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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,063 records · Page 59
All sourcesNASA NTRSDOE OSTI
NASA NTRS1986

A metallurgical route to solar-grade silicon

The aim of the process is to produce silicon for crystallization into ingots that can be sliced to wafers for processing into photovoltaic cells. If the potential purity can be realized, the silicon will also be applicable for ribbon pulling techniques where the purification during crystallization is negligible. The process consists of several steps: selection and purification of raw materials, carbothermic reduction of silica, ladle treatment, casting, crushing, leaching, and melting. The leaching step is crucial for high purity, and the obtainable purity is determined by the solidification before leaching. The most difficult specifications to fulfill are the low contents of boron, phosphorus, and carbon. Boron and phosphorus can be excluded from the raw materials, but the carbothermic reduction will unavoidably saturate the silicon with carbon at high temperature. During cooling carbon will precipitate as silicon carbide crystals, which will be harmful in solar cells. The cost of this solar silicon will depend strongly on the scale of production. It is as yet premature to give exact figures, but with a scale of some thousand tons per year, the cost will only be a few times the cost of ordinary metallurgical silicon.

Schei, A.↗
NASA NTRS1986

Solar silicon from directional solidification of MG silicon produced via the silicon carbide route

A process of metallurgical grade (MG) silicon production is presented which appears particularly suitable for photovoltaic (PV) applications. The MG silicon is prepared in a 240 KVA, three electrode submerged arc furnace, starting from high grade quartz and high purity silicon carbide. The silicon smelted from the arc furnace was shown to be sufficiently pure to be directionally solidified to 10 to 15 kg. After grinding and acid leaching, had a material yield larger than 90%. With a MG silicon feedstock containing 3 ppmw B, 290 ppmw Fe, 190 ppmw Ti, and 170 ppmw Al, blended with 50% of off grade electronic grade (EG) silicon to reconduct the boron content to a concentration acceptable for solar cell fabrication, the 99% of deep level impurities were concentrated in the last 5% of the ingot. Quite remarkably this material has OCV values higher tham 540 mV and no appreciable shorts due to SiC particles.

Rustioni, M.↗
NASA NTRS1987

A system for routing arbitrary directed graphs on SIMD architectures

There are many problems which can be described in terms of directed graphs that contain a large number of vertices where simple computations occur using data from connecting vertices. A method is given for parallelizing such problems on an SIMD machine model that is bit-serial and uses only nearest neighbor connections for communication. Each vertex of the graph will be assigned to a processor in the machine. Algorithms are given that will be used to implement movement of data along the arcs of the graph. This architecture and algorithms define a system that is relatively simple to build and can do graph processing. All arcs can be transversed in parallel in time O(T), where T is empirically proportional to the diameter of the interconnection network times the average degree of the graph. Modifying or adding a new arc takes the same time as parallel traversal.

Tomboulian, Sherryl↗
NASA NTRS1986

Get away special the low-cost route to orbit

NASA has established the Get Away Special (GAS) program as a means for providing anyone who wishes the opportunity to place a small self-contained experimental payload aboard a Space Shuttle mission for a very low cost. The GAS program is now well established, and has a respectable history with 53 payloads flown to date. The GAS experimenters are a diverse group who have demonstrated that people from all walks of life, and from many nations, are interested in working in space. This paper traces the history of the program from its concept through the development phase to the present time, and takes a brief look at the future. It also addresses the steps involved in making a payload reservation and the programmatic and technical relationships that are established between NASA and GAS customers.

Prouty, C.↗
NASA NTRS1986

Sleep, sleepiness, and circadian rhythmicity in aircrews operating on transatlantic routes

A two-phase study was performed on B-747 crew members operating on regular passenger flights with 9-h time difference. In phase I, sleep-log surveys were obtained. The results for the layover period indicate congruent sleep patterns with shifts in sleep onset less than 9 h; sleep duration was prolonged. Phase II consisted of polygraphic sleep recordings and multiple sleep latency tests (MSLTs) applied to four cockpit crews in a baseline period, during the layover, and after return to home base. During the layover, mean bed times were shifted by about 4.5 h, and sleep was disturbed by early and prolonged awakenings which led to a reduction of sleep efficiency. The ECG and rectal temperature recordings gave evidence for a desynchronization of the circadian system and an internal dissociation of different body functions.

