SEARCH · Search NASA

Results for “electrostatic interaction”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,063 records · Page 59

All sources NASA NTRS DOE OSTI

DOE OSTI2019

Dynamic behavior of nanoscale liquids in graphene liquid cells revealed by in situ transmission electron microscopy

Recent advances in graphene liquid cells for in situ transmission electron microscopy (TEM) have opened many opportunities for the study of materials transformations and chemical reactions in liquids with high spatial resolution. However, the behavior of thin liquids encapsulated in a graphene liquid cell has not been fully understood. Here, we report real time TEM imaging of the nanoscale dynamic behavior of liquids in graphene nanocapillaries. Our observations reveal that the interfaces between liquid and gas bubble can fluctuate, leading to the generation of liquid nanodroplets near the interfaces. Liquid nanodroplets often show irregular shape with dynamic changes of their configuration under the electron beam. We consider that the dynamic motion of liquid-gas interfaces might be introduced by the electrostatic energy from transiently charged interfaces. We find that improving the wettability of graphene liquid cells by ultraviolet-ozone treatment can significantly modify the dynamic motion of the encapsulated liquids. Our study provides valuable information of the interactions between liquid and graphene under the electron beam, and it also offers key insights on the nanoscale fluid dynamics in confined spaces.

36 MATERIALS SCIENCE↗

DOE OSTI2021

Self-sorting in supramolecular assemblies

Supramolecular self-assembly enables living organisms to form highly functional hierarchical structures with individual components self-organized across multiple length scales. This has inspired work on multicomponent supramolecular materials to understand factors behind co-assembly versus self-sorting of molecules. We report here on a supramolecular system comprised of negatively charged peptide amphiphile (PA) molecules, in which only a tiny fraction of the molecules (0.7 mol%) were covalently conjugated to one of two different fluorophores, half to fluorescein isothiocyanate (FTIC) and the other half to tetramethylrhodamine (TAMRA). Confocal microscopy of the system revealed self-sorting of the two different fluorescent PA molecules, where TAMRA PA is concentrated in micron-scale domains while FITC PA remains dispersed throughout the sample. From Förster resonance energy transfer and fluorescence recovery experiments, we conclude that conjugation of the negatively charged FITC to PA significantly disrupts its co-assembly with the 99.3 mol% of unlabeled molecules, which are responsible for formation of micron-scale domains. Conversely, conjugation of the zwitterionic TAMRA causes no such disruption. Interestingly, this dissimilar behavior between FITC and TAMRA PA causes them to self-sort at large length scales in the supramolecular system, mediated not by specific interactions among the individual fluorophores but instead by their different propensities to co-assemble with the majority component. We also found that greater ionic strength in the aqueous environment of the system promotes mixing by lowering the electrostatic barriers involved in self-sorting. Furthermore, our results demonstrate great thermodynamic subtlety in the driving forces that mediate self-sorting versus co-assembly in supramolecular peptide assemblies.

36 MATERIALS SCIENCE↗

DOE OSTI2023

Anomalous cross-field transport in a Hall thruster inferred from direct measurement of instability growth rates

The contribution of the electron drift instability to anomalous electron transport is experimentally assessed in a Hall effect discharge. The transport is represented by an anomalous collision frequency, which is related through quasilinear theory to the energy and growth rate of the instability. The wave energy is measured directly with ion saturation probes, while estimates of the growth rate are employed based on both linearized theory and direct measurement. The latter measurement is performed with a bispectral analysis method. The wave-driven collision frequency is compared to measurements of the actual collision frequency inferred from a method based on laser- induced fluorescence. It is found that estimates for transport using linearized theory for the growth differ by over an order of magnitude from the actual anomalous collision frequency in the plasma. The wave-driven anomalous collision frequency with measured growth, however, is shown to agree with the electron collision frequency in magnitude and capture aspects of the trends in spatial variation. This result demonstrates experimentally that wave-driven effects ultimately can explain the observed cross-field transport in these devices. As a result, the implications of this finding are discussed in the context of the key lengthscales that drive the transport as well as the implications identifying reduced fidelity models that could be used to predict anomalous collision frequency.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

