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At least 1,063 records · Page 59

Viscous relaxation of a compressible spherical shell

Analytical solutions for analyzing viscous relaxation of a compressible mantle to surface loading are developed. Two different models are considered: one in which the density step of the core-mantle boundary is held fixed and the other in which the mass of the earth remains invariant with respect to variations of equation of state parameters. For thermodynamic parameters characteristic of the mantle, relaxation times of the fundamental and first overtone modes change by no more than about 30 percent for degree less than four. For a given initial depression, the ratio between the velocity in the lower mantle and that at the surface is bigger for incompressible models than for compressible models. Eigenfunctions between the two models also differ in appearance throughout the mantle, with the incompressible ones being larger for the second model. These results would suggest that the resolution of mantle viscosity may be impaired by the smaller excitation in the lower mantle due to effects of mantle compressibility.

Li, Guoying↗

Experimental and modeling study of fuel interactions with an alkyl nitrate cetane enhancer, 2-ethyl-hexyl nitrate

Our study investigates the autoignition behavior of two gasoline surrogates doped with an alkyl nitrate cetane enhancer, 2-ethyl-hexyl nitrate (2EHN) to better understand dopant interactions with the fuels, including influences of accelerating kinetic pathways and enhanced exothermicity. A primary reference fuel (PRF) blend of n-heptane/iso-octane, and a toluene reference fuel (TRF) blend of n-heptane/iso-octane/toluene are used where the aromatic fraction of the latter is set to 20% (liquid volume), while the content of n-heptane is adjusted so that the overall reactivity of the undoped fuels is similar, e.g., Anti-Knock Index (AKI) of similar to 91, Cetane Number (CN) similar to 25. Doping levels of 0.1, 1.0 and 3.0% (liquid volume basis) are used where tests are conducted within a rapid compression machine (RCM) at a compressed pressure of 21 bar, covering temperatures from 675 to 1025 K with stoichiometric fuel-oxygen ratios at O-2 = 11.4%. At the experimental conditions, it is found that the doping effectiveness of 2EHN is fairly similar between the two fuels, though 2EHN is more effective in the aromatic blend at the lowest temperatures, while it is slightly more effective in the non-aromatic blend at intermediate temperatures. Furthermore, kinetic modeling of the experiments indicates that although some of the reactivity trends can be captured using a detailed model, the extents of predicted Cetane Number enhancement by 2EHN are too large, while differences in fuel interactions for the two fuels result in excessive stimulation of the non-aromatic blend. Sensitivity analysis using the kinetic model indicates that the CH 2 O and CH 3 O 2 chemistry are very sensitive to the dopant at all conditions. The rate of 2EHN decomposition is only important at low temperatures where its decomposition rate is slow due to the high activation energy of the reaction. At higher temperatures, dopant-derived 3-heptyl radicals are predicted to play an important role stimulating ignition. Finally, nitrogen chemistry is important through the 'NO - NO 2 loop' where this can generate substantial amounts of OH. But, at the highest doping levels the formation of methyl and ethyl nitrite, and nitric acid significantly competes with this so that less OH is generated and this constrains the reactivity enhancement of 2EHN.

30 DIRECT ENERGY CONVERSION↗

Controlling Magnetism via Transition Metal Exchange in the Series of Intermetallics Eu( T 1, T 2)5In ( T = Cu, Ag, Au)

