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DOE OSTI2013

The Western Wind and Solar Integration Study Phase 2

The electric grid is a highly complex, interconnected machine, and changing one part of the grid can have consequences elsewhere. Adding wind and solar affects the operation of the other power plants and adding high penetrations can induce cycling of fossil-fueled generators. Cycling leads to wear-and-tear costs and changes in emissions. Phase 2 of the Western Wind and Solar Integration Study (WWSIS-2) evaluated these costs and emissions and simulated grid operations for a year to investigate the detailed impact of wind and solar on the fossil-fueled fleet. This built on Phase 1, one of the largest wind and solar integration studies ever conducted, which examined operational impacts of high wind and solar penetrations in the West(GE Energy 2010).

14 SOLAR ENERGY↗

DOE OSTI2013

The Western Wind and Solar Integration Study Phase 2 (Executive Summary)

14 SOLAR ENERGY↗

DOE OSTI2015

Photovoltaic at Hollywood and Desert Breeze Recreational Centers

In accordance with the goals of the Department of Energy (DOE) Office of Energy Efficiency and Renewable Energy for promoting solar energy as clean, carbon-free and cost-effective, the County believed that a recreational center was an ideal place to promote solar energy technologies to the public. This project included the construction of solar electricity generation facilities (40kW) at two Clark County facility sites, Desert Breeze Recreational Center and Hollywood Recreational Center, with educational kiosks and Green Boxes for classroom instruction. The major objectives and goals of this Solar Project include demonstration of state of the art technologies for the generation of electricity from solar technology and the creation of an informative and educational tool in regards to the benefits and process of generating alternative energy. Clark County partnered with Anne Johnson (design architect/consultant), Affiliated Engineers Inc. (AEI), Desert Research Institute (DRI), and Morse Electric. The latest photovoltaic technologies were used in the project to help create the greatest expected energy savings for60443 each recreational center. This coupled with the data created from the monitoring system will help Clark County and NREL further understand the real time outputs from the system. The educational portion created with AEI and DRI incorporates material for all ages with a focus on K - 12. The AEI component is an animated story telling the fundamentals of how sunlight is turned into electricity and DRI‘s creation of Solar Green Boxes brings environmental education into the classroom. In addition to the educational component for the public, the energy that is created through the photovoltaic system also translates into saved money and health benefits for the general public. This project has helped Clark County to further add to its own energy reduction goals created by the energy management agenda (Resolution to Encourage Sustainability) and the County’s Eco-initiative. Each site has installed photovoltaic panels on the existing roof structures that exhibit suitable solar exposure. The generation systems utilize solar energy creating electricity used for the facility’s lighting system and other electrical requirements. Unused electricity is sent to the electric utility grid, often at peak demand times. Educational signage, kiosks and information have been included to inform and expand the public’s understanding of solar energy technology. The Solar Green Boxes were created for further hands on classroom education of solar power. In addition, data is sent by a Long Term PV performance monitoring system, complete with data transmission to NREL (National Renewable Energy Laboratory), located in Golden, CO. This system correlates local solar irradiance and weather with power production. The expected outcomes of this Solar Project are as follows: (1) Successful photovoltaic electricity generation technologies to capture solar energy in a useful form of electrical energy. (2) Reduction of greenhouse gas emissions and environmental degradation resulting from reduced energy demand from traditional electricity sources such as fossil fuel fired and nuclear power plants. (3) Advance the research and development of solar electricity generation. (4) The education of the general public in regards to the benefits of environmentally friendly electricity generation and Clark County’s efforts to encourage sustainable living practices. (5) To provide momentum for the nexus for future solar generation facilities in Clark County facilities and buildings and further the County’s energy reduction goals. (6) To ultimately contribute to the reduction of dependence on foreign oil and other unsustainable sources of energy. This Solar Project addresses several objectives and goals of the U.S. Department of Energy’s Solar Energy Technology Program. The project improves the integration and performance of solar electricity directly through implementation of cutting edge technology. The project further addresses this goal by laying important ground work and infrastructure for integration into the utility grid in future related projects. There will also be added security, reliability, and diversity to the energy system by providing and using reliable, secure, distributed electricity in Clark County facilities as well as sending such electricity back into the utility electric grid. A final major objective met by the Solar Project will be the displacement of energy derived by fossil fuels with clean renewable energy created by photovoltaic panels.

