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Metrics in Space Life Support Technology Selection

Engineering metrics are useful in space life support technology selection, but they must be carefully used. Metrics are only part of a complete system trade-off. Metrics do harm if they cause neglect of other important technical, organizational, or intuitive decision factors. Two metrics have damaged space life support, closure and Equivalent Systems Mass (ESM). Closure measures the fraction of the required system inputs that are produced by recycling system outputs. Increasing closure produces diminishing returns and becomes increasingly expensive. Increasing closure does not directly contribute to providing better life support. ESM measures the total launch mass required to provide life support. ESM includes the mass of the system hardware and of its power, cooling, pressurized volume, spares, and logistics. ESM predicts launch costs, but recently launch costs have been reduced by a factor of 20 or more. System development cost for space hardware is often much greater than launch cost. The past nearly exclusive use of ESM has led to the neglect of Life Cycle Cost (LCC), reliability, cost, and the other engineering factors. Closure and ESM have misguided space life support technology selection for more than twenty years and have adversely affected the expenditure of 100’s of millions of dollars. Metrics can be effectively used three ways in space life support technology selection: 1. A small set of key engineering metrics for preliminary screening. 2. A full set of engineering to guide technical selection. 3. Combining engineering metrics with organizational, political, and intuitive decision factors to understand technology selection. The past emphasis on closure and ESM served to support recycling life support over resupply and built on the intuitive appeal of a human ecosystem in space.

Harry W Jones↗

The Effective Use of Metrics in Space Life Support System Trade-Offs

Engineering metrics are useful in space life support technology selection, but they must be carefully used. Metrics are only part of a complete system trade-off. Metrics do harm if they cause neglect of other important technical, organizational, or intuitive decision factors. Two metrics have damaged space life support, closure and Equivalent Systems Mass (ESM). Closure measures the fraction of the required system inputs that are produced by recycling system outputs. Increasing closure produces diminishing returns and becomes increasingly expensive. Increasing closure does not directly contribute to providing better life support. ESM measures the total launch mass required to provide life support. ESM includes the mass of the system hardware and of its power, cooling, pressurized volume, spares, and logistics. ESM predicts launch costs, but recently launch costs have been reduced by a factor of 20 or more. System development cost for space hardware is often much greater than launch cost. The past nearly exclusive use of ESM has led to the neglect of Life Cycle Cost (LCC), reliability, cost, and the other engineering factors. Closure and ESM have misguided space life support technology selection for more than twenty years and have adversely affected the expenditure of 100’s of millions of dollars. Metrics can be effectively used three ways in space life support technology selection: 1. A small set of key engineering metrics for preliminary screening. 2. A full set of engineering to guide technical selection. 3. Combining engineering metrics with organizational, political, and intuitive decision factors to understand technology selection. The past emphasis on closure and ESM served to support recycling life support over resupply and built on the intuitive appeal of a human ecosystem in space.

Harry W. Jones↗

An Analysis of Exploration Capability Gaps for Future Habitation Systems to Inform Risk Assessment and Development Priorities

