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At least 1,063 records · Page 59

Microstructural Characteristics and Mechanical Properties in the Laser Beam Welded Joints of High-Strength Microalloyed Steel

The laser beam welded joints of the high-strength microalloyed steel consist of the base metal (BM), the partially transformed heat-affected zone I (PTHAZ-I), the partially transformed heat-affected zone II (PTHAZ-II), the fully transformed heat-affected zone (FTHAZ) and the fusion zone (FZ). The martensite/austenite (M/A) islands of the bainites in the PTHAZ-II are dense versus those in the PTHAZ-I, and the martensites exist in the FTHAZ and the FZ together with the bainites under the slow welding speed. The M/A islands of the bainites and/or the martensites in the PTHAZ become denser under the high welding speed, and the martensites in the FTHAZ and the FZ predominate. The low-angle boundary density and the high local misorientation proportion are used to identify the constituents roughly, consistent with the microstructural characteristics in the welded joints. The misorientation angle distributions are employed to evaluate the degree of the phase transformation, reflecting the change law of the degree of the phase transformation in the welded joints. The hardness and the tensile tests indicate that the HAZ and the FZ are stronger than the BM, dependent on the microstructures in the welded joints. The strengthening in the HAZ and the FZ is mainly attributed to the products of non-equilibrium phase transformation with the high dislocation density.

36 MATERIALS SCIENCE↗

Relationship Between Microstructure and Marine Corrosion Resistance of Martensitic Stainless Steels: A Multiscale Approach

The electrochemical properties of martensitic stainless steels may depend on complex aspects of their microstructure. Three alloys were considered in this study: X30Cr13 (AISI 420), a martensitic stainless steel with a low content of alloying elements; X17CrNi16-2 (AISI 431), chosen for its strong resistance to corrosion; and X5CrNiCu15-5 (AISI 630), chosen for its good mechanical resistance. Voltammetry tests have shown the influence of carbon and chromium content on corrosion resistance. Resistance to pitting appears equivalent for the both. However, heterogeneous corrosion, in relation to δ-ferrite precipitation and chromium carbides at the lath boundaries, appears in the case of X17CrNi16-2. Conversely, non-preferential corrosion occurs in the case of the X5CrNiCu15-5, and a superior passive film stability during immersion in artificial seawater. This counterbalance negative effect of the microstructure. Thus, it achieves an equivalent “macroscopically” corrosion behavior between the two steels.

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Effect of Cobalt Content on Thermal, Mechanical, and Microstructural Properties of Al{sub 0.4}FeCrNiCo{sub x} (x = 0, 0.25, 0.5, 1.0 mol) High-Entropy Alloys

Al{sub 0.4}FeCrNiCo{sub x} (x = 0, 0.25, 0.5, 1.0 mol) high-entropy alloys are developed by arc melting route to investigate the effect of cobalt content on thermal, mechanical, and microstructural properties. The phase, microstructure, and chemical composition are analyzed using x-ray diffraction, transmission electron microscope, and scanning electron microscope with attached energy-dispersive x-ray spectrometer. The obtained results have shown that the Al{sub 0.4}FeCrNiCo{sub x} (x = 0-0.5 mol) high-entropy alloys form a simple FCC + BCC-type solid solution and Al{sub 0.4}FeCrNiCo{sub x=1} HEA forms a single-phase FCC structure. The compressive yield strength, microhardness, and thermal conductivity are observed to decrease from 965.22 to 233.37 MPa, 253.6 to 155.6 HV, and from 4.87 to 2.674 W/mK, respectively, whereas the electrical resistivity is observed to increase from 150.30 to 273.74 µΩ-cm with the addition of cobalt from x = 0-1 mol. Differential scanning calorimetry analysis has indicated that the Al{sub 0.4}FeCrNiCo{sub x} (x = 0, 0.25, 0.5, 1.0 mol) high-entropy alloys are thermally stable up to 1000 °C.

