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Panel Session 1: WM2019 Plenary Session

The plenary panel focused on government and industry world leaders speaking on the pressing issues facing radioactive waste management in 2019 and beyond. Presentations proposed include: 1 - Waste Management Symposium 2019 - Plenary Session (Rumina Velshi, Canadian Nuclear Safety Commission (Canada)); 2 - The DOE 2019 Featured Site - Idaho (Congressman Mike Simpson, United States House of Representatives, Idaho's 2. Congressional District)

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From Banned to Allowed: Pathway to Sub-seabed HLW Repositories - 16279

For many countries the disposal of high-level radioactive waste (HLW) has been delayed due to a number of factors including the Not-In-My-Backyard (NIMBY) syndrome. Sub-seabed disposal has no NIMBY concerns since the disposal facilities utilize sediments underlying approximately 4000 meters of international waters. The technical feasibility of the concept was demonstrated during a 12-year joint effort of over 200 researchers from 10 different countries. Social pressures to keep the oceans off-limits to most disposal activities resulted in termination of the coordinated international effort. However, the treaty banning the concept mandated a 25-year review frequency covering the latest scientific and technical information germane to the activity. An effort is underway to supply information to the signatories of the treaty, in their native languages, so they can make a fully-informed decision -- whether or not to approve an amendment that would allow sub-seabed disposal if determined to be protective of human health and the environment and permitted in accordance with guidelines provided by the International Atomic Energy Agency (IAEA). The information highlights the environmental and safety aspects of the disposal concept within a sensible global stewardship framework. With an amended treaty to allow sub-seabed HLW repositories, the global outlook for nuclear waste disposal would be altered dramatically: the number of potential disposal facilities scattered around the world could be reduced from over sixty land-based to approximately six (three land-based, three sub-seabed). (authors)

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French Atomic and alternative energies commission decommissioning policy and strategies: What is at stake lessons learned and feedback experience - 15013

Since its creation in 1945, the French Atomic Energy and Alternative Energies Commission has carried out research programmes on civil use of nuclear, and its application. CEA has set up and run various types of installations from research (accelerators, pond reactors, fast reactors, laboratories) to industry (power reactor, processing facilities). There are currently more than several tens of facilities which are presently closed down pending dismantling or in the process of being dismantled by CEA, the governmental body for research and development in nuclear and renewable energies. When operating, all these installations have generated radioactive waste. When they are shutdown, either as a result of the programmes for which they were set up, or due to equipment wearing out or being obsolete, these installations must be cleaned up, dismantled and decommissioned, taking into account their nuclear nature and requirements related to safety and environment. During the decommissioning process, the implementer has to deal with safety and site remediation issues. Dealing with these installations is a long-term programme which must be carefully planned and financed in order to optimise its management. The paper will describe the CEA's decommissioning policy, strategies adopted, and draw up lessons learned and feedback experience, showing that: - Safety is guaranteed, - Dismantling is a technically controllable operation, but R and D actions are to be developed for specific problems as characterization or operation in hostile environment. Moreover all the methods and techniques improve as a result of feedback experience, - The amount of material and waste produced by the dismantling are manageable. The very low, low and intermediate level waste can be stored on existing shallow land burial centres, some new repositories have to be created for specific waste (graphite, radium,...) and for high and intermediate level long live waste, which are stored in interim storage , - The dismantling must be optimized, especially by appliance of a good strategy based on rational industrial choices. - Communication and transparency with stakeholders is essential for global process acceptance, - The lessons learned and how feedback experience could benefit for future decommissioning projects. (authors)

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Transport of French PWR steam generators to very low level waste disposal - 15203

When considering the complexity of IAEA nuclear transport regulations, the transport of a Steam Generator (SG) in one un-packaged block from a dismantling plant to a nuclear waste disposal is a challenge. The choices made, the difficulties encountered and the feedback that has been learnt from it are described. The disposal of decommissioning waste requires taking into account not only the constraints of acceptance of the repository but also the specific constraints of transportation from the dismantling plant to the final disposal site. In France, these criteria and regulations are respectively under the supervision of the French National Radioactive Waste Management Agency (ANDRA) and the French Nuclear Safety Authority (ASN). In the course of the dismantling of the EDF PWR plant Chooz A, the four decontaminated SGs were shipped to the ANDRA Very Low Level Waste (VLLW) repository. After removal, the SGs were decontaminated, allowing them to attain the criteria of VLLW and thus be accepted by the ANDRA. However, to transport these decontaminated SGs as single un-packaged blocks, it was necessary to ensure compliance with the Surface Contaminated Object SCO-I regulation criteria. For this, transport safety files were written and surface contamination and radiation criteria checked. One of the four SGs had to be decontaminated again and another one had to be transported under special arrangement. Due to the exceptional nature of the transportation, specialized means of transport and stowage were also studied. (authors)

