DOE OSTI2017
Zirlo (Zircaloy cladding material from Westinghouse) has been widely used as the fuel cladding material in Light Water Reactors because of its high melting point, low susceptibility to corrosion, good thermal and mechanical shock resistance, and low degradation of mechanical properties under irradiation. But as Zirlo reacts with water at high temperature, which can trigger serious accidents, efforts have been made to explore better candidates to replace Zirlo in the water-cooled reactors. SiC-SiC composite is considered as one of the most viable options due to its comparable mechanical performances and corrosion resistance. However, one of the most important properties, thermal diffusivities of both Zirlo and SiC-SiC composite, and their degradation after irradiation, are not well known yet. Ion-irradiated samples are used to study the thermal property degradation caused by irradiation instead of the neutron-irradiated ones due to the significantly lower radioactivity. The microstructural damage is estimated from the software simulation SRIM/TRIM based on the energy and fluence of the ion, and the target material, and represented by DPA (displacement by atom). Different from neutron-irradiated samples, the damaged layer of ion-irradiated samples is only a few to a few tens of micrometers thick, and the damage is depth dependent. It is impossible to directly measure the bulk property change, and a microscale measurement technique is necessary. Laser-based photothermal reflectance technique is one of the ideal methods to measure local thermal conductivity and diffusivity with high spatial resolution. The main principle of this technique is to heat the solid sample using an intensity-modulated laser, and scan the sample with a constant intensity continuous-wave (CW) laser to detect the thermal wave propagation. On bulk, isotropic material, if the heating laser intensity is modulated as a sine wave, thermal diffusivity of the sample can be derived from the phase lag of the thermal wave, scan distance and modulation frequency in a straight forward manner. By using more specific analytical models, thermal conductivity and diffusivity in complicated cases, such as layered structure materials, composite materials, and/or anisotropic materials, are measurable as well. In this work, thermal diffusivity of the light damage layer of the post-irradiation Zirlo and SiC-SiC composite are measured and compared. The Zirlo sample is irradiated by Ni{sup 9+} ion, and SiC-SiC composite material is irradiated by Si{sup 7+} ion. The peak DPA of both sample is similar as ∼10. For ion-irradiated materials, DPA is known to increase with depth before it reaches the peak, and then sharply drop to zero. In term of light damage layer in this manuscript, we mean by the layer with a DPA smaller than 5% maximum value. In this layer DPA increases slowly and smoothly with depth, and the structure and thus thermal properties are more spatially uniform. For the SiC-SiC composite, the measurements are separately conducted on fibers along radial or axial direction, and on the matrix. Our measurement results show that with similar microstructural damage, thermal diffusivity of matrix SiC reduces more significantly than that of Zirlo. For fiber SiC that has a much lower thermal diffusivity than the matrix SiC before irradiation, the post-irradiation effect on thermal diffusivity is not obvious.
11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