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Deformation Behavior and Microstructure Evolution of Powder Metallurgy Ti6Al4V Alloy During Hot Compression

In order to determine appropriate workability parameters for cross-wedge rolling products of powder metallurgy (PM) Ti6Al4V alloys, thermal compression experiments were carried out within the temperature range of 850-1050 °C, the strain rate range of 0.1-10 s{sup −1}, and with a height decrease of 60%. The compression deformation behavior was investigated. A strain-compensated constitutive model was established based on the flow stress curves corrected by the friction, which can predict the flow behaviors under the entirety of the experimental deformation conditions. Moreover, the processing map was developed, and stable and unstable deformation regimes were established. The microstructure analysis illustrated that globularization and dynamic recrystallization were the main deformation mechanisms. The porosity of the compressed samples was greatly reduced and influenced by the temperature and strain rate. Considering the material flow stress, hot processing map, microstructure and porosity, the appropriate hot deformation parameters for PM Ti6Al4V alloy preforms are suggested.

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Effect of Anisotropy on Microstructures and Mechanical Properties of Rolled Ti/Al/Mg/Al/Ti Laminates

TA2/5052Al/AZ31/5052Al/TA2 five-ply laminates were fabricated by hot rolling, and the effect of anisotropy on their microstructures and mechanical properties was studied. After rolling, the Mg/Al and Al/Ti interfaces were both closely connected, but the interfacial shapes were totally different. For the Mg layer microstructures in the middle area, regardless of the direction, dynamic recrystallized (DRXed) grains appeared around the deformation bands. However, twins and a shear zone appeared in the RD sample; the twins decreased in the sample along the 45° angle, and no twins appeared in the TD sample. The Ti layer showed equiaxed grains in different directions, which were attributed to the ability of Ti alloy to anti-deform. The tensile testing results showed that the fracture of the Ti/Al/Mg/Al/Ti laminates can be divided into four stages. The laminate had an ultimate tensile strength of 434 MPa and excellent elongation along the rolling direction (RD), which were attributed to its DRXed grains and twins. In conclusion, the laminates had significant anisotropy due to the presence of Mg alloys.

36 MATERIALS SCIENCE↗

Investigation on Microstructure and Mechanical Properties of TA10–Q245R Composite Plate Formed by Explosive Welding

The titanium alloy TA10 and the carbon steel Q245R are welded by explosive welding, and post-weld heat treatment (PWHT) is carried out for the TA10–Q245R composite plate. Microstructure and mechanical properties of the composite plate are investigated both in as-welded (AW) condition and after PWHT, respectively. Results show that, in AW condition, the bonding interface of composite plate presents wavy morphology, and at both sides of the interface plastic deformation is generated to a certain degree. Near the interface interdiffusion zone of alloying elements exists, and no Fe-Ti intermetallic compound is produced at the interface. SEM images indicate that the tensile fracture of composite plate presents the characteristic of ductile fracture, and no defects such as gas pores or impurities are found on the surface of shear fracture. After PWHT, the interfacial microstructure of the composite plate is obviously changed. Compared with the mechanical properties of the composite plate in AW condition, both tensile strength and shear strength of the composite plate are decreased to a certain extent after PWHT. With various factors into consideration, the suitable heat treatment procedure of TA10–Q245R composite plate is determined as follows: 550 °C × 1.5 h.

36 MATERIALS SCIENCE↗

Microstructure Optimization and Cracking Control of Additive Manufactured Bainite Steel by Gas Metal Arc Welding Technology

In this work, bainite steel thin wall was prepared by additive manufacturing (AM) with an in situ isothermal transformation at 300 °C. The microstructures were analyzed by scanning electron microscopy (SEM), x-ray diffraction (XRD) and transmission electron microscopy (TEM). The mechanical properties of the AM samples were measured by microhardness testing and tensile testing. The results show that the bainite steel thin wall is free from cracks and each layer has a good bond with preceding one. The bainite steel thin wall displays consistent mechanical properties. The formation of the bainite microstructure improves the toughness of the thin wall and reduces the embrittlement caused by dendritic segregation.