Within NASA, exploration capability gaps are defined as the difference between the current state-of-the-art in capabilities and the anticipated needs of future human spaceflight architectures. As NASA and its partners’ capabilities for human exploration of deep space continue to mature, it is necessary to understand the capability gaps that require closure to support future habitation systems, such as the Lunar Surface Habitat (SH) and Mars Transit Habitat (TH) currently in concept development. This paper will identify high-priority capability gaps for exploration habitation and show potential options for gap closure through investment in technology, development, and testing. High-priority capability gaps are divided into the following general taxonomy areas: human health/life support/habitation systems, flight computing and avionics, power and energy storage, communications and navigation, thermal management systems, human exploration destination systems, autonomous systems, sensors and instruments, GNC (guidance, navigation, and control), robotic systems, ground and uncrewed surface systems, and materials/structures/mechanical systems/manufacturing. In the gap identification process, teams of discipline experts from across NASA reviewed the latest habitation architecture needs against current capabilities to understand where gaps may exist. The results of the assessment established a basis for the current state-of-the-art within each gap and identified the capability needs of the proposed exploration missions the gap links to. An assessment of how each test platform (e.g., Ground, International Space Station (ISS), Commercial Low Earth Orbit (LEO) Destinations, Gateway) may be leveraged to mature capabilities and potentially provide a route to gap closure will be discussed. The notional timeline for gap closure to support reference missions and impacts to overall schedule are also assessed where appropriate. Based on the capability gap analysis described above, the paper summarizes important technology maturation considerations for human exploration architectures, with a focus on the Mars TH. The previously published NASA habitation ground rules and assumptions document is used as the basis to classify gaps as enabling, enhancing, or “push” opportunities for a particular architecture. Stepwise technology maturation plans/considerations are presented for some selected critical gaps. Overall, the analysis in this paper is intended to help influence development priorities for habitation systems, where high-priority, critical gaps are those currently assessed as having a low probability of closure by the anticipated need date. Capability gap analysis also informs the risk register for exploration habitation systems and mitigation strategies to ensure readiness of key technologies to support future mission timelines. Linkage between capability gaps for Moon and Mars is noted, as closure of a gap at a Lunar destination may subsequently enable or enhance Mars TH architectures.

technology development↗

An Analysis of Exploration Capability Gaps for Future Habitation Systems to Inform Risk Assessment and Development Priorities

Within NASA, exploration capability gaps are defined as the difference between the current state-of-the-art in capabilities and the anticipated needs of future human spaceflight architectures. As NASA and its partners’ capabilities for human exploration of deep space continue to mature, it is necessary to understand the capability gaps that require closure to support future habitation systems, such as the Lunar Surface Habitat (SH) and Mars Transit Habitat (TH) currently in concept development. This paper will identify high-priority capability gaps for exploration habitation and show potential options for gap closure through investment in technology, development, and testing. High-priority capability gaps are divided into the following general taxonomy areas: human health/life support/habitation systems, flight computing and avionics, power and energy storage, communications and navigation, thermal management systems, human exploration destination systems, autonomous systems, sensors and instruments, GNC (guidance, navigation, and control), robotic systems, ground and uncrewed surface systems, and materials/structures/mechanical systems/manufacturing. In the gap identification process, teams of discipline experts from across NASA reviewed the latest habitation architecture needs against current capabilities to understand where gaps may exist. The results of the assessment established a basis for the current state-of-the-art within each gap and identified the capability needs of the proposed exploration missions the gap links to. An assessment of how each test platform (e.g., Ground, International Space Station (ISS), Commercial Low Earth Orbit (LEO) Destinations, Gateway) may be leveraged to mature capabilities and potentially provide a route to gap closure will be discussed. The notional timeline for gap closure to support reference missions and impacts to overall schedule are also assessed where appropriate. Based on the capability gap analysis described above, the paper summarizes important technology maturation considerations for human exploration architectures, with a focus on the Mars TH. The previously published NASA habitation ground rules and assumptions document is used as the basis to classify gaps as enabling, enhancing, or “push” opportunities for a particular architecture. Stepwise technology maturation plans/considerations are presented for some selected critical gaps. Overall, the analysis in this paper is intended to help influence development priorities for habitation systems, where high-priority, critical gaps are those currently assessed as having a low probability of closure by the anticipated need date. Capability gap analysis also informs the risk register for exploration habitation systems and mitigation strategies to ensure readiness of key technologies to support future mission timelines. Linkage between capability gaps for Moon and Mars is noted, as closure of a gap at a Lunar destination may subsequently enable or enhance Mars TH architectures.

technology development↗

Adapter retention mechanisms

An adapter retention mechanism including an adapter body having a first end and a second end, the first and second ends accepting first and second sets of ganged ferrules in use; a first pair of closure members pivotably connected to the first end of the adapter body, the first pair of closure members comprising first and second locking mechanisms, the first pair of closure members being configured to engage the first set of ganged ferrules; and a second pair of closure members pivotably connected to the second end of the adapter body, the second pair of closure members comprising third and fourth locking mechanisms, the second pair of closure members being configured to engage the second set of ganged ferrules.

