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Resource recovery from urban stock, the example of cadmium and tellurium from thin film module recycling

Highlights: ► The semiconductor layer on thin-film photovoltaic modules can be removed from the glass-plate by vacuum blast cleaning. ► The separation of blasting agent and semiconductor can be performed using flotation with a valuable yield of 55%. ► PV modules are a promising source for the recovery of tellurium in the future. - Abstract: Raw material supply is essential for all industrial activities. The use of secondary raw material gains more importance since ore grade in primary production is decreasing. Meanwhile urban stock contains considerable amounts of various elements. Photovoltaic (PV) generating systems are part of the urban stock and recycling technologies for PV thin film modules with CdTe as semiconductor are needed because cadmium could cause hazardous environmental impact and tellurium is a scarce element where future supply might be constrained. The paper describes a sequence of mechanical processing techniques for end-of-life PV thin film modules consisting of sandblasting and flotation. Separation of the semiconductor material from the glass surface was possible, however, enrichment and yield of valuables in the flotation step were non-satisfying. Nevertheless, recovery of valuable metals from urban stock is a viable method for the extension of the availability of limited natural resources.

36 MATERIALS SCIENCE↗

Advanced Membrane Separation Technologies for Energy Recovery from Industrial Process Streams

Recovery of energy from relatively low-temperature waste streams is a goal that has not been achieved on any large scale. Heat exchangers do not operate efficiently with low-temperature streams and thus require such large heat exchanger surface areas that they are not practical. Condensing economizers offer one option for heat recovery from such streams, but they have not been widely implemented by industry. A promising alternative to these heat exchangers and economizers is a prototype ceramic membrane system using transport membrane technology for separation of water vapor and recovery of heat. This system was successfully tested by the Gas Technology Institute (GTI) on a natural gas fired boiler where the flue gas is relatively clean and free of contaminants. However, since the tubes of the prototype system were constructed of aluminum oxide, the brittle nature of the tubes limited the robustness of the system and even limited the length of tubes that could be used. In order to improve the robustness of the membrane tubes and make the system more suitable for industrial applications, this project was initiated with the objective of developing a system with materials that would permit the system to function successfully on a larger scale and in contaminated and potentially corrosive industrial environments. This required identifying likely industrial environments and the hazards associated with those environments. Based on the hazardous components in these environments, candidate metallic materials were identified that are expected to have sufficient strength, thermal conductivity and corrosion resistance to permit production of longer tubes that could function in the industrial environments identified. Tests were conducted to determine the corrosion resistance of these candidate alloys, and the feasibility of forming these materials into porous substrates was assessed. Once the most promising metallic materials were identified, the ability to form an alumina membrane layer on the surface of the metallic tubes was evaluated. Evaluation of this new style of membrane tube involved exposure to SO 2 containing gases as well as to materials with a potential for fouling. Once the choice of substrate and membrane materials and design were confirmed, about 150 tubes were fabricated and assembled into three modules. These modules were mounted on an industrial size boiler and their performance carefully monitored during a limited testing period. The positive results of this performance test confirm the feasibility of utilizing such a system for recovery of heat and water from industrial waste streams. The improved module design along with use of long metallic substrate tubes with a ceramic membrane on the outer surface resulted in the successful, limited scale demonstration of the Transport Membrane Condenser (TMC) technology in the GTI test facility. This test showed this technology can successfully recover a significant amount of heat and water from gaseous waste streams. However, before industry will make the investment to install a full scale TMC, a full scale system will need to be constructed, installed and successfully operated at a few industrial sites. Companies were identified that had an interest in serving as a host site for a demonstration system.

Keiser, James R.↗

Variable length adjacent partitioning for PTS based PAPR reduction of OFDM signal

