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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,063 records · Page 59
All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

A diabatic circulation experiment in a two-dimensional photochemical model

A two-dimensional photochemical model based on diabatic circulation has been used to simulate the behavior of N2O, CFCl3(F-11) and CF2Cl2(F-12) The circulation is based on estimates of net heating from the ground to 60 km. Eddy diffusion has been reduced with respect to other model studies with Kzz = 2000 sq cm/s everywhere bove 100 mbar. Resulting tracer profiles show reasonable agreement with measured profiles in the tropics and fall off much more sharply with altitude than those produced by models using larger values of Kzz. The agreement obtained is at least as good as that obtained with adjustable, eddy diffusion parameters. The diabatic circulation treatment is more closely related to related to real physical processes and thus more easily interpreted. Diffusive mixing appears to be more important in determining the details of the tracer distributions than the basic morphology.

Guthrie, P. D.↗
NASA NTRS1989

Refractory solids in chondrites and comets: How similar

The grains of ice, dust, and organic material that came together to form the solar system have been preserved to differing degrees in the most primitive solar system bodies, asteroids and comets. The study of samples of asteroids (in the form of chondritic meteorites) reveals that the dust component was extensively altered by high-temperature events and processes in the early solar system, before it was aggregated into chondritic planetesimals. The nature of these high-temperature events and processes is not known, but the evidence of their operation is pervasive and unequivocal. Are the refractory particles in comets likely to be similar to these chondrite components. Probably not (except for the presolar carbonaceous grains in chondrites), because the chondritic components are products of severe thermal processing, and all imaginable energy sources that could have provided the heat tend to diminish with distance from the sun. Every indication is that comets formed at much greater radial distances than asteroids, so the particles they incorporated would have experienced less heating. The possibilities cannot be completely ruled out that comets, too, formed inside the present orbit of Jupiter, or that thermally-processed grains were able to diffuse great radial distances before being incorporated in accreting objects, but it is far more likely that most of the refractory grains in comets have been spared the extreme thermal processing that shaped the character of chondritic components.

Wood, John A.↗
DOE OSTI2018

Stochastic Acceleration of ~0.1–5 keV Pickup Ions in the Heliotail

We seek to understand the quantitative role of the dominant physical processes (charge-exchange, adiabatic heating, stochastic acceleration) governing the proton distribution in the heliotail using observations of hydrogen energetic neutral atoms (ENAs) from the Interstellar Boundary Explorer ( IBEX ). We solve the Parker transport equation for solar wind protons and pickup ions (PUIs) as they propagate from the termination shock (TS) down the heliotail, including charge-exchange between protons and neutral hydrogen atoms as source terms derived from an MHD-fluid and kinetic-neutral simulation of the heliosphere. We compute ENA fluxes at 1 au from the results of the proton transport model and compare them with IBEX observations. We find that, under the assumptions of our model, a stochastic acceleration process is needed to counteract the energy-dependent losses of ~0.1–5 keV PUIs from charge-exchange to reproduce IBEX data. The power-law velocity dependence of the diffusion coefficient (spectral index γ ) is limited to the range 0.67 < γ < 2, and the best fit to IBEX data appears close to γ ~ 1.25. The diffusion rate ~1.1 &#x00d7; 10 -8 km 2 s -3 ( v / v 0 ) 1.25 nearly balances the loss of ~0.1–5 keV PUIs by charge-exchange. Our analysis suggests that cyclotron resonance with two widely known incompressible MHD turbulence: namely, isotropic Kolmogorov and anisotropic Goldreich–Sridhar turbulence, as well as stochastic particle interactions with compressive waves are not by themselves the dominant diffusion mechanisms. However, some intermediate processes may be occurring due to the presence of PUIs.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗
NASA NTRS2015

