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EM Program Expectations on Implementation of DOE O 458: Radiation Protection of Public/Environment - 19553

DOE Order 458.1, Radiation Protection of the Public and Environment, was issued in 2011. DOE sites were given 18 months to implement. The revised Order promulgates requirements for property clearance actions and independent verification. DOE Order 458.1 allows for preapproved authorized limits for the clearance of property. However, when property with the potential to contain residual radioactive material does not meet preapproved authorized limits, an authorized limits package must be developed. The Order contains a range of requirements for demonstrating with reasonable assurance that dose constraints are met for any actual or likely future use of the property to be released. EM has developed a draft guidance document that provides the elements of an authorized limits package. These elements are used to review all authorized limits packages that are submitted to EM. Expected elements include property description and process knowledge documentation, current and likely future use, the conceptual site model, dose modeling methodologies, specific authorized limits, dose- or concentration-based constraints, collective dose estimate to the potentially exposed population, stakeholder communications, description of the As Low As Reasonably Achievable (ALARA) analysis, implementation plan, evaluation of difficult to assess surfaces, and independent verification plan. The draft guidance document also provides further explanation of the desired elements of an independent verification (IV) plan. An IV plan should describe the planning phase, implementation phase, assessment phase, and decision phase of an activity. The planning phase includes scope and cost, concurrent with cleanup contractor procurement, and review and approval of site radiological survey clearance program and IV program plans. The implementation phase assures sufficient collection of data and adjustment can be made as necessary. During the assessment phase, data and reports are reviewed, and coordination between the clean-up contractor and IV personnel occurs. A decision of whether or not the clearance actions need to be altered occurs during the decision phase. IV certification that the clearance action is complete also occurs during the decision phase. Issuance of the final guidance document is meant to improve the consultation process and minimize iterative interactions with EM. Standardizing and formalizing property clearance and IV actions also helps assure that cleanup actions are transparent and sustainable for future scrutiny. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Potential Advantages to Employing an Onsite Laboratory at FUSRAP Sites Contaminated with Radionuclides and Metals - 20353

Various factors that support an evaluation of the relative costs, advantages and disadvantages of utilizing an onsite laboratory or an offsite laboratory for remediation of Formerly Utilized Sites Remedial Action Program (FUSRAP) sites contaminated with radionuclides and metals are presented. In terms of how much more quickly an onsite laboratory provides results versus an offsite laboratory, the results of this study provide tools for calculating the amount of cost savings per day for excavation of contaminated soils for various scenarios including: - State, municipal or local property remediation where the remediation schedule becomes time-critical due to the extra cost and inconvenience to the town or municipality caused by the need for increased security and safety personnel, possible road closures and detours, and the inconvenience to the public due to modified or decreased services of State or municipal facilities; - Residential property where the remediation schedule becomes time-critical due to the inconvenience to the homeowner as well as the importance of maintaining good community relations; - Commercial property where the remediation schedule becomes time-critical due to the hardship and potential loss of revenue endured by the property owner; - Open area where treatment of excavation water is required, and - Open area where treatment of excavation water is not required. For every scenario, the number of matrices, radionuclide and metal contaminants of concern and the project duration are important factors. The costs for the onsite laboratory included the capital costs associated with setting up the lab such as trailer(s) or building(s), power and water hookup, analytical testing equipment, balances, computers, desks and bookcases; support equipment such as hot plates, filtration assemblies, safety equipment, ovens, etc.; and supplies such as glassware, pipettes, filters, etc. and ongoing costs such as labor, chemicals and reagents, standards, cost of the laboratory obtaining certification and maintenance. Offsite laboratory sample testing costs are generally very competitive and typically substantially lower than onsite laboratory costs if only the sample testing costs are considered. The great disadvantage of using an offsite laboratory is that they often cannot guarantee rapid turnaround times for results which creates project delays associated with the remediation process including delays determining the completeness of the characterization and remediation processes, delays in backfilling a property and additional costs for treating wastewater (excavation water, stormwater or both). These costs will vary greatly depending upon the area of the country in which the project is located due to the wide range of labor costs for the onsite laboratory and field workers, as well as the contaminants of interest, matrices and most importantly the size of the impacted area and the number of properties located in that area. This paper provides guidelines for calculating the cost savings that may be realized if an onsite laboratory can generate results more quickly than an offsite laboratory by estimating the costs associated with the remediation process for the various scenarios noted above such as work crew labor costs, excavator and dump truck equipment rentals, wastewater treatment costs (if applicable) and the additional costs incurred by homeowners, commercial property owners and towns/municipalities that are reimbursed by the potentially responsible parties. Key assumptions involve the typical quickest turnaround time provided by the onsite and offsite laboratories. Costs for the operation of a wastewater treatment system and the remediation of a site area or property were provided by personnel who have been involved in the operation of a large FUSRAP site in New Jersey for many years. This study provides valuable information for determining the most cost-effective approach for analysis of project samples and therefore may be used on upcoming FUSRAP projects. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Advanced Mixed Waste Treatment Project Overcomes Challenges to Complete Treatment of Debris Waste - 20616

