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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,063 records · Page 59

Development of a Water Based, Critical Flow, Non-Vapor Compression cooling Cycle

Expansion of a high-pressure liquid refrigerant through the use of a thermostatic expansion valve or other device is commonplace in vapor-compression cycles to regulate the quality and flow rate of the refrigerant entering the evaporator. In vapor-compression systems, as the condensed refrigerant undergoes this expansion, its pressure and temperature drop, and part of the liquid evaporates. We (researchers at Kansas State University) are developing a cooling cycle that instead pumps a high-pressure refrigerant through a supersonic converging-diverging nozzle. As the liquid refrigerant passes through the nozzle, its velocity reaches supersonic (or critical-flow) conditions, substantially decreasing the refrigerant’s pressure. This sharp pressure change vaporizes some of the refrigerant and absorbs heat from the surrounding conditions during this phase change. Due to the design of the nozzle, a shockwave trips the supersonic two-phase refrigerant back to the starting conditions, condensing the remaining vapor. The critical-flow refrigeration cycle would provide space cooling, similar to a chiller, by running a secondary fluid such as water or glycol over one or more nozzles. Rather than utilizing a compressor to raise the pressure of the refrigerant, as in a vapor-cycle system, the critical-flow cycle utilizes a high-pressure pump to drive refrigerant liquid through the cooling cycle. Additionally, the design of the nozzle can be tailored for a given refrigerant, such that environmentally benign substances can act as the working fluid. This refrigeration cycle is still in early-stage development with prototype development several years away. The complex multi-phase flow at supersonic conditions presents numerous challenges to fully understanding and modeling the cycle. With the support of DOE and venture-capital investors, initial research was conducted at PAX Streamline, and later, at Caitin. We (researchers at Kansas State University) have continued development of the cycle and have gained an in-depth understanding of the governing fundamental knowledge, based on the laws of physics and thermodynamics and verified with our testing results. Through this research, we are identifying optimal working fluid and operating conditions to eventually demonstrate the core technology for space cooling or other applications.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Band gap opening in strongly compressed diamond observed by x-ray energy loss spectroscopy

The extraordinary mechanical and optical properties of diamond are the basis of numerous technical applications and make diamond anvil cells a premier device to explore the high-pressure behavior of materials. However, at applied pressures above a few hundred GPa, optical probing through the anvils becomes difficult because of the pressure-induced changes of the transmission and the excitation of a strong optical emission. Such features have been interpreted as the onset of a closure of the optical gap in diamond, and can significantly impair spectroscopy of the material inside the cell. In contrast, a comparable widening has been predicted for purely hydrostatic compressions, forming a basis for the presumed pressure stiffening of diamond and resilience to the eventual phase change to BC8. We here present the first experimental evidence of this effect at geo-planetary pressures, exceeding the highest ever reported hydrostatic compression of diamond by more than 200 GPa and any other measurement of the band gap by more than 350 GPa. We here apply laser driven-ablation to create a dynamic, high pressure state in a thin, synthetic diamond foil together with frequency-resolved x-ray scattering as a probe. The frequency shift of the inelastically scattered x-rays encodes the optical properties and, thus, the behavior of the band gap in the sample. Using the ultra-bright x-ray beam from the Linac Coherent Light Source (LCLS), we observe an increasing direct band gap in diamond up to a pressure of 370 GPa. This finding points to the enormous strains in the anvils and the impurities in natural Type Ia diamonds as the source of the observed closure of the optical window. Our results demonstrate that diamond remains an insulating solid to pressures approaching its limit strength.

36 MATERIALS SCIENCE↗

Effect of Adsorption Compression on Catalytic Chemical Reactions. Final Report

This project determined the effect of adsorption compression on the rates of catalytic chemical reactions. It was shown that in regions of strong adsorption compression there is a dramatic increase in the rate of catalytic chemical reaction. Experiments focused on the conversion of NO to molecular nitrogen and oxygen. Data analysis techniques were developed to allow interpretation of experimental data and prediction of conditions for optimal reaction rates.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Technical Feasibility of Compressed Air Energy Storage (CAES) Utilizing a Porous Rock Reservoir (Appendix)

Pacific Gas & Electric Company (PG&E) conducted a project to explore the viability of underground compressed air energy storage (CAES) technology. CAES uses low-cost, off-peak electricity to compress air into a storage system in an underground space such as a rock formation or salt cavern. When electricity is needed, the air is withdrawn and used to drive a generator for electricity production.

25 ENERGY STORAGE↗

Technical Feasibility of Compressed Air Energy Storage (CAES) Utilizing a Porous Rock Reservoir

Pacific Gas & Electric Company (PG&E) conducted a project to explore the viability of underground compressed air energy storage (CAES) technology. CAES uses low-cost, off-peak electricity to compress air into a storage system in an underground space such as a rock formation or salt cavern. When electricity is needed, the air is withdrawn and used to drive a generator for electricity production.

