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NASA NTRS2021

Tracking Smoke from a Prescribed Fire and its Impacts on Local Air Quality using Temporally Resolved GOES-16 ABI Aerosol Optical Depth (AOD)

Aerosol optical depth (AOD) retrieved from the GOES-16 Advanced Baseline Imager (ABI) was used to track a smoke plume from a prescribed fire in northeastern Virginia on 8 March 2020. Weather and atmospheric conditions created a favorable environment to transport the plume through the Washington, D.C., and Baltimore, Maryland, metro areas in the afternoon and concentrate smoke near the surface, degrading air quality for several hours. ABI AOD with 5-min temporal resolution and 2-km spatial resolution definitively identified the timing and geographic extent of the plume during daylight hours. Comparison to AERONET AOD indicates that ABI AOD captured the relative change in AOD due to passage of the smoke, with a mean absolute error of 0.047. Ground-based measurements of fine particulate matter (PM2.5) confirm deteriorations in air quality coincident with the progression of the smoke. Ceilometer aerosol backscatter profiles verify plume transport timing and indicate that smoke aerosols were well mixed in a shallow boundary layer. This event illustrates the advantages of using multiple datasets to analyze the impacts of aerosols on ambient air quality. Given the quickly evolving nature of the event over several hours, ABI AOD provided information for the public and decision-makers that was not available from any other source, including polar-orbiting satellite sensors. This study suggests that PM2.5 concentrations estimated from ABI AOD can be used to fill in the gaps in nationwide regulatory PM2.5 monitor networks and may be a valuable addition to EPA’s PM2.5 NowCast of current air quality conditions.

satellite observations↗

DOE OSTI2024

A Q-band frequency tunable Doppler backscattering (DBS) system for pedestal and scrape-off layer density fluctuation and flow measurements in the DIII-D tokamak

We present the design and laboratory tests for a new Q-band frequency tunable Doppler backscattering (DBS) system suitable for probing poloidal wavenumber kñ = 6–8 cm−1 density fluctuations and their flow velocities in the pedestal and scape-off layer (SOL) of the DIII-D tokamak. This system will provide new measurements in the increasingly important and under-diagnosed far pedestal and SOL plasma regions. These results are important for experimental transport studies and necessary for the validation of transport models, both of which are important to fusion energy research. The use of a single tunable frequency reduces the complexity and potential failure points as compared to a multichannel system. This new system utilizes a 33–50 GHz tunable source and will be integrated into the current V-band DBS in DIII-D using a broadband Q- and V-band multiplexer. A full-scale mockup of the quasi-optical system was used to test and optimize the performance. These tests include beam profile measurements at different distances (and angles) from a paraboloidal focusing and steering mirror. The measurements cover the full frequency range 33–75 GHz of the integrated/combined Q–V band DBS system and target a large radial coverage of the low-field side of the plasma from ρ = 1.1 to ρ = 0.5, where ρ is the normalized flux surface radial coordinate.

Instruments & Instrumentation↗

NASA NTRS2019

TPSAS-NF1676L-34013-DND

Currently, many experiments pursuing comprehensive characterization of the atmosphere include coordinated observations by both lidar and polarimeters in order to obtain important complimentary information about aerosol properties. The most advanced passive observations by space-based multi-angle polarimeters are sensitive to the properties of aerosol in total atmospheric column, but have very limited sensitivity to vertical structure of the atmosphere. Polarimeter observations can be used not only for retrieval of aerosol optical thickness, but also for deriving microphysical information about aerosol particle shape, size distribution, complex refractive index, and the properties of underlying surface (Dubovik et al., 2019). In a contrast, the lidar observations of atmospheric responses from different altitudes to laser pulses are designed to provide vertical profiles of atmospheric characteristics. Here we present the recent advancement in GRASP algorithm (Generalized Aerosol Retrieval of Atmospheric and Surface Properties) (Dubovik et al., 2011, 2014) that allows simultaneous inversion of co-incident lidar and polarimeter spaceborne observations and derives a united set of vertically resolved aerosol and surface parameters. Such synergetic retrieval is an extension to satellite data of the approach for synergetic processing of active and passive measurements developed earlier by (Lopatin et al., 2013) for ground-based observations. Another addition to these developments is the inclusion of Raman-shifted and volume depolarization backscattering observations that improve sensitivity to the vertical properties of aerosol, while polarimetric observations provide sufficient constraints on aerosol type and loading that generally are missing in lidar signals. The potential and limitations of such synergetic processing is illustrated by application to co-incident PARASOL and CALIPSO data.