Magnetospheric Multiscale Overview and Science Objectives

Magnetospheric Multiscale (MMS), a NASA four-spacecraft constellation mission launched on March 12, 2015, will investigate magnetic reconnection in the boundary regions of the Earth's magnetosphere, particularly along its dayside boundary with the solar wind and the neutral sheet in the magnetic tail. The most important goal of MMS is to conduct a definitive experiment to determine what causes magnetic field lines to reconnect in a collisionless plasma. The significance of the MMS results will extend far beyond the Earth's magnetosphere because reconnection is known to occur in interplanetary space and in the solar corona where it is responsible for solar flares and the disconnection events known as coronal mass ejections. Active research is also being conducted on reconnection in the laboratory and specifically in magnetic-confinement fusion devices in which it is a limiting factor in achieving and maintaining electron temperatures high enough to initiate fusion. Finally, reconnection is proposed as the cause of numerous phenomena throughout the universe such as comet-tail disconnection events, magnetar flares, supernova ejections, and dynamics of neutron-star accretion disks. The MMS mission design is focused on answering specific questions about reconnection at the Earth's magnetosphere. The prime focus of the mission is on determining the kinetic processes occurring in the electron diffusion region that are responsible for reconnection and that determine how it is initiated; but the mission will also place that physics into the context of the broad spectrum of physical processes associated with reconnection. Connections to other disciplines such as solar physics, astrophysics, and laboratory plasma physics are expected to be made through theory and modeling as informed by the MMS results.

Space plasma physics↗
DOE OSTI2020

Influence of Tabula Rasa on Process- and Light-Induced Degradation of Solar Cells Fabricated From Czochralski Silicon

Monocrystalline Si solar cells are fabricated from Czochralski (Cz) Si, which contains 10 17 –10 18 cm -3 oxygen atoms. Cz Si undergoes degradation during high-temperature thermal processing steps, such as dopant diffusion to form the p - n junction. This degradation in the bulk minority carrier lifetime can be related to the formation of oxygen precipitates. We found that a high-temperature annealing process known as tabula rasa (TR) not only mitigates process-induced degradation via oxygen precipitate nuclei dissolution, but also modifies subsequent light-induced degradation. We report on the bulk carrier lifetime of n - and p -type Cz Si after TR, which homogenizes the interstitial oxygen in the bulk Si to its monoatomic form in either an N 2 or O 2 environment. A control sample, which was not subjected to a TR processing step, experienced severe process-induced degradation during a boron emitter thermal budget as oxygen precipitates were formed in the Si bulk. These precipitates could be imaged using photoluminescence. Additionally, samples that underwent a TR processing step prior to the boron emitter thermal budget show efficient gettering of metallic impurities compared to the control sample, which showed a decline in the implied open-circuit voltage after the gettering step. Furthermore, modification of the interstitial oxygen bonding by TR had a strong effect on the light-induced degradation kinetics. Instead of a typically observed monotonic decrease, minority carrier lifetime increases first, followed by a nonmonotonic decrease over a ~20 h period. Finally, we conclude that by modifying the interstitial oxygen bonding via TR pretreatment, p -type Cz Si wafers become substantially resistant to harsh solar cell processes and strongly modified light-induced degradation, which would open alternative ways to mitigate this degradation mechanism.

14 SOLAR ENERGY↗
NASA NTRS1991

Quasi-linear pitch angle and energy diffusion of pickup ions near Comet Halley

The process of ion pickup in the environment of Halley's comet is studied in order to see if velocity diffusion driven by the observed level of turbulence can explain the observed development of the implanted ion distribution. The theoretical description used is based on a quasi-linear approach and considers the implantation and transport of cometary ions along solar wind flow lines. To make such a study requires some way of extrapolating the measurements on the Giotto trajectory into the upstream region; models for mass loading and turbulence are used. A simplified kinetic equation describing the source, convection, and quasi-linear velocity diffusion of the heavy cometary ions is solved numerically along flow lines parallel to the sun-comet line. Full two-dimensional (pitch angle and velocity) distributions are obtained at positions along the Giotto trajectory, which are compared with measurements. This study finds that quasi-linear theory, with the empirical model for the observed turbulence level, produces the right order of pitch angle diffusion.