NASA NTRS2020

Methods of Measuring Secondary Electron Emission and Analysis of Spacecraft Charging Simulation

The scope of the internship project was to help the Electrostatics and Surface Physics Laboratory (ESPL) at KSC gain an understanding as to what parameters related to secondary electron emission (SEE), and electrostatic discharge (ESD) could be measured within its own facilities. As well as assistance in developing a plan for the ESPL to acquire the capabilities to measure other necessary parameters, to reduce the reliance on measurement data from facilities outside of the agency. The intern also worked closely with agency customers of the Launch Services Program (LSP) in expanding the MAPTIS database to incorporate various electrostatic and physical properties of materials used in the Gateway Program. This involved cross-center collaboration with industry and NASA contracted academia members in order to fill in the gaps of data that is missing from the database. Overall, the internship provided assistance in coordinating the approval for more materials to be added to the MAPTIS database, and continuing to assist the team at the ESPL in their consulting work for the agency through the use of various spacecraft charging and ESD simulation programs (i.e., NASCAP, NUMIT2.1). As well as assisting in the CAD design and implementation of an electrodynamic dust shield (EDS) for use in upcoming spaceflight missions. This was all done with the aim of helping the ESPL demonstrate its capabilities for the agency, and to continue expanding and localizing measurement techniques at KSC to help streamline obtaining the information NASA needs to ensure safety in current and future missions.

dust↗

DOE OSTI2020

Gyrokinetic understanding of the edge pedestal transport driven by resonant magnetic perturbations in a realistic divertor geometry

Self-consistent simulations of neoclassical and electrostatic turbulent transport in a DIII-D H-mode edge plasma under resonant magnetic perturbations (RMPs) have been performed using the global total-f gyrokinetic particle-in-cell code x-point gyrokinetic code (XGC), in order to study density pump-out and electron heat confinement. The RMP field is imported from the extended magneto-hydrodynamics code M3D-C1, taking into account the linear two-fluid plasma response. With both neoclassical and turbulence physics considered together, the XGC simulation reproduces two key features of experimentally observed edge transport under RMPs: increased radial particle transport in the pedestal region that is sufficient to account for the experimental pump-out rate and suppression of the electron heat flux in the steepest part of the edge pedestal. In the simulation, the density fluctuation amplitude of modes moving in the electron diamagnetic direction increases due to interaction with RMPs in the pedestal shoulder and outward, while the electron temperature fluctuation amplitude decreases.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

NASA NTRS1980

Electron energy distributions measured during electron beam/plasma interactions

In the large vacuum facility at the NASA-Johnson Space Center an electron beam was projected 20 m parallel to B from a gun with variable accelerating potential (1.0 to 2.5 kV) to an aluminum target. The ionospheric neutral pressure and field were approximated. Beam electron energy distributions were measured directly using an electrostatic deflection analyzer and indirectly with a detector that responded to the X-rays produced by electron impact on the target. At low currents the distribution is sharply peaked at the acceleration potential. At high currents a beam plasma discharge occurs and electrons are redistributed in energy so that the former energy peak broadens to 10-15 percent FWHM with a strongly enhanced low energy tail. At the 10% of maximum point the energy spectrum ranges from less than 1/2 to 1.2 times the gun energy. The effect is qualitatively the same at all pitch angles and locations sampled.

