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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,063 records · Page 59
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NASA NTRS2008

Preparation and Properties of Nanocomposites from Pristine and Modified SWCNTs of Comparable Average Aspect Ratios

Low color, flexible, space-durable polyimide films with inherent and robust electrical conductivity to dissipate electrostatic charge (ESC) have been under investigation as part of a materials development activity for future NASA space missions. The use of single-walled carbon nanotubes (SWCNTs) is one means to achieving this goal. Even though the concentration of SWCNTs needed to achieve ESC dissipation is typically low, it is dependent upon purity, size, dispersion, and functionalization. In this study, SWCNTs prepared by the electric arc discharge method were used to synthesize nanocomposites using the LaRC(TradeMark) CP2 backbone as the matrix. Pristine and functionalized SWCNTs were mixed with an alkoxysilane terminated amide acid of LaRC(TradeMark) CP2 and the soluble imide form of the polymer and the resultant nanocomposites evaluated for mechanical, thermal, and electrical properties. Due to the preparative conditions for the pristine and functionalized SWCNTs, the average aspect ratio for both was comparable. This permitted the assessment of SWCNT functionalization with respect to various interactions (e.g. van der Waals, hydrogen bonding, covalent bond formation, etc.) with the matrix and the macroscopic effects upon nanocomposite properties. The results of this study are described herein.

Smith, Joseph G.↗
NASA NTRSDate not supplied

Better Constraining Supercooled Clouds Could Reduce Projected Warming Spread

The increase of climate sensitivity to rising greenhouse gas concentrations in the coupled model intercomparison project phase 6 (CMIP6) Earth system models (ESMs) compared to CMIP5 ESMs is primarily attributed to a larger extratropical cloud response to climate change, referred to as cloud feedback. The ratio of supercooled liquid cloud water relative to all cloud water, termed liquid phase ratio (LPR), which has also notably increased in many recent ESMs, is thought to be a primary driver of the extratropical cloud feedback increase. Unlike the preponderance of previous studies that compare native model LPR directly with observations, here we evaluate LPR over three ESM generations against Cloud–Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) using an instrument simulator approach, which mimics instrument limitations and uses consistent cloud definitions and resolutions. We find that current coupled model intercomparison project (CMIP) ESMs collectively simulate greater LPR than previous CMIP generations and overestimate LPR compared to observations, contrary to previous findings, likely driven by past inconsistent comparisons of ESM outputs with CALIPSO observations. We further show that greater LPR in ESM present-day climate is unexpectedly correlated with a smaller extratropical cloud feedback, attributable to a decrease of cloud amount exceeding the increase of cloud optical depth. Finally, our results suggest that improving constraints on model LPR using our evaluation framework would likely reduce the spread in CMIP6 climate sensitivities, owing to its effect on extratropical cloud feedback from supercooled clouds.

greenhouse gas concentrations↗
NASA NTRS1973

Condensation in CO2 free jet expansions. I - Dimer formation.

A theoretical and experimental investigation of the kinetics of CO2 dimer formation in the adiabatically expanding core of a free jet expansion has been carried out. The theoretical analysis is based on dimer formation by an efficient termolecular process and dimer destruction by bimolecular collisions. Account is taken of the expected variation of the specific heat ratio during the expansion and of the effective increase in the termolecular collision rate at low temperatures due to the presence of loosely bound orbiting pairs. Experimental dimer concentrations were measured mass spectrometrically by forming a molecular beam from the expanded gas mixture after the onset of molecular flow. Observed dimer concentrations, for a range of pre-expansion conditions of 400 to 900 torr pressure and room temperature, are in good agreement with the theoretical analysis, provided that account is taken of the effect of loosely bound orbiting pairs at low temperatures.

