating to dislocation pileups, Taylor lattices and micro-bands.

36 MATERIALS SCIENCE↗

Implementation of ACTS into sPHENIX Track Reconstruction

Abstract sPHENIX is a high energy nuclear physics experiment under construction at the Relativistic Heavy Ion Collider at Brookhaven National Laboratory (BNL). The primary physics goals of sPHENIX are to study the quark-gluon-plasma, as well as the partonic structure of protons and nuclei, by measuring jets, their substructure, and heavy flavor hadrons in $$p$$ p $$+$$ + $$p$$ p , p + Au, and Au + Au collisions. sPHENIX will collect approximately 300 PB of data over three run periods, to be analyzed using available computing resources at BNL; thus, performing track reconstruction in a timely manner is a challenge due to the high occupancy of heavy ion collision events. The sPHENIX experiment has recently implemented the A Common Tracking Software (ACTS) track reconstruction toolkit with the goal of reconstructing tracks with high efficiency and within a computational budget of 5 s per minimum bias event. This paper reports the performance status of ACTS as the default track fitting tool within sPHENIX, including discussion of the first implementation of a time projection chamber geometry within ACTS.

97 MATHEMATICS AND COMPUTING↗

Crystal plasticity investigation of the microstructural factors influencing dislocation channeling in a model irradiated bcc material

We use a continuum crystal plasticity framework to study the effect of microstructure and mesoscopic factors on dislocation channeling and flow localization in an irradiated model bcc alloy. For simulated dislocation channeling characteristics we correlate the dislocation and defect densities in the substructure, local Schmid factor, and stress triaxiality, in terms of their temporal and spatial evolution. A metric is introduced to assess the propensity for localization and is correlated to the grain-level Schmid factor. We also found that localization generally takes place in grains with a local Schmid factor in the range 0.42 or higher. Surface slip step heights are computed at free surfaces and compared to relevant experiments.

36 MATERIALS SCIENCE↗

The effect of carbon on the microstructures, mechanical properties, and deformation mechanisms of thermo-mechanically treated Fe 40.4 Ni 11.3 Mn 34.8 Al 7.5 Cr 6 high entropy alloys

We investigated the effects of cold rolling followed by annealing on the mechanical properties and dislocation substructure evolution of undoped and 1.1 at. % carbon-doped Fe 40.4 Ni 11.3 Mn 34.8 Al 7.5 Cr 6 high entropy alloys (HEAs). X-ray diffraction, scanning electron microscopy (SEM), transmission electron microscopy (TEM) and atom probe tomography (APT) were employed to characterize the microstructures. The as-cast HEAs were coarse-grained and single phase f.c.c., whereas the thermo-mechanical treatment caused recrystallization (to fine grain sizes) and precipitation (a B2 phase for the undoped HEA; and a B2 phase, and M 23 C 6 and M 7 C 3 carbides for the C-doped HEA). Carbon, which was found to have segregated to the grain boundaries using APT, retarded recrystallization. The reduction in grain size resulted in a sharp increase in strength, while the precipitation, which produced only a small increase in strength, probably accounted for the small decrease in ductility for both undoped and C-doped HEAs. For both undoped and C-doped HEAs, the smaller grain-sized material initially exhibited higher strain hardening than the coarse-grained material but showed a much lower strain hardening at large tensile strains. Wavy slip in the undoped HEAs and planar slip in C-doped HEAs were found at the early stages of deformation irrespective of grain size. At higher strains, dislocation cell structures formed in the 19 μm grain-sized undoped HEA, while microbands formed in the 23 μm grain-sized C-doped HEA. Conversely, localized dislocation clusters were found in both HEAs at the finest grain sizes (5 μm). The inhibition of grain subdivision by the grain boundaries and precipitates lead to the transformation from regular dislocation configurations consisting of dislocation-cells and microbands to irregular dislocation configurations consisting of localized dislocation clusters, which further account for the decrease in ductility. Our investigation of the formation mechanism and strain hardening of dislocation cells and microbands could benefit future structural material design.