Peak-to-Average power ratio (PAPR) is a major drawback in OFDM communication. It leads the power amplifier into nonlinear region operation resulting into loss of data integrity. As such, there is a strong motivation to find techniques to reduce PAPR. Partial Transmit Sequence (PTS) is an attractive scheme for this purpose. Judicious partitioning the OFDM data frame into disjoint subsets is a pivotal component of any PTS scheme. Out of the existing partitioning techniques, adjacent partitioning is characterized by an attractive trade-off between cost and performance. With an aim of determining effects of length variability of adjacent partitions, we performed an investigation into the performances of a variable length adjacent partitioning (VL-AP) and fixed length adjacent partitioning in comparison with other partitioning schemes such as pseudorandom partitioning. Simulation results with different modulation and partitioning scenarios showed that fixed length adjacent partition had better performance compared to variable length adjacent partitioning. As expected, simulation results showed a slightly better performance of pseudorandom partitioning technique compared to fixed and variable adjacent partitioning schemes. However, as the pseudorandom technique incurs high computational complexities, adjacent partitioning schemes were still seen as favorable candidates for PAPR reduction.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Solution Coating of Pharmaceutical Nanothin Films and Multilayer Nanocomposites with Controlled Morphology and Polymorphism

Nanosizing is rapidly emerging as an alternative approach to enhance solubility and thus the bioavailability of poorly aqueous soluble active pharmaceutical ingredients (APIs). Although numerous techniques have been developed to perform nanosizing of API crystals, precise control and modulation of their size in an energy and material efficient manner remains challenging. As such, in this study, we present meniscus-guided solution coating as a new technique to produce pharmaceutical thin films of nanoscale thickness with controlled morphology. We demonstrate control of aspirin film thickness over more than 2 orders of magnitude, from 30 nm to 1.5 μm. By varying simple process parameters such as the coating speed and the solution concentration, the aspirin film morphology can also be modulated by accessing different coating regimes, namely the evaporation regime and the Landau–Levich regime. Using ellipticine—a poorly water-soluble anticancer drug—as another model compound, we discovered a new polymorph kinetically trapped during solution coating. Furthermore, the polymorphic outcome can be controlled by varying coating conditions. We further performed layer-by-layer coating of multilayer nanocomposites, with alternating thin films of ellipticine and a biocompatible polymer, which demonstrate the potential of additive manufacturing of multidrug-personalized dosage forms using this approach.

36 MATERIALS SCIENCE↗

Coupled methane and NO x conversion on Pt + Pd/Al 2 O 3 monolith: Conversion enhancement through feed modulation and Mn 0.5 Fe 2.5 O 4 spinel addition

The performance of a dual-layer Pt-Pd/Al 2 O 3 washcoated monolith promoted by an Al 2 O 3 -supported Mn 0.5 Fe 2.5 O 4 spinel base layer was evaluated with the objective to develop a catalyst with a lower loading of Platinum group metal (PGM) for stoichiometric natural gas vehicle (NGV) emission control. Flow reactor results show that a combination of a lean/rich modulated feed and spinel addition gives enhanced methane and NO conversions compared to a steady-state feed having the same overall composition. Washcoated catalysts – PGM-only, spinel-only, PGM + spinel – were compared over a wide range of operating conditions. The results show a decrease in the methane conversion light-off temperature of up to 85 °C for an application-relevant feed (CH 4 + NO + H 2 + CO + O 2 + H 2 O + CO 2 ) while a moderate 40 °C decrease was observed for a simple feed (CH 4 + O 2 + H 2 O + CO 2 ). In the absence of spinel the modulation enhancement is negatively impacted at high methane conversion (> 80 %). The data show that the O 2 storage and release property of the spinel is needed to fully exploit the modulation enhancement. The mechanism responsible for the enhancement is linked to suppression of O 2 inhibition on the methane oxidation rate near the stoichiometric neutral point (λ = 1). Sufficiently fast cycling achieves a balance between a metallic and oxidic precious metal crystallites favorable for methane activation. The addition of spinel moves this balance closer to the λ = 1 feed, enabling a high oxidation efficiency with lower byproduct NH 3 selectivity. Enhancement in the NO conversion follows the methane conversion due to an easier NO reduction under the slightly rich of stoichiometric feed. Comparison of the PGM + spinel catalysts to PGM-only catalysts shows that the addition of spinel in combination with modulation can achieve the same activity with a lower PGM loading.