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DECOVALEX-2019: An international collaboration for advancing the understanding and modeling of coupled thermo-hydro-mechanical-chemical (THMC) processes in geological systems

The DECOVALEX Project is an international research collaboration for advancing the understanding and modeling of coupled thermo-hydro-mechanical-chemical (THMC) processes in geological systems. DECOVALEX stands for “DEvelopment of COupled Models and VALidation against EXperiments”. The creation of this international initiative, now running for almost 30 years, was motivated by the recognition that prediction of these coupled effects is an essential part of the performance and safety assessment of geologic disposal systems for radioactive waste and spent nuclear fuel, and also for a range of other sub-surface engineering activities. DECOVALEX emphasizes joint analysis and comparative modeling of state-of-the-art field and laboratory experiments, across a range of host rock options and repository designs. Participating research teams are from radioactive waste management organizations, national research institutes, regulatory agencies, universities, and consulting groups, providing a wide range of perspectives and solutions to these complex problems. The most recent phase of the DECOVALEX Project, here referred to as DECOVALEX-2019, started in 2016 and ended in 2019. Modeling teams from 13 international partner organizations participated in the comparative evaluation of seven modeling tasks involving complex field and/or laboratory experiments. Furthermore, this Virtual Special Issue on DECOVALEX-2019 provides an in-depth overview of these collaborative research efforts and how these have advanced the state-of-the-art of understanding and modeling coupled THMC processes.

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Advanced Waste Form and Melter Development for Treatment of Troublesome High-level Wastes

A number of waste components in US defense high level radioactive wastes (HLW) have proven challenging for current Joule heated ceramic melter (JHCM) operations and have limited the ability to increase waste loadings beyond already realized levels. Many of these "troublesome" waste species cause crystallization in the glass melt that can negatively impact product quality or have a deleterious effect on melter processing. Recent efforts at US Department of Energy laboratories have focused on understanding crystallization behavior within HLW glass melts and investigating approached to mitigate the impacts of crystallization so that increases in waste loading can be realized. Advanced glass formulations have been developed to highlight the unique benefits of next-generation melter technologies such as the Cold Crucible Induction Melter (CCIM). Crystal-tolerant HLW glasses have been investigated to allow sparingly soluble components such as chromium to crystallize in the melter but pass out of the melter before accumulating.

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Nuclear fuels storage and transportation planning project strategic crosscutting activities - 15180

The United States Department of Energy's Office of Nuclear Energy (DOE-NE) is conducting planning activities within the Nuclear Fuels Storage and Transportation Planning Project (NFST) to lay the groundwork for implementing interim storage, including associated transportation, per the Administration's Strategy for the Management and Disposal of Used Nuclear Fuel and High-Level Radioactive Waste (Strategy), and to develop a foundation for a new nuclear waste management organization. The NFST is organized into the following four major elements: 1) Consent-Based Siting, 2) Storage, 3) Transportation, and 4) Strategic Crosscuts. This paper discusses those activities underway in the NFST Strategic Crosscuts element. (authors)

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Advanced Low-Temperature Chlorination of Zirconium

Recovery of Zr from nuclear fuel is of high interest because the Zr cladding material comprises up to 50% of the high-level radioactive waste (HLW) that requires disposition. An ideal Zr-recovery process would not only recover the bulk Zr from the fuel or cladding but would also provide decontamination from the components that give rise to the HLW designation. A simplified decontamination pathway providing recovered Zr in compliance with low-level radioactive waste acceptance criteria could significantly reduce the burden of HLW requiring geologic disposition. A newly developed advanced low-temperature chlorination process presents an opportunity to recover a ZrCl4 product that is effectively decontaminated from the elements of concern. This advanced low-temperature chlorination process uses a mixture of the sulfur-containing chlorination compounds sulfur monochloride (S 2 Cl 2 ) and thionyl chloride (SOCl 2 ).

