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At least 1,027 records · Page 57

Iterating on a Design – Further Developments in the Evolution of the Ballistic Limit Equations for the Mars Sample Return Project

The goal of the Mars Sample Return–Capture, Containment, and Return System Project is to retrieve samples launched from the Martian surface and return them to Earth for detailed analysis. An important part of this project is the design of the system’s micrometeoroid protection system, which protects the Earth Entry System and the collected samples during their journey back to Earth. As mission parameters and the micrometeoroid and orbital debris threat became better understood, the design of the micrometeoroid protection system evolved. A key element used in the shield development process is the ballistic limit equation, which is an equation that is used to determine whether or not a particular structural element or system will end up in a failed state as a result of a specified impact. As the design of the Earth Entry System and the micrometeoroid protection system evolved, a new set of ballistic limit equations was needed to better predict and assess the performance of developing shield system designs in anticipation of possible damage from micrometeoroid and orbital debris particle impacts. This paper provides a summary of how a set of initial BLEs were either extended or modified so that the resulting equations were better suited to new types of target configurations being considered, as well as how additional ballistic limit equations were developed where none previously existed.

William P Schonberg↗

Exciton relaxation in carbon nanotubes via electronic-to-vibrational energy transfer

Covalent functionalization of semiconducting single-wall carbon nanotubes (CNTs) introduces new photoluminescent emitting states. These states are spatially localized around functionalization sites and strongly red-shifted relative to the emission commonly observed from the CNT band-edge exciton state. A particularly important feature of these localized exciton states is that because the exciton is no longer free to diffusively sample photoluminescent quenching sites along the CNT length, its lifetime is significantly extended. We have recently demonstrated that an important relaxation channel of such localized excitons is the electronic-to-vibrational energy transfer (EVET). This process is analogous to the Förster resonance energy transfer except the final state of this process is not electronically, but vibrationally excited molecules of the surrounding medium (e.g., solvent). In this work, we develop a theory of EVET for a nanostructure of arbitrary shape and apply it to the specific case of EVET-mediated relaxation of defect-localized excitons in a covalently functionalized CNT. Here, the resulting EVET relaxation times are in good agreement with experimental data.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Evidence for Impact Shock Melting in CM and CI Chondrite Regolith Samples

C class asteroids frequently exhibit reflectance spectra consistent with thermally metamorphosed carbonaceous chondrites, or a mixture of phyllosilicate-rich material along with regions where they are absent. One particularly important example appears to be near-Earth asteroid 1999 JU3, the target of the Hayabusa II sample return mission [1], although not all spectra indicate this. In fact most spectra of 1999 JU3 are featureless, suggesting a heterogeneous regolith. Here we explore an alternative cause of dehydration of regolith of C class asteroids - impact shock melting. Impact shock melting has been proposed to explain some mineralogical characteristics of CB chondrites, but has not been considered a major process for hydrous carbonaceous chondrites. What evidence is there for significant shock melting in the very abundant CMs, or less abundant but still important CI chondrites?

Zolensky, Michael↗

Regional and Localized Deposits on the Moon

Earth-based telescopic remote sensing studies have provided important information concerning lunar pyroclastic deposits. Combined with the returned lunar sample studies and analyses of lunar photography, we have learned a great deal about the nature and origin of these explosive volcanic materials. Lunar pyroclastic deposits are more numerous, extensive, and widely distributed than previously thought. Two generic classes of lunar pyroclastics have been identified, regional and localized. From the former, two separate spectral compositional groups have been identified; one is dominated by Fe(2+)-bearing glasses, the other is composed of ilmenite-rich black spheres. Comparatively, three separate spectral groups have been identified among the localized deposits: highlands-rich, olivine-rich, and mare-rich. Returned sample studies and the recently collected Galileo and Clementine data also corroborate these findings. Albedo data and multispectral imagery suggest that the thicker core deposits of the regional dark mantle deposits (RDMD) are surrounded by pyroclastic debris and subjacent highlands material. The presence of a major component of pyroclastic debris in the regolith surrounding the core regional deposits has important implications for the resource potential of these materials. Both telescopic and orbital spectra indicate that the regional pyroclastic deposits are rich in iron, titanium and oxygen-bearing minerals. Particle shapes vary from simple glass spheres to compound droplets with quench crystallized textures. Their small grain size and friability make them ideal indigenous feedstock. Compared to other resource feedstock sources on the Moon, these pyroclastic materials may be the best oxygen resource on the Moon.

