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At least 1,063 records · Page 59
All sourcesNASA NTRSDOE OSTI
NASA NTRS2002

Cloud Microphysics and Absorption Validation

Vertical distributions of particle size and habit were developed from in-situ data collected from three midlatitude cirrus field campaigns (FIRE-1, FIRE-2, and ARM IOP). These new midlatitude microphysical models were used to develop new cirrus scattering models at a number of wavelengths appropriate for use with the MODIS imager (Nasiri et al. 2002). This was the first successful collaborative effort between all the investigators on this proposal. Recent efforts have extended the midlatitude cirrus cloud analyses to tropical cirrus, using in-situ data collected during the Tropical Rainfall Measurement Mission (TRMM) Kwajalein field campaign in 1999. We note that there are critical aspects to the work: a) Improvement in computing the scattering and radiative properties of ice crystals; b) Requirement for copious amounts of cirrus in-situ data, presented in terms of both particle size and habit distributions; c) Development of cirrus microphysical and optical models for various satellite, aircraft, and ground-based instruments based on the theoretical calculations and in-situ measurements; d) Application to satellite data.

Ackerman, Steven↗
NASA NTRS2006

Observations of Precipitation Size and Fall Speed Characteristics within Coexisting Rain and Wet Snow

Ground-based measurements of particle size and fall speed distributions using a Particle Size and Velocity (PARSIVEL) disdrometer are compa red among samples obtained in mixed precipitation (rain and wet snow) and rain in the Oregon Cascade Mountains and in dry snow in the Rock y Mountains of Colorado. Coexisting rain and snow particles are distinguished using a classification method based on their size and fall sp eed properties. The bimodal distribution of the particles' joint fall speed-size characteristics at air temperatures from 0.5 to 0 C suggests that wet-snow particles quickly make a transition to rain once mel ting has progressed sufficiently. As air temperatures increase to 1.5 C, the reduction in the number of very large aggregates with a diame ter > 10 mm coincides with the appearance of rain particles larger than 6 mm. In this setting. very large raindrops appear to be the result of aggregates melting with minimal breakup rather than formation by c oalescence. In contrast to dry snow and rain, the fall speed for wet snow has a much weaker correlation between increasing size and increasing fall speed. Wet snow has a larger standard deviation of fall spee d (120%-230% relative to dry snow) for a given particle size. The ave rage fall speed for observed wet-snow particles with a diameter great er than or equal to 2.4 mm is 2 m/s with a standard deviation of 0.8 m/s. The large standard deviation is likely related to the coexistence of particles of similar physical size with different percentages of melting. These results suggest that different particle sizes are not required for aggregation since wet-snow particles of the same size can have different fall speeds. Given the large standard deviation of fa ll speeds in wet snow, the collision efficiency for wet snow is likely larger than that of dry snow. For particle sizes between 1 and 10 mm in diameter within mixed precipitation, rain constituted I % of the particles by volume within the isothermal layer at 0 C and 4% of the particles by volume for the region just below the isothermal layer where air temperatures rise from 0" to 0.5"C. As air temperatures increa sed above 0.5 C, the relative proportions of rain versus snow particl es shift dramatically and raindrops become dominant. The value of 0.5 C for the sharp transition in volume fraction from snow to rain is sl ightly lower than the range from 1 .l to 1.7 C often used in hydrolog ical models.

Yuter, Sandra E.↗
NASA NTRS1994

Counting particles emitted by stratospheric aircraft and measuring size of particles emitted by stratospheric aircraft

The ER-2 condensation nuclei counter (CNC) has been modified to reduce the diffusive losses of particles within the instrument. These changes have been successful in improving the counting efficiency of small particles at low pressures. Two techniques for measuring the size distributions of particles with diameters less than 0.17 micrometers have been evaluated. Both of these methods, the differential mobility analyzer (DMA) and the diffusion battery, have fundamental problems that limit their usefulness for stratospheric applications. We cannot recommend either for this application. Newly developed, alternative methods for measuring small particles include inertial separation with a low-loss critical orifice and thin-plate impactor device. This technique is now used to collect particles in the multisample aerosol collector housed in the ER-2 CNC-2, and shows some promise for particle size measurements when coupled with a CNC as a counting device. The modified focused-cavity aerosol spectrometer (FCAS) can determine the size distribution of particles with ambient diameters as small as about 0.07 micrometers. Data from this instrument indicates the presence of a nuclei mode when CNC-2 indicates high concentrations of particles, but cannot resolve important parameters of the distribution.

