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At least 1,045 records · Page 58

Foam-insulated cryo-compressed hydrogen storage vessels for buses

Here, large reductions (40 % vs. compressed gaseous hydrogen vessels and 17 % vs. vacuum insulated cryo-compressed vessels) in hydrogen storage system cost are possible by operating buses with foam-insulated cryo-compressed hydrogen (CcH 2 ) vessels. Detailed thermodynamic analysis reveals that large size and rapid H 2 consumption in buses compensate for the poor performance of foam insulation (∼100 times more conductive than vacuum multilayer insulation), resulting in compact and inexpensive H 2 storage systems with sufficient H 2 capacity for the longest routes (500 km) while maintaining previously identified advantages of CcH 2 systems: increased autonomy, rapid high density refueling, and improved safety, while simultaneously avoiding vacuum insulation stability problems resulting from composite resin outgassing.

Cryo-compressed↗

Kilovoltage Imaging of Implanted Fiducials to Monitor Intrafraction Motion With Abdominal Compression During Stereotactic Body Radiation Therapy for Gastrointestinal Tumors

Purpose: To assess intrafraction respiratory motion using a commercial kilovoltage imaging system for abdominal tumor patients with implanted fiducials and breathing constrained by pneumatic compression during stereotactic body radiation therapy (SBRT). Methods and Materials: A pneumatic compression belt limited respiratory motion in 19 patients with radiopaque fiducials in or near their tumor during SBRT for abdominal tumors. Kilovoltage images were acquired at 5- to 6-second intervals during treatment using a commercial system. Intrafractional fiducial displacements were measured using in-house software. The dosimetric effect of the observed displacements was calculated for 3 sessions for each patient. Results: Intrafraction displacement patterns varied between patients and between individual treatment sessions. Averaged over 19 patients, 73 sessions, 7.6% of craniocaudal displacements exceeded 0.5 cm, and 1.2% exceeded 0.75 cm. The calculated single-session dose to 95% of gross tumor volume differed from planned by an average of −1.2% (range, −11.1% to 4.8%) but only for 4 patients was the total 3-session calculated dose to 95% of gross tumor volume more than 3% different from planned. Conclusions: Our pneumatic compression limited intrafractional abdominal target motion, maintained target position established at setup, and was moderately effective in preserving coverage. Commercially available intrafractional imaging is useful for surveillance but can be made more effective and reliable.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

EBSD analysis of (10–12) twinning activity in Mg–3Al–1Zn alloy during compression

The (10–12) twinning activity of Mg–3Al–1Zn magnesium alloy during uniaxial compression at room temperature has been investigated by electron backscatter diffraction. The results indicated that the twinning activity was closely related with two angles: one was the angle between the c-axis and the compression direction and the other was the angle between the a-axis and the titling direction in the basal plane for a given relation between the c-axis and the compression direction. These two parameters can be used to explain which twinning variant will operate under the given strain path. For the grains containing a single (10–12) twinning variant, the (10–12) twinning variant occurred in a wide range of Schmid factor values (0 < Schmid factor < 0.5) and the Schmid factor rank of 1 or 2 was the most commonly observed. By contrast, for the grains containing two (10–12) twinning variants, the (10–12) twinning activity exhibited a stronger orientation dependence and the combinations of Schmid factor ranks 1–3 and 1–2 were the most commonly observed. - Highlights: • Twinning activity of AZ31 magnesium alloy was investigated by EBSD. • (10–12) twinning shows a strong orientation dependence. • Two angles can be used to explain which twin variant will operate.