Anton Lopatin↗

DOE OSTI2015

Laboratory Experiments and Instrument Intercomparison Studies of Carbonaceous Aerosol Particles

Aerosols containing black carbon (and some specific types of organic particulate matter) directly absorb incoming light, heating the atmosphere. In addition, all aerosol particles backscatter solar light, leading to a net-cooling effect. Indirect effects involve hydrophilic aerosols, which serve as cloud condensation nuclei (CCN) that affect cloud cover and cloud stability, impacting both atmospheric radiation balance and precipitation patterns. At night, all clouds produce local warming, but overall clouds exert a net-cooling effect on the Earth. The effect of aerosol radiative forcing on climate may be as large as that of the greenhouse gases, but predominantly opposite in sign and much more uncertain. The uncertainties in the representation of aerosol interactions in climate models makes it problematic to use model projections to guide energy policy. The objective of our program is to reduce the uncertainties in the aerosol radiative forcing in the two areas highlighted in the ASR Science and Program Plan. That is, (1) addressing the direct effect by correlating particle chemistry and morphology with particle optical properties (i.e. absorption, scattering, extinction), and (2) addressing the indirect effect by correlating particle hygroscopicity and CCN activity with particle size, chemistry, and morphology. In this connection we are systematically studying particle formation, oxidation, and the effects of particle coating. The work is specifically focused on carbonaceous particles where the uncertainties in the climate relevant properties are the highest. The ongoing work consists of laboratory experiments and related instrument inter-comparison studies both coordinated with field and modeling studies, with the aim of providing reliable data to represent aerosol processes in climate models. The work is performed in the aerosol laboratory at Boston College. At the center of our laboratory setup are two main sources for the production of aerosol particles: (a) two well-characterized source of soot particles and (b) a flow reactor for controlled OH and/or O3 oxidation of relevant gas phase species to produce well-characterized SOA particles. After formation, the aerosol particles are subjected to physical and chemical processes that simulate aerosol growth and aging. A suite of instruments in our laboratory is used to characterize the physical and chemical properties of aerosol particles before and after processing. The Time of Flight Aerosol Mass Spectrometer (ToF-AMS) together with a Scanning Mobility Particle Sizer (SMPS) measures particle mass, volume, density, composition (including black carbon content), dynamic shape factor, and fractal dimension. The–ToF-AMS was developed at ARI with Boston College participation. About 120 AMS instruments are now in service (including 5 built for DOE laboratories) performing field and laboratory studies world-wide. Other major instruments include a thermal denuder, two Differential Mobility Analyzers (DMA), a Cloud Condensation Nuclei Counter (CCN), a Thermal desorption Aerosol GC/MS (TAG) and the new Soot Particle Aerosol Mass Spectrometer (SP-AMS). Optical instrumentation required for the studies have been brought to our laboratory as part of ongoing and planned collaborative projects with colleagues from DOE, NOAA and university laboratories. Optical instruments that will be utilized include a Photoacoustic Spectrometer (PAS), a Cavity Ring Down Aerosol Extinction Spectrometer (CRD-AES), a Photo Thermal Interferometer (PTI), a new 7-wavelength Aethalometer and a Cavity Attenuated Phase Shift Extinction Monitor (CAPS). These instruments are providing aerosol absorption, extinction and scattering coefficients at a range of atmospherically relevant wavelengths. During the past two years our work has continued along the lines of our original proposal. We report on 12 completed and/or continuing projects conducted during the period 08/14 to 0814/2015. These projects are described in 17 manuscripts published in refereed journals.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS1999

Improving Scientific Capabilities in Space in the 21st Century: The NASA New Millennium Program