The Advanced Mixed Waste Treatment Project (AMWTP), operated by Fluor Idaho for the Department of Energy Idaho Operations Office, completed the last of its debris waste treatment in the fall of 2019. Concluding that work-scope was certainly not without its challenges. Fluor Idaho and its employees had to adapt to treating extremely challenging waste types, such as high-fissile gram materials and potentially pyrophoric and reactive wastes coming down the stretch. It also had to complete the sizing of large waste boxes from Mound Laboratories in inner-contamination enclosures designed to capture the extremely fine, 'flighty' plutonium-238 in its high-efficiency particulate air filters. Very few waste treatment facilities in the DOE Complex have completed their missions. In fact, most large-scale waste treatment facilities are still under construction with many months or years remaining before 'hot operations' begin. AMWTP is unique because it functioned as a 'one-stop shop.' Transuranic and low-level waste characterization, treatment, certification, and shipping all occurred there. AMWTP concluded the most challenging part of its mission and will continue to ship material out of the state of Idaho for the next decade. This paper will provide a background of the AMWTP mission, and the adaptations to its operating permit, equipment, or treatment processes to address challenging waste types. AMWTP will leave behind a legacy of being one of the most successful waste treatment facilities in the history of the DOE Complex. The facility was well-conceived, well-constructed, and well-executed; it was done right from start to finish. During the course of its waste treatment mission, the facility was required to adapt to changing conditions by treating extremely challenging waste types. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Migration to a fully-integrated control room - 349

The nuclear industry is faced with a pressing need to reduce operating costs in order to remain competitive with other forms of electric generation. While current industry initiatives are focused on incremental gains by streamlining work processes and reducing worker burdens, very few, if any, involve significant reductions in the base workload of a nuclear plant. Migration to a fully-integrated control room affords just such an opportunity. This report describes an NPP digital instrumentation and control (I and C) system design, along with its corresponding human systems interface (HSI) design, which achieves high plant availability, while selectively applying digital equipment redundancy and integrating traditional I and C system partitions, to minimize the digital equipment needed, and thereby minimize initial installation costs and ongoing operations and maintenance (O and M) costs. An additional key component of digital equipment minimization is optimization of the digital interface to conventional plant sensors and controlled plant devices (e.g., pumps, valves), which requires no disturbance to plant cables and results in eliminating thousands of electro-mechanical relay control components. The design is rooted in the highly integrated digital technology applied to the most recent advanced light water reactors under United States (U.S.) Nuclear Regulatory Commission (NRC) design certification review and approval. While this design employs technology from new plants, that technology has been adapted to the modernization of current operating NPPs. Hence, the highly integrated digital I and C and HSI design is referred to as the compact control room digital modernization (CDM). Along with minimal digital equipment, the corresponding HSI design employs compact operator workstations with visual display units (VDU) and soft controls for both the main control room (MCR) and remote shutdown room (RSR), to immediately improve human performance and ultimately facilitate operating staff reduction. Some advanced light water reactors have demonstrated this staff reduction through full scope simulator testing of normal and abnormal plant conditions, with U.S. licensed operating crews from currently-operating U.S. plants. Digital equipment minimization, compact operator workstations, and optimized plant component interfaces that require no disturbance to field cables, also facilitate implementation of the CDM over multiple phases, most of which can be conducted during normal refueling shutdown windows. This phased implementation method includes a novel transition of the I and C, MCR and RSR with an operations centered focus. This paper presents the CDM design, along with qualitative cost/benefit comparisons to currently operating plants with conventional analog I and C and HSI technology; this generation of I and C/HSI is referred to as a conventional control room (CCR). A CCR also includes NPPs that have been upgraded with digital systems, but retain the current partitions between plant I and C systems (i.e., no I and C integration) and retain the current plant system to control board configuration of current NPP control rooms. Even though these comparisons are qualitative, a compelling case is presented for the CDM. (authors)

