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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,027 records · Page 57
All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

Influence of conical wire array geometry on plasma flow and temperature profiles of radiatively cooled jets

The influence of conical wire array geometry on the formation and dynamics of pulsed-power driven plasma jets is investigated. In the experiments, the jet becomes isolated from the inflows as it passes through an aperture, allowing the study of its intrinsic evolution for different conical angles. Here, our results show that, regardless of the array opening angle, the jets are supersonic, highly collisional, and exhibit an exponential axial density decay with a characteristic scale length of 𝐿 𝑛 ≈ 3 mm, significantly shorter than the overall length of the jet. In contrast, axial velocity systematically increases with larger array opening angles. The near invariance of the density profile is attributed to a compensating mechanism between geometric divergence and axial acceleration, consistent with an asymptotically steady flow regime. Additionally, temperature measurements reveal ion-electron thermal decoupling near the base of the jet, with equilibration downstream. Analysis of radiative cooling and collisional energy exchange timescales indicates that the plasma evolves in a radiatively stable regime and that the two-temperature profile is fully described by the competition between both methods. These findings provide valuable information into the internal structure and evolution of pulsed-power plasma jets in regimes dominated by geometric shaping and radiative cooling, demonstrating experimental control over flow acceleration and collimation relevant to both laboratory and astrophysical contexts.

Physics - Plasma physics↗
DOE OSTI2019

Development of a Host-Based Intrusion Detection and Control Device for Industrial Field Control Devices

Industrial control systems contain a multitude of devices deployed into the field to observe and control a physical process. Currently, most of these devices lack common host-based cybersecurity features, which can lead them to be seen as vulnerable targets. The Cymbiote device was developed to address this problem by examining multiple streams of data to determine what might indicate a potential threat, and to evaluate and execute appropriate response actions. This paper discusses the evolution of the Cymbiote device in response to evaluation and testing done on real-world hardware. Experimental results are discussed, as are the new developments that have been made to the device in response to the findings. In addition, we describe future research directions for this approach along with the experimental setup changes in response to the requirements for statistical rigor.

Rice, Theora R.↗
DOE OSTI2016

Stability and Activity of (Pr 1‐x Nd x ) 2 NiO 4 as Cathodes for Solid Oxide Fuel Cells: I. Quantification of Phase Evolution in Pr 2 NiO 4

Praseodymium nickelate (Pr 2 NiO 4 ) is an active oxygen electrode for solid oxide fuel cells, but undergoes phase transition at elevated temperatures (e.g., 750°C). Quantification of this phase evolution in an operating single cell is challenging because of the overlap of X‐ray diffraction ( XRD ) peaks between the cathode and oxide current collector. In this work, we replace the oxide current collector with a gold metal grid, circumventing these challenges by allowing the exposure of the cathode to the X‐ray beam, while eliminating peak overlap. Quantification of the phase evolution was performed by a least‐squares fitting of the linear combination of XRD standards against the experimental patterns. Energy‐dispersive spectroscopy analysis on long‐term operated cells showed the absence of reactions between the gold grids and the cathodes. Additionally, the grids exhibited excellent mechanical stability under operating conditions and enabled similar cell performance as an oxide current collector.

Dogdibegovic, Emir↗
DOE OSTI2016

Multisource inverse-geometry CT. Part II. X-ray source design and prototype

Purpose: This paper summarizes the development of a high-power distributed x-ray source, or “multisource,” designed for inverse-geometry computed tomography (CT) applications [see B. De Man et al., “Multisource inverse-geometry CT. Part I. System concept and development,” Med. Phys. 43, 4607–4616 (2016)]. The paper presents the evolution of the source architecture, component design (anode, emitter, beam optics, control electronics, high voltage insulator), and experimental validation. Methods: Dispenser cathode emitters were chosen as electron sources. A modular design was adopted, with eight electron emitters (two rows of four emitters) per module, wherein tungsten targets were brazed onto copper anode blocks—one anode block per module. A specialized ceramic connector provided high voltage standoff capability and cooling oil flow to the anode. A matrix topology and low-noise electronic controls provided switching of the emitters. Results: Four modules (32 x-ray sources in two rows of 16) have been successfully integrated into a single vacuum vessel and operated on an inverse-geometry computed tomography system. Dispenser cathodes provided high beam current (>1000 mA) in pulse mode, and the electrostatic lenses focused the current beam to a small optical focal spot size (0.5 × 1.4 mm). Controlled emitter grid voltage allowed the beam current to be varied for each source, providing the ability to modulate beam current across the fan of the x-ray beam, denoted as a virtual bowtie filter. The custom designed controls achieved x-ray source switching in <1 μs. The cathode-grounded source was operated successfully up to 120 kV. Conclusions: A high-power, distributed x-ray source for inverse-geometry CT applications was successfully designed, fabricated, and operated. Future embodiments may increase the number of spots and utilize fast read out detectors to increase the x-ray flux magnitude further, while still staying within the stationary target inherent thermal limitations.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2016