NASA's New Millennium Program (NMP) has been chartered to identify and validate in space emerging, revolutionary technologies that will enable less costly, more capable future science missions. The program utilizes a unique blend of science guidance and industry partnering to ferret out technology solutions to enable science capabilities in space which are presently technically infeasible, or unaffordable. Those technologies which present an unacceptably high risk to future science missions (whether small PI-led or operational) are bundled into technology validation missions. These missions seek to validate the technologies in a manner consistent with their future uses, thus reducing the associated risk to the first user, and obtaining meaningful science data as well. The Space Readiness Coherent Lidar Experiment (SPARCLE) was approved as the second NMP Earth Observing mission (EO2) in October 1997, and assigned to Marshall Space Flight Center for implementation. Leading up to mission confirmation, NMP sponsored a community workshop in March 1996 to draft Level-1 requirements for a doppler wind lidar mission, as well as other space-based lidar missions (such as DIAL). Subsequently, a study group was formed and met twice to make recommendations on how to perform a comparison of coherent and direct detection wind lidars in space. These recommendations have guided the science validation plan for the SPARCLE mission, and will ensure that future users will be able to confidently assess the risk profile of future doppler wind missions utilizing EO2 technologies. The primary risks to be retired are: (1) Maintenance of optical alignments through launch and operations on orbit, and (2) Successful velocity estimation compensation for the Doppler shift due to the platform motion, and due to the earth's rotation. This includes the need to account for all sources of error associated with pointing control and knowledge. The validation objectives are: (1) Demonstrate measurement of tropospheric winds from space using a scanning coherent Doppler lidar technique that scales to meet future research (e.g. ESSP) and operational (e.g. NPOESS) mission requirements. Specifically, produce and validate LOS wind data with single shot accuracy of 1-2 m/s in regions of high signal-to-noise ratio (SNR), and low atmospheric wind turbulence and wind shear, (2) Collect the atmospheric and instrument performance data in various scanning modes necessary to validate and improve instrument performance models that will enable the definition of future missions with greater confidence. Such data include aerosol backscatter data over much of the globe, and high SNR data such as that from surface returns, and (3) Produce a set of raw instrument data with which advanced signal processing techniques can be developed. This objective will permit future missions to better understand how to extract wind information from low backscatter regions of the atmosphere.

Raymond, Carol A.↗

NASA NTRS2002

A New Method for Estimating the Single Scattering Phase Functions of Regolith Grains

Hapke's photometric model has been widely used in solar system remote sensing applications for nearly two decades. Recently, Hapke extended his model to describe the coherent-backscatter opposition effect and multiple-scattering by particles with anisotropic single particle phase functions (SPPF's). A practical difficulty for retrieving Hapke's model parameters from typical planet, satellite, and asteroid photometry data sets is that the model employs a large number of adjustable parameters (at least eight) that can be reliably constrained only for a small number of planetary data sets in which both disk-resolved and whole-disk observations are available from opposition to very large phase angles. The present work aims to reduce the number of adjustable parameters and preserve (or even enhance) the model's accuracy and usefulness by expressing Hapke's parameters in terms of more fundamental physical properties on which they mutually depend. The most difficult part of this task, described here, is to develop a simple method for computing the effective SPPF for structurally complex regolith grains from optical constants, grain-size distribution, and average regolith porosity. The development of light-scattering models for irregularly shaped particles is a large, complex subject and many sophisticated methods, such as Discrete Dipole Approximation (DDA) and Monte-Carlo simulations, have been explored elsewhere. Many of these methods are computationally intensive and probably impractical for routine substitution in Hapke's model. Here, progress is reported in developing a practical, semi-empirical method for estimating the directional scattering behavior (i.e. SPPF) of irregular regolith grains. The method employs Optical Transfer Function (OTF) techniques to model how the structural complexity of regolith particles broaden and attenuate the angular distribution of scattered light relative to that expected from ideal spherical particles of equivalent size and composition.

Helfenstein, P.↗

NASA NTRS2020

Synergistic Use of Hyperspectral UV-Visible OMI and Broadband Meteorological Imager MODIS Data for a Merged Aerosol Product

