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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,063 records · Page 59
All sourcesNASA NTRSDOE OSTI
DOE OSTI2017

Three-dimensional Nitrogen-Doped Reduced Graphene Oxide/Carbon Nanotube Composite Catalysts for Vanadium Flow Batteries

The development of vanadium redox flow battery is limited by the sluggish kinetics of the reaction, especially the cathodic VO 2 + /VO 2+ redox couples. Therefore, it is vital to develop new electrocatalyst with enhanced activity to improve the battery performance. Herein, we first synthesized the hydrogel precursor by a facile hydrothermal method. After the following carbonization, nitrogen-doped reduced graphene oxide/carbon nanotube composite was obtained. By virtue of the large surface area and good conductivey, which are ensured by the unique hybrid structure, as well as the proper nitrogen doping, the as-prepared composite presents enhanced catalytic performance toward the VO 2 + /VO 2+ redox reaction. Here, we also demonstrated the composite with carbon nanotube loading of 2 mg/mL exhibits the highest activity and remarkable stability in aqueous solution due to the strong synergy between reduced graphene oxide and carbon nanotubes, indicating that this composite might show promising applications in vanadium redox flow battery.

25 ENERGY STORAGE↗
DOE OSTI2014

Visible light driven photocatalysis and antibacterial activity of AgVO{sub 3} and Ag/AgVO{sub 3} nanowires

Graphical abstract: - Highlights: • Ag/AgVO{sub 3} and pure AgVO{sub 3} nanowires synthesized by sonochemical process. • Characterization done using XRD, SEM, TEM, EDX and BET analysis. • Visible light degradation of RhB by Ag/AgVO{sub 3} within 45 min. • Antibacterial activity of Ag/AgVO{sub 3} demonstrated. - Abstract: Ag/AgVO{sub 3} nanowires and AgVO{sub 3} nanorods were synthesized in aqueous media via a facile sonochemical route. The as-synthesized products were characterized by X-ray diffraction, Brunauer–Emmett–Teller surface area analysis, scanning electron microscopy together with an energy dispersion X-ray spectrum analysis, transmission electron microscopy and UV–vis diffuse reflectance spectroscopy. The results revealed that inert atmosphere promotes the formation of Ag/AgVO{sub 3} nanowires. The photocatalytic studies revealed that the Ag/AgVO{sub 3} nanowires exhibited complete photocatalytic degradation of Rhodamine B within 45 min under visible light irradiation. The antibacterial activity of Ag/AgVO{sub 3} nanowires was tested against Escherechia coli and Bacillus subtilis. The minimum growth inhibitory concentration value was found to be 50 and 10 folds lower than for the antibiotic ciprofloxacin for E. coli and B. subtilis, respectively. The antibacterial properties of the β-AgVO{sub 3} nanorods prove that in case of the Ag dispersed Ag/AgVO{sub 3} nanowires, the enhanced antibacterial action is also due to contribution from the AgVO{sub 3} support.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Preparation and Characterization of Nanocopper Ferrite and Its Green Catalytic Activity in Alcohol Oxidation Reaction

A new type of magnetic material copper ferrite (CuFe{sub 2}O{sub 4}) is successfully manufactured through microwave combustion method. Starch has been tested as a single fuel in this combustion-based synthesis of copper ferrite by using different fuel compositions and equivalence ratios (fuel/oxidant). The formed copper ferrite is characterized by X-ray diffraction analysis, scanning electron microscopy (SEM), transmission electron microscopy (TEM), diffuse reflectance spectroscopy (DRS), and photoluminescence (PL) spectroscopy. Magnetic properties of the prepared copper ferrite are analyzed by vibrating sample magnetometer (VSM). Surface area is measured by the nitrogen adsorption/desorption isotherms. A detailed examination of the morphology of the material in various microwave method-catalyzed processes shows that they provide an optimum catalytic activity due to a combination of lower crystal size and higher activity.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2024