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Evaluation of The Thermophysical Properties and Microstructure of UPu{sub 24}Zr{sub 15} Metallic Fuel

Featuring high burn-up, high fissile and fertile isotopic density, inherent safety characteristics, and favorable thermal response, actinide transmutation metallic fuels are considered to be among the most promising fuel classes for next generation fast reactors. During reactor operation, it is anticipated that fluctuations in chemical potential along the temperature gradient will lead to migration and redistribution of constituents between radial zones of the cylindrical fuel pin, resulting in compositional inhomogeneity and hence unpredictable fuel performance. Limited experimental fuel performance data is available for fuel selection and certification, therefore different compositions of options uranium-plutonium-zirconium (UPu- Zr) alloys have been investigated. Several complementary techniques, including scanning and transmission electron microscopy (SEM and TEM, respectively), differential scanning calorimetry (DSC), and laser flash diffusivity (LFD) techniques were used to characterize the phase distribution, microstructure, and thermophysical properties of unirradiated U-Pu-Zr fuels in both the as-cast and annealed condition. This information is necessary to understand the irradiated microstructure, properties, and performance of U-Pu-Zr fuels.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Validation of the Computational Fluid Dynamics Method using the Aboveground Configuration of the Dry Cask Simulator

Dry cask applicants submit their spent nuclear fuel dry storage and transportation cask designs to the U.S. Nuclear Regulatory Commission (NRC) for certification under Title 10 of the Code of Federal Regulations (10 CFR) Part 72, 'Licensing Requirements for the Independent Storage of Spent Nuclear Fuel, High-Level Radioactive Waste, and Reactor-Related Greater Than Class C Waste'. The NRC staff performs its technical review of these designs in accordance with 10 CFR Part 72 and NUREG-1536, 'Standard Review Plan for Spent Fuel Dry Storage Systems at a General License Facility,' Revision 1, issued July 2010. To ensure that the cask and fuel material temperatures of the dry cask storage system remain within the allowable limits or criteria for normal, off-normal, and accident conditions, the NRC staff performs a thermal review as part of the technical review. Recent applications increasingly have used thermalhydraulic analyses using computational fluid dynamics (CFD) codes (e.g., ANSYS FLUENT) to demonstrate the adequacy of the thermal design. The NRC performs validation studies of the FLUENT CFD code to assist it in making regulatory decisions to ensure adequate protection for storage and transportation casks. Recent advances in dry storage cask designs have significantly increased the maximum thermal load allowed in a cask in part by increasing the efficiency of internal conduction pathways and by increasing the internal convection through greater canister helium pressure. In efforts to further validate these designs, the NRC in conjunction with the Department of Energy and Sandia National Laboratories (SNL) are conducting an experiment to capture the effects of elevated helium pressures and accurately portray the external convection of aboveground and belowground canister dry cask systems.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Progress of full-scale MCNP6{sup TM} model development of NuScale small modular reactor - 25394