Jost, R. J.↗

DOE OSTI2020

Ambient pressure x-ray photoelectron spectroscopy study of water formation and adsorption under two-dimensional silica and aluminosilicate layers on Pd(111)

Ambient pressure x-ray photoelectron spectroscopy (AP-XPS) supported by density functional theory (DFT) calculations was used to characterize the interaction of water with two-dimensional (2D) silica and aluminosilicate bilayers on Pd(111). Starting with oxygen adsorbed at the SiO2/Pd interface, exposure to water caused the SiO 2 -derived XPS peaks to shift to higher binding energy and the removal of an O 1s feature associated with interfacial adsorbed oxygen. These observations were attributed to the formation of a mixed water–hydroxyl interface, which eliminates the interfacial dipolar layer, and its associated electrostatic potential, created by adsorbed oxygen. Interfacial oxygen also reacted with H 2 to produce adsorbed water which also caused an upward binding energy shift of the SiO 2 peaks. Spectra recorded under 0.5 Torr water revealed additional water adsorption and a further shift of the overlayer peaks to higher binding energy. Incorporating Al into the 2D material caused the bilayer peaks to shift to lower binding energy which could be explained by electron donation from the metal to the bilayer. Although the stronger interaction between the bilayer and Pd substrate should restrict interfacial adsorption and reaction, similar trends were observed for water and hydrogen exposure to interfacial adsorbed oxygen. Less water adsorption was observed at the aluminosilicate interface which is a consequence of Al strengthening the bond to the metal substrate. The results reveal how the sensitivity of XPS to interfacial dipoles can be exploited to distinguish reactions taking place in confined spaces under 2D layers and how tuning the composition of the 2D layer can impact such reactions.

Density functional theory↗

DOE OSTI2019

Ionic current in nanochannels grafted with pH-responsive polyelectrolyte brushes modeled using augmented strong stretching theory

Here, we provide a theory to quantify the ionic current (i ion ) in nanochannels grafted with pH-responsive polyelectrolyte (PE) brushes. We consider the PE brushes to be modelled by our recently proposed augmented strong stretching theory (SST) model that improves the existing SST models by incorporating the effects of excluded volume interactions and an extended mass action law. Use of such augmented SST for this problem implies that this is the first study on computing i ion in PE-brush-grafted nanochannels accounting for the appropriate coupled con guration-electrostatic description of the PE brushes. i ion is obtained as functions of PE brush grafting density, medium pH and salt concentration (c ∞ ), and the density of polyelectrolyte chargeable sites (PECS). For large c ∞ , i ion increases linearly with c ∞ (as for such c ∞ , i ion becomes independent of the PE charge and is dominated by the bulk mobility and number density of the electrolyte ions), while iion is independent of c ∞ at small c ∞ (where the EDL electrostatics and the total number of ions in the system is dominated by the hydrogen ions). We further witness an enhancement of i ion for smaller pH and larger grafting density at low and moderate c ∞ , while there is little to no effect of the PECS density on the ionic current except for weakly grafted brushes at low c ∞ . We believe that this study will serve as a theoretical foundation for a large number of applications that are based on the brush-induced modification of the ionic current in a nanochannel.

42 ENGINEERING↗

DOE OSTI2019

Self-assembly of highly asymmetric, poly(ionic liquid)-rich diblock copolymers and the effects of simple structural modification on phase behaviour

A series of thermally processable, phase-separating diblock copolymers made via sequential ATRP of styrene and styrenic ionic liquid (IL) monomers with various alkyl imidazolium substituents were synthesized to cover a wide range of volume fractions, most notably those on the IL-rich side of the phase diagram. Small-angle X-ray scattering (SAXS) analysis was used to confirm melt-state (and glassy state) phase behavior in which all four classic equilibrium diblock copolymer morphologies – body-centered cubic spheres (S BCC ), hexagonally packed cylinders (Hex), lamellae (Lam), and notably, bicontinuous gyroid (Gyr) – were observed. These PS-PIL diblock copolymers were found to have a high degree of conformational asymmetry and/or electrostatic cohesion within the PIL block, highlighted by the shift of the Lam phase window with boundaries falling between f PIL = 0.31 and 0.55. Finally, variation of the alkyl group appeared to influence the strength of the Flory-like interaction parameter of the system, χ PS/PIL , such that simple substitution of methyl by n-butyl on the imidazolium IL substituent resulted in the emergence of the (notoriously segregation-sensitive) Gyr phase, superseding the persistent coexistence of Lam and Hex in the methyl-substituted imidazolium diblock copolymer phase diagram.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1975