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Planning for Nuclear Power Plant Site Visits - 20481

The U.5. Department of Energy Office of Integrated Waste Management (DOE-IWM) is planning for future large-scale transport of commercial spent nuclear fuel (SNF) and high-level radioactive waste (HLW) to eventual disposal and/or storage facilities. As part of its planning efforts, DOE conducts evaluations of removing SNF from nuclear power plant sites. Site visits are a pivotal piece in the site evaluations that are conducted by DOE, and significant planning efforts are undertaken to design and implement site visits. Site visits typically include three days of surveys and meetings, including one day each for the nuclear power plant site visit, evaluating near-site transportation infrastructure, and meeting with community engagement panels or advisory boards. This paper outlines DOE-IWM's planning process for conducting nuclear power plant site visits and summarizes the key activities carried out to prepare for a site visit, including a discussion of the background research conducted prior to a site visit. Additionally, the paper describes the development of reference databases for site visits, the identification of unique site characteristics, and the use of geographic information system (GIS) applications to enhance the quality of the information collected during a site visit. (authors)

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Further Development of an Execution Strategy Analysis (ESA) Capability and Tool for the Management of Spent Nuclear Fuel (SNF) - 17146

An Execution Strategy Analysis (ESA) capability and tool are being developed to evaluate alternative execution strategies for the potential future deployment of a consolidated Interim Storage Facility as part of an integrated waste management system. Application of the ESA approach not only leverages but also goes beyond traditional project analysis tools. The ESA tool allows for ongoing performance assessment of the evolving project execution plans that take into account significant assumptions, risks, and uncertainties throughout the project lifecycle. Development and application of the ESA capability and tool continued in 2016, primarily focusing on enhancing its flexibility to model a range of scenarios regarding how an integrated system for managing spent nuclear fuel and high-level radioactive waste could be deployed. (authors)

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Annual Summary Report for the Remote-Handled Low-Level Waste Disposal Facility—FY2021

This Fiscal Year (FY) 2021 annual summary report (ASR) documents the continued adequacy of the performance assessment (PA), the composite analysis (CA) and associated operating disposal-authorization statement (ODAS) technical basis documents for the Remote Handled (RH) Low-Level Waste (LLW) Disposal Facility at Idaho National Laboratory. Annual review of the adequacy of the PA and CA for the RHLLW Disposal Facility ensures that conclusions of the analyses remain valid in accordance with requirements of Department of Energy (DOE) Order 435.1, “Radioactive Waste Management.” In FY 2021, no significant operational changes or other activities occurred that would cause deviation from the assumptions in the PA and CA pertaining to disposal geometry, verification of waste characteristics, tracking disposal inventories against total limits, facility closure design, or institutional controls. Sixteen total waste-canister shipments were received at the RHLLW Disposal Facility, and 16 total waste canisters were emplaced.

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Impeding 99 Tc(IV) mobility in novel waste forms

Technetium ( 99 Tc) is a long-lived radioactive fission product whose mobility in the subsurface is largely governed by its oxidation state1. Immobilization of Tc in mineral substrates is crucial for radioactive waste management and environmental remediation. Tc(IV) incorporation in spinels2, 3 has been proposed as a novel method to increase Tc retention in glass waste forms. However, experiments with Tc-magnetite under high temperature and oxic conditions showed re-oxidation of Tc(IV) to volatile pertechnetate Tc(VII)O4-.4, 5 Here we address this problem with large-scale ab initio molecular dynamics simulations and propose that elevated temperatures, 1st row transition metal dopants can significantly enhance Tc retention in the order Co > Zn > Ni. Experiments with doped spinels at T=700 ºC provided quantitative confirmation of increased Tc retention in the same order predicted by theory. This work highlights the power of modern state-of-the-art simulations to provide essential insights and generate bottom-up design criteria of complex oxide materials at elevated temperatures.

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Annual Status Report (FY 2020): Performance Assessment for the Environmental Restoration Disposal Facility

DOE O 435.1 and DOE M 435.1-1 require that a determination of continued adequacy of the performance assessment (PA) (CP-60089), composite analysis, and disposal authorization statement (DAS) be made annually, and these guidelines must be used to consider the results of data collection and analysis from research, field studies, and monitoring as well as provide the need to update any radioactive waste management basis documents. Beginning in 1996, the Environmental Restoration Disposal Facility (ERDF) started accepting low-level radioactive, hazardous, and mixed wastes generated during cleanup activities at the Hanford Site. ERDF is composed of a series of cells or disposal areas and can accommodate future design expansions as needed. Currently, there are 10 cells. During this reporting period (fiscal year 2020, which extended from October 1, 2019, through September 30, 2020), approximately 3.39E+04 U.S. tons (3.07E+04 metric tons) of waste was disposed at ERDF. From ERDF inception through September 30, 2020, approximately 18.5 million U.S. tons of waste has been disposed at ERDF, which equates to the consumption of approximately 88% of the disposal volume. As a condition of the DAS, disposal operations within ERDF must be in accordance with the waste acceptance criteria (ERDF-00011) that provide specific radionuclide disposal limits, waste form restrictions, and descriptions of acceptable waste packages in compliance with DOE M 435.1-1 requirements. The ERDF waste acceptance criteria stipulate that waste destined for disposal at ERDF be controlled based on source, physical form, and contaminant concentration and activity levels. There have been no changes to the physical configuration of ERDF or to the waste forms (source, physical form, etc.). No new Unreviewed Disposal Question Screenings or Evaluations have been generated during this reporting period. Therefore, there are no noted impacts to the PA, composite analysis, DAS, or radioactive waste management basis documents resulting from the evaluations and screenings. Sum of fraction analysis shows that the disposed inventory meets both the concentration and inventory threshold requirements. A sum of fractions value is computed for ERDF sensitive radionuclides contributing to the all pathways and air pathway inventory limits. Computed values were 8.85E-02 and 1.78E-01, respectively. The disposed waste inventory remained well under the PA imposed limits. Required monitoring was satisfactorily completed during the fiscal year reporting period (fiscal year 2020). Compliance with performance objectives were met as each of the reported values were well below the established limit. Overall, there are no substantive changes to primary PA assumptions nor changes to the PA analysis conclusion; therefore, compliance with DOE O 435.1 and the DAS is maintained.

