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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,063 records · Page 59
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Impact of Boron-Containing Lubricant Additive on Three-Way Catalyst Reactivity and Physicochemical Properties

Boron-containing compounds are one of the lubricant additive options due to their suitable properties for additives and have been used as commercial lubricant additives. In the present study, the impact of a boron-containing lubricant oil additive, AR9100 (BR), on Pd/Rh-based three-way catalyst (TWC) performance is investigated, and the results are compared with the baseline no-additive (NA) case and the industry standard zinc dialkyl-dithiophosphate (ZDDP) results. Accelerated engine aging is performed using a genset to expose the catalysts to lubricant additives at high temperatures. All aged TWC samples are investigated for reactivity in a bench-flow reactor and characterized using a variety of analytical techniques. Compared with the no-additive case, the temperatures of 90% conversion (T 90 ) of NO, CO, C 3 H 6 , and C 3 H 8 for the ZDDP-aged TWC sample increased by 34, 30, 37, and 48 °C. However, the T 90 of all gas species for the BR-aged TWC sample are similar to the NA-aged TWC sample. Additionally, a significant decrease in water–gas shift reactivity and oxygen storage capacity is observed in the ZDDP-aged sample, but not in the BR-aged sample. Inductively coupled plasma-optical emission spectrometry (ICP-OES) analysis and electron probe microanalysis (EPMA) maps of accelerated engine aging samples show the presence of phosphorus and boron in ZDDP- and BR-aged TWC samples, respectively. However, no boron-related peaks are observed in the X-ray diffraction (XRD) pattern of the BR-aged TWC sample, which may exist in the form of an amorphous phase.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1973

Electron precipitation patterns and substorm morphology.

Statistical analysis of data from the auroral particles experiment aboard OGO 4, performed in a statistical framework interpretable in terms of magnetospheric substorm morphology, both spatial and temporal. Patterns of low-energy electron precipitation observed by polar satellites are examined as functions of substorm phase. The implications of the precipitation boundaries identifiable at the low-latitude edge of polar cusp electron precipitation and at the poleward edge of precipitation in the premidnight sector are discussed.

Hoffman, R. A.↗
NASA NTRS1984

Automatic Phasing for Active Antenna Elements

Automatic phasing system periodically interrupts antenna operation for calibration intervals and measures phase and amplitude response at each active antenna element. Using these measurements, system adjusts phase shift and possibly gain of active elements during operating intervals to give desired antenna-gain pattern.

Wu, C.↗
NASA NTRS1983

Waveform inversion of mantle Love waves: The born seismogram approach

Normal mode theory, extended to the slightly laterally heterogeneous Earth by the first-order Born approximation, is applied to the waveform inversion of mantle Love waves (200-500 sec) for the Earth's lateral heterogeneity at l=2 and a spherically symmetric anelasticity (Q sub mu) structure. The data are from the Global Digital Seismograph Network (GDSN). The l=2 pattern is very similar to the results of other studies that used either different methods, such as phase velocity measurements and multiplet location measurements, or a different data set, such as mantle Rayleigh waves from different instruments. The results are carefully analyzed for variance reduction and are most naturally explained by heterogeneity in the upper 420 km. Because of the poor resolution of the data set for the deep interior, however, a fairly large heterogeneity in the transition zones, of the order of up to 3.5% in shear wave velocity, is allowed. It is noteworthy that Love waves of this period range can not constrain the structure below 420 km and thus any model presented by similar studies below this depth are likely to be constrained by Rayleigh waves (spheroidal modes) only.

Tanimoto, T.↗
NASA NTRS1984

Waveform inversion of mantle Love waves - The Born seismogram approach

Normal mode theory, extended to the slightly laterally heterogeneous earth by the first-order Born approximation, is applied to the waveform inversion of mantle Love waves (200-500 sec) for the earth's lateral heterogeneity at l = 2 and a spherically symmetric anelasticity (Q sub mu) structure. The data are from the Global Digital Seismograph Network (GDSN). The l = 2 pattern is very similar to the results of other studies that used either different methods, such as phase velocity measurements and multiplet location measurements, or a different data set, such as mantle Rayleigh waves from different instruments. The results are carefully analyzed for variance reduction and are most naturally explained by heterogeneity in the upper 420 km. Because of the poor resolution of the data set for the deep interior, however, a fairly large heterogeneity in the transition zones, of the order of up to 3.5 percent in shear wave velocity, is allowed. It is noteworthy that Love waves of this period range can not constrain the structure below 420 km and thus any model presented by similar studies below this depth are likely to be constrained by Rayleigh waves (spheroidal modes) only.