Wegmann, Hans M.↗
NASA NTRS1987

Ketimine modifications as a route to novel amorphous and derived semicrystalline poly(arylene ether ketone) homo- and copolymers

A series of amine terminal amorphous poly(arylene ether ketone) oligomers of controlled molecular weights (2-15 K) were synthesized. These oligomers have been found to undergo 'self-crosslinking' reactions upon heating above 220 C, via the reaction of the terminal amine groups with the in-chain keto carbonyl functionalities. The resulting networks are ductile, chemically resistant, and nonporous. The networks obtained via generated ketimine functionality were characterized by solid state NMR. They have also been found to be remarkably stable toward hydrolysis. Ketimine functional bishalide monomers have also been synthesized. Such monomers have been utilized to synthesize a wide variety of amorphous poly(arylene ether) ketimine polymers. A high molecular weight hydroquinone functional poly(arylene ether) ketimine has been acid treated to regenerate a poly(arylene ether ketone) backbone in solution. This novel procedure thus allows for the synthesis of important matrix resins under relatively mild conditions.

Mohanty, D. K.↗
NASA NTRS1987

Imaginary time path integral Monte Carlo route to rate coefficients for nonadiabatic barrier crossing

Nonadiabatic transitions are central to many areas of chemical and condensed matter physics, ranging from biological electron transfer to the optical properties of one-dimensional conductors. Here, a path integral Monte Carlo method is used to simulate such transitions, based on the observation that nonadiabatic rate coefficients are often dominated by saddle point trajectories that correspond to an imaginary time. Simple analytic theories can be used to continue these imaginary time correlation functions to determine rate coefficients. The advantages and drawbacks of this approach are discussed.

Wolynes, Peter G.↗
NASA NTRS1987

Galileo's new route to Jupiter

NASA's 22-month-long Galileo mission to Jupiter will be devoted to direct sampling of its atmosphere. Attention is presently given to a novel trajectory for the Galileo mission that uses gravity assist from one flyby of Venus and two of the earth. The mission involves an orbiter, carrying ten instruments, and an atmospheric probe, containing six instruments. The novel trajectory concept offers a range of launch and arrival dates. An account is given of the mission profile assuming a November 4, 1989 launch date.

Casani, John R.↗
NASA NTRS1988

Dynamics of the Uranian and Saturnian satellite systems - A chaotic route to melting Miranda?

Miranda's anomalously large inclination, in conjunction with the postaccretional resurfacing of both Miranda and Ariel and anomalously large eccentricities characterizing the inner Uranian satellites, are presently held to suggest the disruption of resonant configurations that once existed in this satellite system. Classical analytical methods for the dynamics of resonance are here used to demonstrate how temporary capture into a second- or higher-order resonance can generate large increases in eccentricity and inclination on comparatively short time-scales. Such capture into resonance may result in chaotic motion.

Dermott, Stanley F.↗
NASA NTRS1988

A new synthetic route to a family of non-classical addition-type thermoplastics. I - Concept and demonstration

A synthesis scheme was developed for a host of nonclassical addition-type thermoplastics (ATT) that can be cured by an addition reaction, leading to a linear polymer structure. The synthesis involves the reaction of an acetylene-terminated prepolymer with either a bismaleimide (BMI) or a biscitraconimide. A new polymer, designated LaRC-RP80, synthesized using this scheme, was found to exhibit several significantly improved properties over the commercial BMI, Kerimid 601, including an eight-fold increase in toughness while maintaining a high Tg, a higher (by 167 C) heat stability, and a 50-percent increase in moisture resistance. In addition, LaRC-RP80 has good hot/wet lap shear strength and processes easily at 288 C without voids in the finished product.

Pater, Ruth H.↗
NASA NTRS1988

Overview and extensions of a system for routing directed graphs on SIMD architectures

Many problems can be described in terms of directed graphs that contain a large number of vertices where simple computations occur using data from adjacent vertices. A method is given for parallelizing such problems on an SIMD machine model that uses only nearest neighbor connections for communication, and has no facility for local indirect addressing. Each vertex of the graph will be assigned to a processor in the machine. Rules for a labeling are introduced that support the use of a simple algorithm for movement of data along the edges of the graph. Additional algorithms are defined for addition and deletion of edges. Modifying or adding a new edge takes the same time as parallel traversal. This combination of architecture and algorithms defines a system that is relatively simple to build and can do fast graph processing. All edges can be traversed in parallel in time O(T), where T is empirically proportional to the average path length in the embedding times the average degree of the graph. Additionally, researchers present an extension to the above method which allows for enhanced performance by allowing some broadcasting capabilities.