03 NATURAL GAS↗

Collisional simulations of the modulator section in coherent electron cooling

The first section of any coherent electron cooling (CeC) system is the modulator, where the density of the electron beam is modulated by the copropagating ion beam. This density modulation is a result of Coulomb collisions between the individual particles of the two beams. The pairwise, stochastic part of the interactions impacts the overall performance of the CeC process. We present the first simulations of the density modulations of the electron beams from a collisional picture of the dynamics, considering the proof-of-principle CeC experiments at Brookhaven National Laboratory. These simulations were performed using PHAD, which is the first efficient, large-scale collisional numerical method in beam physics that we have previously developed and benchmarked. Realistic beam distributions and external fields have been optimized to provide strong modulation signals necessary for variations of coherent electron cooling systems. Cooling performance limits and potential collisionless simulation pitfalls are pointed out. Published by the American Physical Society 2024

43 PARTICLE ACCELERATORS↗

Towards a NEAMS-based high-fidelity model of the MARVEL reactor

This report outlines the progress of Idaho National Laboratory in developing a high-fidelity and high-resolution model of the Microreactor Applications Research Validation and Evaluation reactor. The model was developed under the Nuclear Energy Advanced Modeling and Simulation microreactor application driver at Idaho National Laboratory. The overarching objective of this activity is the development of a high-fidelity multiphysics MARVEL model using NEAMS tools, and to verify and validate NEAMS tools against MARVEL reference simulation and experimental data, respectively. This is a unique opportunity to conduct multiphysics analysis on a soon-to-be-deployed microreactor. This multiphysics model developed under the NEAMS-funded INL microreactor application driver leverages three single-physics models coupled via the MOOSE’s MultiApp and Transfer systems. The latter systems enable in-memory data transfer between MOOSE-based and MOOSE-wrapped applications. The first single-physics model, that functions as main application, leverages Griffin to model the neutron transport in the core through the discontinuous finite element (DFEM) discrete ordinates solver (SN). Several optimization flags that were developed by the Griffin developer team were beta-tested to enhance the solver’s performance. These include the combined use of using_average_xs and update_averaged_xs_on that enable to avoid expensive on-the-fly cross sections evaluations at each linear iterations in favor of evaluations of the macroscopic cross sections at each Picard iteration. The second single-physics model uses BISON to handle solid heat transfer and asymptotic hydrogen redistribution analysis in the fuel. While the model returns consistent results for the temperature and hydrogen distribution in the fuel, a mismatch was noticed in the calculated temperature in the reflector due to the value of the gap conductance used in our model. Ongoing investigations are being performed to assess the origin of this discrepancy. Finally, the System Analysis Module (SAM) was used to model the flow of the sodium-potassium eutectic in the primary loop. A first verification was also performed showing good agreement in terms of mass flow rate and inlet temperature. All mesh files were generated using the MOOSE Reactor module, removing the need for external meshing tools. Notably, this workscope represents one of the initial applications of the MOOSE Reactor module for modeling highly irregular geometries. The use of the reactor module significantly streamlined the mesh generation process. The full multiphysics mode, that combines all the single physics models, was leveraged to conduct initial steady-state multiphysics simulations to compute power, and temperature distribution in the reactor. Initial testing was performed for transient simulations as well. In this case, the new checkpoint restart capability for eigenvalue calculations was tested showing the capability for streamlined restart of transient calculations. Future work will focus on improving the fidelity of the model by performing comprehensive code-to-code comparisons. For instance, the full-core Griffin neutronics model will be benchmarked against MCNP reference results, that were provided by the MARVEL design team. Additionally, the SAM T/H model will be verified against reference RELAP-5 results for selected accident scenarios. Besides code-to-code verification exercises, the model fidelity will be improved by replacing the single-channel SAM model with a more complex SAM-Pronghorn coupled model, in which the sub-channel capability is deployed to obtain radial temperature resolution in the coolant. This model will be developed in synergy with the NEAMS thermal hydraulics team.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Preliminary Thermal Modeling of HI-Storm 100S-218 Version B Storage Modules at Hope Creek Cuclear Power Station ISFSI

As part of the Used Fuel Disposition Campaign of the U. S. Department of Energy, Office of Nuclear Energy (DOE-NE) Fuel Cycle Research and Development, a consortium of national laboratories and industry is performing visual inspections and temperature measurements of selected storage modules at various locations around the United States. This report documents thermal analyses in in support of the inspections at the Hope Creek Nuclear Generating Station ISFSI. This site utilizes the HI-STORM100 vertical storage system developed by Holtec International. This is a vertical storage module design, and the thermal models are being developed using COBRA-SFS (Michener, et al., 1987), a code developed by PNNL for thermal-hydraulic analyses of multi assembly spent fuel storage and transportation systems. This report describes the COBRA-SFS model in detail, and presents pre-inspection predictions of component temperatures and temperature distributions. The final report will include evaluation of inspection results, and if required, additional post-test calculations, with appropriate discussion of results.