Huddleston, D. E.↗
NASA NTRS1983

Acceleration and transport processes - Verification and observations

The general problem of diffusive transport and acceleration of energetic charged particles is considered. The transport of solar-flare particles, solar modulation of galactic cosmic rays and shock acceleration processes on the solar wind are examined and observational tests are summarized. It is concluded that the basic diffusive transport equation is a useful approximation in situations like the solar wind, where turbulent scattering by magnetic irregularities is sufficient to maintain near isotropy. The application of this equation to the interstellar medium andd other, more distant astrophysical regimes is then discussed and implications for gamma-ray astrophysics are outlined. Finally the evidence for interstellar turbulence is reviewed and its consequences briefly discussed.

Jokipii, J. R.↗
DOE OSTI2021

Formation of three-dimensional bicontinuous structures via molten salt dealloying studied in real-time by in situ synchrotron X-ray nano-tomography

Abstract Three-dimensional bicontinuous porous materials formed by dealloying contribute significantly to various applications including catalysis, sensor development and energy storage. This work studies a method of molten salt dealloying via real-time in situ synchrotron three-dimensional X-ray nano-tomography. Quantification of morphological parameters determined that long-range diffusion is the rate-determining step for the dealloying process. The subsequent coarsening rate was primarily surface diffusion controlled, with Rayleigh instability leading to ligament pinch-off and creating isolated bubbles in ligaments, while bulk diffusion leads to a slight densification. Chemical environments characterized by X-ray absorption near edge structure spectroscopic imaging show that molten salt dealloying prevents surface oxidation of the metal. In this work, gaining a fundamental mechanistic understanding of the molten salt dealloying process in forming porous structures provides a nontoxic, tunable dealloying technique and has important implications for molten salt corrosion processes, which is one of the major challenges in molten salt reactors and concentrated solar power plants.

36 MATERIALS SCIENCE↗
NASA NTRS1992

Transient liquid phase diffusion bonding of Udimet 720 for Stirling power converter applications

Udimet 720 has been selected for use on Stirling power converters for space applications. Because Udimet 720 is generally considered susceptible to strain age cracking if traditional fusion welding is used, other joining methods are being considered. A process for transient liquid phase diffusion bonding of Udimet 720 has been theoretically developed in an effort to eliminate the strain age crack concern. This development has taken into account such variables as final grain size, joint homogenization, joint efficiency related to bonding aid material, bonding aid material application method, and thermal cycle.

Mittendorf, Donald L.↗
NASA NTRS2001

Effectiveness of Diffusion Barrier Coatings for Mo-Re Embedded in C/SiC and C/C

Advanced high-temperature cooling applications may often require the elevated-temperature capability of carbon/silicon carbide or carbon/carbon composites in combination with the hermetic capability of metallic tubes. In this paper, the effects of C/SiC and C/C on tubes fabricated from several different refractory metals were evaluated. Though Mo, Nb, and Re were evaluated in the present study, the primary effort was directed toward two alloys of Mo-Re, namely, arc cast Mo-41Re and powder metallurgy Mo-47.5Re. Samples of these refractory metals were subjected to either the PyC/SiC deposition or embedding in C/C. MoSi2(Ge), R512E, and TiB2 coatings were included on several of the samples as potential diffusion barriers. The effects of the processing and thermal exposure on the samples were evaluated by conducting burst tests, microhardness surveys, and scanning electron microscopic examination (using either secondary electron or back scattered electron imaging and energy dispersive spectroscopy). The results showed that a layer of brittle Mo-carbide formed on the substrates of both the uncoated Mo-41Re and the uncoated Mo-47.5Re, subsequent to the C/C or the PyC/SiC processing. Both the R512E and the MoSi2(Ge) coatings were effective in preventing not only the diffusion of C into the Mo-Re substrate, but also the formation of the Mo-carbides. However, none of the coatings were effective at preventing both C and Si diffusion without some degradation of the substrate.