This paper presents the recent progress of development of full-scale MCNP6{sup TM} small modular reactor within NuScale Power LLC (NuScale) using MCNP6{sup TM} version 1.0. This model currently is being used to determine of vessel neutron fluence, nuclear damage, and radiological consequence analysis. The results of the best estimate fluence analysis to support Design Certification Application (DCA) and technical details has been included within License Technical Report (LTR) which had been submitted to US NRC for review in 2017. Currently the detailed analysis of using this full-scale NuScale SMR model is focusing on operational radiological external dose exposure, nuclear damage, nuclear heating and neutron activation of SMR components to support optimized design and RAI (request additional information) response activities. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Comprehensive Performance Calibration Guidance for Perovskites and Other Emerging Solar Cells

Emerging photovoltaic (PV) technologies (e.g., organic, perovskite, and solution processed quantum dot) have attracted remarkable attention with the rapid growth of their efficiencies, and their transition toward commercialization. Accurate and reliable efficiency measurements of these PV technologies are crucial, yet much more complicated than for conventional PV technologies due to the former's pronounced dynamic responses to changes in measurement conditions (e.g., current–voltage (I–V) scan rate and preconditioning) and their susceptibility to degradation. Adjustments to the measurement procedures are therefore necessary so that a reproducible “steady state” is reached during measurement. Furthermore, given the small size of many emerging cells, inappropriate device area definition and solar simulator setup can lead to measurement errors. Here, comprehensive efficiency calibration guidance is offered for emerging solar cells, including area measurement; spectral irradiance translation to standard test conditions; and steady-state electrical performance. The necessity of reporting steady-state efficiency is justified with a statistical performance comparison between conventional and steady-state I–V scans over hundreds of cells the group has received globally for efficiency certifications. The procedures described here do not require specialized measurement instrumentation; what matters most are changes to the measurement protocols. These described changes aim to enable better comparisons between reported efficiencies.

14 SOLAR ENERGY↗

Molecular Precision Engineering for Efficient Binary Organic Photovoltaics through Energy Level and Fibrillar Structure Modulation

Adjusting the energy levels and fibrillar morphology is paramount to enhancing the power conversion efficiency (PCE) of organic solar cells (OSCs). In the present study, an increase in the open-circuit voltage (VOC) is facilitated through the elongation of the alkyl chain within AQx (namely AQx-8), aiming to decrease the free volume ratio (FVR). This reduction in FVR attenuates electron-phonon coupling, thereby augmenting emission efficiency and diminishing the non-radiative energy loss (ΔEnr). To further refine the energy levels and morphological characteristics, the external undecyl chain of AQx-8 is substituted with a shorter carbon chain and cyclohexane noted for its considerable steric hindrance (AQx-H). Additionally, this alteration significantly mitigates intermolecular aggregation, expands the bandgap, and elevates the lowest unoccupied molecular orbital (LUMO) energy level, culminating in an elevated VOC of 0.923 V in devices based on AQx-H. Morphological analysis reveals that blends based on AQx-H exhibit an enhanced multi-length-scale fibrillar structure, which is conducive to exciton dissociation and charge transport, thereby contributing to a high fill factor (FF) nearing 80%. Consequently, this study reports one of the highest binary PCEs documented, standing at 19.5% (with certification at 19.0%).

14 SOLAR ENERGY↗

Black carbon emissions from modern automated cordwood stoves for space heating

Wood burning stove design is improving as regulation become stricter for particulate matter emissions. Here, this study describes results of black carbon (BC) emissions from three modern automated wood stoves when tested in common failure modes using a test protocol that included cold-starts, high and low fuel loading densities, and use of overly large pieces of fuel. Emission sampling was performed using a dilution sampling system in tandem with an aethalometer to measure BC with high time resolution. Results show that the time-weighted average BC emission rates were 0.91, 4.30, and 1.74 g/h for the three stoves tested (A, B, and C respectively), the values, both higher and lower than the United States 2020 certification test emission limit of 2.5 g/h. The results demonstrate good performance overall, given the rigorous nature of the testing protocol used. The aethalometer data showed that the performance was relatively poor during cold-start, when the fuel was ignited and combusted without a coalbed, and when stoves failed to optimize air delivery due to specific loading and output conditions. During the cold-start test section, the average BC emission rate was seven times higher than the overall average for Stove A, 10 times above the average for Stove B, and two times above the average emission rate for Stove C. Calculations of the Average Angstrom Absorption Exponent (AAE) of the exhaust aerosol showed little correlation with BC concentration. The results show that automation results in a quantifiable reduction in particular BC emissions.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

