Search NASA⌕ Search

SEARCH · Search NASA

Results for “Process Sample Analysis”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,027 records · Page 57

A versatile system for biological and soil chemical tests on a planetary landing craft. I - Scientific objectives

We describe an approach for the remote detection and characterization of life in planetary soil samples. A mass spectrometer is used as the central sensor to monitor changes in the gas phase in eleven test cells filled with soil. Many biological assays, ranging from general 'in situ' assays to specific metabolic processes (such as photosynthesis, respiration, denitrification, etc.) can be performed by appropriate additions to the test cell via attached preloaded injector capsules. The system is also compatible with a number of chemical assays such as the analysis of atmospheric composition (both chemical and isotopic), the status of soil water, and the determination of compounds of carbon, nitrogen and sulfur in the soil.

Radmer, R. J.↗

Validating spatial structure in canopy water content using geostatistics

Heterogeneity in ecological phenomena are scale dependent and affect the hierarchical structure of image data. AVIRIS pixels average reflectance produced by complex absorption and scattering interactions between biogeochemical composition, canopy architecture, view and illumination angles, species distributions, and plant cover as well as other factors. These scales affect validation of pixel reflectance, typically performed by relating pixel spectra to ground measurements acquired at scales of 1m(exp 2) or less (e.g., field spectra, foilage and soil samples, etc.). As image analysis becomes more sophisticated, such as those for detection of canopy chemistry, better validation becomes a critical problem. This paper presents a methodology for bridging between point measurements and pixels using geostatistics. Geostatistics have been extensively used in geological or hydrogeolocial studies but have received little application in ecological studies. The key criteria for kriging estimation is that the phenomena varies in space and that an underlying controlling process produces spatial correlation between the measured data points. Ecological variation meets this requirement because communities vary along environmental gradients like soil moisture, nutrient availability, or topography.

Sanderson, E. W.↗

Development of an Integrated Rocket Thrust Chamber Assembly Analysis and Design Toolkit (TCAT)

There are many individual computational tools and methods used to analyze and design components of a rocket engine thrust chamber assembly (TCA) 11,21. To analyze and design a thrust chamber assembly these tools are usually used in sequence while communication of information between these tools is usually done manually. Each component of a TCA is usually designed and optimized individually with limited considerations on system optimized design. This approach is often iterative and can be prone to error. Also at present, expert knowledge of each tool is required. The objective of this software development effort is to select, integrate and automate the best tools into an easy-to-use computational package, the Thrust Chamber Analysis Toolkit (TCAT). This tool will provide a seamless process to analyze and design all or individual components of a thrust chamber assembly. This paper describes the current status of the MAT software development. The selected component codes and their capabilities are briefly described. User and module interfaces and integration status are presented. MAT pre- and post-processing added options are presented and overall MAT capabilities are demonstrated with the results of sample cases. Ongoing and planned model validation efforts are also described. Finally, the MAT future plan options are discussed.

Farhangi, S.↗

Improvements to the Two-Thickness Method for Deriving Acoustic Properties of Materials

The characteristic impedance and other derivative acoustic properties of a material can be derived from impedance tube data using the specific impedance measured from samples with two different thicknesses. In practice, samples are chosen so that their respective thicknesses differ by a factor of 2. This simplifies the solution of the equations relating the properties of the two samples so that the computation of the characteristic impedance is straightforward. This approach has at least two drawbacks. One is that it is often difficult to acquire or produce samples with precisely a factor of 2 difference in thickness. A second drawback is that the phase information contained in the imaginary part of the propagation constant must be unwrapped before subsequent computations are performed. For well-behaved samples, this is not a problem. For ill behaved samples of unknown properties, the phase unwrapping process can be tedious and difficult to automate. Two alternative approaches have been evaluated which remove the factor-of-2 sample thickness requirement and directly compute unwrapped phase angles. One uses a Newton-Raphson approach to solve for the roots of the samples' simultaneous equations. The other produces a wave number space diagram in which the roots are clearly discernable and easily extracted. Results are presented which illustrate the flexibility of analysis provided by the new approaches and how this can be used to better understand the limitations of the impedance tube data.

