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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,063 records · Page 59

Orbit dynamics and geographical coverage capabilities of satellite-based solar occultation experiments for global monitoring of stratospheric constituents

Orbit dynamics of the solar occultation technique for satellite measurements of the Earth's atmosphere are described. A one-year mission is simulated and the orbit and mission design implications are discussed in detail. Geographical coverage capabilities are examined parametrically for a range of orbit conditions. The hypothetical mission is used to produce a simulated one-year data base of solar occultation measurements; each occultation event is assumed to produce a single number, or 'measurement' and some statistical properties of the data set are examined. A simple model is fitted to the data to demonstrate a procedure for examining global distributions of atmospheric constitutents with the solar occultation technique.

Brooks, D. R.↗

A multispacecraft event study of Pc5 ultralow-frequency waves in the magnetosphere and their external drivers

We investigate a quiet time event of magnetospheric Pc5 ultralow-frequency (ULF) waves and their likely external drivers using multiple spacecraft observations. Enhancements of electric and magnetic field perturbations in two narrow frequency bands, 1.5–2 mHz and 3.5–4 mHz, were observed over a large radial distance range from r ~ 5 to 11 RE. During the first half of this event, perturbations were mainly observed in the transverse components and only in the 3.5–4 mHz band. In comparison, enhancements were stronger during the second half in both transverse and compressional components and in both frequency bands. No indication of field line resonances was found for these magnetic field perturbations. Perturbations in these two bands were also observed in the magnetosheath, but not in the solar wind dynamic pressure perturbations. For the first interval, good correlations between the flow perturbations in the magnetosphere and magnetosheath and an indirect signature for Kelvin-Helmholtz (K-H) vortices suggest K-H surface waves as the driver. For the second interval, good correlations are found between the magnetosheath dynamic pressure perturbations, magnetopause deformation, and magnetospheric waves, all in good correspondence to interplanetary magnetic field (IMF) discontinuities. The characteristics of these perturbations can be explained by being driven by foreshock perturbations resulting from these IMF discontinuities. This event shows that even during quiet periods, K-H-unstable magnetopause and ion foreshock perturbations can combine to create a highly dynamic magnetospheric ULF wave environment

79 ASTRONOMY AND ASTROPHYSICS↗

A bioinspired approach for adaptive solid-solid phase change material coatings with optimized surface features for passive thermal regulation

The necessity to reduce global energy consumption calls for innovative strategies in building thermal management. Passive thermal regulation, particularly through bio-inspired designs, offers a promising avenue by mimicking nature's efficient control of optical properties. This research introduces a novel, climate-responsive coating that integrates optimized bio-inspired surface features with a solid-solid phase change material (SS-PCM) to dynamically manage solar absorptivity without adding additional thickness, enabling both heating and cooling as needed. Drawing on the photonic architectures of the Saharan silver ant and Morpho Didius butterfly, we employed a modeling and multi-objective optimization framework to tailor these surface features. Simulations reveal that surface texture, rather than the intrinsic phase transition of the SS PCM, dominates optical control. Relative to a flat SS PCM coating, optimized isotropic random roughness and broader range features yielded the highest passive heating power increase of about 144 % and 319 % respectively suitable for cold climates. Saharan ant-inspired features enhanced passive cooling for hot climates, achieving a 21.8 % improvement. For moderate climates, Butterfly-wing-inspired surface features provided a balanced enhancement of 19 % for heating and 7 % for cooling. Across all cases, the optimized surface features reduced combined heating and cooling energy demand more effectively than the baseline coating, while preserving material thickness. These findings demonstrate that climate-adaptive, optimized bio-inspired surface features can unlock the full potential of SS PCM coatings, providing a versatile pathway to significant energy savings in buildings and other applications. The methodology establishes a framework for designing next-generation adaptive envelopes that leverage natural photonic principles for high-impact, low-cost thermal regulation.

36 MATERIALS SCIENCE↗

Enhancement of chemical oscillations by self-generated convective flows

Chemical feedback loops in fluids can produce not only chemical oscillations, but also density variations that generate solutal buoyancy forces, which in turn initiate fluid flow. Using analytical and computational models, we herein examine how the reaction-induced flows alter the chemical oscillations in a fluid-filled chamber whose top and bottom walls are coated with different enzymes. Due to this chemo-fluidic coupling, the systems form oscillating flow patterns, which combine the characteristic size of the buoyancy-driven convection rolls with the frequency of the chemical oscillations. With changes in the distance between the enzyme-coated walls, the convective flows not only enhance or suppress the chemical oscillations, but also substantially increase the amplitude and frequency of the oscillations and extend the regime of the oscillatory behavior. These design principles can facilitate the development of artificial biochemical networks that act as chemical clocks.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Stars in the local galactic thick disc and halo in Gaia EDR3: a catalogue of half a million local main-sequence stars with photometric metallicities