A detailed chemical kinetic modeling and experimental investigation of the low- and high-temperature chemistry of n-butylcyclohexane

Chemical kinetic models of gasoline, jet, and diesel fuels and their mixtures with bioderived fuels are needed to assess fuel property effects on efficiency, emissions, and other performance metrics in internal combustion and gas turbine engines. As these real fuels have too many fuel components to be included in a chemical kinetic model, surrogate fuels containing fewer components are used to represent them. These surrogate fuels mimic the chemical classes or molecular structures contained in the real fuel. One of the important chemical classes in gasoline, jet, and diesel fuels comprises cyclohexanes. Cyclohexanes comprise about 30% or more by weight in diesel fuel. Also, Mueller et al proposed n-butylcyclohexane (nBCH) as a component in a nine-component surrogate palette to represent the ignition properties, distillation curve, density, and molecular structures of a diesel certification fuel. Herein, experimental measurements of the ignition delay times (IDTs) of nBCH in a shock tube and in a rapid compression machine are reported over a wide range of temperature, pressure, and equivalence ratio important for enabling the validation of a chemical kinetic model for nBCH for combustion in diesel engines. The range of conditions are temperatures of 630–1420 K, pressures of 10, 30, and 50 bar, and equivalence ratios of 0.3, 0.5, 1.0, and 2.0 in ‘air’. A detailed chemical model is developed for nBCH to simulate its ignition at both low and high-temperature conditions and at relevant elevated pressures. The experimentally measured IDTs are used to improve and validate the chemical kinetic model.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

A mathematical assessment of the isolation random forest method for anomaly detection in big data

We present the mathematical analysis of the Isolation Random Forest Method (IRF Method) for anomaly detection, proposed by Liu F.T., Ting K.M. and Zhou Z. H. in their seminal work as a heuristic method for anomaly detection in Big Data. We prove that the IRF space can be endowed with a probability induced by the Isolation Tree algorithm (iTree). In this setting, the convergence of the IRF method is proved, using the Law of Large Numbers. Here, a couple of counterexamples are presented to show that the method is inconclusive and no certificate of quality can be given, when using it as a means to detect anomalies. Hence, an alternative version of the method is proposed whose mathematical foundation is fully justified. Furthermore, a criterion for choosing the number of sampled trees needed to guarantee confidence intervals of the numerical results is presented. Finally, numerical experiments are presented to compare the performance of the classic method with the proposed one.

97 MATHEMATICS AND COMPUTING↗

Standards development for modules in high temperature micro-environments

Photovoltaic (PV) module qualification standards, IEC 61215 and IEC 61730, were designed to apply to “general open-air climates” and IEC 61730 specifically indicated applicability of ambient air temperature of 40°C. Additionally, these standards provided allowances for so-called “open rack mounted PV modules” without a clear definition of “open-rack.” These implied restrictions and allowances meant that hotter climates or thermally restrictive installation methods may not be covered by these often customer-mandated certification standards. This is particularly salient for the significant growth regions of the Middle East and India that would be expected to operate at significantly higher temperatures. The applicability of these documents raised issues over the definition of “open rack” and the fact that the geographic location is just as important as the mounting configuration in assessing the impact of the micro-environment of a PV module. This work summarizes the scientific background for IEC Technical Specification 63126:2020 ED1, titled “Guidelines for qualifying PV modules components and materials for operation at high temperatures.” This standard was recently published by the IEC and is the first step in a systematic effort to rework these standards to address the question of temperature more directly. Instead of specifying a mounting condition, we specify different suites of tests suitable for a system (PV module, mounting style, and location) defined by the 98th percentile cell temperature. With a defined temperature regime to work from, this allowed us to use existing literature research combined with additional modeling work to determine, which tests would need to be modified. This resulted in suggested changes to material thermal indices, thermal cycling temperatures, hot spot testing, ultraviolet testing, and bypass diode testing among other tests and characteristics described in this study.