Three series of intermetallic compounds Eu( T 1, T 2) 5 In (T = Cu, Ag, Au) have been investigated in full compositional ranges. Single crystals of all compounds have been obtained by self-flux and were analyzed by single X-ray diffraction revealing the representatives to fall into two structure types: CeCu 6 ( oP 28, Pnma , a = 8.832(3)–9.121(2) Å, b = 5.306(2)–5.645(1) Å, c = 11.059(4)–11.437(3) Å, V = 518.3(3)–588.9(2) Å 3 ) and YbMo2Al4 ( t I 14, I 4/ mmm , a = 5.417(3)–5.508(1) Å, c = 7.139(2)– 7.199(2) Å, V = 276.1(2)–285.8(1) Å 3 ). The structural preference was found to depend on the cation/anion size ratio, while the positional preference within the CeCu 6 type structure shows an apparent correlation with the anion size. Chemical compression, hence, a change in cell volume, which occurs upon anion substitution appears to be the main driving force for the change of magnetic ordering. While EuAg 5 In shows antiferromagnetic behavior at low temperatures, mixing Cu and Au within the same type of structure results in considerable changes in the magnetism. The Eu(Cu,Au) 5 In alloys with CeCu 6 structure show complex magnetic behaviors and strong magnetic field-induced spin-reorientation transition with the critical field of the transition being dependent on Cu/Au ratio. The alloys adopting the YbMo 2 Al 4 type structure are ferromagnets exhibiting unusually high magnetic moments. The heat capacity of EuAu 2.66 Cu 2.34 In reveals a double-peak structure evolving with the magnetic field. Furthermore, low-temperature X-ray powder diffraction does not show a structural transition.

36 MATERIALS SCIENCE↗

Long-term Isothermal Aging Effects on Weight Loss, Compression Properties, and Dimensions of T650-35 Fabric-reinforced PMR-15 Composites-data

A cooperative program was conducted with the General Electric Aircraft Engines plant in Evendale, Ohio, to study the effects of long-term isothermal aging at elevated temperatures on compression and thermal durability properties of T650 35 fabric-reinforced PMR 15 composites. This degradation study was conducted over an approximate time period of 3 1/2 yr. The aging temperatures were 204, 260, 288, 316, and 343 C. Specimens of different dimensions were evaluated. Specimens with ratios of the cut edge to total surface area of 0.03 to 0.89 were fabricated and aged. The aged and unaged specimens were tested in compression as specified in Test Method for Compressive Properties of Rigid Plastics (ASTM D695M). Thickness changes, degraded surface layer growth, weight loss, and failure modes were monitored and recorded. All property changes were thickness dependent.

Bowles, Kenneth J.↗

Prospects and Limitations of Predicting Fuel Ignition Properties from Low-Temperature Speciation Data

Using chemical kinetic modeling and statistical analysis, we investigate the possibility of correlating key chemical “markers”–typically small molecules–formed during very lean (φ ~ 0.001) oxidation experiments with near-stoichiometric (φ ~ 1) fuel ignition properties. One goal of this work is to evaluate the feasibility of designing a fuel-screening platform, based on small laboratory reactors that operate at low temperatures and use minimal fuel volume. Buras et al. [Combust. Flame2020,216, 472–484] have shown that convolutional neural net (CNN) fitting can be used to correlate first-stage ignition delay times (IDTs) with OH/HO2 measurements during very lean oxidation in low-T flow reactors with better than factor-of-2 accuracy. In this work, we test the limits of applying this correlation-based approach to predict the low-temperature heat release (LTHR) and total IDT, including the sensitivity of total IDT to the equivalence ratio, φ. We demonstrate that first-stage IDT can be reliably correlated with very lean oxidation measurements using compressed sensing (CS), which is simpler to implement than CNN fitting. LTHR can also be predicted via CS analysis, although the correlation quality is somewhat lower than for first-stage IDT. In contrast, the accuracy of total IDT prediction at φ = 1 is significantly lower (within a factor of 4 or worse). Furthermore, these results can be rationalized by the fact that the first-stage IDT and LTHR are primarily determined by low-temperature chemistry, whereas total IDT depends on low-, intermediate-, and high-temperature chemistry. Oxidation reactions are most important at low temperatures, and therefore, measurements of universal molecular markers of oxidation do not capture the full chemical complexity required to accurately predict the total IDT even at a single equivalence ratio. As a result, we find that φ-sensitivity of ignition delay cannot be predicted at all using solely correlation with lean low-T chemical speciation measurements.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

In-situ neutron diffraction of LaCoO₃ perovskite under uniaxial compression. I. Crystal structure analysis and texture development