Substitution Models of Protein Evolution with Selection on Enzymatic Activity

Abstract Substitution models of evolution are necessary for diverse evolutionary analyses including phylogenetic tree and ancestral sequence reconstructions. At the protein level, empirical substitution models are traditionally used due to their simplicity, but they ignore the variability of substitution patterns among protein sites. Next, in order to improve the realism of the modeling of protein evolution, a series of structurally constrained substitution models were presented, but still they usually ignore constraints on the protein activity. Here, we present a substitution model of protein evolution with selection on both protein structure and enzymatic activity, and that can be applied to phylogenetics. In particular, the model considers the binding affinity of the enzyme–substrate complex as well as structural constraints that include the flexibility of structural flaps, hydrogen bonds, amino acids backbone radius of gyration, and solvent-accessible surface area that are quantified through molecular dynamics simulations. We applied the model to the HIV-1 protease and evaluated it by phylogenetic likelihood in comparison with the best-fitting empirical substitution model and a structurally constrained substitution model that ignores the enzymatic activity. We found that accounting for selection on the protein activity improves the fitting of the modeled functional regions with the real observations, especially in data with high molecular identity, which recommends considering constraints on the protein activity in the development of substitution models of evolution.

Ferreiro, David↗
NASA NTRS2002

Micro-Scalable Thermal Control Device

A microscalable thermal control module consists of a Stirling cycle cooler that can be manipulated to operate at a selected temperature within the heating and cooling range of the module. The microscalable thermal control module is particularly suited for controlling the temperature of devices that must be maintained at precise temperatures. It is particularly suited for controlling the temperature of devices that need to be alternately heated or cooled. The module contains upper and lower opposing diaphragms, with a regenerator region containing a plurality of regenerators interposed between the diaphragms. Gaps exist on each side of each diaphragm to permit it to oscillate freely. The gap on the interior side one diaphragm is in fluid connection with the gap on the interior side of the other diaphragm through regenerators. As the diaphragms oscillate working gas is forced through the regenerators. The surface area of each regenerator is sufficiently large to effectively transfer thermal energy to and from the working gas as it is passed through them. The phase and amplitude of the oscillations can be manipulated electronically to control the steady state temperature of the active thermal control surface, and to switch the operation of the module from cooling to heating, or vice versa. The ability of the microscalable thermal control module to heat and cool may be enhanced by operating a plurality of modules in series, in parallel, or in connection through a shared bottom layer.

Matthew E. Moran↗
NASA NTRS2024

Soil Interim Measures Implementation Report Q6 Radar Station – Solid Waste Management Unit 112 Locations of Concern 3 and 10 Kennedy Space Center, Florida