97 MATHEMATICS AND COMPUTING↗

A Perspective on the Successes of the NNSS Underground Test Area (UGTA) Activity - 20221

Between 1951 and 1992, 828 underground nuclear tests were performed at the Nevada National Security Site (NNSS). Underground testing was done in five major testing areas, which included (1) Frenchman Flat, (2) Rainier Mesa/Shoshone Mountain, (3) Yucca Flat/Climax Mine (4) Central Pahute Mesa, and (5) Western Pahute Mesa. About one third of the underground tests were detonated near, at or below the water table, and thus radioactive contamination was introduced to the groundwater system. The U.S. Department of Energy's Underground Test Area (UGTA) Activity was established in the late 1990's to address the fate and movement of residual radioactivity in groundwater, and characterize the risk that it may pose to NNSS workers and the offsite public. It has accomplished this goal through a process of iterative groundwater sampling and numerical groundwater flow and transport modeling, and long-term monitoring. The UGTA Activity draws on the expertise of scientists in the fields of geology, hydrology, radiochemistry, and risk assessment from the U.S. DOE staff, the lead contractor (currently Navarro) and many other organizations, in cooperation with the governing regulatory body, the State of Nevada's Division of Environmental Protection (NDEP). Los Alamos National Laboratory (LANL) is one of the participating research organizations involved with the UGTA Activity. Under the direction of DOE and the lead contractor, LANL's role in UGTA has evolved over time from an initial focus on geologic characterization, to conducting field and laboratory experiments, and finally to its current role of providing modeling and geochemistry expertise to characterize the rates and directions of groundwater and radionuclide movement. In its current role, LANL has either developed or provided the numerical tools for developing flow and transport models in each of the four major testing areas. In addition, LANL has provided an independent assessment of future groundwater flow and transport behavior through the analysis of naturally-occurring geochemical and isotopic tracers in groundwater. The five major testing areas are now in different stages of investigation or closure: (1) Frenchman Flat is in its fifth year of post closure modeling; (2) The Rainier Mesa/Shoshone Mountain Closure Report has been submitted to NDEP and is awaiting approval; (3) The Yucca Flat/Climax Mine Closure Report is under development; and (4) Central and (5) Western Pahute Mesa is still undergoing investigation and flow and transport model development. The success of the UGTA Activity in reaching or approaching closure in three of the five major testing areas is primarily due to the DoE's focus on regulatory closure requirements, but also is in part attributable to a rigorous internal review process and the involvement of NDEP and Nye County water professionals as participants and observers in the reviews. County and state involvement in the internal review process has promoted trust that the U.S. DOE is deeply committed to ensuring the present and future safely of NNSS workers and the surrounding communities. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Development of a Multiphase Adjoint Capability in OpenFOAM

Thermal hydraulic predictions of flow regimes within nuclear reactor cores require significant computational resources and accuracy to ensure that the core design does not violate the thermal limits of materials. Multiphase computational fluid dynamics (CFD) has become a valuable computational capability for predicting flow characteristics as they relate to applications such as nuclear reactor safety and mixing phenomena around spacer grids within fuel assemblies. Multiphase CFD requires closure relationships for both the effects of turbulence as well as the transfer of mass, momentum, and energy between phases. Understanding the sensitivity of the parameters used in closure relationships is important for improving accuracy, but performing rigorous sensitivity analysis is computationally expensive. Adjoint mathematics have been utilized for reactor physics and fluid dynamics applications with respect to verification, sensitivity analysis, adaptive mesh refinement, and optimization. The usage of adjoint methods to predict the sensitivities of a variety of closure relationship parameters within a given problem has been shown to return sensitivity responses with significantly fewer computations than normal 'large-scale' methods. As the complexity of multiphase CFD methods increases, the demand for accurate verification tools and improvements in computational efficiency also increases, making the development of adjoint capabilities an attractive option. Closure relationships that describe interphase momentum physics in multiphase CFD modelling rely heavily on prescribed constants determined from experimental data. Due to the computational efficiency of an adjoint approach, the time to derive these closure relationships could be dramatically reduced, and data assimilation techniques could be used to return probability density functions of closure models derived using experimental data. This work develops a multiphase adjoint capability for the Eulerian-Eulerian two field, two phase equations. Specifically, the adjoint capability has been developed for the sub-cooled nucleate boiling solver boilEulerFoam developed by Dr. Nam Dinh of NC State University within the open-source CFD library OpenFOAM.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Improved treatment of multi-material cells in thermal radiation transport codes