36 MATERIALS SCIENCE↗

Effects of carbon nanotubes on twin and texture evolution of magnesium matrix composite during compression process

Highlights: • The CNTs existing at grain boundaries lead to stress concentration, and stimulate the formation of twins. • Crystal rotation and non-basal slip alternately dominate the deformation of the CNTs/Mg composite. • The texture changes from random texture to strong basal texture, strong non-basal texture at the three corresponding stages. • Crystal rotation and non-basal slip system are the main toughening mechanisms of the CNTs/Mg composite. - Abstract: A compression test is performed to investigate the effects of carbon nanotubes (CNTs) on twin and texture evolution of the 1.0 wt.% CNTs reinforced magnesium matrix (CNTs/Mg) composite. The compression process consists of elastic, yield and hardening stages, and the number of twin significantly increases at the yield stage. During the compression process, the crystal rotation and non-basal slip caused by twin shear alternately dominate the deformation of the 1.0 wt.% CNTs/Mg composite. The CNTs existing at grain boundaries lead to stress concentration, and the stress concentration stimulates the formation of twins at the yield stage. The formed twins interact with dislocations, result in crystal rotation and promotion of the non-basal slip system at the hardening stage under the effect of twin shear, thus, improve the toughness of the CNTs/Mg composite.

36 MATERIALS SCIENCE↗

A finite-strain rate- and pressure-dependent constitutive framework for analyzing shock compression behavior of cemented tungsten carbides to 100 GPa

In the present study a thermodynamically-consistent finite-strain rate-and-pressure-dependent constitutive framework is implemented to analyze the shock-compression behavior of cemented tungsten carbides to 100 GPa. Central to this framework is the use of logarithmic strain with a set of invariant basis that allow the Cauchy stress tensor to be expressed as a sum of three response terms that are mutually orthogonal, thus permitting a complete separation of the deviatoric and volumetric (pressure) response. An overstress viscoplasticity model that includes strain and strain rate hardening along with thermal softening is used to represent the deviatoric response, while a complete Mie-Grüneisen equation of state (EoS) is used to obtain the pressure response. Using this formulation, the shock-induced compression behavior of cemented tungsten carbide - obtained from planar plate impact experiments using a 30 mm powder gun to peak stresses of up to ~100 GPa - is analyzed to better understand the structure of the measured shock wave profiles and the associated in-material shock quantities. Of particular interest is the evolution of material inelasticity and strength, and temperature in the tungsten carbide samples during the shock compression process.

Cemented tungsten carbide↗

Variations of target volume definition and daily target volume localization in stereotactic body radiotherapy for early-stage non–small cell lung cancer patients under abdominal compression

We aimed to compare gross tumor volumes (GTV) in 3-dimensional computed tomography (3DCT) simulation and daily cone beam CT (CBCT) with the internal target volume (ITV) in 4-dimensional CT (4DCT) simulation in stereotactic body radiotherapy (SBRT) treatment of patients with early-stage non–small cell lung cancer (NSCLC) under abdominal compression. We retrospectively selected 10 patients with NSCLC who received image-guided SBRT treatments under abdominal compression with daily CBCT imaging. GTVs were contoured as visible gross tumor on the planning 3DCT and daily CBCT, and ITVs were contoured using maximum intensity projection (MIP) images of the planning 4DCT. Daily CBCTs were registered with 3DCT and MIP images by matching of bony landmarks in the thoracic region to evaluate interfractional GTV position variations. Relative to MIP-based ITVs, the average 3DCT-based GTV volume was 66.3 ± 17.1% (range: 37.5% to 92.0%) (p < 0.01 in paired t-test), and the average CBCT-based GTV volume was 90.0 ± 6.7% (daily range: 75.7% to 107.1%) (p = 0.02). Based on bony anatomy matching, the center-of-mass coordinates for CBCT-based GTVs had maximum absolute shift of 2.4 mm (left-right), 7.0 mm (anterior-posterior [AP]), and 5.2 mm (superior-inferior [SI]) relative to the MIP-based ITV. CBCT-based GTVs had average overlapping ratio of 81.3 ± 11.2% (range: 45.1% to 98.9%) with the MIP-based ITV, and 57.7 ± 13.7% (range: 35.1% to 83.2%) with the 3DCT-based GTV. Even with abdominal compression, both 3DCT simulations and daily CBCT scans significantly underestimated the full range of tumor motion. In daily image-guided patient setup corrections, automatic bony anatomy-based image registration could lead to target misalignment. Soft tissue-based image registration should be performed for accurate treatment delivery.