The retrieval of optimal aerosol datasets by the synergistic use of hyperspectral ultraviolet(UV)–visible and broadband meteorological imager (MI) techniques was investigated. The Aura Ozone Monitoring Instrument (OMI) Level 1B (L1B) was used as a proxy for hyperspectral UV–visible instrument data to which the Geostationary Environment Monitoring Spectrometer (GEMS) aerosol algorithm was applied. Moderate-Resolution Imaging Spectroradiometer (MODIS) L1B and dark target aerosol Level 2 (L2) data were used with a broadband MI to take advantage of the consistent time gap between the MODIS and the OMI. First, the use of cloud mask information from the MI infrared (IR) channel was tested for synergy. High-spatial-resolution and IR channels of the MI helped mask cirrus and sub-pixel cloud contamination of GEMS aerosol, as clearly seen in aerosol optical depth (AOD) validation with Aerosol Robotic Network (AERONET) data. Second, dust aerosols were distinguished in the GEMS aerosol-type classification algorithm by calculating the total dust confidence index (TDCI) from MODIS L1B IR channels. Statistical analysis indicates that the Probability of Correct Detection (POCD) between the forward and inversion aerosol dust models (DS) was increased from 72% to 94% by use of the TDCI for GEMS aerosol-type classification, and updated aerosol types were then applied to the GEMS algorithm. Use of the TDCI for DS type classification in the GEMS retrieval procedure gave improved single-scattering albedo (SSA) values for absorbing fine pollution particles (BC) and DS aerosols. Aerosol layer height (ALH) retrieved from GEMS was compared with Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) data, which provides high-resolution vertical aerosol profile information. The CALIOP ALH was calculated from total attenuated backscatter data at 1064 nm, which is identical to the definition of GEMS ALH. Application of the TDCI value reduced the median bias of GEMS ALH data slightly. The GEMS ALH bias approximates zero, especially for GEMS AOD values of>~0.4 and GEMS SSA values of<~0.95.Finally, the AOD products from the GEMS algorithm and MI were used in aerosol merging with the maximum-likelihood estimation method, based on a weighting factor derived from the standard deviation of the original AOD products. With the advantage of the UV–visible channel in retrieving aerosol properties over bright surfaces, the combined AOD products demonstrated better spatial data availability than the original AOD products, with comparable accuracy. Furthermore, pixel-level error analysis of GEMS AOD data indicates improvement through MI synergy.

aerosol↗

DOE OSTI2017

An ultra-high gain and efficient amplifier based on Raman amplification in plasma

Raman amplification arising from the excitation of a density echelon in plasma could lead to amplifiers that significantly exceed current power limits of conventional laser media. Here we show that 1–100 J pump pulses can amplify picojoule seed pulses to nearly joule level. The extremely high gain also leads to significant amplification of backscattered radiation from “noise”, arising from stochastic plasma fluctuations that competes with externally injected seed pulses, which are amplified to similar levels at the highest pump energies. The pump energy is scattered into the seed at an oblique angle with 14 J sr -1 , and net gains of more than eight orders of magnitude. The maximum gain coefficient, of 180 cm -1 , exceeds high-power solid-state amplifying media by orders of magnitude. The observation of a minimum of 640 J sr -1 directly backscattered from noise, corresponding to ≈10% of the pump energy in the observation solid angle, implies potential overall efficiencies greater than 10%.

42 ENGINEERING↗

NASA NTRS2020

Fusion Approach for Remotely-Sensed Mapping of Agriculture (FARMA): A Scalable Open Source Method for Land Cover Monitoring Using Data Fusion

The increasing availability of very-high resolution (VHR; <2 m) imagery has the potential to enable agricultural monitoring at increased resolution and cadence, particularly when used in combination with widely available moderate-resolution imagery. However, scaling limitations exist at the regional level due to big data volumes and processing constraints. Here, we demonstrate the Fusion Approach for Remotely-Sensed Mapping of Agriculture (FARMA), using a suite of open source software capable of efficiently characterizing time-series field-scale statistics across large geographical areas at VHR resolution. We provide distinct implementation examples in Vietnam and Senegal to demonstrate the approach using WorldView VHR optical, Sentinel-1 Synthetic Aperture Radar, and Sentinel-2 and Sentinel-3 optical imagery. This distributed software is open source and entirely scalable, enabling large area mapping even with modest computing power. FARMA provides the ability to extract and monitor sub-hectare fields with multisensor raster signals, which previously could only be achieved at scale with large computational resources. Implementing FARMA could enhance predictive yield models by delineating boundaries and tracking productivity of smallholder fields, enabling more precise food security observations in low and lower-middle income countries.