Tanimoto, T.↗
NASA NTRS1990

The role of water ice clouds in the Martian hydrologic cycle

A one-dimensional model for the seasonal cycle of water on Mars has been used to investigate the direction of the net annual transport of water on the planet and to study the possible role of water ice clouds, which are included as an independent phase in addition to ground ice and water vapor, in the cycle. The calculated seasonal and spatial patterns of occurrence of water ice clouds are qualitatively similar to the observed polar hoods, suggesting that these polar clouds are, in fact, an important component of water cycle. A residual dry ice in the south acts as a cold trap which, in the absence of sources other than the caps, will ultimately attract the water ice from the north cap; however, in the presence of a source of water in northern midlatitudes during spring, it is possible that the observed distribution of vapor and ice can be in a steady state even if a residual CO2 cap is a permanent feature of the system.

James, Philip B.↗
NASA NTRS1993

Three-body effects in the PSR 1257+12 planetary system

A detailed theoretical analysis of the three-body effects in the putative planetary system of PSR 1257+12 is presented. Ways in which these effects are manifested in the pattern of pulse arrival times are discussed; the dominant perturbation is described as a modulation of the phases of the near-sinusoidal signals of the two planetary companions. Explicit formulas for the time dependence of the oscillating orbital elements that are needed for an improved timing model for this system are provided. If a timing model with fixed, independent Keplerian orbits continues to be used for the timing analysis, and if two planets are indeed orbiting this pulsar, then the three-body effects should become detectable by means of a growth in the postfit residuals as more observations are accumulated. If the typical error in the pulse arrival time measurements is about 10 microsec, the amplitude of the postfit residuals will increase beyond this level with three to five years of timing observations.

Malhotra, Renu↗
NASA NTRS1994

Radial microstrip slotline feed network for circular mobile communications array

In mobile and satellite communications there is a need for low cost and low profile antennas which have a toroidal pattern. Antennas that have been developed for mobile communications include a L-Band electronically steered stripline phased array, a Ka-Band mechanically steered elliptical reflector antenna and a Ka-Band printed dipole. In addition, a L-Band mechanically steered microstrip array, a L-Band microstrip phased array tracking antenna for mounting on a car roof and an X-Band radial line slotted waveguide antenna have been demonstrated. In the above electronically scanned printed arrays, the individual element radiates normally to the plane of the array and hence require a phase shifter to scan the beam towards the horizon. Scanning in the azimuth is by mechanical or electronic steering. An alternate approach is to mount microstrip patch radiators on the surface of a cone to achieve the required elevation angle. The array then scans in the azimuth by beam switching.

Simons, Rainee N.↗
NASA NTRS2002

Techniques for measurement of thoracoabdominal asynchrony

Respiratory motion measured by respiratory inductance plethysmography often deviates from the sinusoidal pattern assumed in the traditional Lissajous figure (loop) analysis used to determine thoraco-abdominal asynchrony, or phase angle phi. We investigated six different time-domain methods of measuring phi, using simulated data with sinusoidal and triangular waveforms, phase shifts of 0-135 degrees, and 10% noise. The techniques were then used on data from 11 lightly anesthetized rhesus monkeys (Macaca mulatta; 7.6 +/- 0.8 kg; 5.7 +/- 0.5 years old), instrumented with a respiratory inductive plethysmograph, and subjected to increasing levels of inspiratory resistive loading ranging from 5-1,000 cmH(2)O. L(-1). sec(-1).The best results were obtained from cross-correlation and maximum linear correlation, with errors less than approximately 5 degrees from the actual phase angle in the simulated data. The worst performance was produced by the loop analysis, which in some cases was in error by more than 30 degrees. Compared to correlation, other analysis techniques performed at an intermediate level. Maximum linear correlation and cross-correlation produced similar results on the data collected from monkeys (SD of the difference, 4.1 degrees ) but all other techniques had a high SD of the difference compared to the correlation techniques.We conclude that phase angles are best measured using cross-correlation or maximum linear correlation, techniques that are independent of waveform shape, and robust in the presence of noise. Copyright 2002 Wiley-Liss, Inc.

