Multiple cycle chromium poisoning and in-situ electrochemical cleaning of LSM-based solid oxide fuel cell cathodes
Not Available
SEARCH · Search NASA
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Not Available
Abstract not provided
Explore the source record for details and available documents.
Highlights: • Syngas free of particles and with very low amount of tar is produced from biomass gasification. • Combination is tested of primary catalyst in the gasifier fluidized bed with catalytic ceramic candles in its freeboard. • Remarkable process intensification and thermal integration is obtained. • The adoption of catalytic filter candles doesn’t increase the required standard filtration surface in practical applications. - Abstract: Heavy organic compounds produced during almond shells gasification in a steam and/or air atmosphere, usually called tar, are drastically reduced in the product gas by using simultaneously in one vessel a ceramic filter placed in the freeboard and a mixture of olivine and dolomite particles in the fluidized bed of the gasifier. The content of tar in the product gas during a reference gasification test with air, in presence of fresh olivine particles only, was 8600 mg/Nm{sup 3} of dry gas. By gasifying biomass with steam at the same temperature level of 820 °C in a bed of olivine and dolomite (20% by weight), and in the presence of a catalytic ceramic filter inserted in the freeboard of the fluidized bed gasifier, the level of tar was brought down to 57 mg/Nm{sup 3} of dry producct gas, with a decrease of more than two orders of magnitude.
Here we explore the relationship between effective cleaning/clearing radii, ECR, and critical suspension velocities, Ucs. Although one set of physics controls both the radial extent of erosion (i.e., the ECR) and the velocity needed to erode from the center of jet impingement to any given location (i.e., Ucs, typically defined from nozzle center to the vessel center), the relationship between these two remains unexplored quantitatively. Here we advance the model of Kuhn, et al., (PNNL-22816, 2013) as described by Pease, et al. (FEDSM2017-69444, 2017) to evaluate the relationship between the effective clearing/cleaning radius and the nozzle velocity on flat surfaces including flat bottomed vessels. Two governing dimensionless groups are identified. We present both a closed form analytical but transcendental solution and a non-iterative approximation modeled after the Serghides approximation of Colebrook’s nonlinear equation for both ECR versus nozzle velocity and Ucs. Comparison of the model to data from flume testing on a flat surface finds reasonable agreement.
The effects of direct plasma chemistries on carbon removal from silicon nitride (SiN{sub x}) and oxynitride (SiO{sub x}N{sub y}) surfaces have been studied by in-situ x-ray photoelectron spectroscopy (XPS) and ex-situ contact angle measurements. The data indicate that O{sub 2} and NH{sub 3} capacitively coupled plasmas are effective at removing adventitious carbon from silicon nitride (SiN{sub x}) and Si oxynitride (SiO{sub x}N{sub y}) surfaces. O{sub 2} plasma treatment results in the formation of a silica overlayer. In contrast, the exposure to NH{sub 3} plasma results in negligible additional oxidation of the SiN{sub x} or SiO{sub x}N{sub y} surface. Ex-situ contact angle measurements show that SiN{sub x} and SiO{sub x}N{sub y} surfaces exposed to oxygen plasma are initially more hydrophilic than surfaces exposed to NH{sub 3} plasma, indicating that the O{sub 2} plasma-induced SiO{sub 2} overlayer is highly reactive toward ambient. At longer ambient exposures (≳10 h), however, surfaces treated by either O{sub 2} or NH{sub 3} plasma exhibit similar steady state contact angles, correlated with rapid uptake of adventitious carbon, as determined by XPS. Surface passivation by exposure to molecular hydrogen prior to ambient exposure significantly retards the increase in contact angle upon exposure to ambient. The results suggest a practical route to enhancing the time available for effective bonding to surfaces in microelectronics packaging applications.
New Jersey’s two currently predominant renewable energy resources are wind and solar, as evidenced by rapid market growth in both areas. As the state carries almost 100,000 megawatts of wind potential on land and offshore—enough to generate all of the current electricity needs of the state—it is no surprise that New Jersey is home to six facilities that manufacture components for wind turbines. Solar photovoltaic growth is also considerable, and at 1,000 megawatts, the state now ranks second in the nation in terms of installed capacity. In large part, this growth has been due to state policies that facilitate solar system installation (such as net metering) and state sales tax and rebate incentives for renewables. The state has committed to generating 22.5% of its electricity from renewable sources by 2021 through its Renewable Energy Portfolio Standard. In 2010, utility companies in New Jersey also invested an impressive $\$$198 million in energy efficiency and recorded savings of 497 million kilowatt hours or enough electricity to power more than 43,000 homes for one year. The utilities’ investment supports four grant programs for energy efficiency offered by New Jersey’s Public Service Electric & Gas Company, as well as a loan program and a rebate program offered by New Jersey Natural Gas.
This annual guide features a comprehensive list of 2014 light-duty alternative fuel and advanced vehicles, grouped by fuel and technology. The guide provides model-specific information on vehicle specifications, manufacturer suggested retail price, fuel economy, energy impact, and emissions. The information can be used to identify options, compare vehicles, and help inform purchase decisions.
The purpose of this paper is to describe multiple studies of wind and solar integration that have found CO 2 reductions of approximately 30%. These studies can be viewed in several ways, including as viable paths to compliance with the EPA rule, alternative ''bookend cases'' to compare to compliance based largely on natural gas, or something in between. The studies in this paper represent a body of work that can help inform the public discussion surrounding the cost and reliability impacts of complying with the proposed EPA CPP.