High-energy-density physics simulations with non-conformal meshes of materials require a multi-material (MM) closure that affects the thermal radiation transport (TRT). We propose a set of novel closures that work for an arbitrary number of materials, both grey and multigroup energy discretizations, and any angular discretization (such as Sn, IMC, or diffusion). For each spatial cell, our closures let each species (ion and electron) of each material have its own temperature, density, and internal energy, but use a single radiation distribution that interacts with all materials within the cell. Our closures maintain energy conservation, do not incur increased computational cost in the TRT solve itself, are compatible with single-material TRT solvers, and do not make any temperature-equilibrium assumptions. Here we test our closures on a wide range of increasingly realistic problems and find them to be robust.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

A geometric perspective on kinetic matter–radiation interaction and moment systems

Here, in this paper, we provide a geometric perspective on the kinetic interaction of matter and radiation, based on a pair bracket approach. We discuss the interaction of kinetic theories via dissipative brackets, with our fundamental example being the coupling of matter, described by the Boltzmann equation, and radiation, described by the radiation transport equation. We explore the transition from kinetic systems to their corresponding moment systems, provide a Hamiltonian description of such moment systems, and give a geometric interpretation of the moment closure problem for kinetic theories. As an application, we discuss in detail diffusion radiation hydrodynamics as an example of a pair bracket formulation on a space of moments corresponding to kinetic matter–radiation interaction. Additionally, using the variable moment closure framework of Burby [J. W. Burby, Variable-moment fluid closures with Hamiltonian structure, Sci. Rep. 13 (2023) 18286, doi:10.1038/s41598-023-45416-5], we show how to construct Hamiltonian moment closures for kinetic transport equations with arbitrary Hamiltonian. Using this general construction, we derive novel Hamiltonian moment closures for pure radiation transport.

97 MATHEMATICS AND COMPUTING↗

Assessment on DNB performance for high pressure subcooled boiling with modified CASL boiling model

Understanding and predicting the Departure from Nucleation Boiling phenomena in the nuclear power industry has been a grand challenge due to its large impact on the reactor safety and operational economics. Over the past several years, CASL THM team has extensively investigated and demonstrated a state of art Multiphase CFD framework to provide a high-fidelity DNB simulation capability based on the two-fluid Eulerian model in conjunction with a wall heat flux partitioning approach. The overarching goal of this task is to develop and demonstrate a robust CFD-based DNB model which is capable of predicting an entire boiling history up to the DNB condition in which the wall boiling mode is transitioning from the nucleate boiling mode to the film boiling mode. Three different flow channel configurations (pipe flow, 5x5 fuel bundle with and without mixing vane tests) were studied and thorough closure sensitivity studies were performed to evaluate the wall boiling and momentum closure effect on the DNB performance. Predicated DNB values were compared to the measurements from high pressure subcooled flow boiling tests resulting in a consistent under-predictive trend for all three validation campaigns in FY16-18. With extensive closure sensitivity study, a modified CASL boiling closure model (i.e. Gen1-FY19) is introduced with the following key changes: 1) improved wall boiling closure for high pressure application, 2) newly calibrated lift and wall lubrication force models with modified interfacial length scale model, and 3) updated liquid phase condensation model calibrated for the subcooled boiling application.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Gen-0 BWR Modeling Application and Validation (L3 Milestone THM.P18.01)