14 SOLAR ENERGY↗

Witnessing Entanglement and Quantum Correlations in Condensed Matter: A Review

The detection and certification of entanglement and quantum correlations in materials is of fundamental and far-reaching importance, and has seen significant recent progress. It impacts both the understanding of the basic science of quantum many-body phenomena as well as the identification of systems suitable for novel technologies. Frameworks suitable to condensed matter that connect measurements to entanglement and coherence have been developed in the context of quantum information theory. These take the form of entanglement witnesses and quantum correlation measures. Here, the underlying theory of these quantities, their relation to condensed matter experimental techniques, and their application to real materials are comprehensively reviewed. In addition, their usage in, e.g., protocols, the relative advantages and disadvantages of witnesses and measures, and future prospects in, e.g., correlated electrons, entanglement dynamics, and entangled spectroscopic probes, are presented. Consideration is given to the interdisciplinary nature of this emerging research and substantial ongoing progress by providing an accessible and practical treatment from fundamentals to application. Particular emphasis is placed on quantities accessible to collective measurements, including by susceptibility and spectroscopic techniques. This includes the magnetic susceptibility witness, one-tangle, concurrence and two-tangle, two-site quantum discord, and quantum coherence measures such as the quantum Fisher information.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Mandating better buildings: a global review of building codes and prospects for improvement in the United States

This paper provides a global overview of the design, implementation, and evolution of building energy codes. Reflecting alternative policy goals, building energy codes differ significantly across the United States, the European Union, and China. This review uncovers numerous innovative practices including greenhouse gas emissions caps per square meter of building space, energy performance certificates with retrofit recommendations, and inclusion of renewable energy to achieve “nearly zero-energy buildings”. These innovations motivated an assessment of an aggressive commercial building code applied to all US states, requiring both new construction and buildings with major modifications to comply with the latest version of the ASHRAE 90.1 Standards. Using the National Energy Modeling System (NEMS), we estimate that by 2035, such building codes in the United States could reduce energy for space heating, cooling, water heating and lighting in commercial buildings by 16%, 15%, 20% and 5%, respectively. Impacts on different fuels and building types, energy rates and bills as well as pollution emission reductions are also examined.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

A homogeneous model for monotone mixed horizontal linear complementarity problems

In this paper, we propose a homogeneous model for the class of mixed horizontal linear complementarity problems. The proposed homogeneous model is always solvable and provides the solution of the original problem if it exists, or a certificate of infeasibility otherwise. Our formulation preserves the sparsity of the original formulation and does not reduce to the homogeneous model of the equivalent standard linear complementarity problem. We study the properties of the model and show that interior-point methods can be used efficiently for the numerical solutions of the homogeneous problem. Finally, numerical experiments show convincingly that it is more efficient to use the proposed homogeneous model for the mixed horizontal linear complementarity problem than to use known homogeneous models for the equivalent standard linear complementarity problem.

97 MATHEMATICS AND COMPUTING↗

Forensic investigation of plutonium metal: a case study of CRM 126

In our study, a certified plutonium metal reference material (CRM 126) with a known production history is examined using analytical methods that are commonly employed in nuclear forensics for provenancing and attribution. Moreover, the measured plutonium isotopic composition and actinide assay are consistent with values reported on the reference material certificate. Model ages from U/Pu and Am/Pu chronometers agree with the documented production timeline. Finally, these results confirm the utility of these analytical methods and highlight the importance of a holistic approach for forensic study of unknown materials.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Radiochronometric analysis of an historic Cs-137 activity standard

In this work, a 137 Cs activity standard discovered during routine inventory was analyzed to determine its model age using radiochronometry. The aqueous activity standard was separated using an established separation method that employs commercially available Sr resin. The method was also tested against a nuclear forensics reference material developed specifically for benchmarking 137 Cs radiochronometry methods. Results of the analyses showed good agreement between the results and the certified values of the reference material. Analysis of the discovered activity standard were also in good agreement with the activity certification date, though uncertainty was higher due to natural Ba contaminating the sample and the stable 133 Cs used as a carrier during the standard’s production.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