14 SOLAR ENERGY↗

DOE OSTI2016

Impacts of Federal Tax Credit Extensions on Renewable Deployment and Power Sector Emissions

Federal tax credits for renewable energy (RE) have served as one of the primary financial incentives for RE deployment over the last two decades in the United States. In December 2015, the wind power production tax credit and solar investment tax credits were extended for five years as part of the Consolidated Appropriations Act of 2016. This report explores the impact that these tax credit extensions might have on future RE capacity deployment and power sector carbon dioxide (CO2) emissions. The analysis examines the impacts of the tax credit extensions under two distinct natural gas price futures as natural gas prices have been key factors in influencing the economic competitiveness of new RE development. The analysis finds that, in both natural gas price futures, RE tax credit extensions can spur RE capacity investments at least through the early 2020s and can help lower emissions from the U.S. electricity system. More specifically, the RE tax credit extensions are estimated to drive a net peak increase of 48-53 GW in installed RE capacity in the early 2020s -- longer term impacts are less certain. In the longer term after the tax credits ramp down, greater RE capacity is driven by a combination of assumed RE cost declines, rising fossil fuel prices, and other clean energy policies such as the Clean Power Plan. The tax credit extension-driven acceleration in RE capacity development can reduce fossil fuel-based generation and lower electric sector CO2 emissions. Cumulative emissions reductions over a 15-year period (spanning 2016-2030) as a result of the tax credit extensions are estimated to range from 540 to 1420 million metric tonnes CO2. These findings suggest that tax credit extensions can have a measurable impact on future RE deployment and electric sector CO2 emissions under a range of natural gas price futures.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

DOE OSTI2015

Combined Heat and Power Market Potential for Opportunity Fuels

This report estimates the potential for opportunity fuel combined heat and power (CHP) applications in the United States, and provides estimates for the technical and economic market potential compared to those included in an earlier report. An opportunity fuel is any type of fuel that is not widely used when compared to traditional fossil fuels. Opportunity fuels primarily consist of biomass fuels, industrial waste products and fossil fuel derivatives. These fuels have the potential to be an economically viable source of power generation in various CHP applications.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

DOE OSTI2012

Life-Cycle Analysis of Alternative Aviation Fuels in GREET

The Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model, developed at Argonne National Laboratory, has been expanded to include well-to-wake (WTWa) analysis of aviation fuels and aircraft. This report documents the key WTWa stages and assumptions for fuels that represent alternatives to petroleum jet fuel. The aviation module in GREET consists of three spreadsheets that present detailed characterizations of well-to-pump and pump-to-wake parameters and WTWa results. By using the expanded GREET version (GREET1_2011), we estimate WTWa results for energy use (total, fossil, and petroleum energy) and greenhouse gas (GHG) emissions (carbon dioxide, methane, and nitrous oxide) for (1) each unit of energy (lower heating value) consumed by the aircraft or(2) each unit of distance traveled/ payload carried by the aircraft. The fuel pathways considered in this analysis include petroleum-based jet fuel from conventional and unconventional sources (i.e., oil sands); Fisher-Tropsch (FT) jet fuel from natural gas, coal, and biomass; bio-jet fuel from fast pyrolysis of cellulosic biomass; and bio-jet fuel from vegetable and algal oils, which falls under the American Society for Testing and Materials category of hydroprocessed esters and fatty acids. For aircraft operation, we considered six passenger aircraft classes and four freight aircraft classes in this analysis. Our analysis revealed that, depending on the feedstock source, the fuel conversion technology, and the allocation or displacement credit methodology applied to co-products, alternative bio-jet fuel pathways have the potential to reduce life-cycle GHG emissions by 55–85 percent compared with conventional (petroleum-based) jet fuel. Although producing FT jet fuel from fossil feedstock sources — such as natural gas and coal — could greatly reduce dependence on crude oil, production from such sources (especially coal) produces greater WTWa GHG emissions compared with petroleum jet fuel production unless carbon management practices, such as carbon capture and storage, are used.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2013