61 RADIATION PROTECTION AND DOSIMETRY↗

Compressibility and permeability of particulated non-recyclable municipal solid waste

Biofuels from non-recyclable municipal solid waste (NMSW) stand at the forefront of energy sustainability. However, their widespread adoption is hampered by persistent material handling issues stemming from the variability in NMSW material properties. An enhanced understanding of particulated NMSW properties, particularly compressibility and permeability, is essential to address the feedstock handling challenges and optimize the handling equipment. This study measures the compressibility and gas permeability of five streams of NMSW materials (i.e., rigid plastics, cardboard, thin film, paper, and foam) and their mixtures under different stress conditions. The results highlight the significant variability in compressibility and gas permeability among different streams, as well as the impacts of particle sizes. A semi-empirical model capable of predicting the gas permeability of NMSW mixtures is established and validated. Here, the results also highlight that reduced NMSW particle size helps promote consistency in NMSW feedstock’s physical and mechanical properties, which is favored for handling equipment design in waste-to-energy recovery facilities.

09 BIOMASS FUELS↗

Effect of Crystallite Size on the Flexibility and Negative Compressibility of Hydrophobic Metal–Organic Frameworks

Flexible nanoporous materials are of great interest for applications in many fields such as sensors, catalysis, material separation, and energy storage. Of these, metal–organic frameworks (MOFs) are the most explored thus far. However, tuning their flexibility for a particular application remains challenging. In this work, we explore the effect of the exogenous property of crystallite size on the flexibility of the ZIF-8 MOF. By subjecting hydrophobic ZIF-8 to hydrostatic compression with water, the flexibility of its empty framework and the giant negative compressibility it experiences during water intrusion were recorded via in operando synchrotron irradiation. It was observed that as the crystallite size is reduced to the nanoscale, both flexibility and the negative compressibility of the framework are reduced by ~25% and ~15%, respectively. These results pave the way for exogenous tuning of flexibility in MOFs without altering their chemistries.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Compressive Creep of Polymer Electrolyte Membranes: A Case Study for Electrolyzers

For proton-exchange membrane (PEM) water electrolyzers to be commercially feasible, PEMs must perform over long lifetimes in liquid environments under compression while maintaining mechanical stability. A hydrated environment, while inherent for operation and conductivity, undermines PEM stability. Mechanical stability of PEMs is commonly characterized in tension, which is not applicable to electrolyzers, wherein PEMs could undergo high pressures. In this study, a compression creep procedure is developed using a custom-designed setup to monitor creep response of hydrated PEMs. Furthermore, our results show that PEMs exhibit continuous creep response under compression over 24 h, with a dependence on the applied pressure and hydration state.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Two-stage Raman compression of laser pulses with controllable phase fronts

The phase front of an ultrashort laser pulse undergoing Raman amplification and compression in inhomogeneous plasma can be controlled such that it is unaffected by density gradients and thus remains focusable. This is achieved by performing the Raman backscattering in two stages. At the first stage, the standard nonlinear Raman compression of a seed wave takes place and produces a short ultraintense pulse, which yet may be poorly focusable. At the second stage, this amplified pulse is scattered again, now serving as a pump, off a second copy of the initial seed. This stage, which utilizes a denser and shorter plasma, is intended not for compression but rather for passing a significant fraction of the energy to the second seed quickly. Then, the output pulse that is produced is not just short and ultraintense, but also has the smooth phase front of the original seed.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Strain softening mechanism at meso scale during micro-compression in an ultrafine-grained pure copper

Strain softening behavior has been found at meso scale using micro-compression testing in an ultrafine-grained (UFG) pure copper by comparison with the typical strain hardening in conventional coarse-grained (CG) material. Microstructural observations show that grain size remains nearly the same including the fraction of high-angle grain boundaries during micro-compression in UFG pure copper. The Kernel average misorientation(KAM) distribution measured by electron backscatter diffraction (EBSD), as a statistical method, is applied to qualitatively evaluate dislocation density in the interior of the grains. It is suggested that the deformation mechanisms are dominated by grain boundary sliding and grain rotation accompanied by dislocation slip in UFG pure copper, which demonstrates that the strain softening behavior is primarily caused by dislocation annihilation during micro-compression.