Coombs, Cassandra R.↗

SPADE: A Rock Crushing and Sample Handling System Developed for Mars Missions

Access to the interior of rocks on Mars is an important goal for understanding Mars petrology and geologic history. The spectral signature of the potentially diverse mineralogy of rocks on Mars is veiled by the ubiquitous dust and may be further hidden by weathered rind. We have developed a rock crusher and sample distribution system under the auspices of NASA s PIDDP program. We call it the SPADE : the Sample Processing and Distribution Experiment. Its purpose is to access the interiors of rocks on Mars and prepare samples for analysis by a suite of in situ instruments.

Hansen, Candice J.↗

Complete resolution across the neodymium/samarium isotopic envelope with a liquid sampling‐atmospheric pressure glow discharge — Orbitrap mass spectrometer

Rationale Nd and Sm isotope ratios play an important role in geological dating and as nuclear forensic signatures; however, the overlap of the respective 144, 148, 150 Nd/Sm isobars requires prior separations to be performed before analysis on typical MS platforms. The work presented here overcomes these isobaric interferences using ultrahigh‐mass resolution to alleviate interference without prior chemical separations. Methods A liquid sampling‐atmospheric pressure glow discharge ion source was coupled to a standard, QExactive Focus Orbitrap mass spectrometer, providing a mass resolution of ~80 k. A Spectroswiss FTMS booster X2 data acquisition package was used to collect extended transients, providing much higher mass resolution; ~230 k and ~600 k are employed here for Nd and Sm isotopes. Results While the standard Orbitrap resolution is far greater than typical “atomic” MS platforms, it was insufficient to alleviate all isobars. The use of a resolution of ~230 k resulted in baseline separation across the entire isotopic envelope for both Nd and Sm. Isotope ratios obtained from Nd:Sm mixtures using high‐resolution were equivalent to those found for individual‐element solutions, while isotope ratios obtained at a resolution of ~80 k (standard for the OEM data system) showed large deviations. Conclusions Use of ultrahigh‐resolution is an attractive alternative to extensive chemical separations to alleviate severe isobaric interferences. Sufficient mass resolution greatly reduces/eliminates the need for sample manipulations (separations) before analysis while reducing costs and total analysis times.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A Numerical Climate Observing Network Design Study

This project was concerned with three related questions of an optimal design of a climate observing system: 1. The spatial sampling characteristics required from an ARGO system. 2. The degree to which surface observations from ARGO can be used to calibrate and test satellite remote sensing observations of sea surface salinity (SSS) as it is anticipated now. 3. The more general design of an climate observing system as it is required in the near future for CLIVAR in the Atlantic. An important question in implementing an observing system is that of the sampling density required to observe climate-related variations in the ocean. For that purpose this project was concerned with the sampling requirements for the ARGO float system, but investigated also other elements of a climate observing system. As part of this project we studied the horizontal and vertical sampling characteristics of a global ARGO system which is required to make it fully complementary to altimeter data with the goal to capture climate related variations on large spatial scales (less thanAttachment: 1000 km). We addressed this question in the framework of a numerical model study in the North Atlantic with an 1/6 horizontal resolution. The advantage of a numerical design study is the knowledge of the full model state. Sampled by a synthetic float array, model results will therefore allow to test and improve existing deployment strategies with the goal to make the system as optimal and cost-efficient as possible. Attachment: "Optimal observations for variational data assimilation".

Stammer, Detlef↗

Effect of non-Poisson samples on turbulence spectra from laser velocimetry

Spectral analysis of laser velocimetry (LV) data plays an important role in characterizing a turbulent flow and in estimating the associated turbulence scales, which can be helpful in validating theoretical and numerical turbulence models. The determination of turbulence scales is critically dependent on the accuracy of the spectral estimates. Spectral estimations from 'individual realization' laser velocimetry data are typically based on the assumption of a Poisson sampling process. What this Note has demonstrated is that the sampling distribution must be considered before spectral estimates are used to infer turbulence scales.

Sree, Dave↗

Mechanical properties and morphology of poly(etheretherKetone)

Mechanical properties and morphology of poly(etheretherketone) (PEEK) were studied for samples having different thermal histories. Isothermal and rate-dependent crystallization were studied to ascertain the relationship between crystallinity/morphology and processing condition. Degree of crystallinity and microstructure were controlled by cooling the melt at different rates, ranging from quenching to slowly cooling, and by annealing amorphous material above the glass transition temperature Tg. It is found that degree of crystallinity was not as important as processing history in determining the room temperature mechanical properties. Samples with the same degree of crystallinity had very different tensile properties, depending on rate of cooling from the melt. All samples yielded by shear band formation and necked down. Quenched films had the largest breaking strains, drawing to 270 percent. Slowly cooled films exhibited ductile failure at relatively low strains. Best combined mechanical properties were obtained from semicrystalline films cooled at intermediate rates from the melt.