Wilson, James Charles↗
DOE OSTI2016

Propagation of electromagnetic wave in dusty plasma and the influence of dust size distribution

The effect of charged dust particle and their size distribution on the propagation of electromagnetic wave in a dusty plasma is investigated. It is shown that the additional collision mechanism provided by charged dust particles can significantly alter the electromagnetic properties of a plasma, leading to the appearance of attenuation of electromagnetic wave through dusty plasma. The attenuation coefficient mainly depends on the dust density, radius, and the charge numbers on the dust surface. The results described here will be used to enhance understanding of electromagnetic wave propagation processed in space and laboratory dusty plasma.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1994

Shape, size, and distribution of magnetic particles in Bjurbole chondrules

Chondrules from the Bjurbole chondritic meteorite (L4) exhibit saturation remanence magnetization (SIRM) values which vary over three orders of magnitude. REM values (Natural Remanence Magnetization/SIRM) for Allende (C3V) and Chainpur (LL3) are less than 0.01 but in Bjurbole some chondrules were found to have REM values greater than 0.1 with several greater than 0.2. REM values greater than 0.1 are abnormal and cannot be acquired during weak field cooling. If exposure to a strong field (whatever the source) during the chondrules' history is responsible for the high REM values, was such history associated with a different processing which might have resulted in different shape, size, and distribution of metal particles compared to chondrules having REM values of less than 0.01? Furthermore, magnetic hysteresis results show a broad range of magnetic hardness and other intrinsic magnetic properties. These features must be related to (1) size and amount of metal; and (2) properties of, and amount of, tetrataenite in the chondrules (all chondrules thus far subjected to thermomagnetic analysis show the presence of tetrataenite). A scanning electron microscopy (SEM) study is underway to determine the relationship between the shape, size, and distribution of metal particles within individual chondrules and the magnetic properties of these chondrules. Results from the SEM study in conjunction with magnetic property data may also help to discern effects from possible lightning strikes in the nebula prior to incorporation of the chondrules into the parent body.

Nava, David F.↗
DOE OSTI2016

National Atmospheric Release Advisory Center dispersion modeling of the Full-scale Radiological Dispersal device (FSRDD) field trials

The results of the National Atmospheric Release Advisory Center (NARAC) model simulations are compared to measured data from the Full-Scale Radiological Dispersal Device (FSRDD) field trials. The series of explosive radiological dispersal device (RDD) experiments was conducted in 2012 by Defence Research and Development Canada (DRDC) and collaborating organizations. During the trials, a wealth of data was collected, including a variety of deposition and air concentration measurements. The experiments were conducted with one of the stated goals being to provide measurements to atmospheric dispersion modelers. These measurements can be used to facilitate important model validation studies. For this study, meteorological observations recorded during the tests are input to the diagnostic meteorological model, ADAPT, which provides 3–D, time-varying mean wind and turbulence fields to the LODI dispersion model. LODI concentration and deposition results are compared to the measured data, and the sensitivity of the model results to changes in input conditions (such as the particle activity size distribution of the source) and model physics (such as the rise of the buoyant cloud of explosive products) is explored. The NARAC simulations predicted the experimentally measured deposition results reasonably well considering the complexity of the release. Lastly, changes to the activity size distribution of the modeled particles can improve the agreement of the model results to measurement.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1991

Measurements

To interpret the effects of aerosols and gases on the atmosphere, information on the vertical and horizontal distribution of aerosol particles, their size distributions and concentration of precursor gases is required. Measurements of aerosols and gases at frequent intervals and over vast areas of atmosphere generally involve remote sensing techniques. These techniques depend on the optical properties of the species studied. Optical properties can vary greatly with aerosol size and refractive index. Remote sensing instruments look at light scattering, extinction, depolarization, and reflection. The chemical composition, phase equilibria, surface properties, and photochemical behavior of stratospheric aerosols are not clearly understood or adequately measured by current technologies. Areas are listed which need technology development.