fusion↗

NASA NTRS2011

An Overview of the GEOS-5 Aerosol Reanalysis

GEOS-5 is the latest version of the NASA Global Modeling and Assimilation Office (GMAO) earth system model. GEOS-5 contains components for atmospheric circulation and composition (including data assimilation), ocean circulation and biogeochemistry, and land surface processes. In addition to traditional meteorological parameters, GEOS-5 includes modules representing the atmospheric composition, most notably aerosols and tropospheric/stratospheric chemical constituents, taking explicit account of the impact of these constituents on the radiative processes of the atmosphere. MERRA is a NASA meteorological reanalysis for the satellite era (1979-present) using GEOS-5. This project focuses on historical analyses of the hydrological cycle on a broad range of weather and climate time scales. As a first step towards an integrated Earth System Analysis (IESA), the GMAO is extending MERRA with reanalyses for other components of the earth system: land, ocean, bio-geochemistry and atmospheric constituents. In this talk we will present results from the MERRA-driven aerosol reanalysis covering the Aqua period (2003-present). The assimilation of Aerosol Optical Depth (AOD) in GEOS-5 involves very careful cloud screening and homogenization of the observing system by means of a Neural Net scheme that translates MODIS radiances into AERONET calibrated AOD. These measurements are further quality controlled using an adaptive buddy check scheme, and assimilated using the Local Displacement Ensemble (LDE) methodology. For this reanalysis, GEOS-5 runs at a nominal 50km horizontal resolution with 72 vertical layers (top at approx. 8Skm). GEOS-5 is driven by daily biomass burning emissions derived from MODIS fire radiative power retrievals. We will present a summary of our efforts to validate such dataset. The GEOS-5 assimilated aerosol fields are first validated by comparison to independent in-situ measurements (AERONET and PM2.5 surface concentrations). In order to asses aerosol absorption on a global scale, we perform a detailed radiative transfer calculation to simulate the UV aerosol index, comparing our results to OMI measurements. By simulating aerosol attenuated backscatter, we use CALIPSO measurements to evaluate the vertical structure of our aerosol estimates, in particular in regions where we have larger discrepancies with OMI. Finally, the consistency of our AOD estimates with estimates from MISR, MODIS/Deep Blue, OMI and PARASOL will be briefly discussed.

da Silva, Arlindo↗

DOE OSTI2016

Friction and wear behavior of nitrogen-doped ZnO thin films deposited via MOCVD under dry contact

Most researches on doped ZnO thin films are tilted toward their applications in optoelectronics and semiconductor devices. Research on their tribological properties is still unfolding. In this work, nitrogen-doped ZnO thin films were deposited on 304 L stainless steel substrate from a combination of zinc acetate and ammonium acetate precursor by MOCVD technique. Compositional and structural studies of the films were done using Rutherford Backscattering Spectroscopy (RBS) and X-ray Diffraction (XRD). The frictional behavior of the thin film coatings was evaluated using a ball-on-flat configuration in reciprocating sliding under dry contact condition. After friction test, the flat and ball counter-face surfaces were examined to assess the wear dimension and failure mechanism. In conclusion, both friction behavior and wear (in the ball counter-face) were observed to be dependent on the crystallinity and thickness of the thin film coatings.