Cebe, Peggy↗

Planetary Protection, Sample Return Missions and Mars Exploration: History, Status, and Future Needs

As the prospect grows for a Mars sample return mission early in the next millennium, it will be important to ensure that appropriate planetary protection (PP) controls are incorporated into the mission design and implementation from the start. The need for these PP controls is firmly based on scientific considerations and backed by a number of national and international agreements and guidelines aimed at preventing harmful cross contamination of planets and extraterrestrial bodies. The historical precedent for the use of PP measures on both unmanned and manned missions traces from post-Sputnik missions to the present, with periodic modifications as new information was obtained. In consideration of the anticipated attention to PP questions by both the scientific/technical community and the public, this paper presents a comprehensive review of the major issues and problems surrounding PP for a Mars Sample Return (MSR) mission, including an analysis of arguments that have been raised for and against the imposition of PP measures. Also discussed are the history and foundations for PP policies and requirements; important research areas needing attention prior to defining detailed PP requirements for a MSR mission; and legal and public awareness issues that must be considered with mission planning.

DeVincenzi, Donald L.↗

Planetary Protection, Sample Return Missions and Mars Exploration: History, Status, and Future Needs

As the prospect grows for a Mars sample return mission early in the next millennium, it will be important to ensure that appropriate planetary protection (PP) controls are incorporated into the mission design and implementation from the start. The need for these PP controls is firmly based on scientific considerations and backed by a number of national and international agreements and guidelines aimed at preventing harmful cross contamination of planets and extraterrestrial bodies. The historical precedent for the use of PP measures on both unmanned and manned missions traces from post-Sputnik missions to the present, with periodic modifications as new information was obtained. In consideration of the anticipated attention to PP questions by both the scientific/technical community and the public, this paper presents a comprehensive review of the major issues and problems surrounding PP for a Mars Sample Return (MSR) mission, including an analysis of arguments that have been raised for and against the imposition of PP measures. Also discussed are the history and foundations for PP policies and requirements; important research areas needing attention prior to defining detailed PP requirements for a MSR mission; and legal and public awareness issues that must be considered with mission planning.

DeVincenzi, Donald L.↗

Analysis of new measurements of Calvert Cliffs spent fuel samples using SCALE 6.2

High quality experimental data for isotopic compositions in irradiated fuel are important to spent fuel applications, including nuclear safeguards, spent fuel storage, transportation, and final disposal. The importance of these data has been increasingly recognized in recent years, particularly as countries like Finland and Sweden plan to open the world’s first two spent fuel geological repositories in 2020s, while other countries, including the United States, are considering extended dry fuel storage options. Destructive and nondestructive measurements of a spent fuel rod segment from a Combustion Engineering 14 × 14 fuel assembly of the Calvert Cliffs Unit 1 nuclear reactor have been recently performed at Oak Ridge National Laboratory (ORNL). These ORNL measurements included two samples selected from adjacent axial locations of a fuel rod with initial enrichment of 3.038 wt% 235 U, which achieved burnups close to 43.5 GWd/MTU. More than 50 different isotopes of 16 elements were measured using high precision measurement methods. Various investigations have assessed the quality of the new ORNL measurement data, including comparison to previous measurements and to calculation results. Previous measurement data for samples from the same fuel rod measured at ORNL are available from experiments performed at Pacific Northwest National Laboratory in the United States and the Khoplin Radium Institute in Russia. Detailed assembly models were developed using the newly released SCALE 6.2 code package to simulate depletion and decay of the measured fuel samples. Furthermore, results from this work show that the new ORNL measurements provide a good quality radiochemical assay data set for spent fuel with relatively high burnup and long cooling time, and they can serve as good benchmark data for nuclear burnup code validation and spent fuel studies.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Determination of U, V, and W from single station Doppler radar radial velocities

The ST/MST (stratosphere troposphere/mesosphere stratosphere troposphere) clear air Doppler radar, or wind profiler, is an important tool in observational meteorology because of its capability to remote observe dynamic parameters of the atmosphere. There are difficulties in transforming the observed radial velocities into meteorological wind components. How this problem has been treated in the past is reviewed, and some of the analysis is recast to a form more suited to the high diagnostic abilities of a number of fixed beam configurations with reference to a linear wind field. The results, in conjunction with other works which treats problems such as the effects of finite sample volumes in the presence of nonhomogeneous atmospheric reflectivity, have implications important to the design of both individual MST/ST radars and MST/ST radar networks. The key parameters to uncoupling terms in the scaling equations are w sub x and w sub y. Whenever the stratiform condition, which states that these two parameters are negligible, is satisfied, a five beam ST radar may determine unbiased values of u, v, and w for sample volumes directly above the radar. The divergence and partial deformation of the flow may also be determined. Three beam systems can determine w and w sub z, but are unable to obtain u and v wind components uncontaminated by vertical sheer terms, even when the stratiform condition is satisfied.