site inspections↗

SU-E-T-65: Characterization of a 2D Array for QA and Pretreatment Plan Verification

Purpose: The OCTAVIUS detector729 is a 2D array of 729 air vented cubic plane parallel ion chambers used for pretreatment verification and QA. In this study we investigated dosimetric characteristics of this system for clinical photon beam dosimetry. Methods: Detector performance evaluation included determination of the location of the effective point of measurement (EPM), sensitivity, linearity, and reproducibility of detector response, as well as output factor, dose rate, and source to surface distance (SSD) dependence. Finally, assessment of wedge modulated fields was carried out. All the evaluations were performed five times for low and high photon energies. For reference measurements, a 0.6 cc ionization chamber was used. Data analysis and comparison of the OCTAVIUS detector with reference ion chamber data was performed using the VeriSoft patient plan verification software. Results: The reproducibility and stability of the measurements are excellent, the detector showed same signal with a maximum deviation of less than 0.5% in short and long term. Results of sensitivity test showed same signal with a maximum deviation of approximately 0.1%. As the detector 729 response is linear with dose and dose rate, it can be used for the measurement at regions of high dose gradient effectively. The detector agrees with the ionization chamber measurement to within 1% for SSD range of 75 to 125 cm. Also, its measured wedge modulated profiles matched very well with ion chamber dose profiles acquired in a water tank. Conclusions: As the response of the detector 729 is linear with dose and dose rate, it can be used for the measurements in the areas of dose gradients effectively. Based on the measurements and comparisons performed, this system is a reliable and accurate dosimeter for QA and pretreatment plan verification in radiotherapy.

60 APPLIED LIFE SCIENCES↗

Low-PAPR interleaved single-carrier FDM scheme for optical wireless communications

As a potential complementary access technology for the 5G wireless systems, optical wireless communication (OWC) gains extensive attention for decades owing to its numerous advantages of broad license-free spectrum, immunity to electromagnetic interference and high-level privacy. However, two rigorous obstacles to achieve high data-rate OWC transmission are the severe nonlinear clipping of transmitter and high-frequency attenuation of OWC system. In this paper, we propose the first interleaved single-carrier frequency-division multiplexing (I-SC-FDM) scheme for OWC systems. Compared with orthogonal frequency-division multiplexing (OFDM), I-SC-FDM has a lower peak-to-average power ratio, which makes it more immune to the nonlinearity clipping in OWC systems. Meanwhile, for the bandwidth-limited OWC systems, I-SC-FDM has better performance on resistance to the serious high-frequency distortion. The simulation results indicate that, under the transmitter nonlinearity and optical-wireless diffuse fading channel, the maximum Q{sup 2} of I-SC-FDM is about 3.44 dB and 3.14 dB higher than that of OFDM when 4-ary quadrature amplitude modulation (4-QAM) and 16-QAM are modulated, respectively. The results show the feasibility and advantages of I-SC-FDM for cost-sensitive OWC systems.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Visualization of Multi-Dimensional Imaging Data for the DIII-D National Fusion Facility