36 MATERIALS SCIENCE↗

NASA NTRS1999

Measuring Tropospheric Winds from Space Using a Coherent Doppler Lidar Technique

The global measurement of tropospheric wind profiles has been cited by the operational meteorological community as the most important missing element in the present and planned observing system. The most practical and economical method for obtaining this measurement is from low earth orbit, utilizing a Doppler lidar (laser radar) technique. Specifically, this paper will describe the coherent Doppler wind lidar (CDWL) technique, the design and progress of a current space flight project to fly such a system on the Space Shuttle, and plans for future flights of similar instruments. The SPARCLE (SPAce Readiness Coherent Lidar Experiment) is a Shuttle-based instrument whose flight is targeted for March, 2001. The objectives of SPARCLE are three-fold: Confirm that the coherent Doppler lidar technique can measure line-of-sight winds to within 1-2 m/s accuracy; Collect data to permit validation and improvement of instrument performance models to enable better design of future missions; and Collect wind and backscatter data for future mission optimization and for atmospheric studies. These objectives reflect the nature of the experiment and its program sponsor, NASA's New Millennium Program. The experiment is a technology validation mission whose primary purpose is to provide a space flight validation of this particular technology. (It should be noted that the CDWL technique has successfully been implemented from ground-based and aircraft-based platforms for a number of years.) Since the conduct of the SPARCLE mission is tied to future decisions on the choice of technology for free-flying, operational missions, the collection of data is intrinsically tied to the validation and improvement of instrument performance models that predict the sensitivity and accuracy of any particular present or future instrument system. The challenges unique to space flight for an instrument such as SPARCLE and follow-ons include: Obtaining the required lidar sensitivity from the long distance of orbit height to the lower atmosphere; Maintaining optical alignments after launch to orbit, and during operations in "microgravity"; Obtaining pointing knowledge of sufficient accuracy to remove the speed of the spacecraft (and the rotating Earth) from the measurements; Providing sufficient power (not a problem on the Shuttle) and cooling to the instrument. The paper will describe the status and challenges of the SPARCLE project, the value of obtaining wind data from orbit, and will present a roadmap to future instruments for scientific research and operational meteorology.

Miller, Timothy L.↗

NASA NTRS2012

Performance Considerations for the SIMPL Single Photon, Polarimetric, Two-Color Laser Altimeter as Applied to Measurements of Forest Canopy Structure and Composition

The Slope Imaging Multi-polarization Photon-counting Lidar (SIMPL) is a multi-beam, micropulse airborne laser altimeter that acquires active and passive polarimetric optical remote sensing measurements at visible and near-infrared wavelengths. SIMPL was developed to demonstrate advanced measurement approaches of potential benefit for improved, more efficient spaceflight laser altimeter missions. SIMPL data have been acquired for wide diversity of forest types in the summers of 2010 and 2011 in order to assess the potential of its novel capabilities for characterization of vegetation structure and composition. On each of its four beams SIMPL provides highly-resolved measurements of forest canopy structure by detecting single-photons with 15 cm ranging precision using a narrow-beam system operating at a laser repetition rate of 11 kHz. Associated with that ranging data SIMPL provides eight amplitude parameters per beam unlike the single amplitude provided by typical laser altimeters. Those eight parameters are received energy that is parallel and perpendicular to that of the plane-polarized transmit pulse at 532 nm (green) and 1064 nm (near IR), for both the active laser backscatter retro-reflectance and the passive solar bi-directional reflectance. This poster presentation will cover the instrument architecture and highlight the performance of the SIMPL instrument with examples taken from measurements for several sites with distinct canopy structures and compositions. Specific performance areas such as probability of detection, after pulsing, and dead time, will be highlighted and addressed, along with examples of their impact on the measurements and how they limit the ability to accurately model and recover the canopy properties. To assess the sensitivity of SIMPL's measurements to canopy properties an instrument model has been implemented in the FLIGHT radiative transfer code, based on Monte Carlo simulation of photon transport. SIMPL data collected in 2010 over the Smithsonian Environmental Research Center, MD are currently being modelled and compared to other remote sensing and in situ data sets. Results on the adaptation of FLIGHT to model micropulse, single'photon ranging measurements are presented elsewhere at this conference. NASA's ICESat-2 spaceflight mission, scheduled for launch in 2016, will utilize a multi-beam, micropulse, single-photon ranging measurement approach (although non-polarimetric and only at 532 nm). Insights gained from the analysis and modelling of SIMPL data will help guide preparations for that mission, including development of calibration/validation plans and algorithms for the estimation of forest biophysical parameters.

Dabney, Philip W.↗

NASA NTRS2000

Sensitivity of MODIS 2.1 micron Channel for Off-Nadir View Angles for Use in Remote Sensing of Aerosol