Palumbo, Daniel L.↗

Development of an Open Rotor Cycle Model in NPSS Using a Multi-Design Point Approach

NASA's Environmentally Responsible Aviation Project and Subsonic Fixed Wing Project are focused on developing concepts and technologies which may enable dramatic reductions to the environmental impact of future generation subsonic aircraft (Refs. 1 and 2). The open rotor concept (also referred to as the Unducted Fan or advanced turboprop) may allow the achievement of this objective by reducing engine emissions and fuel consumption. To evaluate its potential impact, an open rotor cycle modeling capability is needed. This paper presents the initial development of an open rotor cycle model in the Numerical Propulsion System Simulation (NPSS) computer program which can then be used to evaluate the potential benefit of this engine. The development of this open rotor model necessitated addressing two modeling needs within NPSS. First, a method for evaluating the performance of counter-rotating propellers was needed. Therefore, a new counter-rotating propeller NPSS component was created. This component uses propeller performance maps developed from historic counter-rotating propeller experiments to determine the thrust delivered and power required. Second, several methods for modeling a counter-rotating power turbine within NPSS were explored. These techniques used several combinations of turbine components within NPSS to provide the necessary power to the propellers. Ultimately, a single turbine component with a conventional turbine map was selected. Using these modeling enhancements, an open rotor cycle model was developed in NPSS using a multi-design point approach. The multi-design point (MDP) approach improves the engine cycle analysis process by making it easier to properly size the engine to meet a variety of thrust targets throughout the flight envelope. A number of design points are considered including an aerodynamic design point, sea-level static, takeoff and top of climb. The development of this MDP model was also enabled by the selection of a simple power management scheme which schedules propeller blade angles with the freestream Mach number. Finally, sample open rotor performance results and areas for further model improvements are presented.

Hendricks, Eric S.↗

Getting Out of Orbit: Water Recycling Requirements and Technology Needs for Long Duration Missions Away from Earth

Deep-space crewed missions will not have regular access to the Earth's resources or the ability to rapidly return to Earth if a system fails. As crewed missions extend farther from Earth for longer periods, habitation systems must become more self-sufficient and reliable for safe, healthy, and sustainable human exploration. For human missions to Mars, Environmental Control and Life Support Systems (ECLSS) must be able operate for up to 1,100 days with minimal spares and consumables. These missions will require capabilities to more fully recycle atmospheric gases and wastewater to substantially reduce mission costs. Even with relatively austere requirements for use, water represents one of the largest consumables by mass. Systems must be available to extract and recycle water from all sources of waste. And given that there will be no opportunity to send samples back to Earth for analysis, analytical measurements will be limited to monitoring hardware brought on board the spacecraft. The Earth Reliant phase of NASA's exploration strategy includes leveraging the International Space Station (ISS) to demonstrate advanced capabilities for a robust and reliable ECLSS. The ISS Water Recovery System (WRS) includes a Urine Processor Assembly (UPA) for distillation and recovery of water from urine and a Water Processor Assembly (WPA) to process humidity condensate and urine distillate into potable water. Possible enhancements to more fully "close the water loop" include recovery of water from waste brines and solid wastes. A possible game changer is the recovery of water from local planetary resources through use of In Situ Resource Utilization (ISRU) technologies. As part of the development and demonstration sequence, NASA intends to utilize cis-Lunar space as a Proving Ground to verify systems for deep space habitation by conducting extended duration missions to validate our readiness for Mars.