With funding provided from the Office of Fusion Energy Science’s program on Diagnostic Systems for Magnetic Fusion Energy Sciences, the PI and his team have pioneered the development of microwave imaging systems for magnetic fusion plasma diagnostics. Specifically, electron cyclotron emission (ECE) imaging [1], a passive radiometric technique, measures electron temperature fluctuations; and microwave imaging reflectometry (MIR) [2], an active radar imaging technique, measures electron density fluctuations. These microwave imaging diagnostic instruments developed by UC Davis have made important contributions to fusion science in a relatively short period of time from their original installation on DIII-D. The microwave imaging diagnostic technique has matured considerably since the beginning of a fruitful collaboration with DIII-D and PPPL, and has also been adopted at preeminent tokamak facilities worldwide. As discussed in detail in the following, this has continued with the development of revolutionary microwave diagnostic instruments employing monolithic millimeter wave integrated circuit (MMIC) system-on-chip (SoC) technology. Specifically, “chip” receivers mounted in liquid crystal polymer (LCP) modules have been demonstrated to dramatically improve the performance of the electron cyclotron emission imaging (ECEI) system including: 30x improvement in noise temperature thereby permitting absolute 2-D electron temperature images, outstanding shielding against out-of-band interference including microwave bursting which had plagued previous ELM studies using the old quasi-optical mini-lens ECEI system, and independent modules facilitating flexible repair and replacement. Under the “Visualization of multi-dimensional imaging data for the DIII-D National Fusion Facility” program, funding was provided for a research scientist postdoc and a Ph.D. student to support physics studies at DIII-D employing these instruments. This endeavor is synergistic with our current grant under the DOE Fusion Energy Sciences (FES) program on Diagnostic Systems for Magnetic Fusion Energy Sciences. This support considerably increased the scientific output of the diagnostics. The activities were strongly focused in the areas of pedestal and ELM stability, energetic particle confinement, and the early detection and avoidance of tokamak disruptions employing the microwave imaging diagnostic instruments developed under the advanced diagnostics program where imaging of the ELM crash was made possible by the elimination of the interference from the associated microwave “bursts”

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

SU-E-T-309: Dosimetric Comparison of Simultaneous Integrated Boost Treatment Plan Between Intensity Modulated Radiotherapies (IMRTs), Dual Arc Volumetric Modulated Arc Therapy (DA-VMAT) and Single Arc Volumetric Modulated Arc Therapy (SA-VMAT) for Nasopharyngeal Carcinoma (NPC)

Purpose: To compare the plan quality and performance of Simultaneous Integrated Boost (SIB) Treatment plan between Seven field (7F) and Nine field(9F) Intensity Modulated Radiotherapies and Single Arc (SA) and Dual Arc (DA) Volumetric Modulated Arc Therapy( VMAT). Methods: Retrospective planning study of 16 patients treated in Elekta Synergy Platform (mlci2) by 9F-IMRT were replanned with 7F-IMRT, Single Arc VMAT and Dual Arc VMAT using CMS, Monaco Treatment Planning System (TPS) with Monte Carlo simulation. Target delineation done as per Radiation Therapy Oncology Protocols (RTOG 0225&0615). Dose Prescribed as 70Gy to Planning Target Volumes (PTV70) and 61Gy to PTV61 in 33 fraction as a SIB technique. Conformity Index(CI), Homogeneity Index(HI) were used as analysis parameter for Target Volumes as well as Mean dose and Max dose for Organ at Risk(OAR,s).Treatment Delivery Time(min), Monitor unit per fraction (MU/fraction), Patient specific quality assurance were also analysed. Results: A Poor dose coverage and Conformity index (CI) was observed in PTV70 by 7F-IMRT among other techniques. SA-VMAT achieved poor dose coverage in PTV61. No statistical significance difference observed in OAR,s except Spinal cord (P= 0.03) and Right optic nerve (P=0.03). DA-VMAT achieved superior target coverage, higher CI (P =0.02) and Better HI (P=0.03) for PTV70 other techniques (7F-IMRT/9F-IMRT/SA-VMAT). A better dose spare for Parotid glands and spinal cord were seen in DA-VMAT. The average treatment delivery time were 5.82mins, 6.72mins, 3.24mins, 4.3mins for 7F-IMRT, 9F-IMRT, SA-VMAT and DA-VMAT respectively. Significance difference Observed in MU/fr (P <0.001) and Patient quality assurance pass rate were >95% (Gamma analysis (Γ3mm, 3%). Conclusion: DA-VAMT showed better target dose coverage and achieved better or equal performance in sparing OARs among other techniques. SA-VMAT offered least Treatment Time than other techniques but achieved poor target coverage. DA-VMAT offered shorter delivery time than 7F-IMRT and 9F-IMRT without compromising the plan quality.