Remote sensing of aerosol over land, from MODIS will be based on dark targets using mid-IR channels 2.1 and 3.9 micron. This approach was developed by Kaufman et al (1997), who suggested that dark surface reflectance in the red (0.66 micron -- rho(sub 0.66)) channel is half of that at 2.2 micron (rho(sub 2.2)), and the reflectance in the blue (0.49 micron - rho(sub 0.49)) channel is a quarter of that at 2.2 micron. Using this relationship, the surface reflectance in the visible channels can be predicted within Delta.rho(sub 0.49) approximately Delat.rho(sub 0.66) approximately 0.006 from rho(sub 2.2) for rho(sub 2.2) <= 0.10. This was half the error obtained using the 3.75 micron and corresponds to an error in aerosol optical thickness of Delat.tau approximately 0.06. These results, though applicable to several biomes (e.g. forests, and brighter lower canopies), have only been tested at one view angle - the nadir (theta = 0 deg). Considering the importance of the results in remote sensing of aerosols over land surfaces from space, we are validating the relationships for off-nadir view angles using Cloud Absorption Radiometer (CAR) data. The CAR data are available for channels between 0.3 and 2.3 micron and for different surface types and conditions: forest, tundra, ocean, sea-ice, swamp, grassland and over areas covered with smoke. In this study we analyzed data collected during the Smoke, Clouds, and Radiation - Brazil (SCAR-B) experiment to validate Kaufman et al.'s (1997) results for non-nadir view angles. We will show the correlation between rho(sub 0.472), rho(sub 0.675), and rho(sub 2.2) for view angles between nadir (0 deg) and 55 deg off-nadir, and for different viewing directions in the backscatter and forward scatter directions.

Gatebe, C. K.↗

NASA NTRS2011

Potential Scientific Output from the Visible Channels of EPIC Spectroradiometer as Part of the DSCOVR L1 Mission

In addition to 4 UV channels, the EPIC spectroradiometer will provide measurements at 6 visible (and near IR) channels (443,551,680,687.75, 764 and 779.9 nm) at roughly 10 km spatial resolution. The scattering angles are near backscattering and vary between 165 and 176 degree. Two pairs {680 and 687.75 nm} and {764 and 779.9 nm} represent 02 B- and A-bands (and their references) channels; they will be used for cloud height measurements over land and ocean. The B-band channel will contribute to the more absorbing A-band measurements over bright vegetation. A pair {680 and 779.9 nm} will be used for retrieving vegetation properties. Due to the special EPIC geometry, the illuminated part of the leaves will be always observed. As a result, in additional to the traditional Leaf Area Index (LAI), these observations for the first time will provide the sunlit fraction of LAI. Since the sunlit and shaded leaves exhibit different photosynthetic response to incident radiation, these measurements will help to improve global ecological and biogeochemistry models. Finally, a pair {443 and 551 nm} will be used for atmospheric correction. As a by-product of the atmospheric correction algorithm, we also expect to get aerosol optical thickness (AOT) and surface bidirectional reflection function (BRF). The presentation will briefly overview the proposed science algorithms.

Marshak, Alexander↗

DOE OSTI2015

Gallium Oxide Nanostructures for High Temperature Sensors

Gallium oxide (Ga 2 O 3 ) thin films were produced by sputter deposition by varying the substrate temperature (T s ) in a wide range (T s =25-800 °C). The structural characteristics and electronic properties of Ga 2 O 3 films were evaluated using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectrometry (EDS), Rutherford backscattering spectrometry (RBS) and spectrophotometric measurements. The effect of growth temperature is significant on the chemistry, crystal structure and morphology of Ga 2 O 3 films. XRD and SEM analyses indicate that the Ga 2 O 3 films grown at lower temperatures were amorphous while those grown at T s ≥500 oC were nanocrystalline. RBS measurements indicate the well-maintained stoichiometry of Ga 2 O 3 films at T s =300-800 °C. The electronic structure determination indicated that the nanocrystalline Ga 2 O 3 films exhibit a band gap of ~5 eV. Tungsten (W) incorporated Ga 2 O 3 films were produced by co-sputter deposition. W-concentration was varied by the applied sputtering-power. No secondary phase formation was observed in W-incorporated Ga 2 O 3 films. W-induced effects were significant on the structure and electronic properties of Ga2O3 films. The band gap of Ga 2 O 3 films without W-incorporation was ~5 eV. Oxygen sensor characteristics evaluated using optical and electrical methods indicate a faster response in W-doped Ga 2 O 3 films compared to intrinsic Ga 2 O 3 films. The results demonstrate the applicability of both intrinsic and W-doped Ga-oxide films for oxygen sensor application at temperatures ≥700 °C.