Source record↗
DOE OSTI2023

A dynamic parameterization of sulfuric acid–dimethylamine nucleation and its application in three-dimensional modeling

Sulfuric acid (SA) is a governing gaseous precursor for atmospheric new particle formation (NPF), a major source of global ultrafine particles, in environments studied around the world. In polluted urban atmospheres with high condensation sinks (CSs), the formation of stable SA–amine clusters, such as SA–dimethylamine (DMA) clusters, usually initializes intense NPF events. Coagulation scavenging and cluster evaporation are dominant sink processes of SA–amine clusters in urban atmospheres, yet these loss processes are not quantitatively included in the present parameterizations of SA–amine nucleation. We herein report a parameterization of SA–DMA nucleation, based on cluster dynamic simulations and quantum chemistry calculations, with certain simplifications to greatly reduce the computational costs. Compared with previous SA–DMA nucleation parameterizations, this new parameterization was able to reproduce the dependences of particle formation rates on temperature and CSs. We then incorporated it in a three-dimensional (3-D) chemical transport model to simulate the evolution of the particle number size distributions. Simulation results showed good consistency with the observations in the occurrence of NPF events and particle number size distributions in wintertime Beijing and represented a significant improvement compared to that using a parameterization without coagulation scavenging. Quantitative analysis shows that SA–DMA nucleation contributes significantly to nucleation rates and aerosol population during the 3-D simulations in Beijing (>99 % and >60 %, respectively). These results broaden the understanding of NPF in urban atmospheres and stress the necessity of including the effects of coagulation scavenging and cluster stability in simulating SA–DMA nucleation in 3-D simulations. Representing these processes is thus likely to improve model performance in particle source apportionment and quantification of aerosol effects on air quality, human health, and climate.

Li, Yuyang↗
NASA NTRS1989

Concentrations and size distributions of Antarctic stratospheric aerosols

Particle Measuring Systems laser particle spectrometer (ASAS-X and FSSP) probes were used to measure aerosol particle concentrations and size distributions during 11 ER-2 flights between Punta Arenas (53 deg S) and Antarctica (up to 72 deg S) from August 17 to September 22, 1987. The time resolution was 10 s, corresponding to a spatial resolution of 2 km. The data were divided into two size classes (0.05-0.25 and 0.53-5.5 micron radius) to separate the small particle from the coarse particle populations. Results show that the small-particle concentrations are typical for a background aerosol during volcanic quiescence. This concentration is generally constant along a flight track; in only one instance a depletion of small particles during a polar stratospheric cloud (PSC) encounter was measured, suggesting a nucleation of type I PSC particles on background aerosols. Temporary increases of the coarse particle concentrations indicated the presence of tenuous polar stratospheric clouds that were encountered most frequently at the southernmost portion of a flight track and when the aircraft descended to lower altitudes. During 'particle events', particle modes were found at 0.6-micron radius, corresponding to type I PSCs, and occasionally, at 2.0-micron radius corresponding to type II PSCs.