The Philippines has one of the highest electricity prices for commercial and residential consumers in the Association of Southeast Asian Nations (ASEAN) region with prices between $0.12 (commercial) and $0.20 (residential) per kilowatt-hour (kWh) (ERIA 2018). Significant reliance on imported coal and diesel is the primary cause of this cost to ratepayers. This 'hot topic brief' details new policies in the Philippines designed to diversify the country's fuel-mix and the opportunities for investments in renewable energy to reduce prices for consumers and industry. This brief focuses on two recent policies: 1. Renewable Portfolio Standard (RPS): The RPS establishes mandatory targets for each electric distribution utility--both publicly and privately owned--to procure renewable energy through 2030. 2. Green Energy Option Program (GEOP): The GEOP enables companies to independently procure renewable energy from third-party power producers, which can be used to help meet private sector renewable energy goals, unlock lower electricity costs, and increase energy security.
The mining industry is a major source of raw materials for several industries such as manufacturing, transportation, construction, energy, and mining industry itself. It is anticipated that demand for raw materials is going to increase as the population growth and many low-income economies shift to middle-income countries. The increase in mineral demand accompanies by falling mineral ore grade is expected to increase energy demand raising concern of greenhouse gas emission (GHG). Renewable energy can provide mine operators with solutions to several of the challenges they face today, including energy costs, fossil fuel volatility, social license to operate, and meeting environmental, societal, and governance goals. However, the integration of wind, solar, storage, and other renewable technologies face several barriers that are generally not well understood. Many of these barriers will require further research, development, demonstration, and deployment before we see higher levels of renewables adoption in the mining industry. Thus, this report highlights renewable opportunities, barriers, and enabling approaches.
As part of CEF Round 1 funding, Pacific Northwest National Laboratory (PNNL) was engaged by the U.S. Department of Energy (DOE) and the Washington Department of Commerce to work with Puget Sound Energy (PSE), Avista, and Snohomish Public Utility District (SnoPUD) in evaluating the economic and technical performance of each of their battery energy storage systems (BESSs). This report presents the final results of the economic assessment.
The evolution of the electricity sector toward competitive modern markets is occurring over a long period and responding to rapid changes in technologies, business models, and other market factors. No reformed power market anywhere in the world looks the same today as it did a decade ago. Technology has enabled some of the evolution, but perhaps it is more important that people and institutions learn from experience how to make markets better over time. Governments still have an important role—not as the authority controlling prices, but as the authority safeguarding the integrity of the economic processes that create prices in response to supply and demand and ensure reliability and other objectives are met. More VRE resources will change market conditions, but they will not change market fundamentals. Prices provide important signals for new investments and how the grid operates—including new technologies and processes discussed elsewhere in this report. If poor market design or the exercise of market power by a large entity distort these signals, outcomes will cease to be efficient and the public will bear the additional cost. Fundamentally, prices reflect supply, demand, and the cost of technological options.
High renewable penetration will bring different challenges to power system reliability and stability. Reduction of inertia has been of concern for more wide-spread instable events; however, with the advanced control functionalities provided by power electronics interface and proper storage compensation, renewable generators are capable of providing wide-range of grid services that can maintain and improve grid reliability and stability matrices. Many studies and testing has demonstrated those functions and many pilot projects throughout the world had proved the concepts are working.
The continued growth in distributed energy resources is fundamentally changing the way the distribution system is operated and planned. Additionally, an increasing number of grid issues are being regularly experienced by distribution engineers within an increasing number of utilities. Fortunately, these fundamental changes and increasingly regular issues are being addressed via continual improvements in existing distribution system modeling tools—for both tools used by industry and researchers—and via novel modeling methods, which are combining transmission and distribution system modeling to investigate new, often complex, system interactions at the transmission/distribution power system interface. As DERs continue to increase more and more utilities, regulators, and developers are finding usable solutions in the deployment of smart inverters with ever more capable functionalities. This increase in functionality is welcome but comes at the cost of more complex analysis when determining what specific settings should be used for an individual interconnection. With more time, experience, and likely the further development of advanced analysis tools, even higher levels of DER integration will result in a reliable, resilient, low-cost, and safely operating grid.
As states and local governments weigh how to spur economic growth, stimulate job creation, and simultaneously adapt to meet climate goals, modern energy codes, and energy demand, this report provides a simple and transparent method to estimate the size of the workforce needed to support modeled deployments for energy efficiency in buildings, stationary battery energy storage (BES), solar photovoltaics (PV), and land-based wind in 2025 and 2030. In addition to a straightforward estimation method, this report includes state-level job estimates for two different deployment scenarios: a business-as-usual scenario and a more accelerated deployment scenario. The scope of the technologies included in this report is limited to four key energy technologies within the power sector that have strong job growth prospects and widespread geographic deployment potential. Although the included technologies are not all-encompassing, they have generated specific interest from state energy offices across the nation.
While industrial emissions research has historically focused on energy-intensive sectors like steel, cement, and chemicals, this study addresses a critical gap by examining barriers across all the manufacturing industry in the U.S. Sectors like food processing, retail, plastics, and transportation face unique challenges distinct from heavy industry, operating on thin margins with limited bargaining power while experiencing heightened consumer and stakeholder pressure for improved environmental responsibility. Through structured interview data collection process and using quantitative ratings and qualitative analysis, this research identifies and categorizes emission reduction barriers across four key themes: financial, technical, organizational, and regulatory. Unlike energy-intensive industries that may pursue hydrogen or carbon capture technologies, discrete manufacturing industry like automotive, electrical and electronics, and machine manufacturers typically focus on energy efficiency, electrification of thermal processes, and alternate fuel switching, solutions better aligned with their lower-temperature processes and distributed facility profiles. The study’s primary contribution lies in documenting specific barrier manifestations within organizations and identifying proven mitigation strategies that companies have successfully implemented or observed among peers.
Explore the source record for details and available documents.