This report presents a summary of the soil interim measures (IM) implementation activities that occurred from January 23 through June 6, 2023, at the Q6 Radar Station (Q6RS) Solid Waste Management Unit (SWMU) 112, located at the John F. Kennedy Space Center (KSC), Florida. The site is monitored under KSC’s Resource Conservation and Recovery Act Corrective Action Program, which also meets the requirements of Chapter 62-780, Florida Administrative Code. Assessment activities have previously been performed at 10 Q6RS Locations of Concern (LOCs), identified during a SWMU assessment in 2013 (NASA 2013). Since the SWMU assessment, further confirmatory sampling and assessment was conducted for each LOC, and based on the data collected during these assessments, it was determined that Resource Conservation and Recovery Act Facility Investigation to further evaluate soil and groundwater was to be conducted at two LOCs: LOC 1 – Former Underground Storage Tanks (groundwater) and LOC 3 – Radar Antenna Refurbishment Area (soil). The LOC 1 groundwater assessment is ongoing, and the results will be presented under a separate cover. It was also determined that soil IM would be completed at two of the LOCs, LOC 3 and LOC 10 – Compressor Building Condensate Discharge. A Soil IM Work Plan was prepared and submitted in October 2021 (NASA 2021). The plan proposed excavation and disposal of barium and copper impacted soil in the LOC 3 and 10 areas. This report presents a summary and results of the soil IM implementation activities conducted at LOCs 3 and 10. The site contaminates of concern for this soil IM are barium and copper. The activities presented in this report includes soil IM implementation and groundwater sampling. From January 23 through March 24, 2023, AECOM Technical Services, Inc. (AECOM) field personnel conducted IM implementation activities in the LOC 3 and 10 areas. As presented in the IM Work Plan, shallow soils, impacted with metals, were excavated to a depth of 2 feet below land surface in the central area of the site around the radar antenna and associated equipment. AECOM personnel excavated 77.43 tons of soil using hand tools and, when able, heavy equipment. The soils were placed into lined roll-off containers, which were covered and transported under manifest to the Cedar Trail Landfill in Bartow, Florida. The site was restored to original condition using certified clean backfill material (sand), with filter fabric, and gravel. Areas outside of the excavation were restored with grass seed. On June 6, 2023, AECOM field personnel conducted groundwater sampling activities within the soil IM excavation area. AECOM personnel collected one groundwater sample from monitoring well Q6RS-MW0003. The sample was submitted to a fixed-based laboratory for analysis by United States Environmental Protection Agency Method 6020B for metals (barium and copper). Barium and copper were detected at 18 micrograms per liter (µg/L) and 14 µg/L, respectively, and were below the State of Florida Groundwater Cleanup Target Levels (GCTLs) for barium at 2,000 µg/L and copper at 1,000 µg/L.

Chadwick Sloan Lee↗
DOE OSTI2017

Atomically Thin Mesoporous Co 3 O 4 Layers Strongly Coupled with N-rGO Nanosheets as High-Performance Bifunctional Catalysts for 1D Knittable Zinc-Air Batteries [Atomically Thin Mesoporous Co 3 O 4 /N-rGO Nanosheets as the Bifunctional Catalysts for One-Dimensional Knittable Zinc-Air Batteries]

Here, under development for next–generation wearable electronics are flexible, knittable, and wearable energy–storage devices with high energy density that can be integrated into textiles. Herein, knittable fiber–shaped zinc–air batteries with high volumetric energy density (36.1 mWh cm –3 ) are fabricated via a facile and continuous method with low–cost materials. Furthermore, a high–yield method is developed to prepare the key component of the fiber–shaped zinc–air battery, i.e., a bifunctional catalyst composed of atomically thin layer–by–layer mesoporous Co 3 O 4 /nitrogen–doped reduced graphene oxide (N–rGO) nanosheets. Benefiting from the high surface area, mesoporous structure, and strong synergetic effect between the Co 3 O 4 and N–rGO nanosheets, the bifunctional catalyst exhibits high activity and superior durability for oxygen reduction and evolution reactions. Compared to a fiber–shaped zinc–air battery using state–of–the–art Pt/C + RuO 2 catalysts, the battery based on these Co 3 O 4 /N–rGO nanosheets demonstrates enhanced and stable electrochemical performance, even under severe deformation. Such batteries, for the first time, can be successfully knitted into clothes without short circuits under external forces and can power various electronic devices and even charge a cellphone.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Hierarchical Polyelemental Nanoparticles as Bifunctional Catalysts for Oxygen Evolution and Reduction Reactions

Efficient electrocatalysts are critical in various clean energy conversion and storage systems. Polyelemental nanomaterials are attractive as multi-functional catalysts due to their wide compositions and synergistic properties. However, controlled synthesis of polyelemental nanomaterials is difficult due to their complex composition. Herein, we present a one-step synthetic strategy to fabricate a hierarchical polyelemental nanomaterial, which contains ultrasmall precious metal nanoparticles (IrPt, ~5 nm) anchored on spinel-structure transition metal oxide nanoparticles. The polyelemental nanoparticles serve as excellent bifunctional catalysts for the oxygen evolution reaction (OER) and oxygen reduction reaction (ORR). The mass catalytic activity of the polyelemental nanoparticles is 7-times higher than that of Pt in ORR and 28-times that of Ir in OER at the same overpotentials, demonstrating the high activity of the bifunctional electrocatalyst. We attribute this outstanding performance to the controlled multiple elemental composition, mixed chemical states, and large electroactive surface area. The hierarchical nanostructure and polyelemental design of these nanoparticles offers a general and powerful alternative material for catalysis, solar cells, and more.