Effect of canted antiferromagnetic order on the electronic structure in the t–J* model within the cluster perturbation theory

The electronic structure in the two-dimensional t–J* model with canted antiferromagnetic order in an external magnetic field has been calculated within the cluster perturbation theory. In zero external field, the evolution of the Fermi surface with n-type doping has been obtained in good agreement with experimental data on cuprate superconductors. It has been shown that the inclusion of short-range correlations can result in a nonmonotonic dependence of the spectral weight distribution at the Fermi level on the external magnetic field. In contrast to the case of electron doping, such changes in the case of hole doping can be expected at experimentally achievable fields.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2024

Phase-Field Modeling of Thermally-Grown Oxide and the Induced Damage Evolution in Environmental Barrier Coatings

The advent of next-generation hydrogen-based engines necessitates materials capable of withstanding temperatures beyond the reach of current superalloys. SiC-based ceramic matrix composites, augmented with environmental barrier coatings (EBCs), present a promising materials solution. Given the active search for effective and durable EBCs, there is a pressing need for modeling tools to understand and predict damage evolution in these materials to help accelerate their development. This study introduces a phase-field model (PFM) designed to simulate the critical role of thermally grown oxides (TGO) in the degradation and failure of EBCs. The model accounts for the severe volume expansion due to oxidation, alongside phase transformations and microstructural evolution during thermal cycling, offering a comprehensive view of the damage processes. Simulation results are validated against experimental findings reported in the literature, establishing the model's potential as a significant tool for understanding and improving the resilience of EBCs in cyclic oxidative environments.

Cheng, Tianle↗
DOE OSTI2025

Phase Field Modeling of Chemical Reaction Related Damage Evolution in Environmental Barrier Coatings

The advent of next-generation engines necessitates materials capable of withstanding temperatures beyond the reach of current superalloys. SiC-based ceramic matrix composites, augmented with environmental barrier coatings (EBCs), present a promising materials solution. Given the active search for effective and durable EBCs, there is a pressing need for modeling tools to understand and predict damage evolution in these materials to help accelerate their development. This study introduces a phase-field model (PFM) designed to simulate the thermally grown oxides (TGO) and phase transformation in the degradation and failure of EBCs. The model accounts for the severe volume expansion due to oxidation, alongside phase transformations and porosity evolution during thermal cycling, offering a comprehensive view of the damage processes. Simulation results are validated against experimental findings reported in the literature, establishing the model's potential as a significant tool for understanding and improving the resilience of EBCs in cyclic oxidative environments.

fast-diffusion path↗
NASA NTRS1971

Photoactivation of the manganese catalyst of O2 evolution. II A two-quantum mechanism.

A kinetic analysis is presented of the data obtained in previously described kinetic experiments relating to the photoactivation of the Mn complex required for photosynthetic O2 evolution. The results obtained from the computer simulation of the derived kinetic model compare favorably with the experimentally derived values. They also suggest that photoactivation can be rationalized in terms of a two-quantum process.

Radmer, R.↗
NASA NTRS1986

Theoretical studies on the mechanical behavior of granular materials under very low intergranular stresses

The salient aspects of the theoretical modeling of a conventional triaxial test (CTC) of a cohesionless granular medium with stress and strain rate loading are described. Included are a controllable gravitational body force and provision for low confining pressure and/or very low intergranular stress. The modeling includes rational, analytic, and numerical phases, all in various stages of development. The numerical evolutions of theoretical models will be used in final design stages and in the analysis of the experimental data. In this the experimental design stage, it is of special interest to include in the candidate considerations every anomaly found in preliminary terrestrial experimentation. Most of the anomalies will be eliminated by design or enhanced for measurement as the project progresses. The main aspect of design being not the physical apparatus but the type and trajectories of loading elected. The major considerations that have been treated are: appearance and growth of local surface aberrations, stress-power coefficients, strain types, optical strain, radial bead migration, and measures of rotation for the proper stress flux.