Final Performance Report

U.S./China Energy and Environmental Technology Center (EETC), Payson Center for International Development, Law School of Tulane University was officially established in 1997 with initial funds from private sector, US Environmental Protection Agency and the US Department of Energy (DOE.) Lately, DOE has provided EETC funds for operations with cost share from the Ministry of Science and Technology, China. EETC was created to facilitate the development of friendly, broad-based U.S./China relations. Tulane University signed the Memorandum of Understanding (MOU) with the Chinese People’s Institute of Foreign Affairs (1995) to promote the formation of Chinese partners for EETC. EETC’s original goal is to enhance the competitiveness of US clean fossil energy technology in China so that, as her economy expands, local and global environment are well protected. Specifically, through the demonstration and broadly deployment of US developed clean coal technology for power generation, transmission, and emission reductions in China. EETC is also focused on US industry partnerships for local economic development. One of the main the objectives of the EETC is to promote the efficient, responsible production and utilization of energy with a focus on clean fossil energy, promote US clean energy and environmental technologies, and encourage environmental performance while improving the quality of life in China. Another objective is to assist China with environmental and energy policy development and provide supports for China’s development with expertise (best practices) from US industry.

24 POWER TRANSMISSION AND DISTRIBUTION↗

DOE OSTI2016

Carbon Fiber from Biomass

Carbon fiber (CF), known also as graphite fiber, is a lightweight, strong, and flexible material used in both structural (load-bearing) and non-structural applications (e.g., thermal insulation). The high cost of precursors (the starting material used to make CF, which comes predominately from fossil sources) and manufacturing have kept CF a niche market with applications limited mostly to high-performance structural materials (e.g., aerospace). Alternative precursors to reduce CF cost and dependence on fossil sources have been investigated over the years, including biomass-derived precursors such as rayon, lignin, glycerol, and lignocellulosic sugars. The purpose of this study is to provide a comprehensive overview of CF precursors from biomass and their market potential. We examine the potential CF production from these precursors, the state of technology and applications, and the production cost (when data are available). We discuss their advantages and limitations. We also discuss the physical properties of biomass-based CF, and we compare them to those of polyacrylonitrile (PAN)-based CF. We also discuss manufacturing and end-product considerations for bio-based CF, as well as considerations for plant siting and biomass feedstock logistics, feedstock competition, and risk mitigation strategies. The main contribution of this study is that it provides detailed technical and market information about each bio-based CF precursor in one document while other studies focus on one precursor at a time or a particular topic (e.g., processing). Thus, this publication allows for a comprehensive view of the CF potential from all biomass sources and serves as a reference for both novice and experienced professionals interested in CF production from alternative sources.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

DOE OSTI2016

Accounting Methodology for Source Energy of Non-Combustible Renewable Electricity Generation

As non-combustible sources of renewable power (wind, solar, hydro, and geothermal) do not consume fuel, the “source” (or “primary”) energy from these sources cannot be accounted for in the same manner as it is for fossil fuel sources. The methodology chosen for these technologies is important as it affects the perception of the relative size of renewable source energy to fossil energy, affects estimates of source-based building energy use, and overall source energy based metrics such as energy productivity. This memo reviews the methodological choices, outlines implications of each choice, summarizes responses to a request for information on this topic, and presents guiding principles for the U.S. Department of Energy, (DOE) Office of Energy Efficiency and Renewable Energy (EERE) to use to determine where modifying the current renewable source energy accounting method used in EERE products and analyses would be appropriate to address the issues raised above.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