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Studying microbially induced corrosion on glass using ToF-SIMS

Microbially induced corrosion (MIC) is an emerging topic that has huge environmental impacts, such as long-term evaluation of microbial interactions with radioactive waste glass, environmental cleanup and disposal of radioactive material, and weathering effects of microbes. Time-of-flight secondary ion mass spectrometry (ToF-SIMS), a powerful mass spectral imaging technique with high surface sensitivity, mass resolution, and mass accuracy, can be used to study biofilm effects on different substrates. Understanding how to prepare biofilms on MIC susceptible substrates is critical for proper analysis via ToF-SIMS. We present here a step-by-step protocol for preparing bacterial biofilms for ToF-SIMS analysis, comparing three biofilm preparation techniques: no desalination, centrifugal spinning (CS), and water submersion (WS). Comparisons of two desalinating methods, CS and WS, show a decrease in the media peaks up to 99% using CS and 55% using WS, respectively. Proper desalination methods also can increase biological signals by over four times for fatty acids using WS, for example. ToF-SIMS spectral results show chemical compositional changes of the glass exposed in a Paenibacillus polymyxa SCE2 biofilm, indicating its capability to probe microbiologically induced corrosion of solid surfaces. This represents the proper desalination technique to use without significantly altering biofilm structure and substrate for ToF-SIMS analysis. ToF-SIMS spectral results showed chemical compositional changes of the glass exposed by a Paenibacillus bacterial biofilm over 3-month inoculation. Finally, possible MIC products include various phosphate phase molecules not observed in any control samples with the highest percent increases when experimental samples were compared with biofilm control samples.

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Management of technetium contaminated demolition debris from the gaseous diffusion plants at the east Tennessee Technology Park - 15422

The demolition of the final section of the gaseous diffusion plant (GDP) facility formerly known as K-25 at the East Tennessee Technology Park was completed in December of 2013, with the final shipment of waste completed only six months later in June 2014. While most of the radioactive waste shipments would be considered 'routine' by today's standards (lower activity waste was disposed onsite at the Environmental Management Waste Management Facility [EMWMF] and at some offsite commercial disposal facilities with higher activity waste making its way across country to the Nevada National Security Site [NNSS] disposal facility) the final section of K-25, consisting of six cascade 'units', presented some unique technical and stakeholder challenges. Portions of this final section of K-25 were presumed to be heavily contaminated with Technetium-99 (Tc-99) based on sampling and analysis activities conducted during facility deactivation. Tc-99 is known to be highly mobile under a variety of environmental conditions, and is suspected to be potentially mobile in unmitigated landfill conditions, resulting in the need to implement additional engineered controls during facility demolition as well as throughout the management of the resultant waste. A variety of controls were implemented to ensure Tc-99 mobility was controlled and possible consequences mitigated, including isolation and offsite shipment of highest Tc-99 concentration components, as well as construction of a 'cell within a cell' at the EMWMF. This paper will examine the process utilized to develop the controls for management of Tc-99 contaminated waste and will describe those controls. Additionally, it will describe the stakeholder involvement and approval process as well as examining and documenting the efficacy of the controls that were implemented. Finally, this paper will discuss lessons learned from this first of a kind demolition effort and how this experience can be utilized to further refine the Tc-99 waste management approach for the remaining GDPs at ETTP. (authors)

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Considerations for Involving Citizen Science in an Integrated Waste Management System - 17506