French, Kenneth W., Jr.↗
NASA NTRS1996

The Circular Hydraulic Jump in Microgravity

This report summarizes the key experimental results and observations that were obtained under NASA grant NAG 3-1627 from the Fluid Physics Program. The Principle Investigator was Thomas Avedisian. In addition a half-time post-doctoral associate, Ziqun Zhao, was funded for half year. The project monitor was David Chao of the NASA-Lewis Research Center in Cleveland, Ohio. The grant period was originally for one year at $34K and a no-cost extension was applied for and granted for an additional year. The research consisted of an experimental study of the circular hydraulic jump (CHJ) in microgravity using water as the working fluid. The evolution of the CHJ radius was measured during a sudden transition from normal to microgravity in a drop tower. The downstream height of the CHJ was controlled by submerging the target plate in a tank filled with water to the desired depth, and the measurements are compared with an existing theory for the location of the CHJ. Results show that the CHJ diameter is larger in microgravity than normal gravity. The adjustment of the CHJ diameter to a sudden change in gravity occurs over a period of about 200ms for the conditions of the present study, and remains constant thereafter for most of the flow conditions examined. For flow conditions that a CHJ was not first established at normal gravity but which later appeared during the transition tb microgravity, the CHJ diameter was not constant during the period of microgravity but continually changed. Good agreement between measured and predicted CHJ radii is found for normal gravity CHJ radii, but comparatively poorer agreement is observed for the CHJ radii measurements in microgravity.

Avedisian, C. Thomas↗
NASA NTRS2003

The Langley Stability and Transition Analysis Code (LASTRAC) : LST, Linear and Nonlinear PSE for 2-D, Axisymmetric, and Infinite Swept Wing Boundary Layers

During the past two decades, our understanding of laminar-turbulent transition flow physics has advanced significantly owing to, in a large part, the NASA program support such as the National Aerospace Plane (NASP), High-speed Civil Transport (HSCT), and Advanced Subsonic Technology (AST). Experimental, theoretical, as well as computational efforts on various issues such as receptivity and linear and nonlinear evolution of instability waves take part in broadening our knowledge base for this intricate flow phenomenon. Despite all these advances, transition prediction remains a nontrivial task for engineers due to the lack of a widely available, robust, and efficient prediction tool. The design and development of the LASTRAC code is aimed at providing one such engineering tool that is easy to use and yet capable of dealing with a broad range of transition related issues. LASTRAC was written from scratch based on the state-of-the-art numerical methods for stability analysis and modem software technologies. At low fidelity, it allows users to perform linear stability analysis and N-factor transition correlation for a broad range of flow regimes and configurations by using either the linear stability theory (LST) or linear parabolized stability equations (LPSE) method. At high fidelity, users may use nonlinear PSE to track finite-amplitude disturbances until the skin friction rise. Coupled with the built-in receptivity model that is currently under development, the nonlinear PSE method offers a synergistic approach to predict transition onset for a given disturbance environment based on first principles. This paper describes the governing equations, numerical methods, code development, and case studies for the current release of LASTRAC. Practical applications of LASTRAC are demonstrated for linear stability calculations, N-factor transition correlation, non-linear breakdown simulations, and controls of stationary crossflow instability in supersonic swept wing boundary layers.

Chang, Chau-Lyan↗
NASA NTRS2016

High Throughput 600 Watt Hall Effect Thruster for Space Exploration

A nominal 600-Watt Hall Effect Thruster was developed to propel unmanned space vehicles. Both xenon and iodine compatible versions were demonstrated. With xenon, peak measured thruster efficiency is 46-48% at 600-W, with specific impulse from 1400 s to 1700 s. Evolution of the thruster channel due to ion erosion was predicted through numerical models and calibrated with experimental measurements. Estimated xenon throughput is greater than 100 kg. The thruster is well sized for satellite station keeping and orbit maneuvering, either by itself or within a cluster.