60 APPLIED LIFE SCIENCES↗

SU-F-T-186: A Treatment Planning Study of Normal Tissue Sparing with Robustness Optimized IMPT, 4Pi IMRT, and VMAT for Head and Neck Cases

Purpose: We performed a retrospective dosimetric comparison study between the robustness optimized Intensity Modulated Proton Therapy (RO-IMPT), volumetric-modulated arc therapy (VMAT), and the non-coplanar 4? intensity modulated radiation therapy (IMRT). These methods represent the most advanced radiation treatment methods clinically available. We compare their dosimetric performance for head and neck cancer treatments with special focus on the OAR sparing near the tumor volumes. Methods: A total of 11 head and neck cases, which include 10 recurrent cases and one bilateral case, were selected for the study. Different dose levels were prescribed to tumor target depending on disease and location. Three treatment plans were created on commercial TPS systems for a novel noncoplanar 4π method (20 beams), VMAT, and RO-IMPT technique (maximum 4 fields). The maximum patient positioning error was set to 3 mm and the maximum proton range uncertainty was set to 3% for the robustness optimization. Line dose profiles were investigated for OARs close to tumor volumes. Results: All three techniques achieved 98% coverage of the CTV target and most photon plans had less than 110% of the hot spots. The RO-IMPT plans show superior tumor dose homogeneity than 4? and VMAT plans. Although RO-IMPT has greater R50 dose spillage to the surrounding normal tissue than 4π and VMAT, the RO-IMPT plans demonstrate better or comparable OAR (parotid, mandible, carotid, oral cavity, pharynx, and etc.) sparing for structures closely abutting tumor targets. Conclusion: The RO-IMPT’s ability of OAR sparing is benchmarked against the C-arm linac based non-coplanar 4π technique and the standard VMAT method. RO-IMPT consistently shows better or comparable OAR sparing even for tissue structures closely abutting treatment target volume. RO-IMPT further reduces treatment uncertainty associated with proton therapy and delivers robust treatment plans to both unilateral and bilateral head and neck cancer patients with desirable treatment time.

60 APPLIED LIFE SCIENCES↗

Life Cycle Inventory of Current Photovoltaic Module Recycling Processes in Europe

Solar photovoltaic (PV) installations must be properly dismantled and any waste treated and disposed at the end of project life. However, because most of the world's nearly 400 GW of PV systems have been built in the past decade - each expected to operate for between 20 and 30 years - current PV module waste volumes do not yet justify widespread operation of PV recycling facilities. The necessary policies and technologies for recycling PV systems are currently under rapid development. With modifications to the European waste electrical and electronic equipment directive (WEEE 2012/19/EU) in 2012, take back and recycling of PV modules is, in fact, already mandatory in Europe. There, take back and recycling is currently performed in small but annually-increasing quantities. Even though waste treatment is considered part of a module's life cycle, only a few life cycle inventories (LCI) of energy and materials flows are available for the industrial recycling processes that are used today to recycle crystalline silicon-based (c-Si) PV modules. LCI are the data inputs that inform lifecycle assessments which quantify the environmental impacts across the full life cycle of PV modules - from manufacturing and use to end of life. To help progress the industry forward, a survey of European recyclers was performed to characterize existing commercial recycling processes and share associated life cycle inventory data. System Boundaries: The reference unit, or "functional unit" in the vocabulary of life cycle assessment, is defined as the processing of one metric ton of crystalline silicon PV modules in recycling lines for laminated glass, metals, and electronic wastes. Today, all modules are processed in discrete batches, yet not metered at that scale. Thus the process energy for a batch is estimated based on scaled annual production data as well as on input and output streams.

14 SOLAR ENERGY↗

Millimeter-wave home area network prospect with cost-effective RoF links

The growth towards the millimeter-wave band in the home area networks (HAN) leads to high data rate transmission to satisfy the new user services. Unfortunately, the transmission coverage in this band is limited to short distances because of the strong air absorption and obstacles such as walls. The effort is then focused on the extension of the network coverage of the wireless link in this band. Solutions based on multiple connected access points to optical fibers are useful methods to ensure wireless connectivity to the entire home. For HAN applications, radio-over-fiber (RoF) using intensity modulation and direct detection technique is the mostly favorite technology for the transmission of a broadband wireless signal because dealing with a cost-effective solution. We investigate in this paper the performance of such RoF-wireless architecture with low-cost optoelectronic modules through the error vector magnitude (EVM) metric. The RoF links investigated are a directly modulated VCSEL with integrated photoreceiver module, an electroabsorption-modulated laser with PIN photodiode and a Mach–Zehnder Modulator with PIN photodiode. A simulation approach based on equivalent electrical circuit models of photonic components is developed in ADS (Advanced Design System) by using a co-simulation technique that combines both analog and digital signals. The downlink channel of the complete transmission system including wireless channel and frequency conversion circuits to millimeter-wave (mm-wave) band is studied by simulation. The obtained results of EVM show good performances of cost-effective links with QPSK and 16-QAM modulation over a dynamic range of 15 dB.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