36 MATERIALS SCIENCE↗

Relation between pore size and the compressibility of a confined fluid

When a fluid is confined to a nanopore, its thermodynamic properties differ from the properties of a bulk fluid, so measuring such properties of the confined fluid can provide information about the pore sizes. Here, we report a simple relation between the pore size and isothermal compressibility of argon confined in such pores. Compressibility is calculated from the fluctuations of the number of particles in the grand canonical ensemble using two different simulation techniques: conventional grand-canonical Monte Carlo and grand-canonical ensemble transition-matrix Monte Carlo. Our results provide a theoretical framework for extracting the information on the pore sizes of fluid-saturated samples by measuring the compressibility from ultrasonic experiments.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Shock compression response of poly(4-methyl-1-pentene) plastic to 985 GPa

Poly(4-methyl-1-pentene) plastic (PMP) is a hydrocarbon polymer with potential applications to inertial confinement fusion experiments and as a Hugoniot impedance matching standard for equation of state experiments. Using Sandia's Z-machine, we performed a series of flyer plate experiments to measure the principal Hugoniot and reshock states of PMP up to 985 GPa. The principal Hugoniot measurements validate density functional theory (DFT) calculations along the Hugoniot. The DFT calculations are further analyzed using a bond tracking method to understand the dissociation pathway under shock compression. Complete dissociation occurs at a compression factor similar to other sp3-hybridized, C-C bonded systems, which suggests a limiting compression for C-C bonds. The combined experimental and DFT results provide a solid basis for constructing an equation of state model for PMP.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Shock compression response of highly reactive Ni + Al multilayered thin foils

The shock-compression response of Ni + Al multilayered thin foils is investigated using laser-accelerated thin-foil plate-impact experiments over the pressure range of 2 to 11 GPa. The foils contain alternating Ni and Al layers (parallel but not flat) of nominally 50 nm bilayer spacing. The goal is to determine the equation of state and shock-induced reactivity of these highly reactive fully dense thin-foil materials. The laser-accelerated thin-foil impact set-up involved combined use of photon-doppler-velocimetry to monitor the acceleration and impact velocity of an aluminum flyer, and VISAR interferometry was used to monitor the back free-surface velocity of the impacted Ni + Al multilayered target. The shock-compression response of the Ni + Al target foils was determined using experimentally measured parameters and impedance matching approach, with error bars identified considering systematic and experimental errors. Meso-scale CTH shock simulations were performed using real imported microstructures of the cross-sections of the multilayered Ni + Al foils to compute the Hugoniot response (assuming no reaction) for correlation with their experimentally determined equation of state. It was observed that at particle velocities below ∼150 m/s, the experimentally determined equation of state trend matches the CTH-predicted inert response and is consistent with the observed unreacted state of the recovered Ni + Al target foils from this velocity regime. At higher particle velocities, the experimentally determined equation of state deviates from the CTH-predicted inert response. A complete and self-sustained reaction is also seen in targets recovered from experiments performed at these higher particle velocities. The deviation in the measured equation of state, to higher shock speeds and expanded volumes, combined with the observation of complete reaction in the recovered multilayered foils, confirmed via microstructure characterization, is indicative of the occurrence of shock-induced chemical reaction occurring in the time-scale of the high-pressure state. TEM characterization of recovered shock-compressed (unreacted) Ni + Al multilayered foils exhibits distinct features of constituent mixing revealing jetted layers and inter-mixed regions. These features were primarily observed in the proximity of the undulations present in the alternating layers of the Ni + Al starting foils, suggesting the important role of such instabilities in promoting shock-induced intermetallic-forming reactions in the fully dense highly exothermic multilayered thin foils.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Characterization of compressive and short beam shear strength of bamboo opened cell foam core sandwich composites