25 ENERGY STORAGE↗

Technical Feasibility of Compressed Air Energy Storage (CAES) Utilizing a Porous Rock Reservoir, Appendix — Chapter 3

Pacific Gas & Electric Company (PG&E) conducted a project to explore the viability of underground compressed air energy storage (CAES) technology. CAES uses low-cost, off-peak electricity to compress air into a storage system in an underground space such as a rock formation or salt cavern. When electricity is needed, the air is withdrawn and used to drive a generator for electricity production.

25 ENERGY STORAGE↗

Technical Feasibility of Compressed Air Energy Storage (CAES) Utilizing a Porous Rock Reservoir, Appendix — Chapter 4

Pacific Gas & Electric Company (PG&E) conducted a project to explore the viability of underground compressed air energy storage (CAES) technology. CAES uses low-cost, off-peak electricity to compress air into a storage system in an underground space such as a rock formation or salt cavern. When electricity is needed, the air is withdrawn and used to drive a generator for electricity production.

25 ENERGY STORAGE↗

Technical Feasibility of Compressed Air Energy Storage (CAES) Utilizing a Porous Rock Reservoir, Appendix — Chapter 5

Pacific Gas & Electric Company (PG&E) conducted a project to explore the viability of underground compressed air energy storage (CAES) technology. CAES uses low-cost, off-peak electricity to compress air into a storage system in an underground space such as a rock formation or salt cavern. When electricity is needed, the air is withdrawn and used to drive a generator for electricity production.

25 ENERGY STORAGE↗

Technical Feasibility of Compressed Air Energy Storage (CAES) Utilizing a Porous Rock Reservoir, Appendix — Chapter 6

Pacific Gas & Electric Company (PG&E) conducted a project to explore the viability of underground compressed air energy storage (CAES) technology. CAES uses low-cost, off-peak electricity to compress air into a storage system in an underground space such as a rock formation or salt cavern. When electricity is needed, the air is withdrawn and used to drive a generator for electricity production.

25 ENERGY STORAGE↗

Technical Feasibility of Compressed Air Energy Storage (CAES) Utilizing a Porous Rock Reservoir, Appendix — Chapter 7

Pacific Gas & Electric Company (PG&E) conducted a project to explore the viability of underground compressed air energy storage (CAES) technology. CAES uses low-cost, off-peak electricity to compress air into a storage system in an underground space such as a rock formation or salt cavern. When electricity is needed, the air is withdrawn and used to drive a generator for electricity production.

25 ENERGY STORAGE↗

Technical Feasibility of Compressed Air Energy Storage (CAES) Utilizing a Porous Rock Reservoir, Appendix — Chapter 8

Pacific Gas & Electric Company (PG&E) conducted a project to explore the viability of underground compressed air energy storage (CAES) technology. CAES uses low-cost, off-peak electricity to compress air into a storage system in an underground space such as a rock formation or salt cavern. When electricity is needed, the air is withdrawn and used to drive a generator for electricity production.

25 ENERGY STORAGE↗

Technical Feasibility of Compressed Air Energy Storage (CAES) Utilizing a Porous Rock Reservoir, Appendix — Chapter 9

Pacific Gas & Electric Company (PG&E) conducted a project to explore the viability of underground compressed air energy storage (CAES) technology. CAES uses low-cost, off-peak electricity to compress air into a storage system in an underground space such as a rock formation or salt cavern. When electricity is needed, the air is withdrawn and used to drive a generator for electricity production.

25 ENERGY STORAGE↗

Super Rapid Crystal Growth and Quench of Monoclinic Bi-II* During Dynamic Compression

We show that monoclinic Bi-II* forms during a dynamic compression regime with crystal growth rates from melt of approximately 70 m/s. This extreme quench rate implies crystallization by non-diffusive processes and indicates that the liquid had a high degree of pre-ordering. Using ambient condition single crystal structure analysis we show for the first time that the monoclinic distorted phase of Bi (Bi-II) exists at ambient pressure, albeit bound to formation under dynamic compression. We review the pressure, temperature, and time conditions for formation and growth of this structure.