DOE OSTI2016

Absorbing Aerosols Workshop, January 20-21, 2016

A workshop was held at DOE Headquarters on January 20-21, 2016 during which experts within and outside DOE were brought together to identify knowledge gaps in modeling and measurement of the contribution of absorbing aerosols (AA) to radiative forcing. Absorbing aerosols refer to those aerosols that absorb light, whereby they both reduce the amount of sunlight reaching the surface (direct effect) and heat their surroundings. By doing so, they modify the vertical distribution of heat in the atmosphere and affect atmospheric thermodynamics and stability, possibly hastening cloud drop evaporation, and thereby affecting cloud amount, formation, dissipation and, ultimately, precipitation. Deposition of AA on snow and ice reduces surface albedo leading to accelerated melt. The most abundant AA type is black carbon (BC), which results from combustion of fossil fuel and biofuel. The other key AA types are brown carbon (BrC), which also results from combustion of fossil fuel and biofuel, and dust (crustal material). Each of these sources may result from, and be strongly influenced by, anthropogenic activities. The properties and amounts of AA depend upon various factors, primarily fuel source and burn conditions (e.g., internal combustion engine, flaming or smoldering wildfire), vegetation type (in the case of BC and BrC), and in the case of dust, soil type and ground cover (i.e., vegetation, snow, etc.). After emission, AA undergo chemical processing in the atmosphere that affects their physical and chemical properties. Thus, attribution of sources of AA, and understanding processes AA undergo during their atmospheric lifetimes, are necessary to understand how they will behave in a changing climate.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2017

2016 Billion-Ton Report: Advancing Domestic Resources for a Thriving Bioeconomy, Volume 2: Environmental Sustainability Effects of Select Scenarios from Volume 1

With the goal of understanding environmental effects of a growing bioeconomy, the U.S. Department of Energy (DOE), national laboratories, and U.S. Forest Service research laboratories, together with academic and industry collaborators, undertook a study to estimate environmental effects of potential biomass production scenarios in the United States, with an emphasis on agricultural and forest biomass. Potential effects investigated include changes in soil organic carbon (SOC), greenhouse gas (GHG) emissions, water quality and quantity, air emissions, and biodiversity. Effects of altered land-management regimes were analyzed based on select county-level biomass-production scenarios for 2017 and 2040 taken from the 2016 Billion-Ton Report: Advancing Domestic Resources for a Thriving Bioeconomy (BT16), volume 1, which assumes that the land bases for agricultural and forestry would not change over time. The scenarios reflect constraints on biomass supply (e.g., excluded areas; implementation of management practices; and consideration of food, feed, forage, and fiber demands and exports) that intend to address sustainability concerns. Nonetheless, both beneficial and adverse environmental effects might be expected. To characterize these potential effects, this research sought to estimate where and under what modeled scenarios or conditions positive and negative environmental effects could occur nationwide. The report also includes a discussion of land-use change (LUC) (i.e., land management change) assumptions associated with the scenario transitions (but not including analysis of indirect LUC [ILUC]), analyses of climate sensitivity of feedstock productivity under a set of potential scenarios, and a qualitative environmental effects analysis of algae production under carbon dioxide (CO2) co-location scenarios. Because BT16 biomass supplies are simulated independent of a defined end use, most analyses do not include benefits from displacing fossil fuels or other products, with the exception of including a few illustrative cases on potential reductions in GHG emissions and fossil energy consumption associated with using biomass supplies for fuel, power, heat, and chemicals.

09 BIOMASS FUELS↗

DOE OSTI2017

Carbon cycle dynamics within Oregon’s urban-suburban-forested-agricultural landscapes