Ferry, G. V.↗
NASA NTRS1974

A Stokes' velocity photographic method for measuring the size distribution of aerosols

Aerosol particles are allowed to settle in a vertical glass walled vessel, and their settling velocity is determined by photographing them while the light entering the camera is being chopped at a known rate. The settling velocity of each particle can be determined from the photographs, and by applying the Stokes' law, one can calculate the radius of each particle. The Stokes' law for a sphere settling freely in a quiet medium is given. If the volume of the photographed region of the illumination is known, the aerosol number density and size distribution can be obtained. Experiments with alumina particles of given size distributions indicate that the method works accurately. One set of a typical experiment with 3.0-micrometer Al2O3 particles is presented, which shows that the measured size distribution peaks at approximately 3.0 micrometer.

Deepak, A.↗
DOE OSTI2022

Vapor-Phase Aggregation of Cerium Oxide Nanoparticles in a Rapidly Cooling Plasma

Local conditions, such as temperature and oxygen availability, have a pronounced effect on the formation and evolution of fallout following a nuclear explosion. While the behavior of nuclear-relevant materials such as uranium has begun to be explored under a wider range of environments, little is known about the behavior of plutonium. Here, using cerium as a surrogate, we track the vapor-phase aggregation of cerium oxide nanoparticles created in a plasma flow reactor under conditions of controlled temperature at two different oxygen fugacities. In situ optical emission spectroscopy is used to measure the variations in the spectral intensity of atomic and molecular species with temperature and oxygen content. We find that the relative rate of gas-phase oxidation of cerium is highly dependent on both temperature and local redox conditions within the flow reactor, to the extent that doubling the oxygen availability effectively doubles the amount of vapor-phase cerium monoxide at high temperatures (>2000 K). Condensed cerium oxide nanoparticles are also collected and analyzed ex situ via transmission electron microscopy and grazing-incidence small-angle X-ray scattering to determine their elemental composition, crystal structure, and size distribution. The size and morphology of the condensed nanoparticles are independent of local redox conditions, forming the same crystal type with the same size distribution regardless of oxygen availability. Postcondensation particle evolution, however, is found to be predominantly driven by temperature, with the average particle size increasing as particles cool and subsequently aggregate. These results expand our understanding of the chemical and physical behavior of refractory oxides that form during the early stages of fallout formation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1979

Radiative transfer modeling applied to sea water constituent determination

Optical radiation from the sea is influenced by pigments dissolved in the water and contained in discrete organisms suspended in the sea, and by pigmented and unpigmented inorganic and organic particles. The problem of extracting the information concerning these pigments and particulates from the optical properties of the sea is addressed and the properties which determine characteristics of the radiation that a remote sensor will detect and measure are considered. The results of the application of the volume scattering function model to the data collected in the Gulf of Mexico and its environs indicate that the size distribution of the concentrations of particles found in the sea can be predicted from measurements of the volume scattering function. Furthermore, with the volume scattering function model and knowledge of the absorption spectra of dissolved pigments, the radiative transfer model can compute a distribution of particle sizes and indices of refraction and concentration of dissolved pigments that give an upwelling light spectrum that closely matches measurements of that spectrum at sea.

Faller, K. H.↗
DOE OSTI2022

Experimental Set-up for the Study of Chemical Fractionation and Aerosol Dynamics

Experimental investigations of chemical fractionation/phase partition and aerosol dynamics in high-temperature environment were reviewed and discussed. Particle composition and size distribution are the key data for aerosol dynamics predictive model and simulation. However, there were no particle size distribution available from the previous works. Nucleation, condensation, and coagulation are three key physical processes driving the fractionation or phase partition thereby the aerosol dynamics. A new approach was proposed to experimentally observe fractionation/phase partition and provide data for validating the predictive model for aerosol dynamics in the simulation of bomb debris formation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1974

A standard particle sizer-velocimeter

A standard particle sizer-cum-velocimeter is described, which was designed and built for the purpose of providing a standard source of aerosols of known size-distribution, moving with a known velocity, for the purpose of calibrating the continuous wave (CW) CO2-Laser Doppler Velocimeters at Marshall Space Flight Center. The instrument is designed with the capabilities of: (1) monitoring the size-distribution of particles of diameters larger than 1.0 microns; (2) measuring flow velocities in the range 0.05 - 100.0 cm/sec; (3) photographing particles of diameters above 0.2 microns moving at slow speeds (approximately 0.1 cm/sec); (4) measuring the size-distribution of particles settling in quiet air (or convection velocities of less than 0.15 cm/sec); and (5) use in the laboratory or in the field.