We present a catalogue of 551 214 main-sequence stars in the local (d < 2 kpc) Galactic thick disc and halo, based on a search of stars with large proper motions ($\mu _{\rm tot} \gt 40.0~\rm mas\, yr^{-1}$) in the Gaia Early Data Release 3. We derive photometric metallicity calibrated from the colour–luminosity–metallicity distribution of 20 047 stars with spectroscopic metallicities, collected from various spectroscopic surveys, including SDSS SEGUE/APOGEE, GALAH DR3, and LAMOST DR6. We combine these results to construct an empirical colour–magnitude–metallicity grid, which can be used to estimate photometric metallicities for low-mass metal-poor stars of K and M subtypes from their absolute G magnitude and colour values. We find that low-mass, high-velocity stars in our catalogue share similar kinematics as reported in recent studies of more luminous Galactic halo stars. The pseudo-kinematic analysis of our sample recovers the main local halo structures, including the Gaia–Enceladus Stream and the Helmi stream; aside from these, the local halo stars appear to show a remarkably smooth distribution in velocity space. Since the future Gaia data release will provide radial velocity measurements for only a small number of our sample, our catalogue provides targets of high interest for the future spectroscopic observation programs.

79 ASTRONOMY AND ASTROPHYSICS↗

Quantum Theory of Semiconductor Photo-Catalysis and Solar Water Splitting / Theory and Computation for Semiconductor Catalysis of Solar Water Splitting / Static and Dynamic Thermal Effects in Solids. Final Report

This is the final report. The finished research was published in 27 journal papers listed below. The topics fall roughly into seven categories: Photochemistry of water at the GaN ($10\bar{1}0$) surface; Quasiparticles: Band electrons and Anharmonic phonons; Quasiharmonic theory; Anharmonic lattice thermal conductivity; Water and Ice; Electron-phonon effects; and, Alloy theory.

36 MATERIALS SCIENCE↗

Investigating Local Carrier Dynamics in PERC Patterned CdTe Solar Cells

Remarkable progress has been achieved in CdTe photovoltaics (PVs) to further improve cell performance while reducing manufacturing costs. Researchers optimized the front contact that leads the short-circuit current density (J sc ) over 31mA/cm 2 (e.g., (Zn, Mg)O buffer layer and/or alloying CdTe with Se). Reese et al. reported an open-circuit voltage (V oc ) over 1 V with group-V doped single crystal, showing the feasibility of increasing V oc in CdTe PV that is fixed to less than 900 mV in most cases. Recent studies suggested that the V oc improvement in polycrystalline CdTe PVs requires well-passivated back contact. One possible strategy is to use CdMgTe alloy (E g > 1.8 eV), where the band-gap offset (ΔE CB ≈ 0.2 eV) reflects minority carrier electrons, thereby decreasing surface recombination. Another strategy is to utilize a stable Al 2 O 3 layer as an electron reflector; experimental works confirmed the improved performance with a conformal Al 2 O 3 layer. In this configuration, the precise control of Al 2 O 3 (≈1 nm) over the entire CdTe layer is essential because the J sc greatly depends on the tunneling current. While promising, both CdMgTe and Al 2 O 3 passivation on CdTe introduce unfavorable valence band offset that blocks the hole transport. Kephart et al. proposed a patterned passixc vation layer (≈ 20 nm Al 2 O 3 ) with point contacts (≈ 3 μm in diameter) that extract hole carriers. This configuration is similar to the passive emitter and rear contact (PERC) design that has been extensively studied in Si PVs. While remarkably high carrier lifetime and photoluminescence (> 10 X) were measured, consistent improvement in V oc and efficiency in this CdTe PERC were not yet observed. At this time, it is unclear how the surface potential is distributed in the presence of patterned Al 2 O 3 reflectors and how this additional field impacts the PV performance for Cu-doped and group-V doped CdTe PERC devices. To tackle this challenge, we develop robust nanofabrication and characterization platform to study CdTe PERC devices consisting of a patterned Al 2 O 3 layer on CdSe( 1-x )Te x (Cu-doped, GrV-doped; x = 0 to 1; CST). First Solar supplies high-quality CST materials. The dark and light I-Vs under 1-sun illumination are extracted for a series of each set of devices. We perform quantitative and qualitative PV analysis for a series of Cu-doped and Gr-V doped PERC devices, showing notably different V oc changes for GrV-doped compared to Cu-doped PERC devices. This project attempts to produce individual contacts on single grains and grain boundaries to measure lateral transport. As a model system, we use a CdSe( 1-x )Te x film on glass prepared by a colossal grain growth (CGG) technique at National Renewable Research Laboratories (NREL). Our preliminary results confirm that intergranular transport is hindered by the electrical barrier formed near grain boundaries. The PERC fabrication and the lateral transport measurement platform developed in this project can easily be applied to other types of advanced CdSe( 1-x )Te x architectures to better understand local photocarrier transport, in turn, providing the fundamental knowledge to improve the performance of CdTe PVs.