Our overarching goal was to develop and utilize an observation-based analysis framework to assess interactions between climate and mosaics of land use, land cover and urbanization on regional carbon, water, and energy dynamics, and potential changes associated with land management and climate. Carbon, water and energy cycling was quantified for the range of current and potential land uses under present and future climates. The study region of Oregon has a strong climatic gradient from the coastal mesic forests (2500mm ppt) to the Willamette Valley, Cascade Mountains, and the Northern Great Basin semi-arid “cold desert” to the east (300 mm). The study was focused on the effects of (1) conversion of semi-arid sagebrush and Willamette Valley agricultural crops to bioenergy production; (2) afforestation of idle land and rangelands deemed suitable for forests or poplar crops under future climate conditions. We found that net ecosystem production (NEP), the net of ecosystem photosynthesis and respiration, was 10 times higher in the high biomass forests of the Coast Range compared with drier regions like sagebrush in the Northern Great Basin, which was nearly zero (Schmidt et al. 2016). The state total NEP averaged about 30 teragrams carbon (Tg C) per year for the years 2012 to 2014 using our model framework that we developed for predictions of current and future NEP, and compared well with our detailed inventory estimates (28 Tg C annual average for 2011-2015 for forests only; Law et al. 2017). Running our model framework until the year 2050, we found that climate alone only increased NEP by less than 1 Tg C per decade (~3%) using the current trajectory of carbon dioxide emissions, however, changes are expected to be more rapid in subsequent years. We evaluated the possibility of land use change from grass seed crops to poplar for bioenergy, which slightly increased NEP by 2050. The most important variable for carbon sequestration estimates (net carbon sources and sinks) is net ecosystem carbon balance (NECB), which accounts for NEP and losses associated with harvest removals and wildfire emissions. Here, we focus on forests because they have the largest effect on carbon sequestration. We found that NECB in Oregon averaged 18.8 Tg C per year in 2011-2015, offsetting fossil fuel emissions (16 Tg C per year). Annual fire emissions reducing NECB by about 5% (0.97 Tg C per year) in the state. The mesic Coast Range and West Cascades ecoregions that make up the western third of Oregon account for 60% of the forest NECB. This analysis illustrates that annual emissions from forests disturbances are low relative to annual fossil fuel emissions for the same area (Law et al. 2017, Hudiburg et al. in review).

09 BIOMASS FUELS↗

DOE OSTI2017

Demonstrating Hybrid Heat Transport and Energy Conversion System Performance Characterization Using Intelligent Control Systems

The debate continues on the magnitude and validity of climate change caused by human activities. However, there is no debate about the need to make buildings, modes of transportation, factories, and homes as energy efficient as possible. Given that climate change could occur with the wasteful use of fossil fuel and the fact that fossil energy costs could and will swing wildly, it is imperative that every effort be made to utilize energy sources to their fullest. Hybrid energy systems (HES) are two or more separate energy producers used together to produce energy commodities. The HES this report focuses on is the use of nuclear reactor waste heat as a source of further energy utilization. Nuclear reactors use a fluid to cool the core and produce the steam needed for the production of electricity. Traditionally this steam, or coolant, is used to convert the energy then cooled elsewhere. The heat is released into the environment without being used further. By adding technologies to nuclear reactors to use the wasted heat, a system can be developed to make more than just electricity and allow for loading following capabilities.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

DOE OSTI2018

GeoVision Analysis Supporting Task Force Report: Geothermal Hybrid Systems

This report documents findings from the Hybrid Systems Task Force of the U.S. Department of Energy's (DOE) Geothermal Technologies Office (GTO) Geothermal Vision Study (GeoVision Study). The GeoVision Study projects and quantifies the future electric and nonelectric deployment potentials of geothermal technologies within a range of scenarios in addition to their impacts on U.S. jobs, the economy, and environment. The Hybrid Systems Task Force is one of seven task forces within the GeoVision Study with the others being Exploration and Confirmation, Potential to Penetration, Thermal Applications, Reservoir Maintenance and Development, Institutional Market Barriers, and Social and Environmental Impacts. A summary of the study is captured in DOE’s report, GeoVision: Harnessing the Heat Beneath Our Feet. The Hybrid Systems Task Force investigated geothermal hybrid systems that have potential to increase the utilization of geothermal resources and/or decrease the costs of geothermal power generation. Applications evaluated include: hybrid thermal power generation in which geothermal energy is coupled with solar or fossil heat sources; use of geothermal energy to provide process heat for thermal desalination or CO 2 capture from fossil power plants; analysis of compressed air energy storage augmented with geothermal energy; as well as an assessment of potential mineral recovery from geothermal brines. This report additionally discusses areas of research and development that should be pursued to enhance the ability of geothermal hybrid systems to provide valuable benefits in operational flexibility, reduction of project risks, increased energy security, and the ability to recover critical and strategic materials.