3D-Printed, Superelastic Polypyrrole–Graphene Electrodes with Ultrahigh Areal Capacitance for Electrochemical Energy Storage

Disruptive custom electronics require a transformation in energy storage systems from traditional thin-film units to shape conformable 3D components. However, current thick electrodes suffer from uncontrollable geometries and architectures, which lead to ion diffusion limitations, and poor mechanical properties. Here, designed, superelastic polypyrrole (PPy)-coated graphene aerogel (GA) electrodes are fabricated via 3D printing and polymer self-assembly methods. This resilient GA template (up to 90% compression) can be printed into any desired shape including engineered 3D architectures with periodic macropores, which promote the uniform deposition and adhesion of PPy onto the support. Additionally, the coated PPy thin film increases the specific gravimetric capacitance of the GA electrode from 14 to 395 F g -1 with 90% retention after 5000 charging–discharging cycles. The capacitance remains the same value after 100 times compression cycles. It also improves the compressive strength by one order of magnitude from 0.14 to 2.4 MPa. Areal capacitance and energy density of the PPy–GA electrode are 2 F cm -2 and 0.78 mWh cm -2 , respectively, which to the best of the knowledge break the record for compressible electrodes, respectively. This approach enables the fabrication of complex architectured energy storage modules with enhanced compressibility, ultrahigh areal electrochemical performance, and excellent cyclability.

25 ENERGY STORAGE↗

Fully Inkjet‐Printed, 2D Materials‐Based Field‐Effect Transistor for Water Sensing

Abstract Despite significant progress in solution‐processing of 2D materials, it remains challenging to reliably print high‐performance semiconducting channels that can be efficiently modulated in a field‐effect transistor (FET). Herein, electrochemically exfoliated MoS 2 nanosheets are inkjet‐printed into ultrathin semiconducting channels, resulting in high on/off current ratios up to 10 3 . The reported printing strategy is reliable and general for thin film channel fabrication even in the presence of the ubiquitous coffee‐ring effect. Statistical modeling analysis on the printed pattern profiles suggests that a spaced parallel printing approach can overcome the coffee‐ring effect during inkjet printing, resulting in uniform 2D flake percolation networks. The uniformity of the printed features allows the MoS 2 channel to be hundreds of micrometers long, which easily accommodates the typical inkjet printing resolution of tens of micrometers, thereby enabling fully printed FETs. As a proof of concept, FET water sensors are demonstrated using printed MoS 2 as the FET channel, and printed graphene as the electrodes and the sensing area. After functionalization of the sensing area, the printed water sensor shows a selective response to Pb 2+ in water down to 2 ppb. This work paves the way for additive nanomanufacturing of FET‐based sensors and related devices using 2D nanomaterials.

36 MATERIALS SCIENCE↗

Nonlinear model predictive control for mode‐switching operation of reversible solid oxide cell systems

Abstract Solid oxide cells (SOCs) are a promising dual‐mode technology for the production of hydrogen through high‐temperature water electrolysis, and the generation of power through a fuel cell reaction that consumes hydrogen. Switching between these two modes as the price of electricity fluctuates requires reversible SOC operation and accurate tracking of hydrogen and power production set points. Moreover, a well‐functioning control system is important to avoid cell degradation during mode‐switching operation. In this article, we apply nonlinear model predictive control (NMPC) to an SOC module and supporting equipment and compare NMPC performance to classical proportional‐integral (PI) control strategies, while switching between the modes of hydrogen and power production. While both control methods provide similar performance across various metrics during mode switching, NMPC demonstrates a significant advantage in reducing cell thermal gradients and curvatures (mixed spatial‐temporal partial derivatives), thereby helping to mitigate long‐term degradation.

08 HYDROGEN↗