Hall Thrusters↗
NASA NTRS2015

Visualization and Quantification of Rotor Tip Vortices in Helicopter Flows

Helicopter aeromechanics encompasses a highly vortical flow field. The vortices generated at each blade tip contain unsteady, complex, three-dimensional structures, which interact with each other, other blades, the fuselage and various components of the helicopter. It is crucial to understand vortex kinematics and their subsequent dynamic evolution. Much research has been devoted to the understanding of helicopter vortex dynamics, including a number of experimental studies.1-6 In May 2010 Particle Image Velocimetry (PIV) measurements of a full-scale UH-60A rotor were acquired in the National Full-Scale Aerodynamics Complex (NFAC) 40- by 80-Foot Wind Tunnel.1 These measurements were taken at a plane just downstream of the advancing blade in the vicinity of the blade tip—the so-called PIV plane. The resulting PIV data were then processed using an ensemble-average approach to create graphical representations of the vortical wake velocity and vorticity fields, which, in turn, have enhanced the understanding of rotorcraft vortical wake flow field physics and have provided a more detailed validation of vortical wake computer simulations.7 A common approach used to analyze flow field features is to compute and plot color contour maps of various scalar quantities such as pressure, velocity magnitude and vorticity magnitude. For example, the color map of the vorticity magnitude is typically used to determine vortical flow structure. With this approach the vortex core may appear larger or smaller, depending on the contour levels that are selected. Thus, the resulting visualization is sensitive to user-specified contour levels. For vortex core radius measurements, it is more accurate to calculate the vortex core radius using the cross-flow velocity profile across the vortex core. The task of extracting the cross-flow velocity profile can be time consuming with existing tools since the user needs to manually select the core center then specify sampling points along the profile axis. The task becomes even more challenging when the associated grid system uses AMR (Adaptive Mesh Refinement) where the profile axis could span multiple grid blocks. There are a number of existing techniques for profiling of vortex core attributes;8-9 however, these techniques are not fully automatic in that the user still needs to select the vortex core center to compute the cross-flow velocity profile. The present study introduces a new color map scheme that is based on the vortex core radius, which is fully automatic and does not require user intervention. Analysis and visualization of blade tip vortices on the PIV plane using the proposed new color map scheme are described in Section II. The new approach is evaluated using two case studies, which are described in Section III. The paper ends with a summary in Section IV.

Quantification↗
NASA NTRSDate not supplied

Low-Temperature Formation of Carbonaceous Grains from PAHs

Astronomical observations have detected interstellar carbon in the form of polycyclic aromatic hydrocarbons(PAHs) as well as carbonaceous dust, confirming its presence in both gaseous and solid phases. The goal of this study is to experimentally investigate low-temperature chemical pathways between these two phases in order to better understand the evolution of cosmic carbon. Cosmic dust analogs are produced in the supersonic expansion of an argon jet seeded with aromatic molecules: benzene, naphthalene, anthracene, phenanthrene, and pyrene. These are prototype aromatic molecules of compact and non compact structure, and are used to evaluate the effect of precursor structure on the molecular complexity of the resulting grains. The seeded jet is exposed to an electrical discharge and the carbonaceous grains are collected and probed ex situ via laser desorption mass spectrometry. Mass spectra reveal a rich molecular diversity within the grains, including fragments of the parent molecule but also growth into larger complex organic molecules (COMs). In all experiments, the largest number of products is found in the m/z range 200-250, and C16H10 (attributed to pyrene and/or its isomers) is found to be a dominant product, pointing at the formation of this stable PAH as a preferential route in the growth to larger PAHs. Comparison to mass spectra from the Murchison meteorite reveals a similar dominance of compounds related toC16H10 at m/z = 202. Evidence of the methyl addition-cyclization mechanism in the anthracene experiment is reported. PAH structure is found to impact the dust production yield, as seen by the greater yield for the anthracene compared to the phenanthrene experiment. PAH growth at low temperatures via barrierless routes involving the addition of alkyl- and phenyl-type radicals is suggested as a viable pathway to COMs. These results suggest that PAH growth and dust formation from PAHs are feasible at low temperatures in photon-dominated regions and circumstellar envelopes.

L Gavilan↗
NASA NTRSDate not supplied

Evidence for Present Day Volcanism on Venus: A Case Study of Idunn Mons

Idunn Mons in Imdr Regio on Venus is perhaps one of the best studied volcanoes on Venus in part due to having both radar and night-time emissivity data of the region [1-3]. Smrekar et al. [1] first presented night-time emissivity data of Idunn Mons from the VIRTIS instrument on Venus Express, which showed that some lava flows have high emissivity consistent with unweathered basalt. Smrekar et al. [1], based on known weathering rates at that time, suggested that the lava flows were less than 2.5 million years old and possible as young as 250,000 years old. However, recent experimental work has shown that basaltic rocks and associated minerals in contact with the Venusian caustic atmosphere would react quickly to produce rinds of alteration materials coating the surface and obscure emissivity signatures of igneous minerals within a few to ~10,000 years [4-9]. These new experimentally derived weathering and oxidation rates were used to suggest that lava flows at Idunn Mons with unweathered signatures are quite young and Idunn Mons may be volcanically active today [4, 8]. Independent geologic mapping and related stratigraphic reconstruction over the study area is consistent with the experimental results [2, 10]. Considering all the available evidence, we have taken a comprehensive approach combining these recent experimental results with previous orbital night-time emissivity, as well as atmospheric measurements, to constrain the evolution of Idunn Mons [3,10]. Our results suggest that Idunn Mons is both volcanically and tectonically active today, and that volcanism and tectonic activity are likely related [11]. Venus being volcanically active has been suggested at other volcanic centers, as well [e.g. 12-17]. Therefore, we use Idunn Mons specifically as a case study of a potentially active volcano that may be detectable by the upcoming fleet of missions that will be arriving at Venus in the next decade.