Non-NASA Center↗
NASA NTRS1985

Omnidirectional, circularly polarized, cylindrical microstrip antenna

A microstrip cylindrical antenna comprised of two concentric subelements on a ground cylinder, a vertically polarized (E-field parallel to the axis of the antenna cylinder) subelement on the inside and a horizontally polarized (E-field perpendicular to the axis) subelement on the outside. The vertical subelement is a wraparound microstrip radiator. A Y-shaped microstrip patch configuration is used for the horizontally polarized radiator that is wrapped 1.5 times to provide radiating edges on opposite sides of the cylindrical antenna for improved azimuthal pattern uniformity. When these subelements are so fed that their far fields are equal in amplitude and phased 90.degree. from each other, a circularly polarized EM wave results. By stacking a plurality of like antenna elements on the ground cylinder, a linear phased array antenna is provided that can be beam steered to the desired elevation angle.

Stanton, Philip H.↗
NASA NTRS2013

Prediction of the Arctic Oscillation in Boreal Winter by Dynamical Seasonal Forecasting Systems

This study assesses the prediction skill of the boreal winter Arctic Oscillation (AO) in the state-of-the-art dynamical ensemble prediction systems (EPSs): the UKMO GloSea4, the NCEP CFSv2, and the NASA GEOS-5. Long-term reforecasts made with the EPSs are used to evaluate representations of the AO, and to examine skill scores for the deterministic and probabilistic forecast of the AO index. The reforecasts reproduce the observed changes in the large-scale patterns of the Northern Hemispheric surface temperature, upper-level wind, and precipitation according to the AO phase. Results demonstrate that all EPSs have better prediction skill than the persistence prediction for lead times up to 3-month, suggesting a great potential for skillful prediction of the AO and the associated climate anomalies in seasonal time scale. It is also found that the deterministic and probabilistic forecast skill of the AO in the recent period (1997-2010) is higher than that in the earlier period (1983-1996).

Coupled Models↗
NASA NTRS2023

Magnetosonic ULF Waves With Anomalous Plasma–Magnetic Field Correlations: Standing Waves and Inhomogeneous Plasmas

Ultra-low frequency (ULF) wave observations across the heliosphere often rely on the sign of correlations between plasma (density/pressure) and magnetic field perturbations to distinguish between fast and slow magnetosonic modes. However, the assumptions behind this magnetohydrodynamic result are not always valid, particularly within the magnetosphere which is inhomogeneous and supports standing waves along the geomagnetic field. Through theory and a global simulation, we find both effects can result in anomalous plasma–magnetic field correlations. The interference pattern in standing waves can lead both body and surface magnetosonic waves to have different cross-phases than their constituent propagating waves. Furthermore, if the scale of gradients in the background are shorter than the wavelength or the waves are near-incompressible, then advection by the wave of inhomogeneities can overcome the wave's inherent sense of compression. These effects need to be allowed for and taken into account when applying the typical diagnostic to observations.

MHD Waves↗
NASA NTRS1992

Prediction of performance of two-phase flow nozzle and liquid metal magnetohydrodynamic (LMMHD) generator for no slip condition

Two-phase LMMHD energy conversion systems have potentially significant advantages over conventional systems such as higher thermal efficiency and substantial simplicity with lower capital and maintenance costs. Maintenance of low velocity slip is of importance for achieving high generator efficiency. A bubbly flow pattern ensures very low velocity slip. The full governing equations have been written out, and a computer prediction code has been developed to analyze performance of a two-phase flow LMMHD generator and nozzle under conditions of no slip. Three different shapes of a LMMHD generator have been investigated. Electrical power outputs are in the 20 kW range. Generator efficiency exceeds 71 percent at an average void fraction of about 70 percent. This is an appreciable performance for a short generator without insulating vanes for minimizing electrical losses in the end regions.