Glass, David E.↗
DOE OSTI2019

Theoretical Analysis of the EPR Spectrum Saturation Effect with Account for Spectral Diffusion in a System with a Gaussian Distribution of Spin Resonance Frequencies

We have analyzed the effect of saturation of the EPR spectrum for the model situation when a set of resonance frequencies of spin packets is described by a Gaussian distribution and spectral diffusion, which is a random process without correlation, exists. We have obtained the form of the spectrum for arbitrary values of magnetic–resonant parameters: relaxation times for the longitudinal and transverse components of the magnetization vector of the system, the spectral diffusion rate, the dispersion of the Gaussian distribution of resonance frequency, and the magnetic induction of the microwave field. We have derived an analytic expression for the saturation curve of the EPR spectrum. Detailed analysis of the dependence of the spectrum saturation curve on the spin system parameters is performed for the optimal case when the microwave field frequency coincides with the average frequency of the Gaussian distribution for resonance frequencies. The value of the microwave field induction at which the peak of the saturation curve is attained has been determined for arbitrary values of the paramagnetic relaxation time, spectral diffusion rate, and dispersion of the Gaussian spin frequency distribution. We have formulated the algorithm for determining the spin–lattice relaxation time using the experimentally determined microwave field induction for which the saturation curve passes through the peak. It should be noted that numerical calculations have been performed for parameters typical of EPR spectroscopy. The general analytic expression derived for the shape of the spectrum in the saturation conditions and qualitative conclusions concerning the effect of spectral diffusion on the saturation of stationary spectra obtained in this study can also be used in other fields of spectroscopy.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
NASA NTRS2000

Mechanically Induced g-Jitter from Space Station Rotary Joints

The mission of the International Space Station is to provide a working laboratory in orbit for research in engineering, life sciences, and microgravity. Among the microgravity disciplines that are preparing to utilize this international resource are materials processing, combustion, fluid dynamics, biotechnology, and fundamental physics. The Station promises to enable significant advances in each of these areas by making available a research facility in which gravitational and other accelerations, and their corresponding buoyancy and diffusion effects on various physical processes, are orders of magnitude lower than they are on Earth. In order to fulfill this promise, it is not enough for the Space Station to simply replicate a typical terrestrial scientific laboratory in orbit. Although an orbiting laboratory is free of most of the effects of gravitational acceleration by virtue of its free fall condition, it also produces structural vibration or jitter that can interfere with the processes under study. To ensure the quality of the acceleration environment and enable a successful mission, the Space Station Program has limited potential disturbances in two ways: first, by isolating the most sensitive payloads from the vehicle structure, and second, by quieting major disturbances at their sources. The first area, payload isolation, is implemented inside the pressurized modules at the rack level. Sub-rack level isolators have also been developed. This paper addresses the second area, disturbance source limits, for one of the major sources of mechanical noise on the Space Station: the Solar Alpha Rotary Joints. Due to the potential for large disturbances to the microgravity environment, an initial analytical prediction of rotary joint vibration output was made. Key components were identified and tested to validate the analytical predictions. Based on the component test results, the final vibration output of the joints was verified by a test on each fully assembled flight unit. This paper describes the Space Station microgravity requirements, the rotary joint hardware, and the disturbance producing aspects of joint operation. The test setup, instrumentation, test conditions, and results for the component level and system level measurements are described. An overall forcing function that describes the maximum torque imparted to the Station is created based on the test results, and these disturbances are shown to meet the applicable Space Station microgravity requirements.