Dorfeld, W. G.↗
NASA NTRS1981

Combustion of solid carbon rods in zero and normal gravity

In order to investigate the mechanism of carbon combustion and to assess the importance of gravitational induced convection on the process, zero and normal gravity experiments were conducted in which spectroscopic carbon rods were resistance ignitied and burned in dry oxygen environments. In the zero-gravity drop tower tests, a blue flame surrounded the rod, showing that a gas phase reaction in which carbon monoxide was oxidized to carbon dioxide was taking place. The ratio of flame diameter to rod diameter was obtained as a function of time. It was found that this ratio was inversely proportional to both the oxygen pressure and the rod diameter. In the normal gravity tests, direct mass spectrometric sampling was used to measure gas phase concentrations. The gas sampling probe was positioned near the circumference of a horizontally mounted 0.615 cm diameter carbon rod, either at the top or at angles of 45 deg to 90 deg from the top, and yielded concentration profiles of CO2, CO, and O2 as a function of distance from the surface. The mechanism controlling the combustion process was found to change from chemical process control at the 90 deg and 45 deg probe positions to mass transfer control at the 0 deg probe position at the top of the rod. Under the experimental conditions used, carbon combustion was characterized by two surface reactions, 2C + O2 yields 2CO and CO2 + C yields 2CO, and a gas phase reaction, 2CO + O2 yields 2CO2.

Spuckler, C. M.↗
NASA NTRS1981

Development of silane-hydrolysate binder for UV-resistant thermal control coatings

Detailed characterizaton and formulation studies were performed on a methyltriakoxysilane hydrolysate as a binder for thermal control coatings. The binder was optimized by varying hydrolysis temperature, time, catalyst type, and water concentration. The candidate coating formulations, based on this binder with TiO2 pigment, were optimized via a detailed series of sprayed test panels that included the parameters of binder/pigment ratio, ethanol content, pigment particle size, coating thickness and cure conditions. A typical optimized coating was prepared by acetic acid catalyzed hydrolysis of methyltriethoxysilane with 3.25 mol-equivalents of water over a 24 hour period at room temperature. The resulting hydrolysate was directly mixed with pre-milled TiO2 (12 grams pigment/26 grams binder) to yield a sprayable consistency. Panels were sprayed to result in a nominal cure coating thickness of 2 mils. Cure was affected by air drying for 24 hr at room temperature plus 72 hr at 150 F. These coatings are typically extremely tough and abrasion-resistant, with an absorptance (alpha) of 0.20 and emittance (e) of 0.89. No significant coating damage was observed in the mandrel bend test, even after exposure to thermal cycling from -160 to 160 F. Vacuum exposure of the coatings for 930 hours at 1 equivalent UV sun resulted in no visible degradation and no significant increase in absorptance.

Patterson, W. J.↗
NASA NTRS1981

A new method for inferring carbon monoxide concentrations from gas filter radiometer data

A method for inferring carbon monoxide concentrations from gas filter radiometer data is presented. The technique can closely approximate the results of more costly line-by-line radiative transfer calculations over a wide range of altitudes, ground temperatures, and carbon monoxide concentrations. The technique can also be used over a larger range of conditions than those used for the regression analysis. Because the influence of the carbon monoxide mixing ratio requires only addition, multiplication and a minimum of logic, the method can be implemented on very small computers or microprocessors.

Wallio, H. A.↗
NASA NTRS1981

Regimes of traction in concentrated contact lubrication

Experimental evidence is presented for the existence of three regimes of traction in concentrated contacts. Data are obtained in a rolling contact simulator by varying the lubricant, temperature, rolling speed, load and surface roughness at a fixed slide-to-roll ratio. At lower thicknesses the mixed regime is encountered, and traction is increased due to asperity interaction, while at higher film thicknesses, the lubricant pressure is distributed over a greater area than the Hertzian region, resulting in a lower average pressure and reduced traction.

Bair, S.↗
NASA NTRS1984

The role of surface generated radicals in catalytic combustion

The role of surface generated OH radicals in determining the catalytic ignition characteristics for propane oxidation on platinum were studied. The experiments were conducted in a stacked-plate, catalyst bed. Transient measurements, during catalytic ignition, of the catalyst's axial temperature profile were made and the effect of equivalence ratio, inlet temperature and inlet velocity was investigated. These measurements will provide insights which will be useful in planning and interpreting to OH measurements. Attempts to measure OH concentration in the catalyst bed using resonance absorption spectroscopy were unsuccessful, indicating that OH concentrations are below 10 to the 16th power/cc but still possibly above equilibrium values. Measurements are currently underway using forward scatter laser induced fluorescence which should extend the OH detection limits several orders of magnitude below the equilibrium concentrations.

Santavicca, D. A.↗
NASA NTRS1985

Experimental study of the spray characteristics of a research airblast atomizer

Airblast atomization was studied using a especially designed atomizer in which the liquid first impinges on a splash plate, then is directed radially outward and is atomized by the air passing through two concentric, vaned swirlers that swirl the air in opposite directions. The effect of flow conditions, air mass velocity (mass flow rate per unit area) and liquid to air ratio on the mean drop size was studied. Seven different ethanol solutions were used to simulate changes in fuel physical properties. The range of atomizing air velocities was from 30 to 80 m/s. The mean drop diameter was measured at ambient temperature (295 K) and atmospheric pressure.