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Evolution of the Microstructure and Hardness of Fe-8Cr-2.1Mo-Si-V Die Steel at Different Cooling Rates after Hot Deformation

In this study, the effect of microstructure evolution, especially that involving the proeutectoid carbides, on hardness distribution of ledeburite steel containing 8% chromium content was investigated at different cooling rates after hot deformation. The continuous cooling transformation was carried out using a fully automatic transformation measuring apparatus under cooling rates in the range of 0.03-80 °C/s. The transformation temperatures, Ac1, Ac3 and Ms, were measured by dilatometry. A nanoindentation test was employed to evaluate the mechanical properties of the cooled specimens. The evolution of microstructure indicated that the proportion trend of the precipitated carbides was dependent on the cooling rates. In addition, a mixture of pearlite and proeutectoid carbides was observed under slow cooling rates in the range of 0.03-0.2 °C/s, for which only a martensite transformation took place in austenite, and the proeutectoid carbides precipitated negligibly at cooling rates greater than or equal to 10 °C/s. The results also showed that the nanohardness significantly decreased and then slowly increased to a stable value with increasing cooling rates, which was similar to the content trend of the carbides that precipitated during the cooling process.

36 MATERIALS SCIENCE↗

Effect of Heat Treatment on Microstructure and Mechanical Properties of Extruded Mg-4Zn-1.5Al-2Sn Alloy

The microstructure and mechanical properties of extruded Mg-4Zn-1.5Al-2Sn (ZAT422) alloy under different heat treatments were investigated by optical microscopy, scanning electron microscopy, x-ray diffraction, transmission electron microscopy, micro-hardness tests, and tensile tests. The results show that the as-extruded and heat-treated ZAT422 alloys mainly consisted of α-Mg and Mg{sub 2}Sn, and no ternary phase was detected. After aging, the amount of secondary phase precipitates increased significantly and the mechanical properties were improved. Among all the heat treatments, T5 heat treatment at 150 °C for 25 h resulted in the best combination of strength and ductility for ZAT422 alloy. The ultimate tensile strength, yield strength, and elongation (ε{sub f}) were found to be 290, 182 MPa, and 20%, respectively. Based on microstructural characterization, the variations in mechanical properties of the alloy subjected to heat treatment were analyzed in detail.

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A Study on the Microstructures and Properties of Selective Laser Melted Babbitt Metals

Babbitt metal cubes were prepared by means of selected laser melting (SLM) process using Sn—11% Sb—6% Cu alloy powders; their microstructures were studied using optical microscope (OM), SEM, EDS, XRD and DSC; and their mechanical properties were tested using Vickers hardness and tensile methods. The results show that fully dense Babbitt metal components can be prepared by using appropriate SLM process parameters and an interlayer staggered laser scanning strategy. Anisotropy characteristics appear in both the microstructure and mechanical properties of SLM-Babbitt cubic specimens. The average hardness was in the range of 32.5 HV0.05 to 35.3 HV0.05. Both tensile strength and elongation were somewhat higher in a direction parallel to the laser scanning speed (Y axis) than in a direction perpendicular to the laser scanning speed (X axis). The strengthening mechanism is suggested to include solid solution strengthening of oversaturated Sb in the Sn matrix, as well as dispersion strengthening of finely dispersed SnSb and Cu{sub 6}Sn{sub 5} particles. The overgrown acicular Cu{sub 6}Sn{sub 5} phases at low laser scanning speeds and void formation at higher laser scanning speeds seriously deteriorate the mechanical properties of the SLM-Babbitt specimens.

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Impact of Cryogenic Treatment on Mechanical Behavior and Microstructure of Ti-6Al-4V ELI Biomaterial

Ti-6Al-4V with its ELI variant is a potential biomaterial for structural implants. However, its poor resistance to plastic shearing results in poor tribological properties that hinders its widespread use in biomedical implants. Cryogenic treatment being an established technique for improving wear resistance and other mechanical properties of ferrous materials is applied on Ti-6Al-4V ELI alloy. To ensure comprehensive investigations, the widely studied microstructures of Ti-6Al-4V ELI, i.e., lamellar, martensite, two variants of bimodal and mill annealed are considered in this work. Deep cryogenic treatment at the soaking temperature (− 196 °C) for 24 h soaking time followed by tempering has been applied. The impact of cryogenic treatment has been assessed in terms of changes in the mechanical behavior including wear resistance, hardness, tensile properties and impact strength. The alterations in mechanical behavior due to cryogenic treatment are correlated with microstructure evolution. Cryogenic treatment has caused significant improvement in mechanical behavior of Ti-6Al-4V ELI alloy.