Clark, W. L.↗

Maneuver Design and Calibration for the Genesis Spacecraft

Genesis is the fifth mission selected as part of NASA's Discovery Program. The objective of Genesis is to collect solar wind samples for a period of approximately two years while in a halo orbit about the Earth-Sun L I point. At the end of this period, the samples are to be returned to a specific recovery point on the Earth for subsequent analysis. This goal has never been attempted before and presents a formidable challenge in terms of mission design and operations, particularly planning and execution of propulsive maneuvers. To achieve a level of cost-effectiveness consistent with a Discovery-class mission, the Genesis spacecraft design was adapted to the maximum extent possible from designs used on earlier missions, such as Mars Global Surveyor (MGS) and Stardust, another sample collection mission. The spacecraft design for Genesis is shown. Spin stabilization was chosen for attitude control, in lieu of three-axis stabilization, with neither reaction wheels nor accelerometers included. This precludes closed-loop control of propulsive maneuvers and implies that any attitude changes, including spin changes and precessions, will behave like translational propulsive maneuvers and affect the spacecraft trajectory. Moreover, to minimize contamination risk to the samples collected, all thrusters were placed on the side opposite the sample collection canister. The orientation and characteristics of thrusters are indicated. For large maneuvers (>2.5 m/s), two 5 lbf thrusters will be used for delta v, with precession to the burn attitude, followed by spin-up from 1.6 to 10 rpm before the burn and spin down to 1.6 rpm afterwards, then precession back to the original spin attitude. For small maneuvers (<2.5 m/s), no spin change is needed and four 0.2 lbf thrusters are used for Av. Single or double 360 deg. precession changes are required whenever the desired delta v falls inside the two-way turn circle (about 0.4 m/s) based on the mass properties, spin rate and lever arm lengths based on thruster locations. In such instances, delta v resulting from spacecraft precession cannot be used effectively as a component of the desired delta v, and must therefore be removed by precessing at least one complete revolution around the turn circle. To eliminate cross-track execution errors, a second revolution in the opposite direction would also be performed. This paper will address the design of propulsive maneuvers in light of the aforementioned challenges and other constraints. Maneuver design will be performed jointly by the Navigation Team at JPL and the Spacecraft Team at LMA, based on the process indicated . Typical maneuver timelines will be presented which address considerations introduced by attitude changes. These include nutation, which is introduced by precessing or spinning down and must be given sufficient time to damp out prior to execution of subsequent events, as well as sun and earth pointing constraints, which must be considered to ensure sufficient spacecraft power and to minimize telecommunications interruptions, respectively. The paper will include a description of how individual propulsive maneuvers are resolved into components to account for delta v from translational burns and spacecraft attitude changes required to carry out such maneuvers. Contributions to maneuver delta v arising from attitude changes, based on mass properties for the period just after launch, are indicated. Similar curves will be presented spanning all mission phases from launch through return. A set of closed-form equations for resolving maneuver components, base on a specific delta v required for correction or deterministic changes to the spacecraft trajectory will be presented, as well. In addition to nominal maneuvers, special calibration maneuvers are planned to improve open-loop modeling of maneuvers and to reduce execution errors. Uncalibrated execution errors are indicated. Such errors could be reduced by 50% or more over the course of the mission. Special calibrations are of particular importance for the return leg of the mission, since the sample canister must be returned to a specific location within the Utah Test and Training Range (UTTR) for mid-air retrieval. An entry angle tolerance of no less than +/- 0.08 deg. is required to achieve this objective. Biasing of the final return maneuvers coupled with a specific maneuver mode to use a series of well-characterized spin changes to effect these maneuvers is part of the current Genesis baseline mission plan. Another important objective of calibrations is to better characterize precession maneuvers. Such maneuvers are part of most propulsive maneuvers, but are also required periodically to maintain sun-pointing for power or daily during solar-wind pointing during collection periods. Although relatively small, such maneuvers will have a significant cumulative impact on orbit determination, particularly in the halo portion of the mission. The current mission design also calls for three stationkeeping maneuvers during each halo orbit of approximately six months duration. These stationkeeping maneuvers may be sufficiently small that single or double 360 deg. precession changes may be required. Because there are no accelerometers on board the spacecraft, calibration can only be performed with the aid of ground-based radiometric tracking. To establish a high degree of accuracy in characterizing the magnitude of burns, the spacecraft spin axis should be along the line of sight to the Earth, providing Doppler measurements with <1 mm/sec accuracy in S-Band. Emission constraints allow such alignment only during certain portions of the mission when the Earth-spacecraft-sun geometry is favorable. The impact of precessions, or burns at times when geometry is not favorable, can be assessed by reconstruction of the spacecraft trajectory using tracking arcs of several days before and after the event.