This milestone report describes the Consortium for Advanced Simulation of Light Water Reactors (CASL) work conducted for completion of the thermal hydraulics Methods (THM) Level 3 milestone L3:THM.P18.01 Gen-0 BWR Modeling Application and Validation. The extension of existing boiling closure designed for Pressurized Water Reactors (PWRs) to the high void fraction condition of Boiling Water Reactors (BWRs) is one of the challenges for Multiphase Computational Fluid Dynamics (M-CFD) applications. In the efforts aimed at developing the advanced boiling closure for BWRs, the baseline closure model, so-called ‘Zero’ closure, has been developed by leveraging the experience gained through the Numerical Nuclear Reactor project. This baseline closure model is physics-based, simplest and robust, but it does not contain any explicit descriptions of the complex high void fraction mechanisms. This is a continuation of the CASL thermal-hydraulic study to develop and assess the CFD-BWR models. In FY-17, the applicability has been evaluated against the international OECD/NRC BFBT benchmark data. In the present work, we assessed the capability of CFD-BWR model for void drift phenomena in the modern BWR fuel designs which make use of both full-length and part-length rods.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Spatiotemporally dynamic implicit large eddy simulation using machine learning classifiers

In this article, we utilize machine learning to dynamically determine if a point on the computational grid requires implicit numerical dissipation for large eddy simulation (LES). The decision making process is learnt through a priori training on quantities derived from direct numerical simulation (DNS) data. In particular, we compute eddy-viscosities obtained through the coarse-graining of DNS quantities and utilize their projection onto a Gaussian distribution to categorize areas that may require dissipation. If our learning determines that closure is necessary, an upwinded scheme is utilized for computing the non-linear Jacobian. In contrast, if it is determined that closure is unnecessary, a symmetric and second-order accurate energy and enstrophy preserving Arakawa scheme is utilized instead. This results in a closure framework that precludes the specification of any model-form for the small scale contributions of turbulence but deploys an appropriate numerical dissipation from explicit closure driven hypotheses. Here, this methodology is deployed for the Kraichnan turbulence test-case and assessed through various statistical quantities such as angle-averaged kinetic energy spectra and vorticity structure functions. Our framework thus establishes a link between the use of explicit LES ideologies for closure and numerical dissipation-based modeling of turbulence leading to improved statistical fidelity of a posteriori simulations.

42 ENGINEERING↗

The starch-deficient plastidic PHOSPHOGLUCOMUTASE mutant of the constitutive crassulacean acid metabolism (CAM) species Kalanchoë fedtschenkoi impacts diel regulation and timing of stomatal CO2 responsiveness

Abstract Background and Aims Crassulacean acid metabolism (CAM) is a specialized type of photosynthesis characterized by a diel pattern of stomatal opening at night and closure during the day, which increases water-use efficiency. Starch degradation is a key regulator of CAM, providing phosphoenolpyruvate as a substrate in the mesophyll for nocturnal assimilation of CO2. Growing recognition of a key role for starch degradation in C3 photosynthesis guard cells for mediating daytime stomatal opening presents the possibility that starch degradation might also impact CAM by regulating the provision of energy and osmolytes to increase guard cell turgor and drive stomatal opening at night. In this study, we tested the hypothesis that the timing of diel starch turnover in CAM guard cells has been reprogrammed during evolution to enable nocturnal stomatal opening and daytime closure. Methods Biochemical and genetic characterization of wild-type and starch-deficient RNAi lines of Kalanchoë fedtschenkoi with reduced activity of plastidic phosphoglucomutase (PGM) constituted a preliminary approach for the understanding of starch metabolism and its implications for stomatal regulation in CAM plants. Key Results Starch deficiency reduced nocturnal net CO2 uptake but had negligible impact on nocturnal stomatal opening. In contrast, daytime stomatal closure was reduced in magnitude and duration in the starch-deficient rPGM RNAi lines, and their stomata were unable to remain closed in response to elevated concentrations of atmospheric CO2 administered during the day. Curtailed daytime stomatal closure was linked to higher soluble sugar contents in the epidermis and mesophyll. Conclusions Nocturnal stomatal opening is not reliant upon starch degradation, but starch biosynthesis is an important sink for carbohydrates, ensuring daytime stomatal closure in this CAM species.