36 MATERIALS SCIENCE↗

Comparative Corrosion Behavior of Five Different Microstructures of Rebar Steels in Simulated Concrete Pore Solution with and Without Chloride Addition

The present work discusses the effect of five different microstructures, coarse, fine and very fine ferrite–pearlite, martensite and tempered martensite, made by furnace cooling, air cooling, forced air-cooling, water quenching and tempering, respectively, of a rebar steel on its corrosion performance in freely aerated with and without chloride-contaminated simulated concrete pore solution using the dynamic polarization and electrochemical impedance spectroscopy. The corrosion performance of the steels with five different microstructures relates to the polarization resistance, protective ability of rusts and the extent of the galvanic attack. The corrosion rate of the steels has been found to be comparable in the simulated concrete pore (SCP) solution. However, in chloride-containing SCP solution, corrosion rate has been found to increase in the following sequence: forced air-cooled–air-cooled–quenched–furnace-cooled–tempered steels.

36 MATERIALS SCIENCE↗

Effect of Tungsten Inert Gas Arc Remelting on Microstructure and Wear Properties of Plasma-Sprayed NiCr-Cr{sub 3}C{sub 2} Coating

In this work, a NiCr-Cr{sub 3}C{sub 2} coating was prepared on an AISI 1045 steel substrate by plasma spraying and then remelted with the tungsten inert gas (TIG) arc method. The purpose was to study the effects of TIG remelting treatment on the microstructure, mechanical properties and wear properties of a plasma-sprayed NiCr-Cr{sub 3}C{sub 2} coating. The results show that after TIG remelting, the density of the coating increased, the internal porosity decreased from 8.1 to 0.2%, and the number of cracks and inclusions greatly reduced. The hardness of the coating also became uniform and increased from 1007 to 1141 HV{sub 0.1}, with an obvious increase of 13.3%, and the fracture toughness increased by 321.3%. The wear volume after TIG remelting at room temperature was reduced by 59.5%, and the wear pattern changed from brittle fracture and abrasive wear to abrasive wear and adhesive wear. The wear loss at 700 °C was also reduced by 43.6%, and the wear pattern was transformed from brittle fracture and fatigue wear caused by oxidation to oxidative wear and adhesive wear. Therefore, TIG remelting treatment can effectively improve the microstructure, mechanical properties and wear resistance of a plasma-sprayed NiCr-Cr{sub 3}C{sub 2} coating.

36 MATERIALS SCIENCE↗

Effects of Postweld Heat Treatment on Microstructure and Properties of Laser-Welded Ti-24Al-15Nb Alloy Joint

The microstructure evolution and mechanical properties of laser-welded joints of Ti-24Al-15Nb alloy under different postweld heat treatment (PWHT) conditions were systematically investigated. The results show that the microstructure is very sensitive to PWHT temperatures. The weld zone consists of B2 and O phases after PWHT. With the PWHT temperatures increasing from 850 to 1000 °C, the amount of O phase decreases gradually, while the grains of O precipitates become coarser. After PWHT, there are some thin acicular O precipitates in heat-affected zone (HAZ), and the decomposition of α{sub 2}-phase caused by niobium diffusion can be observed in the HAZ. The PWHT can significantly increase the microhardness of joints, resulting from O phase precipitation hardening effect. The tensile strength and elongation of joints can be remarkably improved after PWHT, which was closely related to the strengthening effect of O precipitates and slip transmission between O and B2 phases. In addition, the results indicate that the best mechanical properties can be achieved only when the number and size of O phase and B2 phase are the best match.