Williams, Kenneth E.↗

Petrologic constraints on the pressure, temperature, time and composition of the Martian interior

Petrologic analysis of surface samples has been used to deduce pressure and temperature conditions existing in the crust and upper mantle at specific times in the Earth's history, as well as to estimate the chemical and mineralogical composition of the crust and upper mantle. The same techniques can be applied to samples of the Martian surface to provide P, T, time and composition constraints of the Martian interior. Estimates of P and T conditions existing at a given time would, in turn, provide strong constraints on the thermal evolution of Mars. Knowledge of the chemical and mineralogical composition of the Martian interior is of fundamental importance in assessing the early history of the solar system. A general petrological approach is outlined, describing the kinds of sample required, summarizing current understanding of the Martian interior based on experimental petrology, and outlining some of the important experiments needed to allow a full petrologic interpretation of Martian samples.

Holloway, John R.↗

Neutron imaging analysis using jupyter Python notebook

Abstract Independently of the image modality (x-rays, neutrons, etc), image data analysis requires normalization, a preprocessing step. While the normalization can sometimes easily be generalized, the analysis is, in most cases, specific to an experiment and a sample. Although many tools (MATLAB, ImageJ, VG Studio…) offer a large collection of pre-programmed image analysis tools, they usually require a learning step that can be lengthy depending on the skills of the end user. We have implemented Jupyter Python notebooks to allow easy and straightforward data analysis, along with live interaction with the data. Jupyter notebooks require little programming knowledge and the steep learning curve is bypassed. Most importantly, each notebook can be tailored to a specific experiment and sample with minimized effort. Here, we present the pros and cons of the main methods to analyse data and show the reason why we have found that Jupyter Python notebooks are well suited for imaging data processing, visualization and analysis.

Bilheux, Jean-Christophe (ORCID:0000000321726487)↗

ROSAT Observations of a Complete Nearby Sample of Low Luminosity Radio Galaxies

We are studying the X-ray emission in a sample of nearby radio galaxies. The X-rays probe several important components: (1) the active galactic nuclei; (2) the interstellar medium of the host galaxy; and (3) the intergalactic or intracluster medium through which the jets propagate. The interaction of the radio plasma with the hot ambient gas will allow us to constrain the properties of the environments and the energetics of the radio source propagation. We have made excellent progress reducing the ROSAT new and archival data on our complete sample of nearby radio galaxies. The data reduction has taken longer than originally anticipated because we have identified bubbles of x-ray emission around many of the central galaxies and we have been exploring many different methodologies for assuring the results are robust before we publish and complete our interpretation. We have now begun the final phases of the work, with a draft paper under construction and a planned for submission date of early 2001. This work comprises 1/3 of the thesis work of a graduate student and will be the final phase in the completion of the thesis.

Baum, Stefi↗

Grover-QAOA for 3-SAT: quadratic speedup, fair-sampling, and parameter clustering

Abstract The SAT problem is a prototypical NP-complete problem of fundamental importance in computational complexity theory with many applications in science and engineering; as such, it has long served as an essential benchmark for classical and quantum algorithms. This study shows numerical evidence for a quadratic speedup of the Grover Quantum Approximate Optimization Algorithm (G-QAOA) over random sampling for finding all solutions to 3-SAT (All-SAT) and Max-SAT problems. G-QAOA is less resource-intensive and more adaptable for these problems than Grover’s algorithm, and it surpasses conventional QAOA in its ability to sample all solutions. We show these benefits by classical simulations of many-round G-QAOA on thousands of random 3-SAT instances. We also observe G-QAOA advantages on the IonQ Aria quantum computer for small instances, finding that current hardware suffices to determine and sample all solutions. Interestingly, a single-angle-pair constraint that uses the same pair of angles at each G-QAOA round greatly reduces the classical computational overhead of optimizing the G-QAOA angles while preserving its quadratic speedup. We also find parameter clustering of the angles. The single-angle-pair protocol and parameter clustering significantly reduce obstacles to classical optimization of the G-QAOA angles.

Zhang, Zewen (ORCID:000000032258613X)↗