59 BASIC BIOLOGICAL SCIENCES↗

Charge radii in covariant density functional theory: A global view

A systematic global investigation of differential charge radii has been performed within the CDFT framework for the first time. Theoretical results obtained with conventional covariant energy density functionals and the separable pairing interaction of Tian et al. [Phys. Lett. B 676, 44 (2009)] are compared with experimental differential charge radii in the regions of the nuclear chart in which available experimental data crosses the neutron shell closures at N=28,50,82, and 126. The analysis of absolute differential radii of different isotopic chains and their relative properties indicate clearly that such properties are reasonably well described in model calculations in the cases when the mean-field approximation is justified. However, while the observed clusterization of differential charge radii of different isotopic chains is well described above the N=50 and N=126 shell closures, it is more difficult to reproduce it above the N=28 and N=82 shell closures because of possible deficiencies in the underlying single-particle structure. The impact of the latter has been evaluated for spherical shapes and it was shown that the relative energies of the single-particle states and the patterns of their occupation with increasing neutron number have an appreciable impact on the evolution of the δ$\langle$r2$\rangle$N,N' values. These factors also limit the predictive power of model calculations in the regions of high densities of the single-particle states of different origin. It is shown that the kinks in the charge radii at neutron shell closures are due to the underlying single-particle structure and due to weakening or collapse of pairing at these closures. The regions of the nuclear chart in which the correlations beyond mean field are expected to have an impact on charge radii are indicated; the analysis shows that the assignment of a calculated excited prolate minimum to the experimental ground state allows us to understand the trends of the evolution of differential charge radii with neutron number in many cases of shape coexistence even at the mean-field level. It is usually assumed that pairing is a dominant contributor to odd-even staggering (OES) in charge radii. Our analysis paints a more complicated picture. It suggests a new mechanism in which the fragmentation of the single-particle content of the ground state in odd-mass nuclei due to particle-vibration coupling provides a significant contribution to OES in charge radii.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Turbulent transport and mixing in transitional Rayleigh-Taylor unstable flow: A priori assessment of gradient-diffusion and similarity modeling

Data from a 1152×760×1280 direct numerical simulation of a Rayleigh-Taylor mixing layer modeled after a small-Atwood-number water-channel experiment is used to investigate the validity of gradient diffusion and similarity closures a priori. The budgets of the mean flow, turbulent kinetic energy, turbulent kinetic energy dissipation rate, heavy-fluid mass fraction variance, and heavy-fluid mass fraction variance dissipation rate transport equations across the mixing layer were previously analyzed at different evolution times to identify the most important transport and mixing mechanisms. Here a methodology is introduced to systematically estimate model coefficients as a function of time in the closures of the dynamically significant terms in the transport equations by minimizing the L2 norm of the difference between the model and correlations constructed using the simulation data. It is shown that gradient-diffusion and similarity closures used for the turbulent kinetic energy K, turbulent kinetic energy dissipation rate ε, heavy-fluid mass fraction variance S, and heavy-fluid mass fraction variance dissipation rate χ equations capture the shape of the exact, unclosed profiles well over the nonlinear and turbulent evolution regimes. Using order-of-magnitude estimates for the terms in the exact transport equations and their closure models, it is shown that several of the standard closures for the turbulent production and dissipation (destruction) must be modified to include Reynolds-number scalings appropriate for Rayleigh-Taylor flow at small to intermediate Reynolds numbers. The late-time, large Reynolds number coefficients are determined to be different from those used in shear flow applications and largely adopted in two-equation Reynolds-averaged Navier-Stokes (RANS) models of Rayleigh-Taylor turbulent mixing. In addition, it is shown that the predictions of the Boussinesq model for the Reynolds stress agree better with the data when additional buoyancy-related terms are included. It is shown that an unsteady RANS paradigm is needed to predict the transitional flow dynamics from early evolution times, analogous to the small Reynolds number modifications in RANS models of wall-bounded flows in which the production-to-dissipation ratio is far from equilibrium. Although the present study is specific to one particular flow and one set of initial conditions, the methodology could be applied to calibrations of other Rayleigh-Taylor flows with different initial conditions (which may give different results during the early-time, transitional flow stages, and perhaps asymptotic stage). Finally, the implications of these findings for developing high-fidelity eddy viscosity-based turbulent transport and mixing models of Rayleigh-Taylor turbulence are discussed.