Fabris, G.↗
DOE OSTI2024

A microscopic perspective on moiré materials

Quantum materials research has experienced a veritable renaissance in the past 6 years, with a surge of experimental reports of nearly every known electronic phase of matter and of several unique and unexpected phases, all found in an emerging class of highly tunable 2D materials, known as moiré materials1,2,3. Here, moiré materials are designed through either the rotational misalignment of identical 2D atomic crystals or the lattice mismatch of dissimilar 2D atomic crystals (Fig. 1). Both these incommensurability conditions cause long-wavelength (~10 nm) interference patterns between the two constituent atomic lattices, forming an enlarged moiré superlattice that generically hosts flat electronic bands, which are highly conducive to correlated, collective phases of matter.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Magnetoresistance anomaly during the electrical triggering of a metal-insulator transition

Phase separation naturally occurs in a variety of magnetic materials and it often has a major impact on both electric and magnetotransport properties. In resistive switching systems, phase separation can be created on demand by inducing local switching, which provides an opportunity to tune the electronic and magnetic state of the device by applying voltage. Here we explore the magnetotransport properties in the ferromagnetic oxide La 0.7 ⁢Sr 0.3 ⁢MnO 3 (LSMO) during the electrical triggering of an intrinsic metal-insulator transition (MIT), which produces volatile resistive switching. This switching occurs in a characteristic spatial pattern, i.e., the formation of a high-resistance barrier perpendicular to the current flow, enabling an electrically actuated ferromagnetic-paramagnetic-ferromagnetic phase separation. At the threshold voltage of the MIT triggering, both anisotropic and colossal magnetoresistances exhibit anomalies including a large increase in magnitude and a sign flip. Computational analysis revealed that these anomalies originate from the coupling between the switching-induced phase separation state and the intrinsic magnetoresistance of LSMO. Furthermore, this work demonstrates that driving the MIT material into an out-of-equilibrium resistive switching state provides the means for electrical control of the magnetotransport phenomena.

Complex oxides↗
NASA NTRS1984

Mossbauer spectroscopy and X-ray diffraction of samples from the Santa Catharina iron meteorite

Conversion electron Mossbauer spectroscopy (CEMS) of samples from the Santa Catharina iron meteorite shows the presence of the ordered iron-nickel phase with 50% Ni, tetrataenite, and of the paramagnetic iron-nickel phase with 25% Ni. The FeNi phase with 50% Ni amounts to 70% of the iron-nickel alloys. Futhermore, the CEM spectra show the presence of small peaks from one or more spinel compounds. These small peaks are more pronounced when regions near the rim of the samples are analyzed. The X-ray diffraction of different areas of the samples, both optically dark and optically light areas, shows the presence of a diffraction pattern from a single f.c.c. lattice with a lattice parameter of a=3.58A This means that the two different Fe-Ni phases seen in the CEMS analysis occupy the same lattice. The X-ray photographs also show the presence of super-structure reflections from the ordered FeNi phase, and that the orientation of the f.c.c. lattice is the same within the whole sample.

Roy-Poulsen, H.↗
NASA NTRS1987

Statistics and dynamics of persistent anomalies

Persistent anomalies with recurrent spatial patterns play an important role in the atmosphere's low-frequency variability. A connection between statistical and dynamical methods of description and prediction of persistent anomalies is established by computing and analyzing the empirical orthogonal functions (EOFs) in a simple deterministic model, on the one hand, and in Southern Hemisphere geopotential heights, on the other. The dynamical model is governed by the fully nonlinear, equivalent-barotropic vorticity equation on the sphere, with simplified forcing, dissipation and topography. The Southern Hemisphere data consist in gridded daily maps of 500 mb heights from June 1972 to July 1983. Two types of persistent anomalies appear in this time series, both having a strong wavenumber-three component; they differ by the value of the constant phase of this wave and by the strength of the wavenumber-one component. The first two EOFs bear a striking resemblance to these two patterns. It is concluded that the dynamical interpretation of EOFs is their pointing from the time mean to the most populated regions of the system's phase space. Pursuing this interpretation, a Markov-chain formulation of transitions from one persistent anomaly regime to another is introduced, and the implications for long-range forecasting are discussed.

Mo, Kingtse C.↗
NASA NTRS1986

Rare earth element patterns in Archean high-grade metasediments and their tectonic significance

REE data on metasedimentary rocks from two different types of high-grade Archean terrains are presented and analyzed. The value of REEs as indicators of crustal evolution is explained; the three geologic settings (in North America, Southern Africa, and Australia) from which the samples were obtained are described; and the data are presented in extensive tables and graphs and discussed in terms of metamorphic effects, the role of accessory phases, provenance, and tectonic implications (recycling, the previous extent of high-grade terrains, and a model of Archean crustal growth). The diversity of REE patterns in shallow-shelf metasediments is attributed to local provenance, while the Eu-depleted post-Archean patterns are associated with K-rich plutons from small, stable early Archean terrains.

Taylor, Stuart Ross↗