15 GEOTHERMAL ENERGY↗

DOE OSTI2014

T-Q Diagram and Heat Source Assessment – Preliminary Evaluation

Presentation of a preliminary assessment of the fossil fuel heat sources for integration with the supercritical CO2 cycle: (1) PC, Air/Oxy, (2) CFB, Air/Oxy, (3) PFBC, Air/Oxy. It shows the development of T-Q diagrams to evaluate the effectiveness of various heat sources for the supercritical CO2 cycle. Heat sources include fossil fuels, Nuclear, and Solar. Conclusions include: (1) Current CFB (Air/Oxy) T-Q profile more suited to sCO2 cycle (for TIT < CFB furnace temperature), (2) PC/CFB design needs to be modified to take advantage of the high efficiency sCO2 cycle and (3) sCO2 cycle should be optimized to match the heat source better.

CFB↗

DOE OSTI2018

Final TCF Report for Earth Battery: Storing Energy with Compressed Air and Heated Brine in Porous Rock

Cost-effective reductions in greenhouse gas (GHG) emissions are best achieved when all low-carbon energy resources are fully utilized. This includes base-load power: nuclear energy (NE) and fossil energy (FE), integrated with CO 2 capture, use, and storage (CCUS), and variable renewable energy (VRE) (wind and solar); but, current CCUS options don’t justify CO 2 -capture costs and existing energy-storage approaches lack the capacity and storage duration needed to fully utilize all forms of low-carbon energy without curtailment. The Earth Battery is designed to meet these challenges by synergistically integrating conventional- and renewable-energy resources, allowing each to contribute more efficiently to the grid than if operated independently. The Earth Battery stores energy underground as pressure and heat, using compressed air and/or CO 2 , together with heated brine. These fluids are stored in either saline aquifers used for CO 2 or natural gas (NG) storage or in oil and gas reservoirs, making deployment possible over much of the U.S. We can provide enormous energy-storage capacity and duration. The main goal of this study was to assess the techno-economic feasibility of the versions of the Earth Battery that use compressed air energy storage (CAES). Current CAES systems use NG turbines and store air in salt caverns, which limits geographic deployment. Conventional CAES wastes much of the heat of air compression, comprising half of the compression energy. Our technology addresses these deficiencies by using permeable sedimentary rock to store air and the heat of compression as heated brine. When electricity is needed, air and hot brine are produced, with hot brine used to pre-heat air before it is fed into the expanders. Key factors affecting round-trip efficiency are (1) pressure loss in the air-storage reservoir, which depends on permeability (> 100 mD being needed for efficient operations) and (2) temperature loss in the hot-brine storage reservoir, which decreases with time as the storage formation heats up. The original scope of this project was to conduct a techno-economic assessment of diurnal storage with the CAES Earth Battery, including (1) Adiabatic CAES, which requires no fossil fuel and (2) NG/CAES, where one or more of the expansion stages are NG fueled. During its assessment, we found NG/CAES, generates excess heat of compression that can be put into long-term (seasonal) storage and be utilized in a combined-cycle fashion with the addition of steam turbines. This resulted in our developing a new Earth Battery technology, which we call the Thermal Earth Battery. We conducted energy-system analyses for the Thermal Earth Battery for various combinations of heat sources: (1) heat of FE combustion, (2) excess heat of compression from NG/CAES, and (3) solar thermal energy (STE). The other Earth Battery class we developed compresses CO 2 , rather than air; hence, it is called Compressed CO 2 Energy Storage (CCES). Finally, we developed an improved, more efficient, more versatile version of the Allam cycle, which uses pressurized CO 2 , and developed various options for integrating renewable energy and energy storage. Our improved Allam-cycle technology minimizes cooling-water consumption, while enabling reliable, dispatchable renewable energy. Although not anticipated in our original scope of work, our Topic 1 project evolved into a highly productive discovery process wherein we developed a portfolio of Earth Battery configuration options and use cases. Our ultimate objective was to evaluate those options and use cases and determine the most optimal first best use options for our Earth Battery technology. That process resulted in identifying seasonal energy storage as a niche where no other energy storage technology could compete with us. As a result, we have identified the Thermal Earth Battery, which uses conventional steam-turbine components, and our improved Allam-cycle integrated with renewable energy and energy storage as the most promising technologies to commercialize in our Topic 2 proposal. Finally, our scope included finding a commercialization team for a Topic 2 continuation of this project, which we have successfully completed.