Barta, Daniel J.↗

Polar Resources Ice Mining Experiment-1 (PRIME-1) NASA’s First Polar Drilling and Volatiles Detection Mission

The US Administration announced in 2019 that NASA would return to the Moon where it would seek to establish a sustainable lunar presence. In Situ Resource Utilization (ISRU) is needed to sustain and grow hu-man surface exploration and it is therefore a vital part of ensuring this bold endeavor. ISRU requires ground-truth on physical, mineral, and volatile characteristics of the resources. Water, a key and game-changing resource, exists in the polar regions of the Moon. Learning to harvest and use this resource first requires understanding where the resource is abundantly located and on what scales. Harvested water, which is usable for life support and fuel, must be identified, quantified, and assessed for its mining feasibility. The project goal for PRIME-1 is to develop a flight-ready instrumentation package that can assess the volatiles at a polar lunar landing location. PRIME-1 is the combination of two instruments; Mass Spectrometer observing lunar operations (MSolo) and The Regolith and Ice Drill for Exploring New Terrain (TRIDENT). TRIDENT is an 1-meter augering drill capable of bringing incremental lunar regolith samples to the surface for volatile analysis. MSolo is a modified, commercial-off-the-shelf (COTS) mass spectrometer capable of qualifying and quantifying atomic species in the 1-100 amu range, including isotopic differentiation. These two lunar flight instruments operating together make up the PRIME-1 instrument suite. PRIME-1 intends to fly on and operate from a static lunar lander acquired by the NASA Commercial Lunar Payload Services (CLPS) acquisition process. The PRIME-1 payload suite was selected to fly on Intuitive Machines Nova-C lander, and is currently targeting a late Fall 2023 landing attempt.

MSolo↗

Polar Resources Ice Mining Experiment-1 (PRIME-1) NASA’s First Polar Drilling and Volatiles Detection Mission

The US Administration announced in 2019 that NASA would return to the Moon where it would seek to establish a sustainable lunar presence. In Situ Resource Utilization (ISRU) is needed to sustain and grow hu-man surface exploration and it is therefore a vital part of ensuring this bold endeavor. ISRU requires ground-truth on physical, mineral, and volatile characteristics of the resources. Water, a key and game-changing resource, exists in the polar regions of the Moon. Learning to harvest and use this resource first requires understanding where the resource is abundantly located and on what scales. Harvested water, which is usable for life support and fuel, must be identified, quantified, and assessed for its mining feasibility. The project goal for PRIME-1 is to develop a flight-ready instrumentation package that can assess the volatiles at a polar lunar landing location. PRIME-1 is the combination of two instruments; Mass Spectrometer observing lunar operations (MSolo) and The Regolith and Ice Drill for Exploring New Terrain (TRIDENT). TRIDENT is an 1-meter augering drill capable of bringing incremental lunar regolith samples to the surface for volatile analysis. MSolo is a modified, commercial-off-the-shelf (COTS) mass spectrometer capable of qualifying and quantifying atomic species in the 1-100 amu range, including isotopic differentiation. These two lunar flight instruments operating together make up the PRIME-1 instrument suite. PRIME-1 intends to fly on and operate from a static lunar lander acquired by the NASA Commercial Lunar Payload Services (CLPS) acquisition process. The PRIME-1 payload suite was selected to fly on Intuitive Machines Nova-C lander, and is currently targeting a late Fall 2023 landing attempt.

MSolo↗

Sinus Viscositatis: Implications of Young, KREEPy Mare Eruptions for Lunar Volatile Abundances and Origins

Volatiles such as H 2 O and OH have been conclusively shown to exist across the Moon following over a decade of detailed sample analysis and remote sensing. Several mechanisms deliver volatiles to the lunar surface, including exogenous sources such as asteroid or comet bombardment (i.e., H 2 O, CO 2 , CH 4 , NH 3 , S), solar wind (i.e., H, He, Ne, Ar, Na, C, O), and galactic cosmic rays (i.e., noble gases like Xe), or endogenous sources such as outgassing from igneous lithologies (i.e., H 2 O, OH, CO 2 , S, Ar, Cl, F). Processes such as impact gardening and temperature-driven adsorption/desorption have likely supported further transport of species across the lunar surface, thus a mixture of sources is thought to be preserved. Nonetheless, volatile origins, abundances, and cycling on the Moon are not well understood and require further investigation.