Acosta, W. A.↗
NASA NTRS1984

Absolute OH absorption cross sections (for lidar measurements)

Experimental data are employed to calculate absorption cross sections for several rotational lines in the OH A-X system. The cross sections are computed as functions of the spectral and line widths and temperature of a laser beam, and account for lifetimes and branching ratios. Detection limits for the P1(2) transition of the (1,0) band were examined. The oscillator strengths and cross-sections obtained are important for quantifying OH concentrations in the stratosphere from lidar return signals.

Mcgee, T. J.↗
NASA NTRS1986

A direct time series comparison between the La Jolla and Belfast radiocarbon records

For many years it has been widely assumed that the variations in the level of atmospheric carbon-14 were due to statistical fluctuations arising from experimental error. This is understandable since the signal/noise ratio is very low and the time sequences representing the variations are strongly stochastic. Interlaboratory comparisons show that baseline variations in the absolute value of the carbon-14 concentration do exist. However, assuming linearity, the delta 14C values are independent of these. The importance of assessing the quantitive reality of the delta 14C values is based upon their expression of the interplanetary cosmic ray source function, because in the range of 100 to 1000 year periods, there appears to be no evidence that the Earth's magnetic field is the source modulating function. Therefore the modulation is either due to changes in the solar atmosphere propagated out into the solar wind, or extra-heliospheric pressure effects, but these appear to be unlikely for the periods noted here. The recent availability of the new high quality Belfast time sequence of delta 14C now permits a simple mutual assessment of the several sequences which are available. Since the La Jolla record has been a standard for many years , these two were chosen for a simple comparison. Although differences exist, the close agreement between these two sequences, one carried out on White mountain Bristlecone pines, and the other done using Irish peat bog wood, is striking. This correlation between the two strongly reinforces the statistical view that the delta 14C record is that of real interplanetary modulation of the cosmic ray source leading to the generation of atmospheric 14C.

Sonett, C. P.↗
NASA NTRS1985

Experimental study of the spray characteristics of a research airblast atomizer

Airblast atomization was studied using a especially designed atomizer in which the liquid first impinges on a splash plate, then is directed radically outward and is atomized by the air passing through two concentric, vaned swirlers that swirl the air in opposite directions. The effect of flow conditions, air mass velocity (mass flow rate per unit area) and liquid to air ratio on the mean drop size was studied. Seven different ethanol solutions were used to simulate changes in fuel physical properties. The range of atomizing air velocities was from 30 to 80 m/s. The mean drop diameter was measured at ambient temperature (295 K) and atmospheric pressure.

Acosta, W. A.↗
NASA NTRS1988

Atmospheric and surface compositional studies of Mercury and the moon

The atmosphere of the Moon and Mercury will be studied by means of high resolution spectroscopy of sodium and potassium resonance line emissions. The variation of metal vapor abundances with time, and with location will be measured with a view to understanding the origin and evolution of these elements in the atmospheres of the Moon and Mercury. Infrared spectroscopic measurements will be made of Mercury to determine the surface mineralogy, predicated on the availability of the Kuiper Airborne Observatory and infrared charge coupled device (CCD). During the past year, an excellent series of measurements were completed of the spatial distribution of sodium on Mercury. Sodium was found to be concentrated at the polar regions, and to be displaced towards the terminator by solar radiation pressure. Sodium and potassium were discovered in the atmosphere of the Moon. The ratio of sodium to potassium approximates that of the lunar regolith. Thermal infrared measurements of Mercury showed that the Christiansen peak was located shortwards of 8 micrometer, which indicates an acidic mineralogy.

Potter, A. E.↗
NASA NTRS1989

Three-dimensional stress analysis of plain weave composites

Techniques were developed and described for performing three-dimensional finite element analysis of plain weave composites. Emphasized here are aspects of the analysis which are different from analysis of traditional laminated composites, such as the mesh generation and representative unit cells. The analysis was used to study several different variations of plain weaves which illustrate the effects of tow waviness on composite moduli, Poisson's ratios, and internal strain distributions. In-plane moduli decreased almost linearly with increasing tow waviness. The tow waviness was shown to cause large normal and shear strain concentrations in composites subjected to uniaxial load. These strain concentrations may lead to earlier damage initiation than occurs in traditional cross-ply laminates.