Theory of type 3b solar radio bursts

During the initial space-time evolution of an electron beam injected into the corona, the strong beam-plasma interaction occurs at the head of the beam, leading to the amplification of a quasi-monochromatic large-amplitude plasma wave that stabilizes by trapping the beam particles. Oscillation of the trapped particles in the wave troughs amplifies sideband electrostatic waves. The sidebands and the main wave subsequently decay to observable transverse electromagnetic waves through the parametric decay instability. This process gives rise to the elementary striation bursts. Owing to velocity dispersion in the beam and the density gradient of the corona, the entire process may repeat at a finite number of discrete plasma levels, producing chains of elementary bursts. All the properties of the type IIIb bursts are accounted for in the context of the theory.

Smith, R. A.↗

NASA NTRS1976

Theory of type IIIb solar radio bursts

Smith, R. A.↗

NASA NTRS1979

Dust in cosmic plasma environments

Cosmic dust is invariably immersed in a plasma and a radiative environment. Consequently, it is charged to some electrostatic potential which depends on the properties of the environment as well as the nature of the dust. This charging affects the physical and dynamical properties of the dust. In this paper the basic aspects of this dust-plasma interaction in several cosmic environments - including planetary magnetospheres, the heliosphere and the interstellar medium - are discussed. The physical and dynamical consequences of the interaction, as well as the pertinent observational evidence, are reviewed. Finally, the importance of the surface charge during the condensation process in plasma environments is stressed.

Mendis, D. A.↗

NASA NTRS2003

Polar Plasma Wave Investigation Data Analysis in the Extended Mission

The low latitude boundary layer (LLBL) is a region where solar wind momentum and energy is transferred to the magnetosphere. Enhanced "broadband" electric plasma waves from less than 5 Hz to l0(exp 5) Hz and magnetic waves from less than 5 Hz to the electron cyclotron frequency are characteristic of the LLBL. Analyses of Polar plasma waves show that these "broadband" waves are actually discrete electrostatic and electromagnetic modes as well as solitary bipolar pulses (electron holes). It is noted that all wave modes can be generated by approx. 100 eV to approx. 10 keV auroral electrons and protons. We will review wave-particle interactions, with focus on cross- diffusion rates and the contributions of such interactions toward the formation of the boundary layer. In summary, we will present a scenario where the global solar wind-magnetosphere interaction is responsible for the auroral zone particle beams, and hence for the generation of plasma waves and the formation of the boundary layer. It is speculated that all planetary magnetospheres will have boundary layers and they will be characterized by similar currents and plasma wave modes.

Gurnett, Donald A.↗

NASA NTRS2004

Polar Plasma Wave Investigation Data Analysis in the Extended Mission

The low latitude boundary layer (LLBL) is a region where solar wind momentum and energy is transferred to the magnetosphere. Enhanced "broadband" electric plasma waves from less than 5 Hz to 10(exp 5) Hz and magnetic waves from less than 5 Hz to the electron cyclotron frequency are characteristic of the LLBL. Analyses of Polar plasma waves show that these "broadband" waves are actually discrete electrostatic and electromagnetic modes as well as solitary bipolar pulses (electron holes). It is noted that all wave modes can be generated by approx. 100 eV to approx. 10 keV auroral electrons and protons. We will review wave-particle interactions, with focus on cross-diffusion rates and the contributions of such interactions toward the formation of the boundary layer. In summary, we will present a scenario where the global solar wind-magnetosphere interaction is responsible for the auroral zone particle beams, and hence for the generation of plasma waves and the formation of the boundary layer. It is speculated that all planetary magnetospheres will have boundary layers and they will be characterized by similar currents and plasma wave modes.