A. J. Gawronska↗

Maximizing Macromolecule Crystal Size for Neutron Diffraction Experiments

A challenge in neutron diffraction experiments is growing large (greater than 1 cu mm) macromolecule crystals. In taking up this challenge we have used statistical experiment design techniques to quickly identify crystallization conditions under which the largest crystals grow. These techniques provide the maximum information for minimal experimental effort, allowing optimal screening of crystallization variables in a simple experimental matrix, using the minimum amount of sample. Analysis of the results quickly tells the investigator what conditions are the most important for the crystallization. These can then be used to maximize the crystallization results in terms of reducing crystal numbers and providing large crystals of suitable habit. We have used these techniques to grow large crystals of Glucose isomerase. Glucose isomerase is an industrial enzyme used extensively in the food industry for the conversion of glucose to fructose. The aim of this study is the elucidation of the enzymatic mechanism at the molecular level. The accurate determination of hydrogen positions, which is critical for this, is a requirement that neutron diffraction is uniquely suited for. Preliminary neutron diffraction experiments with these crystals conducted at the Institute Laue-Langevin (Grenoble, France) reveal diffraction to beyond 2.5 angstrom. Macromolecular crystal growth is a process involving many parameters, and statistical experimental design is naturally suited to this field. These techniques are sample independent and provide an experimental strategy to maximize crystal volume and habit for neutron diffraction studies.

Judge, R. A.↗

A summary of phase analysis on Apollo 14 samples

The results of an analysis of lunar samples from Apollo 14 are presented. The large number of breccias returned from the Fra Mauro formation show that impact events are an important rock forming mechanism on the moon. Larger rocks as well as micro breccias bear structural resemblance to brecciated chondrites and terrestrial impactites. Many show evidence of repetitious events of break-up and accumulation welding. The surface of the regolith has become thoroughly mixed by this process. Most components however appear locally derived from basalts rich in feldspar and Kreep components, similar to rocks such as 14310.

Fredriksson, K.↗

Determining the rate of forest conversion in Mato Grosso, Brazil, using Landsat MSS and AVHRR data

AVHRR-LAC thermal data and Landsat MSS and TM spectral data were used to estimate the rate of forest clearing in Mato Grosso, Brazil, between 1981 and 1984. The Brazilian state was stratified into forest and nonforest. A list sampling procedure was used in the forest stratum to select Landsat MSS scenes for processing based on estimates of fire activity in the scenes. Fire activity in 1984 was estimated using AVHRR-LAC thermal data. State-wide estimates of forest conversion indicate that between 1981 and 1984, 353,966 ha + or - 77,000 ha (0.4 percent of the state area) were converted per year. No evidence of reforestation was found in this digital sample. The relationship between forest clearing rate (based on MSS-TM analysis) and fire activity (estimated using AVHRR data) was noisy (R-squared = 0.41). The results suggest that AVHRR data may be put to better use as a stratification tool than as a subsidiary variable in list sampling.

Nelson, Ross↗

Computer-aided boundary delineation of agricultural lands

The National Agricultural Statistics Service of the United States Department of Agriculture (USDA) presently uses labor-intensive aerial photographic interpretation techniques to divide large geographical areas into manageable-sized units for estimating domestic crop and livestock production. Prototype software, the computer-aided stratification (CAS) system, was developed to automate the procedure, and currently runs on a Sun-based image processing system. With a background display of LANDSAT Thematic Mapper and United States Geological Survey Digital Line Graph data, the operator uses a cursor to delineate agricultural areas, called sampling units, which are assigned to strata of land-use and land-cover types. The resultant stratified sampling units are used as input into subsequent USDA sampling procedures. As a test, three counties in Missouri were chosen for application of the CAS procedures. Subsequent analysis indicates that CAS was five times faster in creating sampling units than the manual techniques were.