25 ENERGY STORAGE↗
DOE OSTI2023

Concentration‐Dependent Inhibition of Mesophilic PETases on Poly(ethylene terephthalate) Can Be Eliminated by Enzyme Engineering

Abstract Enzyme‐based depolymerization is a viable approach for recycling of poly(ethylene terephthalate) (PET). PETase from Ideonella sakaiensis ( Is PETase) is capable of PET hydrolysis under mild conditions but suffers from concentration‐dependent inhibition. In this study, this inhibition is found to be dependent on incubation time, the solution conditions, and PET surface area. Furthermore, this inhibition is evident in other mesophilic PET‐degrading enzymes to varying degrees, independent of the level of PET depolymerization activity. The inhibition has no clear structural basis, but moderately thermostable Is PETase variants exhibit reduced inhibition, and the property is completely absent in the highly thermostable HotPETase, previously engineered by directed evolution, which simulations suggest results from reduced flexibility around the active site. This work highlights a limitation in applying natural mesophilic hydrolases for PET hydrolysis and reveals an unexpected positive outcome of engineering these enzymes for enhanced thermostability.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Key properties of mixed cerium and zirconium microspheres prepared by the internal gelation process with previously boiled HMTA and urea

The internal gelation process using previously boiled hexamethylenetetramine-urea was used in exploratory study to produce CeO 2 –ZrO 2 microspheres, which can serve as a simulant for ceramic transuranic fuel particles and as a viable three-way catalyst. The calcined CeO 2 and ZrO 2 microspheres with Barrett–Joyner–Halenda (BJH) pore size and volumes of 8–10 nm and 0.19–0.20 mL/g, respectively, had many more surface cracks than their relatively smooth CeO 2 –ZrO 2 counterparts even though the BJH pore sizes and volumes of mixed oxide spheres were lower at 3 nm and 0.11–0.12 mL/g, respectively. The Brunauer–Emmett–Teller (BET) surface areas for the CeO 2 and ZrO 2 microspheres were 74 and 93 m2/g, respectively, and the BET surface areas for the mixed oxides were much greater at 155–158 m 2 /g, which should improve catalytic performance. Overall, the catalytic activity of each microsphere composition was confirmed through the oxidation of carbon monoxide.

36 MATERIALS SCIENCE↗
DOE OSTI2016

Microwave synthesis and photocatalytic activities of ZnO bipods with different aspect ratios

Highlights: • We synthesized linked ZnO nanorods by a facile microwave method. • The effect of reaction parameters on ZnO was investigated. • ZnO bipods with different aspect ratios were prepared. • The photocatalytic performance of ZnO bipods was evaluated. - Abstract: Linked ZnO nanorods have been successfully prepared via a facile microwave method without any post-synthesis treatment. The X-ray diffraction (XRD) patterns indicated the precursor had completely transformed into the pure ZnO crystal. The images of field emitting scanning electron microscope (FESEM) and transmission electron microscope (TEM) showed that linked ZnO nanorods consisted predominantly of ZnO bipods. The formation process of the ZnO bipods was clearly discussed. ZnO bipods with different aspect ratios have been obtained by tuning the concentrations of reagents and microwave power. Moreover, the photocatalytic performance of ZnO bipods with different aspect ratios for degradation of methylene blue was systematically evaluated. The results of photocatalytic experiments showed that the photocatalytic activity increased with the aspect ratios of ZnO bipods increased. The reason is that ZnO bipods with larger aspect ratio have higher surface area, which can absorb more MB molecules to react with ·OH radicals.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Pt alloy nanoparticles decorated on large-size nitrogen-doped graphene tubes for highly stable oxygen-reduction catalysts