Boucher, Robert L.↗
DOE OSTI2023

Alpha

What is this parameter called alpha, and why is it so important? To answer these questions we consider the density of fission neutrons at any point $_r^→$ = (x, y, z) inside a volume of fissionable material. Ignoring neutron absorption, this time-varying density of neutrons is determined by two physical processes --- generation of more neutrons by fission chain reactions, and the loss of neutrons by diffusion to and through the surface. A simple, approximate mathematical description of these processes is the diffusion equation for the average neutron density n($_r^→$, t) including a fission source term.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2020

Interfacial solvation and slow transport of hydrated excess protons in non-ionic reverse micelles

This work employs molecular dynamics simulations to investigate the solvation and transport properties of hydrated excess protons (with a hydronium-like core structure) in non-ionic Igepal CO-520 reverse micelles of various sizes in a non-polar solvent. Multiscale Reactive Molecular Dynamics (MS-RMD) simulations were used to describe vehicular and hopping diffusion during the proton transport process. As detailed herein, an excess proton shows a marked tendency to localize in the interfacial region of micellar water pools. Slow proton transport was observed which becomes faster with increasing micellar size. Further analysis reveals that the slow diffusion of an excess proton is a combined result of slow water diffusion and the low proton hopping rate. This study also confirms that a low proton hopping rate in reverse micelles stems from the interfacial solvation of hydrated excess protons and the immobilization of interfacial water. The low water density in the interfacial region makes it difficult to form a complete hydrogen bond network near the hydrated excess proton, and therefore locks in the orientation of hydrated proton cations. The immobilization of the interfacial water also slows the relaxation of the overall hydrogen bond network.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Facilitated transport membranes for H 2 purification from coal-derived syngas: A techno-economic analysis

A single-stage membrane process has been designed for using facilitated transport membranes (FTMs) to decarbonize the coal-derived syngas from an integrated gasification combined cycle (IGCC) power plant. The necessary process model and costing method have also been developed to assess the technical feasibility and process economics. In order to account for the carrier saturation phenomenon associated with FTMs, a homogeneous reactive diffusion model is integrated into the process model. The techno-economic study reveals that the mitigated carrier saturation upon bulk CO 2 removal can lead to appreciable increases in the CO 2 permeance and CO 2 /H 2 selectivity, which can be utilized to achieve 95% CO 2 purity and 95% H 2 recovery with a CO 2 /H 2 selectivity of 50 at the complete carrier saturation. FTMs with different facilitated transport characteristics can also be arranged in a hybrid membrane configuration to render a H 2 recovery of 99% and a cost of electricity of $\$118.5$ /MWh, which is 12.5% lower than that of the benchmark Selexol process.

42 ENGINEERING↗
DOE OSTI2019

First-principles study of hydrogen diffusion and self-clustering below tungsten surfaces

The diffusion and self-clustering nucleation behavior of hydrogen (H) without vacancies below tungsten (W) surfaces are important for understanding the retention of deuterium (D) in W crystals exposed to high-flux and low-energy D plasma. The H migration energy and binding energy of H to self-clusters near the W(100), W(110), and W(111) surfaces have been investigated by first-principles computer simulations using density functional theory. H diffusion from adsorption sites on the W(100), W(110), and W(111) surfaces into solute sites in the bulk requires energies of at least 1.21, 1.78, and 1.80 eV, respectively, while 0.27, 0.31, and 0.24 eV for the reverse process. In addition, the lateral diffusion of H between two subsurface layers below the W surfaces has been investigated. Two H atoms at a depth of 0.08 nm below the W(110) surface have the highest binding energy, followed by H atom pairs below the W(111) and W(110) surfaces. The nucleation and stability of H clusters depend on the surface orientation. A planar configuration between the first nearest neighbor {100} planes is energetically favorable for H self-clustering below the W(100), W(110), and W(111) surfaces. In conclusion, the thermal stability of a platelet containing 16 H atoms below the W surfaces at 300 and 600 K was also studied by ab initio molecular dynamics simulations, which indicate that the H platelet below a W(111) surface is more stable than that below either the W(100) or the W(110) surface.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
NASA NTRS1995