The dynamics of texture formation, changes in crystal structure, and stress accommodation mechanisms have been studied in perovskite-type R3⁻c rhombohedral LaCoO₃ during uniaxial compression using in-situ neutron diffraction. The in-situ neutron diffraction revealed the complex crystallographic changes causing the texture formation and significant straining along certain crystallographic directions during compression, which are responsible for the appearance of hysteresis and non-linear ferroelastic deformation in the LaCoO₃ perovskite. The irreversible strain after the first loading was connected with the appearance of non-recoverable changes in the intensity ratio of certain crystallographic peaks, causing non-reversible texture formation. However, in the second loading/unloading cycle, the hysteresis loop was closed and no further irrecoverable strain appeared after deformation. The significant texture formation is responsible for an increase in the Young's modulus of LaCoO₃ at high compressive stresses, ranging from 76 GPa at the very beginning of the loading to 194 GPa at 900 MPa at the beginning of the unloading curve.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Compressed Sensing with Sparse Corruptions: Fault-Tolerant Sparse Collocation Approximations

The recovery of approximately sparse or compressible coefficients in a polynomial chaos expansion is a common goal in many modern parametric uncertainty quantification (UQ) problems. However, relatively little effort in UQ has been directed toward theoretical and computational strategies for addressing the sparse corruptions problem, where a small number of measurements are highly corrupted. Such a situation has become pertinent today since modern computational frameworks are sufficiently complex with many interdependent components that may introduce hardware and software failures, some of which can be difficult to detect and result in a highly polluted simulation result. In this paper we present a novel compressive sampling--based theoretical analysis for a regularized $\ell^1$ minimization algorithm that aims to recover sparse expansion coefficients in the presence of measurement corruptions. Our recovery results are uniform (the theoretical guarantees hold for all compressible signals and compressible corruptions vectors) and prescribe algorithmic regularization parameters in terms of a user-defined a priori estimate on the ratio of measurements that are believed to be corrupted. We also propose an iteratively reweighted optimization algorithm that automatically refines the value of the regularization parameter and empirically produces superior results. Lastly, our numerical results test our framework on several medium to high dimensional examples of solutions to parameterized differential equations and demonstrate the effectiveness of our approach.

97 MATHEMATICS AND COMPUTING↗

Investigation of specimen size effects by in-situ microcompression of equal channel angular pressed copper

Here, micropillar compression testing was implemented on Equal Channel Angular Pressed copper samples ranging from 200 nm to 10 µm in side length in order to measure the mechanical properties yield strength, first load drop during plastic deformation at which there was a subsequent stress decrease with increasing strain, work hardening, and strain hardening exponent. Several micropillars containing multiple grains were investigated in a 200 nm grain sample. The effective pillar diameter to grain size ratios, D/d , were measured to be between 1.9 and 27.2. Specimens having D/d ratios between 0.2 and 5 were investigated in a second sample that was annealed at 200 °C for 2 h with an average grain size of 1.3 µm. No yield strength or elastic modulus size effects were observed in specimens in the 200 nm grain size sample. However work hardening increases with a decrease in critical ratios and first stress drops occur at much lower stresses for specimens with D/d ratios less than 5. For comparison, bulk tensile testing of both samples was performed, and the yield strength values of all micropillar compression tests for the 200 nm grained sample are in good agreement with the yield strength values of the tensile tests.

36 MATERIALS SCIENCE↗

Strength and texture of Pt compressed to 63 GPa

Angle- and energy-dispersive X-ray diffraction experiments in a radial geometry were performed in the diamond anvil cell on polycrystalline platinum samples at pressures up to 63 GPa. Observed yield strength and texture depend on grain size. For samples with 70–300-nm particle size, the yield strength is 5–6 GPa at ∼60 GPa. Coarse-grained (∼2-μm particles) Pt has a much lower yield strength of 1–1.5 GPa at ∼60 GPa. Face-centered cubic metals Pt and Au have lower strength to shear modulus ratio than body-centered cubic or hexagonal close-packed metals. While a 300-nm particle sample exhibits the 〈110〉 texture expected of face-centered-cubic metals under compression, smaller and larger particles show a weak mixed 〈110〉 and 〈100〉 texture under compression. Differences in texture development may also occur due to deviations from uniaxial stress under compression in the diamond anvil cell.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Hygrothermal Effect on Composites Under In-Plane Fatigue at Stress Ratios of R = −1 and R = 0.1: An Analysis of Quasi-Isotropic Stitched Carbon Fibers