36 MATERIALS SCIENCE↗

The effect of grain orientation on nanoindentation behavior of model austenitic alloy Fe-20Cr-25Ni

Instrumented nanoindentation was used in this paper to investigate the hardness, elastic modulus, and creep behavior of an austenitic Fe-20Cr-25Ni model alloy at room temperature, with the indented grain orientation being the variant. The samples indented close to the {111} surfaces exhibited the highest hardness and modulus. However, nanoindentation creep tests showed the greatest tendency for creep in the {111} indented samples, compared with the samples indented close to the {001} and {101} surfaces. Scanning electron microscopy and cross-sectional transmission electron microscopy revealed slip bands and dislocations in all samples. The slip band patterns on the indented surfaces were influenced by the grain orientations. Deformation twinning was observed only under the {001} indented surfaces. Finally, microstructural analysis and molecular dynamics modeling correlated the anisotropic nanoindentation-creep behavior with the different dislocation substructures formed during indentation, which resulted from the dislocation reactions of certain active slip systems that are determined by the indented grain orientations.

36 MATERIALS SCIENCE↗

Building kit for metal cation binding sites in proteins

Starting with conformations of calcium-binding sites in parvalbumin and integrin (representative structures of EF-hand and calcium blade zones, respectively) we introduce four new different local Ca{sup 2+}-recognition units in proteins: a one-residue unit type I (ORI); a three-residue unit type I (TRI); a one-residue unit type II (ORII) and a three-residue unit type II (TRII). Based on the amount and nature of variable atoms, the type I and II units theoretically can have four and twelve variants, respectively. Analysis of known “Ca{sup 2+}-bound functional niches” in proteins revealed presence of almost all possible variants of Ca{sup 2+}-recognition units in actual structures. Parvalbumin, integrin alpha-IIb and sixteen other proteins with different Ca{sup 2+}-bound functional niches contain various consecutively joined combinations of OR(I/II) and TR(I/II) units. Such a OR(I/II)+TR(I/II) joint unit forms a tripeptide, which uses three main-chain atoms for metal binding: nitrogen{sub n} (Donor), oxygen{sub n} (Acceptor) and nitrogen{sub n+2} (Donor). Thus, taken together, the described ORI, TRI, ORII and TRII units can serve as elementary blocks to construct more complex calcium recognizing substructures in a variety of calcium binding sites of unrelated proteins.

60 APPLIED LIFE SCIENCES↗

A combination of deep eutectic solvent and ethanol pretreatment for synergistic delignification and enhanced enzymatic hydrolysis for biorefinary process

Here, a novel pretreatment system containing deep eutectic solvents and ethanol (DES-E) for synergistic carbohydrate conversion and delignification was reported in this study. The DES-E pretreatment resulted in an enhanced glucose yield compared to individual DES and ethanol pretreatment for the three tested biomass, including Broussonetia papyrifera, corn stover and pine. To further explore the delignification mechanism, the solubilized lignin and residual lignin from Broussonetia papyrifera was recovered and extracted, then thoroughly characterized. The highest total OH content was found in the DES-E solubilized lignin, which could be used as antioxidant. The presence of ethanol in pretreatment liquor could protect the β-O-4 substructure from breakage and reduce lignin condensation, which favors the subsequent enzymatic hydrolysis. Comparable glucose yield and delignification performance was achieved by recycled DES. DES-E pretreatment offers a promising method for lignin isolation and cellulose digestibility improvement simultaneously.

09 BIOMASS FUELS↗

A scalable domain decomposition method for FEM discretizations of nonlocal equations of integrable and fractional type

Nonlocal models allow for the description of phenomena which cannot be captured by classical partial differential equations. The availability of efficient solvers is one of the main concerns for the use of nonlocal models in real world engineering applications. Here, we present a domain decomposition solver that is inspired by substructuring methods for classical local equations. In numerical experiments involving finite element discretizations of scalar and vectorial nonlocal equations of integrable and fractional type, we observe improvements in solution time of up to 14.6x compared to commonly used solver strategies.