Hydrogen passivation of n+p and p+n heteroepitaxial InP solar cell structures

High-efficiency, heteroepitaxial (HE) InP solar cells, grown on GaAs, Si or Ge substrates, are desirable for their mechanically strong, light-weight and radiation-hard properties. However, dislocations, caused by lattice mismatch, currently limit the performance of the HE cells. This occurs through shunting paths across the active photovoltaic junction and by the formation of deep levels. In previous work we have demonstrated that plasma hydrogenation is an effective and stable means to passivate the electrical activity of dislocations in specially designed HE InP test structures. In this work, we present the first report of successful hydrogen passivation in actual InP cell structures grown on GaAs substrates by metalorganic chemical vapor deposition (MOCVD). We have found that a 2 hour exposure to a 13.56 MHz hydrogen plasma at 275 C reduces the deep level concentration in HE n+n InP cell structures from as-grown values of approximately 10(exp 15)/cm(exp -3), down to 1-2 x 10(exp 13)/cm(exp -3). The deep levels in the p-type base region of the cell structure match those of our earlier p-type test structures, which were attributed to dislocations or related point defect complexes. All dopants were successfully reactivated by a 400 C, 5 minute anneal with no detectable activation of deep levels. I-V analysis indicated a subsequent approximately 10 fold decrease in reverse leakage current at -1 volt reverse bias, and no change in the forward biased series resistance of the cell structure which indicates complete reactivation of the n+ emitter. Furthermore, electrochemical C-V profiling indicates greatly enhanced passivation depth, and hence hydrogen diffusion, for heteroepitaxial structures when compared with identically processed homoepitaxial n+p InP structures. An analysis of hydrogen diffusion in dislocated InP will be discussed, along with comparisons of passivation effectiveness for n+p versus p+n heteroepitaxial cell configurations. Preliminary hydrogen-passivated HE InP cell results will also be presented.

Chatterjee, B.↗
DOE OSTI2022

Modeling of deposit formation in mesoporous substrates via atomic layer deposition: Insights from pore‐scale simulation

Atomic layer deposition (ALD) has been a promising technique in fabricating membranes and tuning their properties with a precision at the atomic level. Fabrication of zeolitic imidazolate framework (ZIF) membranes using the ligand-induced permselectivation (LIPS) method starts with the formation of an oxide in a mesoporous substrate by ALD and is followed by the transformation of this oxide to ZIF using imidazolate vapor treatment. The objective of the ALD step is to block the mesopores with a thin deposit, that is, one with small penetration depth and small thickness on the top surface of the substrate. Unlike typical ALD on nonporous substrates, where all available sites react per ALD cycle, thin deposit formation in a mesoporous substrate requires that only a small fraction of the available deposition sites (i.e., close to the substrate surface) is subjected to ALD. Consequently, reactant dosing and duration of pulses are important process variables which, together with diffusion and reaction kinetics determine the deposit structure. Quantitative understanding of the interplay of these variables and phenomena can enable the rational design of ALD within mesoporous substrates. Here, we extend our earlier modeling effort considering the coexistence of ALD both inside the pores and on the external surface of the substrate. Finite-volume based models were developed and validated to simulate the two distinct modes of deposition cycle by cycle. The total mass uptake of the substrate with ALD cycles can be predicted using the combined surface deposition and pore reaction–diffusion models as affirmed by in situ quartz crystal microbalance experimental data. The ALD reactor model combined with the deposition model can accurately capture the number of ALD cycles needed to block the pores of the substrate. Based on the model, we designed a modified ALD process and examined the performance of the corresponding LIPS membranes. Furthermore, the present modeling work provides a new understanding of the deposit formation via ALD within mesoporous substrates for a variety of membrane applications.

atomic layer deposition↗