The aeronautic structures normally operate under high levels of hygroscopic moisture from the surrounding environment at different temperature ranges while in service. Under such conditions, the behavior of laminate composite submitted to cyclic or static loadings can change drastically. In order to understand those effects in stitched fabrics, fatigue tests with open-hole specimens were carried out with a stress ratio of R = −1 and R = 0.1. The specimens were fatigue-tested as provided (environmental conditions) and after exposed to hygrothermal weathering conditions. Based on evidences from recent studies available in the open literature, e.g., effect of water diffusion on epoxy matrix, the overall results indicated a significant reduction in stiffness after the specimens are exposed to hygrothermal effects. The reduction in matrix stiffness, in this case, enhanced the fatigue strength in tension–tension load (R = 0.1) when compared to the specimens in normal conditions. The opposite occurs for the specimens loaded with stress ratio of R = −1, in which the delamination mechanisms changed during the loading reversion from tension to compression that promoted early delamination. Therefore, this process reduced the fatigue life of the specimens under hygrothermal condition. Then, by fractographic investigation, it was verified fracture patterns that regard to mode II damage in R = −1, in which mode II fracture toughness is known to decrease in the presence of water molecules.

36 MATERIALS SCIENCE↗

Evolution of global and local deformation in additively manufactured octet truss lattice structures

Additively manufactured lattice truss structures, often referred to as architected cellular materials, present significant advantages over conventional structures due to their unique characteristics such as high strength-to-weight ratios and surface area-to-volume ratios. These geometrically complex structures, however, come with concomitant challenges for qualification and inspection. In this study, compression testing interrupted with micro-computed tomography inspection was conducted to monitor the evolution of global and local deformation throughout the loading process of 304L stainless steel octet truss lattice structures. Both two- and three-dimensional image analysis techniques were leveraged to characterize geometric heterogeneities resulting from the laser powder bed fusion manufacturing process as well as track the structure throughout deformation. Variations from model-predicted behavior resulting from these heterogeneities are considered relative to the predicted and actual responses of the structures during compression to better understand, model, and predict the octet truss lattice structure compression response.

36 MATERIALS SCIENCE↗

Design of composite polymer electrolytes for Li ion batteries based on mechanical stability criteria

Mechanical properties and conductivity were computed for several composite polymer electrolyte structures. A multi-phase effective medium approach was used to estimate effective conductivity. The Mori-Tanaka approach was applied for calculating the effective stiffness tensor of the composites. An analysis of effective mechanical properties was performed in order to identify the composite structures, which would be capable of blocking the dendrites forming in Li-ion battery when Li metal is used as anode. The data on conductivity, elastic modulus, and Poisson s ratio can be used to formulate design criteria for solid electrolytes that would exhibit appropriate stiffness and compressibility to suppress lithium dendrite growth while maintaining high effective conductivities.

25 ENERGY STORAGE↗

Dynamics of cylindrical converging shock waves interacting with aerodynamic obstacle arrays