36 MATERIALS SCIENCE↗

Effect of Chromium Content on Microstructure, Hardness, and Wear Resistance of As-Cast Fe-Cr-B Alloy

The effects of chromium content on microstructure, hardness and wear resistance of as-cast Fe-xCr-1.0B (x = 0, 4, 8, 12, 16, 20) alloys were investigated by means of optical microscope (OM), scanning electron microscope (SEM), x-ray diffractometer (XRD), hardness tester and ring block wear tester. The results showed that the microstructures of chromium-free alloy were mainly composed of pearlite, ferrite, and eutectic borocarbides, and the hardness was very low, only 18.8 HRC. With the increase in chromium content, the matrix of as-cast Fe-Cr-B alloy gradually began to transform from pearlite and ferrite to lath martensite, and the type of borocarbides changed from Fe{sub 2}(B, C) to M{sub 2}(B, C), M{sub 7}(C, B){sub 3} and M{sub 23}(C, B){sub 6} (M = Fe, Cr). When the chromium content was 12 wt.%, the hardness of alloy reached the highest value of 61.1 HRC, and the wear resistance of alloy was the best. The results of worn surface analysis showed that the wear failure of as-cast Fe-Cr-B alloy was mainly caused by multiple plastic deformation and micro-cutting.

36 MATERIALS SCIENCE↗

On the Microstructure and Solidification Behavior of N-Bearing Ti-46Al-8Ta (at.%) Intermetallic Alloys

Ti-46Al-8Ta (at.%) intermetallic alloys exhibit acceptable strength at low and high temperatures with good oxidation resistance. Different alloying elements are usually added to TiAl-based alloys to develop required properties. In this work, effects of N addition up to 2 at.% on microstructural features and solidification behavior of the Ti-46Al-8Ta alloy is investigated. The achieved results showed that alloying with N causes dendrite refinement and reduction of the retained metastable B2 phase in the as-cast microstructure. The dendrite morphology is also changed from fourfold to fivefold and then sixfold symmetry by increasing N content. The effect of N on interlamellar spacing, amount of constituent phases, and lattice parameters was not uniform. Increasing N content resulted in an increase in both small punch maximum load and hardness up to 1.05 at.%, whereas further N alloying, despite increasing of hardness, led to a drop in the maximum load.

36 MATERIALS SCIENCE↗

Multiscale Modeling of Microstructural Evolution in Fused-Coating Additive Manufacturing

A quantitative phase field model with adaptive-computational-domain-expansion (ACDE) method was developed to simulate the microstructural evolution in fused-coating additive manufacturing process. A heat transfer and fluid flow model was established to investigate the solidification behavior of the molten pool in a single deposited layer. The solidification parameters such as temperature gradient and solidification rate were calculated from the macroscopic model and then fed into the phase field model to get the microstructure at different positions within a single deposited layer. Columnar dendrites were formed at the bottom of the deposited layer, and equiaxed dendrites appeared in the upper part of the layer. The ACDE method is used to improve the simulation efficiency. The metallographic experiments and energy-dispersive spectrometer analysis for composition were conducted on the fused-coating specimen, and the results were in good accordance with the simulations.

36 MATERIALS SCIENCE↗

Effect of Solutionizing Time on Improving the Microstructure and Mechanical Properties of Aged AZ80 Mg Alloy

The effects of solutionizing soak time and aging on the microstructure and mechanical properties of cast AZ80 Mg alloy were investigated. Optical microscopy, scanning electron microscopy and x-ray diffraction revealed the dissolution of β-Mg{sub 17}Al{sub 12} phase in the solution-treated samples which was later detected in the aged condition. Solution treatments at 420 °C for 4-16 h with water quenching followed by aging at 200 °C for 10 h were carried out, causing discontinuous precipitates to be formed with different precipitate morphologies at the various soak times. The discontinuous precipitates were observed to transform from the interdendritic segregation to parallel lamellae with increasing soak time to 8-10 h. As the soak time increased to 16 h, parallel lamellae transformed into tree-like precipitate morphology. The results showed significant changes in the interlamellar spacing at different soak times, and such precipitate morphology could influence the microstructure and mechanical properties after the aging process. A good combination of strength and ductility was obtained when the cast AZ80 Mg alloy was solution-treated at 420 °C for 10 h and aged at 200 °C for 10 h. Compared to the as-cast condition, a significant increase in ultimate tensile strength (50%), yield strength (47%) and elongation (43%) were observed.

36 MATERIALS SCIENCE↗