25 ENERGY STORAGE↗

DOE OSTI2018

Supply Chain Sustainability Analysis of Renewable Hydrocarbon Fuels via Indirect Liquefaction, Ex Situ Catalytic Fast Pyrolysis, Hydrothermal Liquefaction, Combined Algal Processing, and Biochemical Conversion: Update of the 2018 State-of-Technology Cases and Design Cases

This technical report describes the SCSAs for the production of renewable hydrocarbon transportation fuels via a range of conversion technologies: (1) renewable high octane gasoline (HOG) via indirect liquefaction (IDL) of woody lignocellulosic biomass (note that the IDL pathway in this SCSA represents the syngas conversion design in the 2018 SOT and 2022 design cases [Tan et al., 2018]); (2) renewable gasoline (RG) and diesel (RD) blendstocks via ex situ catalytic fast pyrolysis of woody lignocellulosic biomass; (3) RD via hydrothermal liquefaction (HTL) of wet sludge from a wastewater treatment plant; (4) renewable hydrocarbon fuels via biochemical conversion of herbaceous lignocellulosic biomass; (5) renewable diesel via HTL of a blend of algae and woody biomass; and (6) renewable diesel via combined algae processing (CAP). This technical report focuses on the environmental performance of these six biofuel production pathways in their 2018 SOT cases, as well as in their design cases (future target projections). The results of these renewable hydrocarbon fuel pathways in these SCSA analyses update those for the respective 2015 and 2016 SOT cases (Edward Frank et al. 2016; Hao Cai et al. 2016, 2017; Cai et al. 2018) in the case of IDL, algae CAP, and biochemical conversion pathways. They also provide an opportunity to examine the impact of technology improvements in both biomass feedstock production and biofuel production that have been achieved in 2018 SOTs on the sustainability performance of these renewable transportation fuels, and they reflect updates to Argonne National Laboratory’s Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET®) model, which was released in October 2018 (Wang et al. 2018). These GREET updates include production of natural gas, electricity, and petroleum-based fuels that can influence biofuels’ supply chain greenhouse gas (GHG) (CO2, CH4, and N2O) emissions, water consumption and air pollutant emissions. GHG emissions, water consumption, and 2 nitrogen oxides (NOx) emissions are the main sustainability metrics assessed in this analysis. In this analysis, we define water consumption as the amount of water withdrawn from a freshwater source that is not returned (or returnable) to a freshwater source at the same level of quality. Life-cycle fossil energy consumption and net energy balance, which is the life-cycle fossil energy consumption deducted from the renewable biofuel energy produced, are also assessed.