36 MATERIALS SCIENCE↗

Spherical Platen versus Flat Platens in Compression Testing of PBX 9502

For ~15 years and perhaps longer, Pantex Plant has used a spherical platen in their compression load train when performing compression tests for Core Surveillance and HE Qualification. As our mechanical testing team at Los Alamos National Laboratory has always worked closely with our Pantex colleagues, and has maintained very similar practices in terms of calibration and testing, the author of this report has documented discussions with Pantex personnel (Robert Spence, et al.) dating back to ~2003, discussing the pros and cons of spherical platen use. LANL used spherical platens for a year or two, but determined issues and discontinued the practice. Based on multiple Engineering Evaluations (EE), LANL opportunities to watch Pantex procedures, it is our understanding that Pantex continued to use spherical platens from circa 2003 (or earlier) through summer 2019, despite the discontinued practice at LANL and the strong encouragement from LANL that spherical platens introduced error and should not be used. The short study reported here was intended to provide quantitative argument as to why spherical platens should not be used. As of a mechanical testing EE in August 2019, and after the testing of this LANL study was complete, LANL was informed by Pantex personnel that the practice of using spherical platens had recently been discontinued with no obvious problems or changes to the quality of the data. Although the urgency is gone for reporting our results, this is a brief quick summary of the data we collected.

42 ENGINEERING↗

Supercritical Reforming of Wet Ethanol for High Efficiency Direct-injection Heavy-duty Compression-ignition Engines

The purpose of the research was to investigate the potential of using a mature bio-fuel in heavy-duty compression ignition engines. By co-optimizing both the fuel characteristics and engine system the potential for a superior outcome was demonstrated. The use of wet bio-ethanol eliminates the majority of the energy intensive distilling and dehydrating fuel production processes, which moves the fuel towards carbon neutral and also lowers the fuel costs. The relatively high water content of the resulting fuel is leveraged in the proposed novel combustion system by incorporating an integrated high efficiency exhaust waste heat recovery system. This results in significantly higher thermal efficiency. In addition the combustion system features low criteria pollutant emissions and the potential to reduce the initial cost of the engine system hardware. Substantial societal benefits are demonstrated through the co-optimization of the fuel and engine system. A computational proof-of-concept study has been performed to demonstrate the potential benefits of a novel wet ethanol heavy-duty compression ignition combustion system featuring integrated exhaust waste heat recovery. A combined in-cylinder closed cycle 3D computational fluid dynamics (CFD) - 1D engine system simulation approach was used. The models were validated to baseline engine data using diesel fuel and then applied to the wet ethanol study. The original concept was to maximize exhaust waste heat recovery through supercritical reforming of the wet ethanol fuel. Phase I simulation results indicated that the optimal solution for maximum engine efficiency gains were realized through maximizing thermo-mechanical recuperation with negligible fuel reformation. The results show the potential to achieve impressive gains in brake thermal efficiency (BTE) over the base diesel engine. The potential to increase BTE up to 20.9% over the base diesel engine was demonstrated, with even larger gains possible through reduced in-cylinder heat transfer losses. The majority of the efficiency gains were realized through integrated high efficiency exhaust waste heat recovery. The concept also has the potential to achieve future ultra-low NO x emissions standards and negligible engine-out soot emissions. The mixing controlled combustion of high temperature wet ethanol features relatively low engine-out NO x emissions without the need for exhaust gas recirculation (EGR). The soot free combustion enabled by the relatively high oxygen content of ethanol also allows for the use of stoichiometric mixing controlled combustion, which is not practical with diesel fuel. When stoichiometric combustion is used a simple passive 3-way catalyst can be used for exhaust emissions after-treatment and near zero tailpipe emissions. The Phase I simulations results have defined the system layout and requirements in preparation for the Phase II experimental proof-of-concept study. The potential applications of the research include most current applications of diesel engines. The Phase I study focused on heavy-duty on-highway class 8 trucks. However, virtually any application that requires highly efficient clean power generation would benefit from the novel engine system proposed. The results indicate substantial fuel cost savings and reduced greenhouse gas emissions with similar or reduced initial system hardware costs compared to modern diesel engine systems.

09 BIOMASS FUELS↗

End-of-Life Evaluation of Compressed Natural Gas Vehicle Fuel Tanks

This study evaluated the structural integrity of Type III and Type IV CNG fuel tanks from the Los Angeles (LA) County Metropolitan Transportation Authority to characterize the fuel tank conditions after experiencing a full service life of 15 years in transit bus application. The data produced provide insight about the condition of the CNG fuel tanks at the conclusion of their defined EOL and potential risks of continued operation of the CNG vehicle without replacement of the expired fuel tanks. In addition to physical testing performed on the fuel tanks, a nondestructive evaluation of modal acoustic emission (MAE) was utilized to assess the structural integrity of the tanks. The CNG fuel tanks were evaluated in their received condition and after experiencing artificial damage. The MAE results were then compared to visual inspection results of the procedures defined in the Compressed Gas Association’s (CGA’s) C-6.2 and C-6.4 standards (Compressed Gas Association 2013; 2012) to better understand the effectiveness of the visual inspection and potential safety risks of continued use of the tanks.

03 NATURAL GAS↗