42 ENGINEERING↗

Mine Flooding History of a Regional Below-Drainage Coalfield Dominated by Barrier Leakage (1970–2014)

A 44-year record of water level fluctuations in a series of adjacent closed underground mines documents the history of closure and mine flooding in the Fairmont Coalfield, one of the oldest coal mining districts in the Pittsburgh coal basin, West Virginia, USA. As closures proceeded and mines began to flood, US environmental regulations were first enacted mandating mine water control and treatment, rendering uncontrolled surface discharges unacceptable. The purpose of this study is to present this flooding history and to identify critical events that determined how mine pools evolved in this case. Also examined is the strategy developed to control and treat water from these mines. Flooding is visualized using both water level hydrographs and mine flooding maps with the latter constructed assuming mine water hydraulic continuity between one or more mines. The earliest flooding formed small pools within near-surface mines closed prior to 1962 yet still pumped following closure to minimize leaking into adjacent still-active workings. These subpools gradually enlarged and merged as more closures occurred and the need for protective pumping was removed, forming what is today referred to as the unconfined Fairmont Pool. Later, deeper mines, separated by intact updip barriers from the Fairmont Pool, were closed and flooded more gradually, supplied in large part by leakage from the Fairmont Pool. By 1985, all mines except 2 had closed and by 1994 all had fully flooded, with the Fairmont Pool interconnected to deeper single mine pools via barrier leakage. As protective pumping ceased, the Fairmont Pool rose to a water level 3 m higher than surface drainage elevation and in 1997 discharged from an undermined section of Buffalo Creek near the Monongahela River. The principal mine operator in the basin then designed a pumping system to transfer water from the Fairmont Pool to their existing treatment facilities to the north, thus terminating the discharge. It may be concluded that the progress of mine flooding was influenced by mining history and design, by the timing of closures, by barrier leakage conditions, and by geologic structure. A key element in how flooding proceeded was the presence of a series of intact barriers separating deep from shallow mines. The shallow mines closed and flooded early, but then lost sufficient water by barrier leakage into the deeper mines to delay the completion of flooding until after the deep mines had all closed and flooded as well. Intensive mine water control has continued from the 1997 breakout to the present. The final water control scheme was likely unanticipated and serendipitous; future district-wide mining efforts should be advised to consider in advance closeout strategies to control mine water postmining.

Donovan, Joseph J.↗

Assessing Gaseous Hydrogen Assisted Fatigue Crack Growth Susceptibility of Pipeline Steel Weld Fusion Zones and Heat Affected Zones

The objective of this work was twofold: (1) measure reliable fatigue crack growth relationships for X65 steel and its girth weld in high-pressure hydrogen gas to enable structural integrity assessments of hydrogen pipelines, and (2) evaluate the hydrogen accelerated fatigue crack growth susceptibility of the weld fusion zone and heat-affected zone relative to the base metal. Fatigue crack growth relationships (da/dN versus ΔK) were measured for girth welded X65 pipeline steel in high pressure hydrogen gas (21 MPa) and in air. Hydrogen assisted fatigue crack growth was observed for the base metal (BM), fusion zone (FZ), and heat-affected zone (HAZ), and was manifested through crack growth rates reaching nearly an order of magnitude acceleration over rates in air. Addditionally, at higher ΔK values, crack growth rates of BM, FZ, and HAZ were coincident; however, at lower ΔK, the fatigue crack growth relationships exhibited some divergence with the fusion zone having the highest crack growth rates. These relative fatigue crack growth rates in the BM, FZ, and HAZ were provisional, however, since both crack closure and residual stress contributed to the crack-tip driving force in specimens extracted from the HAZ. Despite the relatively high applied R-ratio (R = 0.5), crack closure was detected in the heat affected zone tests, in contrast to the absence of crack closure in the base metal tests. Crack closure corrections were performed using the adjusted compliance ratio method and the effect of residual stress on K max was determined by the crack-compliance method. Crack-tip driving forces that account for closure and residual stress effects were quantified as a weighted function of ΔK and K max (i.e., K norm ), and the resulting da/dN versus K norm relationships showed that the HAZ exhibited higher hydrogen accelerated fatigue crack growth rates than the BM at lower K norm values.