Gurnett, Donald A.↗

DOE OSTI2022

Combined effects of emitter–emitter and emitter–plasmonic surface separations dictate photoluminescence enhancement in a plasmonic field

The brightness of an emitter can be enhanced by metal-enhanced fluorescence, wherein the excitonic dipole couples with the electromagnetic field of the surface plasmon. In this report, we experimentally map the landscape of photoluminescence enhancement (EF exp ) of emitters in a plasmonic field as a function of the emitter–emitter separation, s, and the emitter–plasmon distance, t. We use Au nanoparticles overcoated with inert spacers as plasmonic systems and CdSe/ZnS quantum dots (QDs) as an emitter bearing opposite surface charges. The t and s are varied by changing the spacer thickness and number density of QDs on the plasmonic surface, respectively. The electrostatic binding of emitters on the plasmonic surface and their number density are established by following the variation of zeta-potential. EF exp is high, when t is short and s is large; nevertheless, it decreases when the emitter–emitter interaction dominates due to plasmon assisted nonradiative processes. In the absence of a plasmonic field, the enhancement observed is attributed to environmental effects and is independent of s, confirming the role of the electric field. Indeed, the distance dependence of EF exp closely follows the decay of the plasmonic field upon dilution of the emitter concentration on nanoparticles’ surface (s = 18 nm). The QD–plasmon system is visualized in the framework of the Thomson problem, and classical electrodynamics calculations give the trends in t and s dependence of the photoluminescence. Being the first report on the simultaneous dependence of t and s on plasmon-enhanced photoluminescence, the results presented herein will open newer opportunities in the design of hybrid systems with a high brightness.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1987

Electromagnetic jets from compact objects

The possibility that at least some astrophysical jets are initially electromagnetic in origin is examined. Subsequent pick-up of ionization would convert such electromagnetic jets into hydrodynamic jets. In such a model, relativistic outflow is formed into highly collimated beams simply through the interaction with the surrounding medium. Forming jets under such general circumstances is encouraging in view of the range of scales that appear to be involved. The overall properties of such jets are largely determined by a single dimensionless parameter: the characteristic electrostatic potential drop rewritten as a particle Lorentz factor. Consequently, the determination of any one observable, such as the total power output, also determines the particle energy scale, the electromagnetic field strengths, etc.

Michel, F. Curtis↗

NASA NTRS2004

8th Spacecraft Charging Technology Conference

The 8th Spacecraft Charging Technology Conference was held in Huntsville, Alabama, October 20-24, 2003. Hosted by NASA s Space Environments and Effects (SEE) Program and co-sponsored by the Air Force Research Laboratory (AFRL) and the European Space Agency (ESA), the 2003 conference saw attendance from eleven countries with over 65 oral papers and 18 poster papers. Presentation topics highlighted the latest in spacecraft charging mitigation techniques and on-orbit investigations, including: Plasma Propulsion and Tethers; Ground Testing Techniques; Interactions of Spacecraft and Systems With the Natural and Induced Plasma Environment; Materials Characterizations; Models and Computer Simulations; Environment Specifications; Current Collection and Plasma Probes in Space Plasmas; On-Orbit Investigations. A round-table discussion of international standards regarding electrostatic discharge (ESD) testing was also held with the promise of continued discussions in the off years and an official continuation at the next conference.

Minor, J. L.↗

NASA NTRS2011

Solar Wind Access to Lunar Polar Craters: Feedback Between Surface Charging and Plasma Expansion

Determining the plasma environment within permanently shadowed lunar craters is critical to understanding local processes such as surface charging, electrostatic dust transport, volatile sequestration, and space weathering. In order to investigate the nature of this plasma environment, the first two-dimensional kinetic simulations of solar wind expansion into a lunar crater with a self-consistent plasma-surface interaction have been undertaken. The present results reveal how the plasma expansion into a crater couples with the electrically-charged lunar surface to produce a quasi-steady wake structure. In particular, there is a negative feedback between surface charging and ambipolar wake potential that allows an equilibrium to be achieved, with secondary electron emission strongly moderating the process. A range of secondary electron yields is explored, and two distinct limits are highlighted in which either surface charging or ambipoiar expansion is responsible for determining the overall wake structure.

Zimmerman, M. I.↗