Cheng, Thomas D.↗

Contamination on LDEF: Sources, distribution, and history

An introduction to contamination effects observed on the Long Duration Exposure Facility (LDEF) is presented. The activities reported are part of Boeing's obligation to the LDEF Materials Special Investigation Group. The contamination films and particles had minimal influence on the thermal performance of the LDEF. Some specific areas did have large changes in optical properties. Films also interfered with recession rate determination by reacting with the oxygen or physically shielding underlying material. Generally, contaminant films lessen the measured recession rate relative to 'clean' surfaces. On orbit generation of particles may be an issue for sensitive optics. Deposition on lenses may lead to artifacts on photographic images or cause sensors to respond inappropriately. Particles in the line of sight of sensors can cause stray light to be scattered into sensors. Particles also represent a hazard for mechanisms in that they can physically block and/or increase friction or wear on moving surfaces. LDEF carried a rather complex mixture of samples and support hardware into orbit. The experiments were assembled under a variety of conditions and time constraints and stored for up to five years before launch. The structure itself was so large that it could not be baked after the interior was painted with chemglaze Z-306 polyurethane based black paint. Any analysis of the effects of molecular and particulate contamination must account for a complex array of sources, wide variation in processes over time, and extreme variation in environment from ground to launch to flight. Surface conditions at certain locations on LDEF were established by outgassing of molecular species from particular materials onto adjacent surfaces, followed by alteration of those species due to exposure to atomic oxygen and/or solar radiation.

Pippin, Gary↗

Characterization of spacecraft humidity condensate

When construction of Space Station Freedom reaches the Permanent Manned Capability (PMC) stage, the Water Recovery and Management Subsystem will be fully operational such that (distilled) urine, spent hygiene water, and humidity condensate will be reclaimed to provide water of potable quality. The reclamation technologies currently baselined to process these waste waters include adsorption, ion exchange, catalytic oxidation, and disinfection. To ensure that the baseline technologies will be able to effectively remove those compounds presenting a health risk to the crew, the National Research Council has recommended that additional information be gathered on specific contaminants in waste waters representative of those to be encountered on the Space Station. With the application of new analytical methods and the analysis of waste water samples more representative of the Space Station environment, advances in the identification of the specific contaminants continue to be made. Efforts by the Water and Food Analytical Laboratory at JSC were successful in enlarging the database of contaminants in humidity condensate. These efforts have not only included the chemical characterization of condensate generated during ground-based studies, but most significantly the characterization of cabin and Spacelab condensate generated during Shuttle missions. The analytical results presented in this paper will be used to show how the composition of condensate varies amongst enclosed environments and thus the importance of collecting condensate from an environment close to that of the proposed Space Station. Although advances were made in the characterization of space condensate, complete characterization, particularly of the organics, requires further development of analytical methods.

Muckle, Susan↗

Evaluating Subgrid-Scale Properties of Low Clouds over the Beaufort Sea in Arctic System Reanalysis using ARISE Airborne In Situ Observations