14 SOLAR ENERGY↗

Long-term Dynamical Stability in the Outer Solar System. I. The Regular and Chaotic Evolution of the 34 Largest Trans-Neptunian Objects

We carried out an extensive analysis of the stability of the outer solar system, making use of the frequency analysis technique over short-term integrations of nearly 100,000 test particles, as well as a statistical analysis of 200 1 Gyr long numerical simulations, which consider the mutual perturbations of the giant planets and the 34 largest trans-Neptunian objects (we have called all 34 objects “dwarf planets,” DPs, even if probably only the largest of them are true DPs). From the frequency analysis, we produced statistical diffusion maps for a wide region of the a–e phase-space plane; we also present the average diffusion time for orbits as a function of perihelion. We later turned our attention to the 34 DPs, making an individualized analysis for each of them and producing a first approximation of their future stability. From the 200 distinct realizations of the orbital evolution of the 34 DPs, we classified the sample into three categories, including 17 stable, 11 unstable, and 6 resonant objects; we also found that, statistically, two objects from the sample will leave the trans-Neptunian region within the next gigayear, most likely being ejected from the solar system, but with a nonnegligible probability of going inside the orbit of Neptune, either to collide with a giant planet or even falling to the inner solar system, where our simulations are no longer able to resolve their continuous evolution.

79 ASTRONOMY AND ASTROPHYSICS↗

Mercury’s Chaotic Secular Evolution as a Subdiffusive Process

Abstract Mercury’s orbit can destabilize, generally resulting in a collision with either Venus or the Sun. Chaotic evolution can causeg 1 to decrease to the approximately constant value ofg 5 and create a resonance. Previous work has approximated the variation ing 1 as stochastic diffusion, which leads to a phenomological model that can reproduce the Mercury instability statistics of secular andN-body models on timescales longer than 10 Gyr. Here we show that the diffusive model significantly underpredicts the Mercury instability probability on timescales less than 5 Gyr, the remaining lifespan of the solar system. This is becauseg 1 exhibits larger variations on short timescales than the diffusive model would suggest. To better model the variations on short timescales, we build a new subdiffusive phenomological model forg 1 . Subdiffusion is similar to diffusion but exhibits larger displacements on short timescales and smaller displacements on long timescales. We choose model parameters based on the behavior of theg 1 trajectories in theN-body simulations, leading to a tuned model that can reproduce Mercury instability statistics from 1–40 Gyr. This work motivates fundamental questions in solar system dynamics: why does subdiffusion better approximate the variation ing 1 than standard diffusion? Why is there an upper bound ong 1 , but not a lower bound that would prevent it from reachingg 5 ?

Astronomy & Astrophysics↗

The Induced Magnetic Field of the Moon: Conductivity Profiles and Inferred Temperature

Electromagnetic induction in the moon driven by fluctuations of the interplanetary magnetic field is used to determine the lunar bulk electrical conductivity. The present data clearly show the north-south and east-west transfer function difference as well as high frequency rollover. The difference is shown to be compatible over the mid-frequency range with a noise source associated with the compression of the local remanent field by solar wind dynamic pressure fluctuations. Models for two, three, and four layer; current layer, double current layer, and core plus current layer moons are generated by inversion of the data using a theory which incorporates higher order multipoles. Core radii conductivities generally are in the range 1200 to 1300 km and 0.001 to 0.003 mhos/m; and for the conducting shell 1500 to 1700 km with 0.0001 to 0.0007 mhos/m with an outer layer taken as nonconducting. Core temperature based on available olivine data is 700 to 1000 C.

Sonett, C. P.↗

The induced magnetic field of the moon - Conductivity profiles and inferred temperature.

Electromagnetic induction in the moon driven by fluctuations of the interplanetary magnetic field is used to determine the lunar bulk electrical conductivity. The earlier data are now augmented by an order of magnitude. The present data clearly show the north-south and east-west transfer function difference as well as the high-frequency rollover suggested earlier. The difference is shown to be compatible over the midfrequency range (0.001 to 0.01 Hz) with a noise source associated with the compression of the local remanent field by solar wind dynamic pressure fluctuations. The rollover of the transfer functions is shown to result from higher order magnetic multipole radiation; electric multipoles appear supressed, although a vestigial TM interaction may still be present. Models for two, three, and four layer; current layer, double current layer, and core plus current layer moons are generated by inversion of the data, using a theory that incorporates higher-order multipoles.

Sonett, C. P.↗

Pioneer 10 observations of the solar wind interation with Jupiter

Pioneer 10 Plasma Analyzer experiment flight data during the Jupiter flyby are presented. The observations show that the interaction of Jupiter's magnetic field with the solar wind is similar in many ways to that at earth, but the scale size is over 100 times larger. Jupiter is found to have a detached standing bow shock wave of high Alfven Mach number. Jupiter has a prominent magnetopause which deflects the magnetosheath plasma and excludes its direct entry into the Jovian magnetosphere. The sunward hemisphere of Jupiter's outer magnetosphere is found to be highly inflated with thermal plasma and a high beta region which is highly responsive to changes in solar wind dynamic pressure. Observational arguments are presented which tend to discount a thin disklike magnetosphere but, rather, favor a Jovian magnetosphere, albeit probabily considerably flattened as compared to the earth's magnetosphere, yet still with reasonable thickness. Results concerning the shock jump conditions, the magnetosheath flow field and inferred internal magnetospheric plasma are presented.

Wolfe, J. H.↗