02 PETROLEUM↗

DOE OSTI2020

Distributed fiber sensing systems for 3D combustion temperature field monitoring in coal-fired boilers using optically generated acoustic waves (Final Report)

In this project, we have developed and tested three kinds of fiber optic sensing systems for real time monitoring of temperature variations within an industrial scale boiler furnace. The fiber optic sensing systems target spatial and temporal distributions of high temperature profiles in a boiler furnace in fossil power plants. The reconstructed temperature profile will provide critical input for the control mechanisms to optimize the combustion process. This temperature profile will address the essential problem for fossil power plants in achieving higher efficiency and fewer pollutant emissions. Acoustic pyrometer systems have been used to reconstruct temperature field of power plant boilers based on measuring TOF (times-of-flight) of sound waves along some straight paths in a 2D cross-section of the boiler. In this project, optically generated acoustic signals from a fiber optic sensing system have replaced the acoustic signals generated from an electrical transducer. A 3D reconstruction algorithm replaced the previous 2D model. In this project, three kinds of fiber optic sensing systems have been developed and tested. They are fiber optic sensing system I, fiber optic sensing system II (Distributed Sensing System I) and fiber optic sensing system III (Distributed Sensing System II). For fiber optic sensing system I, the fiber optic ultrasound generator acts as a signal generator. A microphone, hydrophone or other electronic devices serve as a signal receiver. In this system, there are one generator and one receiver. Distance test, water temperature test, air temperature test, air temperature reconstruction, and GE ISBF pilot test were performed by Fiber optic sensing system I. The fiber optic sensing system I successfully detected temperature in all these tests. We got 2D temperature reconstruction results by using the fiber optic sensing system I and it matched the reference data. The fiber optic sensing system I successfully survived in GE ISBF boiler environment (480 °F). For fiber optic sensing system II (Distributed Sensing System I), it is an all optical ultrasound system. The fiber optic ultrasound generator acts as a signal generator. Fiber Bragg Grating (FBG) and Fabry-Perot (FP) sensor act as a signal receiver. In this system, there is one generator and one receiver. Aluminum plate temperature test, furnace high temperature test, and GE ISBF pilot test were performed by the fiber optic sensing system II. Fiber optic sensing system II successfully detected the temperature in all these tests. The fiber optic sensing system II successfully survived at up to 700 °C furnace environment and 320 °C GE ISBF boiler environment. For fiber optic sensing system III (Distributed Sensing System II), it is also an all optical ultrasound system. The fiber optic ultrasound generator acts as a signal generator. Multiple FP fiber sensors act as signal receivers. In this system, there is one generator and three receivers. Three GE ISBF pilot tests were performed by fiber optic sensing system III. The fiber optic sensing system III survived in the cold flow tests in GE’s ISBF pilot test facility. However, we didn’t get high temperature data by using this system since the nanosecond laser issues. During the period of the project, test trials, data simulation and algorithm optimization was performed successfully. For real time temperature field construction, the sampling rate must be fast enough to capture the field variations. The technology of Code-division multiple access (CDMA) is well studied which could allow parallel multiplexing, even if signals overlap in time or frequencies. Moreover, it has been known that extending the length of signal significantly improves SNR. For acoustic signals, these multiplexing techniques have also been widely used, mainly for sonar and acoustic communications. The CDMA modulation technique has been proposed and studied to guarantee high network throughput, low channel access delay and low energy consumption. We have studied the temperature field reconstruction using Gaussian Radial Basis Functions (GRBF)-based approximation approach. Reconstruction of 3D temperature field using Neural Networks with measured TOF and known propagation paths is feasible. 2D and 3D temperature field reconstruction simulation results are achieved. The milestone status is shown in Table 1. We finished milestone 1-8 and milestone 10. For milestone 9, we did three pilot tests by using the fiber optic sensing system III (Distributed Sensing System II) at GE Power. However, due to the failure of the ns laser, we did not get the temperature results. We conducted some additional tasks that were not originally proposed: 1) We fabricated a fiber optic sensing system I and did a pilot test based on this system. 2) In the proposal, we proposed two pilot tests at GE Power. In reality, we finished at least seven pilot tests at GE Power. GE Power has made a lot of efforts for supporting the pilot tests. 3) We got a simulation results based on CDMA. In summary, most of the tasks have been accomplished. The outcome of this project removed a few barriers that hinder the achievement of the final product of the distributed sensing systems. With the successful accomplishment of this project, a prototype of the fiber optic sensing system can be fabricated to attract more interests from companies and other funding agencies.

47 OTHER INSTRUMENTATION↗