Whitcomb, John D.↗
NASA NTRS1990

The significance of biomass burning as a source of carbon monoxide and ozone in the Southern Hemisphere tropics - A satellite analysis

Carbon monoxide mixing ratios obtained by the October 1984 Measurement of Air Pollution from Satellites (MAPS) experiment are compared with the distribution of October 1984 Total Ozone Mapping Spectrometer (TOMS) ozone concentrations. The TOMS and MAPS data show coincident high values of ozone and carbon monoxide over central South America and southeastern Africa. The 1984 MAPS data are also compared with tropospheric ozone concentrations derived from 6 years of TOMS and Stratospheric Aerosol and Gas Experiment (SAGE) I and II measurements. Examination of the October climatological distribution of tropospheric ozone also reveals high concentrations over central South America and southeastern Africa. These coincident high values of CO and ozone in the rural southern tropics are most likely due to biomass burning and the subsequent transport of CO and ozone by large-scale weather patterns. It appears that both CO and ozone are being transported thousands of kilometers from their source regions by the prevailing winds.

Watson, Catherine E.↗
NASA NTRS1991

Systematic study of sulfur isotopic composition in iron meteorites and the occurrence of excess S-33 and S-36

The paper concentrates on isotopic measurements of sulfur in different sulfur-carrier phases: troilite inclusions, Fe-Ni alloy, and schreibersite (possibly including daubreelite). Variations in S-34 isotope ratio are observed in some troilite inclusions, and no evidence of nucleosynthetic sulfur isotopic anomalies are found in the troilite inclusions. Excesses of S-33 and S-36 are observed in both FeNi alloy and schreibersite of Grant, Santa Clara, Tlacotepec, and Gibeon, with schreibersite possessing the greater magnitude of presumably spallogenic S-33 and S-36. It is concluded that the magnitude of the observed fractionation is consistent with troilite dissociation and/or vaporization following a collisional impact.

Gao, Xia↗
NASA NTRS1993

Experimental investigation of turbine disk cavity aerodynamics and heat transfer

An experimental investigation of turbine disk cavity aerodynamics and heat transfer was conducted to provide an experimental data base that can guide the aerodynamic and thermal design of turbine disks and blade attachments for flow conditions and geometries simulating those of the space shuttle main engine (SSME) turbopump drive turbines. Experiments were conducted to define the nature of the aerodynamics and heat transfer of the flow within the disk cavities and blade attachments of a large scale model simulating the SSME turbopump drive turbines. These experiments include flow between the main gas path and the disk cavities, flow within the disk cavities, and leakage flows through the blade attachments and labyrinth seals. Air was used to simulate the combustion products in the gas path. Air and carbon dioxide were used to simulate the coolants injected at three locations in the disk cavities. Trace amounts of carbon dioxide were used to determine the source of the gas at selected locations on the rotors, the cavity walls, and the interstage seal. The measurements on the rotor and stationary walls in the forward and aft cavities showed that the coolant effectiveness was 90 percent or greater when the coolant flow rate was greater than the local free disk entrainment flow rate and when room temperature air was used as both coolant and gas path fluid. When a coolant-to-gas-path density ratio of 1.51 was used in the aft cavity, the coolant effectiveness on the rotor was also 90 percent or greater at the aforementioned condition. However, the coolant concentration on the stationary wall was 60 to 80 percent at the aforementioned condition indicating a more rapid mixing of the coolant and flow through the rotor shank passages. This increased mixing rate was attributed to the destabilizing effects of the adverse density gradients.

Daniels, W. A.↗
NASA NTRS1992

Flow effects in a vertical CVD reactor

A model is presented to simulate the non-Boussinesq flow in a vertical, two-dimensional, chemical vapor deposition reactor under atmospheric pressure. Temperature-dependent conductivity, mass diffusivity, viscosity models, and reactive species mass transfer to the substrate are incorporated. In the limits of small Mach number and small aspect ratio, asymptotic expressions for the flow, temperature, and species fields are developed. Soret diffusion effects are also investigated. Analytical solutions predict an inverse relationship between temperature field and concentration field due to Soret effects. This finding is consistent with numerical simulations, assisting in the understanding of the complex interactions amongst the flow, thermal, and species fields in a chemically reacting system.

Young, G. W.↗