The U.S. Department of Energy's (DOE's) goal is to develop solutions for the long-term, sustainable management of the nation's spent nuclear fuel (SNF) and high-level radioactive waste (HLW). The DOE has been exploring options for an integrated waste management system to transport, store, and dispose of SNF and HLW from commercial electricity generation, as well national defense activities. To support its efforts, DOE has been exploring ways to seek broad input from the public. The role of citizen science in a wide range of projects is increasing. In the U.S. 2013 and 2015 Open Government National Action Plans, the U.S. government encouraged all Federal agencies to pursue public participation through citizen science, and a large number of agencies and organizations have responded. This paper explores the potential for considering citizen science projects as part of an integrated waste management system, including the siting of facilities. A literature review was performed to gain insights into how citizen science projects can be effectively developed and deployed, including success factors and lessons learned. Results highlight the experiences shared by many people who have developed and implemented citizen science projects, which provide valuable context for potential application to a facility siting process. (authors)

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The U.S. DOE-EM International Program - 17411

The U.S. Department of Energy (DOE) Office of Environmental Management (EM) has a mission to complete the safe clean-up of the environmental legacy resulting from six decades of weapons production and energy research. This effort is recognized as one of the largest and most diverse and technically complex environmental clean-up operations in the world. The overall strategy to address this challenge includes several components, one of which involves leveraging the expertise within the International community, when applicable. The opportunities related to international collaborations are an important component of the DOE EM strategy for the clean-up mission, providing excellent forums for EM to stay beneficially engaged with the international community and our global partners. EM has been supporting the clean-up mission of the Department through international collaborations for almost 20 years. The EM International Program is sponsored by the DOE EM Office of the Chief of Staff (EM-2.1), which directly supports the DOE-EM Office of Assistant Secretary (EM-1), in coordination with the entire EM organization. The primary objective of the EM International Program is to provide benefit to the Department in successful completion of the EM clean-up mission, through establishing strategic approaches for specific international collaboration initiatives that are focused on appropriate strategic program goals. The EM International Program strategy to support the EM mission includes many facets, but they can generally be grouped into two primary areas. First, the EM International Program maintains, establishes, and/or participates in international agreements such that appropriate mechanisms are available for conducting international collaborations with foreign government organizations, educational institutions and private industry to leverage resources and link international experience and expertise, in support of the EM mission and compliant with US foreign policy. Second, through coordination with the EM Office of Technology Development (EM-3.2), the EM International Program leverages these agreements to identify mutually beneficial opportunities to evaluate, test, and adapt technologies, capabilities, and expertise for application to EM mission needs. These activities directly support goals within the current DOE Strategic Plan 2014 - 2018, issued in April 2014. Working with the Office of Technology Development, the EM International Program is developing a process for identifying and selecting collaborative international technology projects for Fiscal Year 2017 (FY17) that have high potential impact to the EM mission. The technical scope of these activities is expected to span the entire EM mission, including tank waste and nuclear materials management; groundwater and soil remediation; deactivation and decommissioning; and radioactive waste disposal operations. Depending on budget availability, these collaborative activities are expected to be awarded by mid-FY17. (authors)

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Integrated Waste Feed Qualification Program for Direct LAW Feed to WTP - 16421

The Hanford Tank Waste Treatment and Immobilization Plant (WTP) is a one-of-a-kind facility being designed and constructed for DOE by Bechtel National, Inc. (BNI) and principal subcontractor URS, to process and vitrify radioactive waste stored in underground tanks at the Hanford Site. The Tank Operations Contractor (TOC), Washington River Protection Solutions (WRPS), has the responsibility to retrieve, stage, pretreat, and deliver feed directly to the WTP Low Activity Waste (LAW) Vitrification Facility. The Direct Feed LAW (DFLAW) scenario is being considered by DOE as a strategy to treat Hanford tank wastes as soon as practicable. Extensive planning is underway by One System, an effort with joint participation by WTP and TOC personnel. The initial focus of One System is to achieve the required integration to ensure the waste feed meets acceptance requirements for processing in the TOC Low Activity Waste Pretreatment System (LAWPS) and WTP LAW facilities. The integrated waste feed qualification program approach for DFLAW was defined by One System during a four-day workshop. The effort resulted in a feasible approach for integrating LAWPS and LAW feed acceptance requirements to vitrify low-activity waste while complying with facility design basis, safety basis, waste acceptance criteria, and glass product compliance. The defined qualification program will provide a systematic approach to test newly staged feed campaigns at bench-scale using actual tank waste samples. The required integration and basis for obtaining sufficient and necessary data to qualify the feed for DFLAW facilities are discussed in this paper. (authors)

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