The paper presents the compressive and the short beam shear strength of a sandwich composite with opened cell foam made of bamboo fiber as the core and plywood as the skins. The core thickness was varied from 10 mm to 40 mm keeping the volume fraction of fiber constant. Several test s were carried out including the core density, flatwise compressive and the short beam shear testing in three point bending. The results show that the density of bamboo opened cell foam is comparable with commercial plastic foam, such as polyurethane foam. The compressive strength tends to increase linearly with increasing the core thickness. The short beam shear failure load of the sandwich composite increases with the increase of core thickness, however on the contrary, the short beam shear strength which tends to sharply decrease from the thickness of 10 mm to 30 mm and then becomes flat.

36 MATERIALS SCIENCE↗

Transparency of the strong shock-compressed diamond for 532 nm laser light

An optical reflectivity and transmissivity model for the shock-compressed diamond is established and used to calculate the optical reflectivity and transmissivity of the diamond under different shock compressions. The simulated results indicate that the reflection occurs at the shock front and does not depend on the thickness of the compressed diamond, but the transmissivity decreases with the thickness. The simulated reflectivity is consistent with the experimental results in the literature, which validates the model. It is shown that the diamond keeps transparent when the shock pressure is lower than 2.00 Mbar, and becomes opaque but does not reflect the probe laser as the shock pressure increases from 2.00 Mbar to 4.60 Mbar and reflects the probe laser markedly when the shock pressure is higher than 4.60 Mbar.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Exploration of CdTe quantum dots as mesoscale pressure sensors via time-resolved shock-compression photoluminescent emission spectroscopy

The nanometer size of CdTe quantum dots (QDs) and their unique optical properties, including size-tunable narrow photoluminescent emission, broad absorption, fast photoluminescence decay, and negligible light scattering, are ideal features for spectrally tagging the shock response of localized regions in highly heterogeneous materials such as particulate media. In this work, the time-resolved laser-excited photoluminescence response of QDs to shock-compression was investigated to explore their utilization as mesoscale sensors for pressure measurements and in situ diagnostics during shock loading experiments. Laser-driven shock-compression experiments with steady-state shock pressures ranging from 2.0 to 13 GPa were performed on nanocomposite films of CdTe QDs dispersed in a soft polyvinyl alcohol polymer matrix and in a hard inorganic sodium silicate glass matrix. Time-resolved photoluminescent emission spectroscopy was used to correlate photoluminescence changes with the history of shock pressure and the dynamics of the matrix material surrounding the QDs. The results revealed pressure-induced blueshifts in emitted wavelength, decreases in photoluminescent emission intensity, reductions in peak width, and matrix-dependent response times. Data obtained for these QD response characteristics serve as indicators for their use as possible time-resolved diagnostics of the dynamic shock-compression response of matrix materials in which such QDs are embedded as in situ sensors.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Three-dimensional nonlinear ideal MHD equilibria with field-aligned incompressible and compressible flows

The equilibrium properties of three-dimensional ideal magnetohydrodynamics (MHD) are investigated. Incompressible and compressible flows are considered. The governing equations are taken in a steady state such that the magnetic field is parallel to the plasma flow. Equations of stationary equilibrium for both of incompressible and compressible MHD flows are derived and described in a mathematical mode. For incompressible MHD flows, Alfvénic and non-Alfvénic flows with constant and variable magnetofluid density are investigated. For Alfvénic incompressible flows, the general three-dimensional solutions are determined with the aid of two potential functions of the velocity field. For non-Alfvénic incompressible flows, the stationary equilibrium equations are reduced to two differential constraints on the potential functions, flow velocity, magnetofluid density, and the static pressure. Some examples which may be of some relevance to axisymmetric confinement systems are presented. For compressible MHD flows, equations of the stationary equilibrium are derived with the aid of a single potential function of the velocity field. The existence of three-dimensional solutions for these MHD flows is investigated. Several classes of three-dimensional exact solutions for several cases of nonlinear equilibrium equations are presented.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