Justin Filiberto↗
DOE OSTI2016

Modelling of LOCA Tests with the BISON Fuel Performance Code

BISON is a modern finite-element based, multidimensional nuclear fuel performance code that is under development at Idaho National Laboratory (USA). Recent advances of BISON include the extension of the code to the analysis of LWR fuel rod behaviour during loss-of-coolant accidents (LOCAs). In this work, BISON models for the phenomena relevant to LWR cladding behaviour during LOCAs are described, followed by presentation of code results for the simulation of LOCA tests. Analysed experiments include separate effects tests of cladding ballooning and burst, as well as the Halden IFA-650.2 fuel rod test. Two-dimensional modelling of the experiments is performed, and calculations are compared to available experimental data. Comparisons include cladding burst pressure and temperature in separate effects tests, as well as the evolution of fuel rod inner pressure during ballooning and time to cladding burst. Furthermore, BISON three-dimensional simulations of separate effects tests are performed, which demonstrate the capability to reproduce the effect of azimuthal temperature variations in the cladding. The work has been carried out in the frame of the collaboration between Idaho National Laboratory and Halden Reactor Project, and the IAEA Coordinated Research Project FUMAC.

BISON code↗
DOE OSTI2025

Synthesis and Characterization of [Ni(H 2 O)(7-P Ph 2 N ArSO3 ) 2 ](NaBF 4 ) for Light-Driven Quantum Dot-Catalyst Hydrogen Evolution

Light-driven hydrogen generation from water is a route to carbon-neutral fuels. However, the integrated light absorbers and catalysts must be compatible and functional under the same conditions. A sulfate-functionalized complex, [Ni(H 2 O)(7-P Ph 2 N ArSO3 ) 2 ](NaBF 4 ), where P Ph 2 N ArSO3 = 4-(3,6-diphenyl-1,3,6-azadiphosphepan-1-yl)benzenesulfonate), was synthesized and characterized. A solid-state structure from single-crystal X-ray crystallography is also reported. The electrocatalytic activity for hydrogen evolution of this complex in 7:3 H 2 O:CH 3 CN was characterized by cyclic voltammetry and controlled potential electrolysis, with a maximum observed rate of 83 s –1 . Density functional theory was used to characterize the favorable binding of the sulfate functionalities to cadmium sulfide quantum dots. Experimental assembly of these catalysts onto cadmium sulfide quantum dots was successful. In conclusion, both fast electron transfer and light-driven pH-dependent hydrogen evolution were observed.

36 MATERIALS SCIENCE↗
DOE OSTI2024

An integrated experimental–modeling approach to identify key processes for carbon mineralization in fractured mafic and ultramafic rocks

Abstract Controlling atmospheric warming requires immediate reduction of carbon dioxide (CO2) emissions, as well as the active removal and sequestration of CO2 from current point sources. One promising proposed strategy to reduce atmospheric CO2 levels is geologic carbon sequestration (GCS), where CO2 is injected into the subsurface and reacts with the formation to precipitate carbonate minerals. Rapid mineralization has recently been reported for field tests in mafic and ultramafic rocks. However, unlike saline aquifers and depleted oil and gas reservoirs historically considered for GCS, these formations can have extremely low porosities and permeabilities, limiting storage volumes and reactive mineral surfaces to the preexisting fracture network. As a result, coupling between geochemical interactions and the fracture network evolution is a critical component of long-term, sustainable carbon storage. In this paper, we summarize recent advances in integrating experimental and modeling approaches to determine the first-order processes for carbon mineralization in a fractured mafic/ultramafic rock system. We observe the critical role of fracture aperture, flow, and surface characteristics in controlling the quantity, identity, and morphology of secondary precipitates and present where the influence of these factors can be reflected in newly developed thermo-hydro-mechanical–chemical models. Our findings provide a roadmap for future work on carbon mineralization, as we present the most important system components and key challenges that we are overcoming to enable GCS in mafic and ultramafic rocks.

58 GEOSCIENCES↗