Pt alloy nanoparticles supported on Vulcan XC-72 (Pt/C) are the most effective catalysts for kinetically sluggish oxygen reduction reaction (ORR) in proton exchange membrane fuel cells. However, significant performance degradation has been observed with the Pt/C catalysts due to agglomeration and Ostwald ripening of Pt nanoparticles largely resulting from the corrosion of carbon supports. In this paper, we developed a Pt alloy catalyst through annealing Pt nanoparticles deposited on nitrogen/metal co-doped large-size graphene tubes (NGTs). The in-situ formation of PtM (M: Co and Ni) alloy during the annealing process contributes to the improvement of the catalytic activity and stability. During the accelerated stress tests (AST), after 20 000 potential cycles (0.6–1.0 V vs. RHE), the retained electrochemical surface area (ECSA) of the PtM/NGT catalyst is more than 2 times larger than that of the Pt/C catalyst. As for the AST tests of carbon corrosion, after 30 000 potential cycles (1.0–1.5 V vs. RHE) at room temperature, the NGT morphologies are well maintained and no ECSA loss of this PtM catalyst is observed, indicating excellent corrosion-resistance. Even at harsher 60 °C, the PtM/NGT catalyst exhibits only insignificant loss (6 mV) of E 1/2 while the Pt/C catalyst shows significant degradation (47 mV loss in E 1/2 ). Finally, the improved stability of PtM/NGT catalyst is attributed to the highly graphitized NGTs and possible synergistic effects between the NGT carbon support and the PtM alloy nanoparticles.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Defect-mediated selective hydrogenation of nitroarenes on nanostructured WS 2

Transition metal dichalcogenides (TMDs) are well known catalysts as both bulk and nanoscale materials. Two-dimensional (2-D) TMDs, which contain single- and few-layer nanosheets, are increasingly studied as catalytic materials because of their unique thickness-dependent properties and high surface areas. Here, colloidal 2H-WS 2 nanostructures are used as a model 2-D TMD system to understand how high catalytic activity and selectivity can be achieved for useful organic transformations. Free-standing, colloidal 2H-WS 2 nanostructures containing few-layer nanosheets are shown to catalyze the selective hydrogenation of a broad scope of substituted nitroarenes to their corresponding aniline derivatives in the presence of other reducible functional groups. Microscopic and computational studies reveal the important roles of sulfur vacancy-rich basal planes and tungsten-terminated edges, which are more abundant in nanostructured 2-D materials than in their bulk counterparts, in enabling the functional group selectivity. At tungsten-terminated edges and on regions of the basal planes having high concentrations of sulfur vacancies, vertical adsorption of the nitroarene is favored, thus facilitating hydrogen transfer exclusively to the nitro group due to geometric effects. At lower sulfur vacancy concentrations on the basal planes, parallel adsorption of the nitroarene is favored, and the nitro group is selectively hydrogenated due to a lower kinetic barrier. These mechanistic insights reveal how the various defect structures and configurations on 2-D TMD nanostructures facilitate functional group selectivity through distinct mechanisms that depend upon the adsorption geometry, which may have important implications for the design of new and enhanced 2-D catalytic materials across a potentially broad scope of reactions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2017

Southeast Carbon Sequestration Partnership (SECARB) Phase III Anthropogenic Test at Citronelle Field, Mobile Co., AL. Post-Injection Period Reservoir Modeling Report