Cylindrical converging shock waves interacting with an array of aerodynamic obstacles are investigated numerically for diverse shock strengths and for different obstacle configurations in air in standard conditions. The considered number of obstacles N is 4, 6, 8, 16, and 24. Obstacles are lenticular airfoils with thickness-to-chord ratios t/c of 0.07, 0.14, and 0.21. The distances of the airfoil leading edge from the shock focus point (r{sub LE})/(r{sub LE}{sup ref}) are 1, 2, and 2.5, where r{sub LE}{sup ref}=7 is the dimensionless reference distance from the origin. Considered impinging shock Mach numbers M{sub s} are 2.2, 2.7, and 3.2 at the reference distance from the origin. The reference experimental configuration (N=8,t/c =0.14,r{sub LE}=7,M{sub s}=2.7) was proposed by Kjellander et al. [“Thermal radiation from a converging shock implosion,” Phys. Fluids 22, 046102 (2010)]. Numerical results compare fairly well to available one-dimensional models for shock propagation and to available experimental results in the reference configuration. Local reflection types are in good agreement with the classical criteria for planar shock waves. The main shock reshaping patterns are identified and their dependence on the shock strength and obstacle configuration is exposed. In particular, different shock patterns are observed after the leading edge reflection, which results in polygonal shock wave with N, 2N, 3N, and 4N sides. The largest temperature peak at the origin is obtained for the 8- and the 16-obstacle configurations and for the smallest thickness to length ratio, 0.07, located at distance from the origin of 2r{sub LE}{sup ref}. In terms of compression efficiency at the origin, the 16-obstacle configuration is found to perform slightly better than the reference 8-obstacle configuration—with an efficiency increase of about 2%-3%, which is well within the model accuracy—thus confirming the goodness of the obstacle arrangement proposed by Kjellander and collaborators.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Solar Wind Turbulence from 1 to 45 au. III. Anisotropy of Magnetic Fluctuations in the Inertial Range Using Voyager and ACE Observations

We examine both Voyager and Advanced Composition Explorer magnetic field measurements at frequencies that characterize the inertial range and evaluate the anisotropy of the fluctuations as they relate to both the compressive component and underlying wavevector anisotropy of the turbulence. The magnetic fluctuation anisotropy as it relates to the compressive component is directly dependent upon both the plasma beta of the thermal proton component and the ratio of magnetic fluctuation magnitude to the strength of the mean magnetic field. This has been seen before at 1 au. The magnetic fluctuation anisotropy in the plane perpendicular to the mean magnetic field, which is a measure of the anisotropy of the underlying wavevector distribution, should depend on the angle between the mean magnetic field and the radial direction and should be confined to values between one and the index of the power spectrum, which is typically 5/3. Our results show that the average of this anisotropy exceeds the value of the spectral index and is out of bounds with the theory. Although the results are suggestive of past analyses, we find that spherical expansion of the turbulence may offer at least a partial explanation of the apparent amplification of this measured anisotropy.

heliosphere↗

Exhaust-nozzle characterisitcs for a twin-jet variable-wing-sweep fighter airplane model at Mach numbers to 2.2

A wind-tunnel investigation has been conducted to determine the exhaust-nozzle aerodynamic and propulsive characteristics for a twin-jet variable-wing-sweep fighter airplane model. The powered model was tested in the Langley 16-foot transonic tunnel and in the Langley 4-foot supersonic pressure tunnel at Mach numbers to 2.2 and at angles of attack from about minus 2 to 6 deg. Compressed air was used to simulate the nozzle exhaust flow at values of jet total-pressure ratio from approximately 1 (jet off) to about 21. Effects of configuration variables such as speed-brake deflection, store installation, and boundary-layer thickness on the the nozzle characteristics were also investigated.

Reubush, D. E.↗

Collapsing cloud models for Bok globules

The dynamic collapse of rotating gas clouds is calculated for a wide range of initial conditions. Properties of cloud models are compared with observed radio and optical properties of Bok globules, to test the hypothesis that globules undergo collapse and to determine parameters which are not easily observed. Five of the six globules studied are consistent with collapse models. It is inferred that these objects have masses of about 100 solar masses and ages smaller than their free-fall times. Inferred initial densities are much larger than minimum densities for gravitational collapse, suggesting that collapse is initiated by strong external compression or that globules are fragments of larger condensed clouds. Values inferred for the (C-13)O/H2 ratio are smaller than previous estimates and depend strongly on cloud density.

Villere, K. R.↗