Deepak, A.↗
DOE OSTI2018

Azores 2017 Field Campaign Report

Aerosol particles play an important role for the regional and global climate. Therefore, a network of measurement sites has been established worldwide, but only a small fraction of them is capturing the marine boundary layer (MBL) while approximately 70% of the Earth’s surface is covered with water. The main focus of this project is to improve the knowledge of sources and exchange processes of aerosol particles in general (German Research Foundation [DFG] project WE 2757/2-1) and of cloud condensation nuclei in particular (DFG project HE 6770/2-1) in the MBL in the northeastern Atlantic Ocean where the influence of local anthropogenic sources is negligible. The main hypothesis of the project is that long-range transport of aerosols from North America as well as new particle formation in the free troposphere (FT) and at cloud edges followed by vertical transport contribute significantly to the aerosol budget in the MBL. The knowledge of sources and sinks of aerosol particles in combination with vertical exchange between FT and MBL is a prerequisite to predict aerosol particle number concentrations in the lowest regions of the MBL and its influence on the formation of clouds. These processes are not sufficiently quantified over the ocean up to now. To verify the hypothesis stated above, vertical exchange processes and particle sources over the Azores will be quantified using data of 17 measurement flights with high spatial resolution using a helicopter-borne platform developed at the Leibniz Institute for Tropospheric Research (TROPOS). Here, aerosol particle number concentration and vertical wind speed have been measured with a temporal resolution allowing the direct estimate of the vertical turbulent flux of aerosol particles in different heights for the first time. In addition, aerosol particle number size distributions, number concentrations of cloud condensation nuclei (CCN), cloud droplet number concentration (CDNC), and particle absorption at three different wavelengths have been determined. The data analysis is ongoing and final results are not available yet. The detailed analysis of these data will be used to conclude sources and origin of the investigated aerosol particles.

Eastern North Atlantic, marine boundary layer, aer↗
DOE OSTI2022

Medium controlled aggregative growth as a key step in mesoporous silica nanoparticle formation

Near monodisperse mesoporous silica nanoparticles (MSN) represent a promising and rapidly developing type of mesoporous silica materials; however, the vast data on their synthesis remains unorganized and ill-understood. We systematically studied the formation of MSN under basic and neutral conditions using various temperatures, CTAB concentrations, hydrolyzing agents (triethanolamine, ammonia, phosphate buffers), and media with different colloidal stabilization properties (with ethanol as a cosolvent and monovalent salts). In the typical conditions for the preparation of stable MSN colloids, the particle size was controlled by colloidal stabilization by the medium (solvent type, ionic strength, and surfactant concentration) in agreement with the “aggregative growth” mechanism, rather than by solely the hydrolysis and condensation rates conventionally used for data interpretation in the classical nucleation theory. Medium properties (pH, ion types and concentration, polarity) also defined the efficiency of silica-surfactant cooperative self-assembly, which directly affected the porosity, mesopore size and pore wall thickness. Interestingly, this traditional silica-surfactant route showed a limited effect on the particle size, emphasizing the dominating role of colloidal stabilization in the studied reaction conditions. In situ pH measurements showed that every reaction medium has unique pH evolution profiles depending on the buffer capacity, hydrolysis and condensation rates. Reaction systems that fail to maintain the working pH can lead to non-porous products or undesired particle morphology and size distribution. The established particle formation mechanism allowed us to formulate comprehensive guidelines for preparing relatively concentrated colloids of near monodisperse (PDI 5–15%) mesoporous 30–700 nm silica spheres with variable porosity and mesopore size. Here, these findings will be particularly useful in designing new mesoporous silica-containing materials for biomedical applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