Tomboulian, Sherryl↗
NASA NTRS1990

En route noise: NASA propfan test aircraft (corrected data - simplified procedure)

Surface noise measurements were made during a joint National Aeronautics and Space Administration (NASA) and Federal Aviation Administration (FAA) program to study the high-altitude, low-frequency acoustic noise propagation characteristics of the Advanced Turboprop (propfan) Aircraft. The measurements were made on October 26-31, 1987 in Huntsville, Alabama and on April 3-13, 1989 at the White Sands Missile Range (WSMR), New Mexico. To effectively compare flight-to-flight data as received on the ground, the procedures and practices of Federal Air Regulation (FAR) Part 36 were used as a guide in adjusting the measured ground data at the time of LA(sub MAX) to a set of reference conditions. After the data for each event were processed using slow detector characteristics, the data record at LA(sub MAX) was then identified and the coordinates of the aircraft at the time of emission were calculated, taking into account atmospheric refraction effects. The effects of atmospheric absorption through the test day and reference day atmosphere were also taken into account and the 1/3-octave data were adjusted accordingly.

Rickley, E. J.↗
NASA NTRS1990

En route noise of turboprop aircraft and their acceptability: Report of tests

The development of propfan-powered aircraft has been observed with great interest. It is obvious that during cruising flight, the aircraft powerplant (propellers) cause a noise clearly perceivable on the ground. It is the audible frequency spectrum of the propfan powerplants relative to the high tip speeds that presents the problem. A flight test was conducted on 30 April, 1989 at the Frankfurt Airport. Results of the test flight are present.

Held, Wolf↗
NASA NTRS1990

Sound propagation elements in evaluation of en route noise of advanced turbofan aircraft

Cruise noise from an advanced turboprop aircraft is reviewed on the basis of available wind tunnel data to estimate the aircraft noise signature at the source. Available analytical models are used to evaluate the sound levels at the ground. The analysis allows reasonable estimates to be made of the community noise levels that might be generated during cruise by such aircraft, provides the basis for preliminary comparisons with available data on noise of existing aircraft during climb and helps to identify the dominant elements of the sound propagation models applicable to this situation.

Sutherland, Louis C.↗
NASA NTRS1987

Linear acene derivatives - New routes to pentacene and naphthacene and the first synthesis of a triptycene with two anthracene moieties

The cycloaddition of o-xylylene to arene 1,4-endoxides was used to construct linear arene derivatives. An analogous sequence but with naphthalene 1,4-endoxides gave naphthacenes. Dehydration of the di adducts from 4 and anthracene 1,4:5,8-diendoxides gave a mixture of 5,9,14,18- and 5,8,15,18-tetrahydroheptacenes 3 and 9. The previously unknown triptycene 2 was synthesized from 5,14-dihydropentacene, an intermediate in the new pentacene synthesis, in three steps and 29 percent overall yield.

Luo, Jihmei↗
NASA NTRS1988

Bisannelation with a benzo(1,2-c:4,5-c-prime) difuran equivalent - A new route to linear acene derivatives

It was observed that the base peak in the mass spectra of all the Diels-Alder bis adducts of anthracene diendoxide as well as of its tetrahydro derivative appear at m/e 158, corresponding to the radical cation of benzo(1,2-c:4,5-c-prime) difuran (BDF). This paper describes a synthetic equivalent of BDF and demonstrates its utility for obtaining linear acene derivatives.

Luo, Jihmei↗
NASA NTRS1990

The route to chaos for the Kuramoto-Sivashinsky equation

The results of extensive numerical experiments of the spatially periodic initial value problem for the Kuramoto-Sivashinsky equation. This paper is concerned with the asymptotic nonlinear dynamics at the dissipation parameter decreases and spatio-temporal chaos sets in. To this end the initial condition is taken to be the same for all numerical experiments (a single sine wave is used) and the large time evolution of the system is followed numerically. Numerous computations were performed to establish the existence of windows, in parameter space, in which the solution has the following characteristics as the viscosity is decreased: a steady fully modal attractor to a steady bimodal attractor to another steady fully modal attractor to a steady trimodal attractor to a periodic attractor, to another steady fully modal attractor, to another periodic attractor, to a steady tetramodal attractor, to another periodic attractor having a full sequence of period-doublings (in parameter space) to chaos. Numerous solutions are presented which provide conclusive evidence of the period-doubling cascades which precede chaos for this infinite-dimensional dynamical system. These results permit a computation of the length of subwindows which in turn provide an estimate for their successive ratios as the cascade develops. A calculation based on the numerical results is also presented to show that the period doubling sequences found here for the Kuramoto-Sivashinsky equation, are in complete agreement with Feigenbaum's universal constant of 4,669201609... . Some preliminary work shows several other windows following the first chaotic one including periodic, chaotic, and a steady octamodal window; however, the windows shrink significantly in size to enable concrete quantitative conclusions to be made.

Papageorgiou, Demetrios T.↗