47 OTHER INSTRUMENTATION↗

NASA NTRS2003

Geoscience Laser Altimeter System: Characteristics and Performance of the Altimeter Receiver

The Geoscience Laser Altimeter System (GLAS) on board ICESat spacecraft measures the surface height (altimetry) via the time of flight of its 1064 nm laser pulse. The GLAS laser transmitter produces 6 ns wide pulses with 70 mJ energy at 1064 nm at a 40 Hz rate. The altimeter receiver consists of a telescope, aft optics, a silicon avalanche photodiode, and electronic amplifiers. The transmitted and echo pulse waveforms are digitized at 1 GHz rate. The laser pulse time of flight is determined on the ground from the two digitized pulse waveforms and their positions in the full waveform record (about 5.4 ms ong) by computing the pulse centroids or by curve fitting. The GLAS receiver algorithms in on board software selects the two waveform segments containing the transmitted and the echo pulses and sends them to ground. The probability of echo pulse detection and the accuracy of time of flight measurement depend on the received signal level, the background light within the receiver field of view, the inherent detector and amplifier noise, the quantization of the digitizer, and some times by cloud obscurations. A receiver model has been developed to calculate the probability of detection and accuracy of the altimeter measurements with these noise sources. From prelaunch testing, the minimum detectable echo pulse energy for 90% detection probability was about 0.1 fj/pulse onto the detector. Such a receiver sensitivity allows GLAS to measure the surface height through clouds with optical density less than 2. The echo pulse energy required to achieve 10 cm ranging accuracy was found to be about 3 times higher than the minimum detectable signal level. The smallest single shot range measurement error, which was determined by ranging to a fixed target with strong echo pulses and no background light, was 2 to 3cm. The maximum linear response echo pulse energy was 10 fJ/pulse for the strongest echo signals, assuming a Lambertian scattering snow surface, clear sky atmosphere transmission, and no pulse width spreading due to surface slopes. Results from the initial 38 days of GLAS operation on-orbit with Laser 1, showed the echo pulse energies varied, as expected, over a wide dynamic range due to the variability of atmosphere transmission and Earth surface characteristics. The receiver was able to reliably detect the ground surface echoes and measure time of flight under such dynamic conditions, except when there were dense clouds. When over Antarctica, the echo pulse energies were several times stronger than predicted. This suggests that the 1064 nm backscattering from the snow pack and ice-sheet &ce are not completely Lambertian but is somewhat peaked at opposit.ion. With Laser 1, the peak amplitude of the echo pulses from flat ice sheets under clear sky conditions exceeded the linear response range of the receiver, causing some pulse waveform distortion due to saturation. We have characterized the effects of receiver saturation on the time of flight, pulse width, and pulse energy measurements for flat surface by testing a night spare detector in the lab with simulated echo pulses. A data processing algorithm that minimizes the errors due to saturation for these measurements are described.

Sun, Xiao-Li↗

DOE OSTI2017

Role of atomic-level defects and electronic energy loss on amorphization in LiNbO 3 single crystals

Understanding complex non-equilibrium defect processes, where multiple irradiation mechanisms may take place simultaneously, is a long standing subject in material science. The separate and combined effects of elastic and inelastic energy loss are a very complicated and challenging topic. In this work, LiNbO 3 has been irradiated with 0.9 MeV Si + and 8 MeV O 3+ , which are representative of regimes where nuclear (S n ) and electronic (S e ) energy loss are dominant, respectively. The evolution of damage has been investigated by Rutherford backscattering spectrometry (RBS) in channeling configuration. Pristine samples were irradiated with 0.9 MeV Si + ions to create different pre-existing damage states. Below the threshold (S e,th = 5–6 keV nm –1 ) for amorphous track formation in this material, irradiation of the pristine samples with a highly ionizing beam of 8 MeV O 3+ ions, with nearly constant S e of about 3 keV nm –1 , induces a crystalline to amorphous phase transition at high ion fluences. In the pre-damaged samples, the electronic energy loss from the 8 MeV O 3+ ions interacts synergistically with the pre-existing damage, resulting in a rapid, non-linear increase in damage production. There is a significant reduction in the incubation fluence for rapid amorphization with the increasing amount of pre-existing damage. Here, these results highlight the important role of atomic-level defects on increasing the sensitivity of some oxides to amorphization induced by electronic energy loss. Controlling the nature and amount of pre-damage may provide a new approach to tuning optical properties for photonic device applications.

36 MATERIALS SCIENCE↗