Arctic low clouds influence the evolution of the Arctic system through their effects on radiative fluxes, boundary layer mixing, stability, turbulence, humidity, and precipitation. Unfortunately, atmospheric models and retrospective analysis (reanalysis) products struggle to accurately simulate the occurrence and properties of low clouds in the Arctic. To better understand the magnitude and possible causes of this problem, we analyze the disagreements between the Arctic System Reanalysis version 2 (ASR) and data taken during the September 2014 Arctic Radiation-IceBridge Sea and Ice Experiment (ARISE) airborne campaign conducted over the Beaufort Sea. Previous analysis of grid scale-averaged meteorological variables revealed a lack of cloud water produced in ASR, related to warm/dry biases, a failure to produce sufficient cloud water in conditions that are observed to be favorable for large cloud water values, and sampling issues with the ARISE flight paths. However, ARISE collected meteorological observations at one second intervals, offering spatial data resolution comparable to the subgrid scale of ASR. Subgrid scale properties and processes must be parameterized in conventional atmospheric models and reanalyses such as ASR, and often rely on assumed distributions of meteorological variables about the grid box mean state. To enable an examination of the realism of ASR’s subgrid scale properties, we use high resolution data from ARISE determine the “subgrid scale” distributions of cloud water and thermodynamic variables in the real atmosphere. Preliminary results show that the subgrid scale distribution of thermodynamic variables about the grid scale mean resembles the triangular distribution assumed in many bulk microphysical parameterization schemes, but also with tails resembling Gaussian distributions. The main goal is to understand the partitioning of the total available atmospheric water into water vapor and cloud water. Models typically covert some percentage of total water in a grid box to cloud water based on the estimated amount of supersaturation from the assumed vapor distribution. The ARISE measurements can reveal the relationship between subgrid scale supersaturation and the partition between cloud water and water vapor.

Jason Brant Dodson↗

Observations of Regional Biomass Burning and Urban Trace Gas Enhancement Ratios in Southeast Asia and their Relationship with Aerosol Composition and Air Quality

Biomass burning in Southeast Asia is a major pollutant source contributing to poor air quality throughout the region. Thus, understanding these emissions is critical for predicting and mitigating their health impacts. While there have been many studies reporting ground-based and satellite measurements, airborne regional scale measurements to tie the two together have not been common. The 2019 Cloud, Aerosol and Monsoon Processes Philippines Experiment (CAMP2Ex) field campaign examined Southeast Asian regional sources and their effects on aerosol/cloud interactions using a combination of airborne, shipborne, and ground-based measurements. Flights sampled a variety of airmasses in the Philippine, South China, and Sulu seas during both monsoonal and post-monsoonal conditions. Thus, CAMP2Ex provides a unique opportunity to study how transported and local emissions affect air quality trends and airmass chemical composition. In this analysis, correlated airborne in situ enhancement ratios of CH4 and CO are used to identify source regimes of high urban or biomass burning influence as well as urban regimes with different emission factors. Combined with HYSPLIT backtrajectories, these source regimes are examined for their effects on ozone, NOy, and aerosol chemical composition. For example, while observed O3/CO enhancement ratios remain constant for urban differing source regimes, NOy/CO ratios are observed to vary across these regimes. For biomass burning sources, O3/CO enhancement ratios are observed to be lower than previously reported by measurements in the region.

Joshua Paul Digangi↗

Input-output characterization of an ultrasonic testing system by digital signal analysis

Ultrasonic test system input-output characteristics were investigated by directly coupling the transmitting and receiving transducers face to face without a test specimen. Some of the fundamentals of digital signal processing were summarized. Input and output signals were digitized by using a digital oscilloscope, and the digitized data were processed in a microcomputer by using digital signal-processing techniques. The continuous-time test system was modeled as a discrete-time, linear, shift-invariant system. In estimating the unit-sample response and frequency response of the discrete-time system, it was necessary to use digital filtering to remove low-amplitude noise, which interfered with deconvolution calculations. A digital bandpass filter constructed with the assistance of a Blackman window and a rectangular time window were used. Approximations of the impulse response and the frequency response of the continuous-time test system were obtained by linearly interpolating the defining points of the unit-sample response and the frequency response of the discrete-time system. The test system behaved as a linear-phase bandpass filter in the frequency range 0.6 to 2.3 MHz. These frequencies were selected in accordance with the criterion that they were 6 dB below the maximum peak of the amplitude of the frequency response. The output of the system to various inputs was predicted and the results were compared with the corresponding measurements on the system.

Williams, J. H., Jr.↗