97 MATHEMATICS AND COMPUTING↗

Casein micelles and their internal structure

The internal structure of casein micelles was studied by calculating the small-angle neutron and X-ray scattering and static light scattering spectrum (SANS, SAXS, SLS) as a function of the scattering contrast and composition. We predicted experimental SANS, SAXS, SLS spectra self consistently using independently determined parameters for composition size, polydispersity, density and voluminosity. The internal structure of the casein micelles, i.e. how the various components are distributed within the casein micelle, was modeled according to three different models advocated in the literature; i.e. the classical sub-micelle model, the nanocluster model and the dual binding model. In this paper we present the essential features of these models and combine new and old experimental SANS, SAXS, SLS and DLS scattering data with new calculations that predict the spectra. Further evidence on micellar substructure was obtained by internally cross linking the casein micelles using transglutaminase, which led to casein nanogel particles. In contrast to native casein micelles, the nanogel particles were stable in 6 M urea and after sequestering the calcium using trisodium citrate. The changed scattering properties were again predicted self consistently. An important result is that the radius of gyration is independent of contrast, indicating that the mass distribution within a casein micelle is homogeneous. Experimental contrast is predicted quite well leading to a match point at a D{sub 2}O volume fraction of 0.41 ratio in SANS. Using SANS and SAXS model calculations it is concluded that only the nanocluster model is capable of accounting for the experimental scattering contrast variation data. All features and trends are predicted self consistently, among which the 'famous' shoulder at a wave vector value Q = 0.35 nm{sup -1}. In the nanocluster model, the casein micelle is considered as a (homogeneous) matrix of caseins in which the colloidal calcium phosphate (CCP) nanoclusters are dispersed as very small (about 2 nm) 'cherry stones' at an average distance of 18.6 nm. Attached to the surface of the nanoclusters are the centers of phosphorylation (3-5 nearby phosphorylated amino acid residues) of the caseins. The tails of the caseins, much larger than the CCP clusters, then associate to form a protein matrix, which can be viewed as polymer mesh with density fluctuations at the 2 nm scale. The association of the tails is driven by a collection of weak interactions. We explicitly use weak interactions as a collective term for hydrophobic interactions, hydrogen bonding, ion bonding, weak electrostatic Van der Waals attraction and other factors (but not the strong calcium phosphate interaction) leading to self association. The association is highly cooperative and originates in the weak interactions. It is the cooperativety that leads to a stable casein micelle. Invariably, K-casein is thought to limit the process of self association leading to stabilization of the native casein micelle.

08 HYDROGEN↗

Dynamic fracture of glass fiber-reinforced ductile polymer matrix composites and loading rate effect

Here, the dynamic fracture of S-2 glass fiber-reinforced polymer matrix composites (FRPMCs) was investigated in this study. The matrix ductility was improved by a recently developed network topology modification technique via mixing partially reacted substructures (mPRS). The composite material was manufactured and characterized by micro-CT scanning and scanning electron microscopy (SEM). Dynamic single-edge notched bending (d-SENB) experiments were performed on the composites by using a modified split-Hopkinson pressure bar. Each specimen’s fracture process was visualized by ultrafast X-ray imaging. Such in-situ radiography enabled identifying the damage initiation below 50-micron scale and inspecting its propagation through the internal structures of opaque composites, thereby accurately quantifying the composites’ mechanical properties. Furthermore, the identical d-SENB experiments were designed and the digital image correlation (DIC) was employed to monitor the stress wave propagation on the composite specimens. The force and deflection measurements were modified and correlated to the physical damage processes. Besides, quasi-static SENB experiments were conducted to identify the loading rate effects on the composites’ fracture behaviors. The force and deflection history, bending stiffness, energy dissipation, and fracture toughness at different loading rates were quantified and compared. Finally, post-fracture analysis by micro-CT scanning and SEM provided physical observations on the variation of the fracture morphology by different loading rates.

42 ENGINEERING↗