The Southeast Carbon Sequestration Partnership (SECARB) Anthropogenic Test is a U.S. Department of Energy funded fully integrated carbon capture and storage initiative designed to demonstrate deep underground injection and containment of anthropogenic CO 2 sourced from Alabama Power’s Plant Barry. From August 20, 2012 to September 1, 2014, a total of 114,014 metric tonnes of CO 2 were transported via pipeline from Plant Barry and stored in a saline aquifer under a portion of the Citronelle Field operated by Denbury Onshore, LLC near Citronelle, Alabama. A major component of this project was to test and develop techniques to monitor, verify and account (MVA) for the CO 2 stored in the aquifer by the project. A suite of technologies were applied and developed to demonstrate non-endangerment of underground sources of drinking water (USDW’s) and to ensure that CO2 does not migrate out of intended zones within the subsurface. This involved several levels of monitoring: 1) Surface monitoring, 2) shallow groundwater monitoring, 3) deep reservoir monitoring and experimental MVA activities. Numerical models were developed to determine the project’s Area of Review (AoR) and to investigate the simulated advancement of the CO 2 plume through the subsurface aquifer for 30 years after the end of injection. An initial baseline area of review of 1,700 ft. was established. The key results demonstrating non-endangerment of USDW’s are presented.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2025

Savannah River Site Climatology for Research Activities Conducted Onsite and in P-Area (1994-2023)

This report presents a climatology of meteorological variables at the Savannah River Site (SRS) using measurements from the P-Area and Central Climatology meteorological towers to support research activities at the Savannah River Site. Key values included in this report are wind, surface pressure, temperature, relative humidity, soil moisture, cloud fraction, cloud base, lightning, atmospheric stability, and boundary layer parameters. The Central Climatology tower is useful in that it is instrumented at four levels, allowing for an examination of height dependence on some variables.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Savannah River Site Climatology for Research Activities Conducted Onsite and in P-Area (1994-2023)

Executive Summary This report presents a climatology of meteorological variables at the Savannah River Site (SRS) using measurements from the P-Area and Central Climatology meteorological towers to support research activities at the Savannah River Site. Key values included in this report are wind, surface pressure, temperature, relative humidity, soil moisture, cloud fraction, cloud base, lightning, atmospheric stability, and boundary layer parameters. The Central Climatology tower is useful in that it is instrumented at four levels, allowing for an examination of height dependence on some variables.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1971

Lunar-Surface Closeup Stereoscopic Photography on the Sea of Tranquility (Apollo 11 Landing Site)

Analysis of returned lunar samples provides limited information about lunar geology. To obtain information about in-place lunar material, a closeup stereoscopic camera capable of photographing small-scale surface features was built and was used at the Apollo 11 landing site. Stereoscopic photographs were taken of surface areas relative to the lunar module, and the surfaces photographed were analyzed. The photographs are classified into five groups: soil disturbed by astronaut activities, generally undisturbed soil, loose aggregate surface material, crater bottoms with prominent glass deposits, and hard rock deposits. Glass deposits in the returned samples are described for comparison with the features observed in the photographs. The stereoscopic photographs were of outstanding quality and show the nature of lunar-surface material in detail. Lunar topography was reconstructed from the photographs with an analytical plotter. The photography results indicate that the closeup composition and genesis of lunar soil at the Apollo 11 landing site.

Greenwood, W. R.↗
NASA NTRS1988

Outgassing asymmetry of periodic comet Encke. I - Apparitions 1924-1984

A concept of a collimated flow of ejecta from a discrete source (vent) on the surface of a rotating cometary nucleus is applied to P/Encke, based on positional observations of its sunward fanlike coma at 13 apparitions between 1924 and 1984. The major results include a finding that the observations are consistent with an invariable position of the rotation pole during the 60 yr (yielding an obliquity of 70 deg), although this is not to be interpreted as an indication that the nucleus is not precessing. Two vents are identified on the nucleus surface: one on the northern hemisphere at a latitude of +55 deg, of an estimated sublimitation area of 0.4 sq km, which is active along the inbound leg of the comet's orbit until a few days preperihelion and again beginning several weeks postperihelion; the other on the southern hemisphere at -75 deg, of an estimated area of 0.6 sq km, whose activity prevails in the intervening time. There appears to be a significant difference between the two regions in terms of dust content in their emissions.

Sekanina, Z.↗