36 MATERIALS SCIENCE↗

2016 Annual Summary Report for the Area 3 and Area 5 Radioactive Waste Management Sites at the Nevada National Security Site, Nye County, Nevada: Review of the Performance Assessments and Composite Analyses

The Maintenance Plan for the Performance Assessments and Composite Analyses for the Area 3 and Area 5 Radioactive Waste Management Sites at the Nevada Test Site (National Security Technologies, LLC 2007a) requires an annual review to assess the adequacy of the performance assessments (PAs) and composite analyses (CAs), with the results submitted to the U.S. Department of Energy (DOE) Office of Environmental Management. The Disposal Authorization Statements for the Area 3 and Area 5 Radioactive Waste Management Sites (RWMSs) also require that such reviews be made and that secondary or minor unresolved issues be tracked and addressed as part of the maintenance plan.The U.S. Department of Energy, National Nuclear Security Administration Nevada Field Office (NNSA/NFO) performed an annual review of the Area 3 and Area 5 RWMS PAs and CAs for federal fiscal year (FY) 2016. This annual summary report presents results and conclusions of the FY 2016 review, and determines the adequacy of the PAs and CAs. Operational factors (e.g., waste forms and containers, facility design, and waste receipts), closure plans, monitoring results, and research and development (R&D) activities were reviewed to determine the adequacy of the PAs. Likewise, the environmental restoration activities at the Nevada National Security Site (NNSS) relevant to the sources of residual radioactive material that are considered in the CAs, the land-use planning, and the results of the environmental monitoring and R&D activities were reviewed to determine the adequacy of the CAs. Important developments in FY 2016 include the following: Development of a new Area 5 RWMS closure inventory estimate based on disposals through FY 2016, Evaluation of new or revised waste streams by special analysis, and Development and acceptance of version 4.200 of the Area 5 RWMS GoldSim PA/CA model. The Area 3 RWMS has been in inactive status since July 1, 2006, with the last shipment received in April 2006. The FY 2016 review of operations, facility design, closure plans, monitoring results, and R&D results for the Area 3 RWMS indicates no changes that would impact PA validity. The conclusion of the annual review is that all performance objectives can be met and the Area 3 RWMS PA remains valid. There is no need to revise the Area 3 RWMS PA. Review of Area 5 RWMS operations, design, closure plans, monitoring results, and R&D activities indicates that no significant changes have occurred. The FY 2016 PA results, generated with the Area 5 RWMS v4.200 GoldSim PA model, indicate that there continues to be a reasonable expectation of meeting all performance objectives. All results remain less than 50% of their performance objectives. The results and conclusions of the Area 5 RWMS PA are judged valid, and there is no need to the revise the PA. A review of changes potentially impacting the CAs indicates that no significant changes occurred in FY 2016. A new Corrective Action Unit (CAU), CAU 576, with corrective action sites near the Area 3 RWMS and Area 5 RWMS was identified in FY 2016. The sites are currently under investigation and not expected to be important sources for the CA. The continuing adequacy of the CAs was evaluated with the new models, and no significant changes that would alter the CAs’ results or conclusions were found. The revision of the Area 3 RWMS CA, which will include the Yucca Flat Underground Test Area (CAU 97) source, is scheduled for FY 2024, following the completion of the Corrective Action Decision Document/Corrective Action Plan. Inclusion of the Frenchman Flat Underground Test Area (CAU 98) source in the Area 5 RWMS CA is planned pending the completion of the CAU 98 Closure Report in FY 2017. Near-term R&D efforts will focus on continuing development of the PA, CA, and inventory models for the Area 3 and Area 5 RWMSs.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